Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “phase pure”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 451 records · Page 25

Major episodes of geologic change - Correlations, time structure and possible causes

Published data sets of major geologic events of the past about 250 Myr (extinction events, sea-level lows, continental flood-basalt eruptions, mountain-building events, abrupt changes in sea-floor spreading, ocean-anoxic and blackshale events and the largest evaporite deposits) have been synthesized (with estimated errors). These events show evidence for a statistically significant periodic component with an underlying periodicity, formally equal to 26.6 Myr, and a recent maximum, close to the present time. The cycle may not be strictly periodic, but a periodicity of about 30 Myr is robust to probable errors in dating of the geologic events. The intervals of geologic change seem to involve jumps in sea-floor spreading associated with episodic continental rifting, volcanism, enhanced orogeny, global sea-level changes and fluctuations in climate. The period may represent a purely internal earth-pulsation, but evidence of planetesimal impacts at several extinction boundaries, and a possible underlying cycle of 28-36 Myr in crater ages, suggests that highly energetic impacts may be affecting global tectonics. A cyclic increase in the flux of planetesimals might result from the passage of the Solar System through the central plane of the Milky Way Galaxy - an event with a periodicity and mean phasing similar to that detected in the geologic changes.

Rampino, Michael R.↗

Thermal Analysis of Magnetically-Coupled Pump for Cryogenic Applications

Magnetically-coupled pump is under evaluation at Kennedy Space Center for possible cryogenic applications. A major concern is the impact of low temperature fluid flows on the pump performance. As a first step toward addressing this and related issues, a computational fluid dynamics and heat transfer tool has been adopted in a pump geometry. The computational tool includes (i) a commercial grid generator to handle multiple grid blocks and complicated geometric definitions, and (ii) an in-house computational fluid dynamics and heat transfer software developed in the Principal Investigator's group at the University of Florida. Both pure-conduction and combined convection-conduction computations have been conducted. A pure-conduction analysis gives insufficient information about the overall thermal distribution. Combined convection-conduction analysis indicates the significant influence of the coolant over the entire flow path. Since 2-D simulation is of limited help, future work on full 3-D modeling of the pump using multi-materials is needed. A comprehensive and accurate model can be developed to take into account the effect of multi-phase flow in the cooling flow loop, and the magnetic interactions.

Senocak, Inanc↗

The effect of Fresnel phase on scattering from a vegetation layer

Models for scattering from a vegetation layer treated as a collection of discrete scatterers usually assume far field interaction among scatterers. In a real vegetation medium such as a deciduous forest it is not always true that each leaf is in the far field of the others. This paper examines the additional effect when scatterers are permitted to be in the Fresnel zone. It is found that this in general causes the backscattering coefficient to be higher and also to have a larger rate of increase with frequency than the case of purely far field interaction.

Lee, K. K.↗

The effect of solid phase reactions on the ballistic properties of propellants

The combustion of NH4ClO4 composite propellants has been studied between 15 and 3000 psi. The emphasis in the program has been on determining the mechanisms by which the fuel components influence the burning rate of the composites. In order to have flexibility in the choice and concentration of the fuel component all combustion experiments were performed with pressed power strands. The fuels studied included those which affected the combustion mechanism of the composite primarily through their effect on: (1) the oxidizer decomposition mechanism and (2) the composite surface temperature. The combustion of pure and doped NH4ClO4 was studied using both pressed powder strands and pressed end burning motor grains. The experimental approach has been essentially a chemical one with emphasis on perturbing those reactions which occur on or immediately adjacent to the surface (zone of influence) of the composite.

Schmidt, W. G.↗

Interstellar grain mantles

Interstellar molecular grain mantles are an important component of the interstellar dust inside dense molecular clouds as evidenced by the detection of absorption bands at 2.97, 3.08, 4.61, 6.0 and 6.8 microns. Mantles may also be the precursors of more complex grain mantles in the diffuse interstellar medium. The molecular composition of these icy grain mantles were calculated employing gas phase as well as grain surface reactions. The calculated mixtures consist mainly of the molecules H2O, H2CO, N2, CO, O2, H2O2, NH2, and their deuterated counterparts in varying ratios. The exact compositions depend strongly on the physical conditions in the gas phase. The absorption spectra of H2O with other molecules was studied in the laboratory. Optical constants were determined for a few selected mixtures. Extinction and polarization cross sections across the 3 micron ice band were calculated. A comparison with the observations towards BN shows that the low frequency wing observed on this feature is due to absorption by a mixture of H2O and other molecules rather than scattering by large, pure H2O ice grains.

