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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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The method for producing a heat resistant, semi-inorganic compound is discussed. Five examples in which various alcohols, phenols, and aromatic carbonic acids are used to test heat resistance and solubility are provided.
Maximum char yield was obtained with a copolymer containing 25% mol fraction DGEBE and 75% mol fraction DGEBA (Epon 828). To achieve the high values (above 40%), a large quantity of catalyst (trimethoxyboroxine) was necessary. Although a graphite laminate 1/8" thick was successfully fabricated, the limited life of the catalyzed epoxy copolymer system precludes commercial application. Char yields of 45% can be achieved with phenolic cured epoxy systems as indicated by data generated under NAS2-10207 contract. A graphite laminate using this type of resin system was fabricated for comparison purposes. The resultant laminate was easier to process and because the graphite prepreg is more stable, the fabrication process could readily be adapted to commercial applications.
The stagnation-point ablation rates of a graphite, a carbon-carbon composite, and four carbon-phenolic materials are measured in an arc-jet wind tunnel with a 50 percent hydrogen-50 percent helium mixture as the test gas. Flow environments are determined through measurements of static and impact pressures, heat-transfer rates to a calorimeter, and radiation spectra, and through numerical calculation of the flow through the wind tunnel, spectra, and heat-transfer rates. The environments so determined are: impact pressure approximately equal to 3 atm, Mach number approximately equal to 2.1, convective heat-transfer rate approximately equal to 14 kW/sq cm, and radiative heat-transfer rate approximately equal to 7 kW/sq cm in the absence of ablation. Ablation rates are determined from the measured rates of mass loss and recession of the ablation specimens. Compared with the predicted ablation rates obtained by running RASLE and CMA codes, the measured rates are higher by about 15 percent for all tested materials.
The process of ablation is calculated for the stagnation region of a flat disk in a radiation-dominated, massive-blowing environment produced in a ballistic range filled with argon. Flow environments are determined by solving the boundary-layer equations while radiative transfer is calculated through a line-by-line spectral computation. The resulting wall heat-transfer rates are coupled with an existing material's response code to determine surface recession and char thickness. The calculation is performed for six 5-cm-diam models made of carbon-phenolic and carbon-carbon composite launched in the Track-G facility at the Arnold Engineering Development Center. Significant surface recessions are predicted to occur for these models due mostly to radiative heating.
Alternative sandwich panel decorative films were investigated as replacements for the polyvinyl fluoride currently used in aircraft interiors. Candidate films were studied for flammability, smoke emission, toxic gas emission, flame spread, and suitability as a printing surface for the decorative acrylic ink system. Several of the candidate films tested were flame modified polyvinyl fluoride, polyvinylidene fluoride, polyimide, polyamide, polysulfone, polyphenylsulfone, polyethersulfone, polybenzimidazole, polycarbonate, polyparabanic acid, polyphosphazene, polyetheretherketon, and polyester. The films were evaluated as pure films only, films silk-screened with an acrylic ink, and films adhered to a phenolic fiberglass substrate. Films which exhibited the highest fire resistant properties included PEEK polyetheretherketon, Aramid polyamide, and ISO-BPE polyester. Previously announced in STAR as N83-22320
The extent of convective and radiative heating for a Saturn entry probe is investigated in the absence and presence of ablation mass injection. The flow in the shock layer is assumed to be axisymmetric, viscous and in local thermodynamic equilibrium. The importance of chemical nonequilibrium effects for both the radiative and convective nonblowing surface heating rates is demonstrated for prescribed entry conditions. Results indicate that the nonequilibrium chemistry can significantly influence the rate of radiative heating to the entry probes. With coupled carbon-phenolic ablation injection, the convective heating rates are reduced substantially. Turbulence has little effect on radiative heating but it increases the convective heating considerably.