Bregman, J.↗

Cosmic curvature and condensation

It is shown that the universe may consist of a patchwork of domains with different Riemann curvature constants k = 0, +/-1. Features of a phase transition in which flat space breaks up in a transition 2k0 - k(-) + k(+) with initial scale factors R(-) = R(+) are postulated and explored. It is shown that such a transition is energetically permitted, has the equivalent of a Curie temperature, and can lead in a natural way to the formation of voids and galaxies. It is predicted that, if the ambient universe on average is well fitted by a purely k(-) space, with only occasional domains of k(+) containing galaxies, a density parameter of (A(z sub c + 1)) super -1 should be expected, where z sub c represents the redshift of the earliest objects to have condensed, and A takes on values ranging from about 5 to 3. Present observations of quasars would suggest a density of about 0.03 or 0.05, respectively, but it could be lower if earlier condensation took place.

Harwit, Martin↗

A new test method for the assessment of the arc tracking properties of wire insulation in air, oxygen enriched atmospheres and vacuum

Development of a new test method suitable for the assessment of the resistance of aerospace cables to arc tracking for different specific environmental and network conditions of spacecraft is given in view-graph format. The equipment can be easily adapted for tests at different realistic electrical network conditions incorporating circuit protection and the test system works equally well whatever the test atmosphere. Test results confirm that pure Kapton insulated wire has bad arcing characteristics and ETFE insulated wire is considerably better in air. For certain wires, arc tracking effects are increased at higher oxygen concentrations and significantly increased under vacuum. All tests on different cable insulation materials and in different environments, including enriched oxygen atmospheres, resulted in a more or less rapid extinguishing of all high temperature effects at the beginning of the post-test phase. In no case was a self-maintained fire initiated by the arc.

Koenig, Dieter↗

Recent Advancements in the PATO Material Response Code

Introduction: Predicting the complicated multiphysics phenomena during atmospheric entry requires high-fidelity modeling tools to refine estimates of mission risks during entry. To this end, new capabilities are being added to the Porous-material Analysis Toolbox based on OpenFOAM (PATO). PATO is an open-source software for Computational Material Response (CMR) of reactive porous materials submitted to high-temperature environments. The objective of this work is to highlight current efforts to add to and improve upon the modeling capabilities of PATO. These include efforts to loosely couple PATO with other discipline specialized codes including hypersonic Computational Fluid Dynamics (CFD), to assess the interaction effects between pyrolysis gas blowing and the boundary layer, and Computational Solid Mechanics (CSM), to address modeling of mechanical erosion. Other refinements include surface phenomena modeling capabilities to address the effects of silicone-based coatings applied to the TPS during flight preparation, and a unified multiphase solver for a mixed porous-material and plain-fluid domain. Coupling CMR with CFD (CMR/CFD): A loose coupling between PATO and the Data Parallel Line Relaxation (DPLR) CFD code has been achieved by making use of a blowing boundary condition at the heatshield surface available in DPLR. Starting with heat flux estimates with no pyrolysis gas blowing at the surface, blowing gases are computed by the CMR and passed to the CFD such that aerothermal properties of the environment can be recomputed for a new CMR computation. This leads to an iterative process which is supplemented with an estimate of the radiative heat flux using the Nonequilibrium air radiation (NEQAIR) program. The entire iterative process is illustrated in Figure 1. This coupling strategy has been utilized in computing the MSL material response. The goal is to compare the coupled CMR/CFD results with material response results obtained using traditional blowing corrections. Coupling CMS with CMR: A mechanical erosion model is currently being implemented in PATO to account for the additional mass removal induced by high shear conditions. The modeling process at each timestep consists of updating the mechanical properties as a function of temperature and computing the stress tensor and displacement fields of the material. Then, a failure criteria model determines the regions in which the stress exceeds the ultimate strength values resulting in mesh movement to account for mass removal. This model allows the material response simulation to compute the recession due to both oxidation and shear-induced erosion. The model is demonstrated by computing material response of sphere-cone arc jet samples. Surface Modeling Capabilities: NuSil, a silicone-based coating, was sprayed onto the MSL and Mars 2020 heatshields to mitigate shedding of phenolic dust. To better understand the effects of the NuSil coating on the material response, a novel model has been implemented in PATO. In this model, the equilibrium of the charred NuSil surface is modeled as pure silica, and a constant offset, inspired by the classical spallation model, is added to the the char blowing rate and wall enthalpy to reproduce HyMETS experimental results. The model has also been used to estimate the 3D material response of the MSL heatshield. Unified Solver: In addition to the iterative loose coupling approach mentioned above, a multiphase unified solver is being developed to couple the environment (plain-fluid phase) and the porous-material phase. The solver is based on the volume averaged conservation of mass, momentum, and energy for the macroscale with closure models which include microscale effects through effective physicochemical properties. The unified solver has been used to compute flow through a porous plug and solve the Beavers and Joseph problem. Since the strong coupling between phases is inherent to this solver, modeling assumptions present in other coupling methods of material response are mitigated. This strategy also makes it feasible to capture the competition between surface and volume ablation in the same computational domain, which is usually not possible with other coupling approaches.

Material Response↗

Recent Trends in the Analysis of Quasioptical Systems

The recent trend in microwave instruments is the use of multiple millimeter and submillimeter wavelength bands. These systems are typically analyzed by using physical optics, Gaussian beams or ray tracing techniques. Physical optics offers high accuracy at the expense of computation time. This trade-off becomes particularly apparent in the analysis of multiple reflector antennas, such as beam waveguide antennas, where physical optics is used to compute the current on each reflector from the current on the previous reflector. At the other end of the spectrum is ray tracing approaches that ignore diffraction effects entirely. These methods are fast but sacrifice the ability to predict some effects accurately. An intermediate approach is to use an appropriate set of expansion functions to model the field between the reflectors. If the set is chosen wisely only a few coefficients need to be determined from each reflector current. The field is then computed at the next reflector through the use of the expansion functions and their coefficients rather than by using the previous reflector current. For a beam waveguide system with no enclosing tubes an excellent set of expansion functions is the Gaussian beam mode set. In many cases a preliminary design which includes the effects on diffraction may be obtained by considering only the fundamental mode and a thin lens model for the reflectors. Higher-order modes are included to model the effects of the curved reflector, which include asymmetric distortion of the beam, cross polarization, and beam truncation. This paper describes a computer code implementing higher-order Gaussian beam scattering by multiple reflector systems. There are four essential steps in the algorithm. (1) Compute the current on the first reflector using physical optics using either a feed model or by an incident set of Gaussian beam modes. (2) Find the direction of propagation for the reflected Gaussian beam-set using ray tracing. (3) Determine the waist size and location for the output beam set by examining the amplitude and phase distribution of the current on the reflector. (4) Compute the amplitudes of the individual modes in the output mode set. These steps are then repeated for each addition reflector in the chain. In each of these cases the previous Gaussian beam set provides the input field for the current calculation. Details of the four steps discussed above will be discussed. Examples will compare results from the Gaussian beam approach to pure physical optics, illustrating both its merits and limitations. Hybrid approaches capable of eliminating some of the limitations will also be discussed.