This paper presents thermal protection system (TPS) requirements for a potential Titan aerocapture vehicle. Shock-layer solutions are obtained for a nominal trajectory through the current Titan model atmosphere. Fully laminar and fully turbulent solutions are presented along the blunted fore-cone in the windward symmetry plane of a bent-biconic vehicle. Using these solutions to define the aerothermodynamic environment, transient material-response solutions are obtained for a Galileo-type TPS with a carbon-phenolic ablator heat shield. Shock-layer results indicate that turbulent flow is the more realistic flow condition. They also show that the lengthy aerocapture heating pulse is dominated by convective heating. The TPS results show that the required insulation thickness is uniformly about 4 cm along the fore-cone because of the long heat-soak period. The total heat-shield thickness is 6.4 cm at the stagnation point, and 4.7 cm near the end of the fore-cone. These TPS requirements are greater than those presented in a previous Titan aerocapture study.
Unit cools to 4 K by adiabatic demagnetization. Two porous matrices of paramagnetic material gadolinium/gallium/garnet held in long piston called displacer, machined out of Micarta (phenol formaldehyde polymer). Holes in side of displacer allow heat-exchange fluid to flow to and through matrices within. Piston seals on displacer prevent substantial mixing of fluid in two loops. Magnetic refrigerator provides continuous rather than "one-shot" cooling.
The near-catastrophic erosion of the STS-8A solid rocket booster nozzle was the instigating factor in the recent, and on-going, intensive investigation of carbon/phenolic composite materials. Much of this effort has been focused on the effect of sodium contamination on the carbon fibers. It is known that sodium acts as a catalyst in the oxidation of the fibers at elevated temperatures. A study was undertaken to determine what changes were caused by variation in sodium content. Investigations were conducted in three areas: (1) phenolic resin; (2) carbon/phenolic prepreg; and (3) cured laminates. Due to the exploratory nature of the studies, a variety of tests in addition to those normally run in production facilities were considered. The experimental methodologies and results of these experiments are discussed, and recommendations for improving techniques and extending the research program are presented.
The pin retainer band is a 1-1/4 in. wide by about 1/32 in. thick steel band that is stretched over the pins circumferentially at the joints of the solid rocket booster (SRB) motor case segments. Its purpose is to hold the retaining pins in place during flight. Since the band is thin and is mounted stretched, or under tension, over the pins which are greased in place, it is necessary to protect it thermally. Three typical areas of the band location on the SRB motor case joints were chosen for verifying the cork thermal prection system (TPS) performance on the band: the joint in front of the attach ring, at the aft skirt joint in front of the kick ring and in an unperturbed area at the forward segments of the SRB motor cases. The kick ring area pin retainer band cork TPS passed the test requirements in the region where there are no phenolic splice caps. In the splice cap areas where the band TPS is closed out around the splice with K5NA, additional amounts of K5NA material is required to adequately protect the steel band. TPS requirements were easily met in the one location where the ends of the steel band are joined together after installation and tensioning. The attack ring area pin retainer band TPS did not quite pass the heat load requirements with the .375 in. thick cork TPS as used for the kick ring area band. It is recommended that the cork thickness here be increased to .50 in. The unperturbed area band TPS presented no problems.
Several 1/24-scale models of the Galileo Probe made of carbon-phenolic materials were flown in a ballistic range to test their ablation characteristics. Mostly radiative or all-convective heating environments were produced by using argon or air as the test gas, respectively, to simulate the Jovian entry heating environments. The experimental results were compared with the theoretical predictions made using the computer codes of radiating shock layer environment (RASLE) and charring materials ablation (CMA). The experimental data obtained in argon agreed approximately with the theoretical predictions. The data for air agreed approximately with the theory when turbulence and surface roughness effects were accounted for. The data imply that the Galileo Probe heat shield was adequately designed.
Window-belt panel for airplanes fire resistant and generates little smoke when exposed to flames. Panel incorporates fire-shield layer adding minimal weight but delays or prevents fire from burning through. Structural core of panel is Nomex or equivalent polyamide paper honeycomb. Fire shield, made of fluororubber sheet, incorporated in multiple-ply facing bonded to core. Outer layers of multiple-ply facing and back face of panel consist of biwoven carbon-cloth impregnated with phenolic resin.