Hoppe, D. J.↗

Recent Advancements in the PATO Material Response Code

Introduction: Predicting the complicated multiphysics phenomena during atmospheric entry requires high-fidelity modeling tools to refine estimates of mission risks during entry. To this end, new capabilities are being added to the Porous-material Analysis Toolbox based on OpenFOAM (PATO) [1,2,3]. PATO is an open-source software for Computational Material Response (CMR) of reactive porous materials submitted to high-temperature environments. The objective of this work is to highlight current efforts to add to and improve upon the modeling capabilities of PATO. These include efforts to loosely couple PATO with other discipline specialized codes including hypersonic Computational Fluid Dynamics (CFD), to assess the interaction effects between pyrolysis gas blowing and the boundary layer, and Computational Solid Mechanics (CSM), to address modeling of mechanical erosion. Other refinements include surface phenomena modeling capabilities to address the effects of silicone-based coatings applied to the TPS during flight preparation, and a unified multiphase solver for a mixed porous-material and plain-fluid domain. Coupling CMR with CFD (CMR/CFD): A loose coupling between PATO and the Data Parallel Line Relaxation (DPLR) [4] CFD code has been achieved by making use of a blowing boundary condition at the heatshield surface available in DPLR. Starting with heat flux estimates with no pyrolysis gas blowing at the surface, blowing gases are computed by the CMR and passed to the CFD such that aerothermal properties of the environment can be recomputed for a new CMR computation. This leads to an iterative process which is supplemented with an estimate of the radiative heat flux using the Nonequilibrium air radiation (NEQAIR) [5] program. The entire iterative process is illustrated in Figure 1. This coupling strategy has been utilized in computing the MSL material response. The goal is to compare the coupled CMR/CFD results with material response results obtained using traditional blowing corrections. Coupling CMS with CMR: A mechanical erosion model is currently being implemented in PATO to account for the additional mass removal induced by high shear conditions. The modeling process at each timestep consists of updating the mechanical properties as a function of temperature and computing the stress tensor and displacement fields of the material. Then, a failure criteria model determines the regions in which the stress exceeds the ultimate strength values resulting in mesh movement to account for mass removal. This model allows the material response simulation to compute the recession due to both oxidation and shear-induced erosion. The model is demonstrated by computing material response of sphere-cone arc jet samples. Surface Modeling Capabilities: NuSil, a silicone-based coating, was sprayed onto the MSL and Mars 2020 heatshields to mitigate shedding of phenolic dust. To better understand the effects of the NuSil coating on the material response, a novel model has been implemented in PATO. In this model, the equilibrium of the charred NuSil surface is modeled as pure silica, and a constant offset, inspired by the classical spallation model, is added to the the char blowing rate and wall enthalpy to reproduce HyMETS experimental results. The model has also been used to estimate the 3D material response of the MSL heatshield [6]. Unified Solver: In addition to the iterative loose coupling approach mentioned above, a multiphase unified solver is being developed to couple the environment (plain-fluid phase) and the porous-material phase. The solver is based on the volume averaged conservation of mass, momentum, and energy for the macroscale with closure models which include microscale effects through effective physicochemical properties. The unified solver has been used to compute flow through a porous plug and solve the Beavers and Joseph problem [7]. Since the strong coupling between phases is inherent to this solver, modeling assumptions present in other coupling methods of material response are mitigated. This strategy also makes it feasible to capture the competition between surface and volume ablation in the same computational domain, which is usually not possible with other coupling approaches.

Thermal Protection Systems↗

Electrical conductivity and phase diagram of binary alloys. 21: The system palladium-chromium

Pd-Cr alloys were investigated by thermal analysis, hardness measurements, X-ray analysis, microscopic examination of etched pieces, and temperature-resistance curves of the solid alloys. Only one compound, Pd2Cr3, m, 1389 deg, is formed. It possesses a cubic face centered lattice and forms with excess Pd a series of solid solutions with a minimum m.p. at 45 atoms% Pd. Hardness maximum appears at the Pd2Cr3 point. Pd2Cr3 forms no solid solutions with Cr but eutectic point appears at 25 atoms% Pd, m. 1320 deg. The sp. resistance of pure Cr in an atom of H, indicates no allotropic forms. Cr2O3 is solid in molten Cr. Pure Cr melts at 1890 plus or minus 10 deg but Cr contg. Cr2O3 starts to melt at 1770 to 1790 deg.