Report discusses tests of commercial phenol/formaldehyde resins to establish relationships among composition before use, behavior during curing, and strength after curing. Resin used in carbon/carbon laminates. In curing process, two molecules of phenol joined together in sequence of reactions involving molecule of formaldehyde. Last step of sequence, molecule of water released. Sequence repeats until one of ingredients used up, leaving solidified thermoset plastic. Issues to be resolved: number and relative abundances of ingredients, presence of certain chemical groups, heat-producing ability of resin, and range of molecular weights present.
The synthesis of resins with terminal acetylene groups has provided a promising technology to yield high performance structural materials. Because these resins cure through an addition reaction, no volatile by-products are produced during the processing. The cured products have high thermal stability and good properties retention after exposure to humidity. Resins with a wide variety of different chemical structures between the terminal acetylene groups are synthesized and their mechanical properties studied. The ability of the acetylene cured polymers to give good mechanical properties is demonstrated by the resins with quinoxaline structures. Processibility of these resins can be manipulated by varying the chain length between the acetylene groups or by blending in different amounts of reactive deluents. Processing conditions similar to the state-of-the-art epoxy can be attained by using backbone structures like ether-sulfone or bis-phenol-A. The wide range of mechanical properties and processing conditions attainable by this class of resins should allow them to be used in a wide variety of applications.
Research on high temperature resin systems has intensified. In the Aerospace Industry, the motivation for this increased activity has been to replace heat resistant alloys of aluminum, stainless steel and titanium by lighter weight glass and carbon fiber reinforced composites. Applications for these structures include: (1) engine nacelles involving long time exposure (thousands of hours) to temperatures in the 150 to 300 C range, (2) supersonic military aircraft involving moderately long exposure (hundreds of hours) to temperatures of 150 to 200 C, and (3) missile applications involving only brief exposure (seconds or minutes) to temperatures up to 500 C and above. Because of fatigue considerations, whenever possible, it is preferable to bond rather than mechanically fasten composite structures. For this reason, the increased usage of high temperature resin matrix systems for composites has necessitated the devlopment of compatible and equally heat stable adhesive systems. The performance of high temperature epoxy, epoxy phenolic and condensation polyimide adhesives is reviewed. This is followed by a discussion of three recently developed types of adhesives: (1) condensation reaction polyimides having improved processing characteristics; (2) addition reaction polyimides; and (3) bismaleimides.
This paper describes the design and development of a Vuilleumier cycle cryocooler (VM cooler) operating below 8 K, for the application of small superconducting devices. Liquid nitrogen has been used as a heat sink of the hot displacer. The annular gap between the phenolic displacer and SUS 304 stainless cylinder has been used as a gap regenerator. In order to obtain the cooling temperature below 3 K, we designed a single stage VM cooler which is precooled to 10 K by another two stage VM cooler. The effect of the mean operating pressure, cycle speed and phase difference between the hot and cold displacer of each VM cooler will be also discussed, including the experimental results.
The state-of-the-art fabrication techniques for composite materials are such that stringent species-specific acceptance criteria must be generated to insure product reliability. Non-destructive evaluation techniques including computed tomography (CT), X-ray radiography (RT), and ultrasonic scanning (UT) are investigated and compared to determine their applicability and limitations to graphite epoxy, carbon-carbon, and carbon-phenolic materials. While the techniques appear complementary, CT is shown to provide significant, heretofore unattainable data. Finally, a correlation of NDE techniques to destructive analysis is presented.
Commercial and experimental fire retardants were screened as potential fire retardants for acrylic printing inks used on aircraft interior sandwich panels. The fire retardants are selected according to their physical properties and their thermostabilities. A criterion for selecting a more stable fire retardant is established. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) are used to determine thermostabilities. Results show that the fire retardant formulations are more thermally stable than the acrylic ink control. It is determined that an ink formulation containing a brominated phenol and carboxy-terminated butadiene acrylonitrile which has been modified with a brominated polymeric additive (BPA), yields the highest limiting oxygen index (LOI) of all the compounds tested. All of the fire-retardant formulations have a higher oxygen index than the baseline acrylic ink.