Grube, G.↗

Effect of magnesium oxide content on oxidation behavior of some superalloy-base cermets

The effect of increasing magnesium oxide (MgO) content on the cyclic oxidation resistance of hot-pressed cermets of MgO in NiCrAlY, MgO in Hoskins-875, MgO in Inconel-702, and MgO in Hastelloy-X was investigated. The cermets with magnesium oxide levels of 5, 10, 20, and 40 vol percent were examined. The cyclic oxidation behavior of these cermets at 1100 and 1200 C in still air was determined by a thermogravimetric method supplemented by X-ray diffraction analysis and light and electron microscopy. In all instances, MgO prevented grain growth in the metallic phase. No evidence of oxidation along interphase boundaries was detected. Cermets of MgO in NiCrAlY and MgO in Hoskins-875 were superior to cermets of MgO in Inconel-702 and MgO in Hastelloy-X. Their oxidation resistance was degraded only when the MgO content was 40 vol percent. The oxidation behavior of MgO-in-Inconel-702 powder cermets containing 5- and 10-vol percent MgO was approximately similar to that of pure Inconel-702 compacts. The 20- and 40-vol percent MgO content reduced the oxidation resistance of MgO-in-Inconel-702 powder cermets relative to that of pure Inconel-702.

Zaplatynsky, I.↗

High-Flux Atomic-Oxygen Source

Beams of pure ground-state oxygen atoms produced. Accelerated electrons strike beam of O2 gas in dissociative-attachment region, producing O- ions. O- ions accelerated to desired final energy and pass through photodetachment region to form 0(3P) atoms. These pass between electric field plates to remove O- and e and strike target. Designed specifically to study degradation of materials and spacecraft glow phenomena in low Earth orbits, used to study gas-phase collision phenomena involving energetic oxygen atoms.

Chutjian, A.↗

Precise orbit determination for NASA's earth observing system using GPS (Global Positioning System)

An application of a precision orbit determination technique for NASA's Earth Observing System (EOS) using the Global Positioning System (GPS) is described. This technique allows the geometric information from measurements of GPS carrier phase and P-code pseudo-range to be exploited while minimizing requirements for precision dynamical modeling. The method combines geometric and dynamic information to determine the spacecraft trajectory; the weight on the dynamic information is controlled by adjusting fictitious spacecraft accelerations in three dimensions which are treated as first order exponentially time correlated stochastic processes. By varying the time correlation and uncertainty of the stochastic accelerations, the technique can range from purely geometric to purely dynamic. Performance estimates for this technique as applied to the orbit geometry planned for the EOS platforms indicate that decimeter accuracies for EOS orbit position may be obtainable. The sensitivity of the predicted orbit uncertainties to model errors for station locations, nongravitational platform accelerations, and Earth gravity is also presented.

Williams, B. G.↗

Graphite solubility and co-vesiculation in basalt-like melts at one-ATM

The identity and source of the vapor phase that caused lunar lava-fountaining and vesiculation in lunar basalts continues to be of interest because of its implications for the composition and state of the lunar interior and because of its implications for lunar resources. In light of the apparent near-absence of H2O on the Moon, it has been suggested that the vapor phase may be CO2-CO. This premise is supported by the presence of carbon on the surface of volcanic glass beads. However, although the rapid exsolution of CO2 from a melt during decompression may be consistent with firefountaining, it fails to provide a satisfying explanation for vesiculation in mare basalt where exsolution of the gas phase would more reasonably be related to cooling/crystallization at low pressure rather than decompression from high pressure. Also, geochemical trends in lunar volcanic glasses suggest that their source has an oxygen fugacity more reducing than the iron-wustite buffer, an oxygen fugacity that is inconsistent with presence of dissolved CO2-CO at depth. The results of experiments in which a vesicular 'basalt' is produced from a melt equilibrated with graphite and pure CO gas at one atmosphere pressure are reported. The vesiculation is apparently related to exsolution of CO or a CO species during cooling of the melt or growth of quench crystals. Additionally, particulate carbon dispersed through the quenched sample suggests that elemental carbon is either in solution in the melt prior to quenching or tends to go into suspension perhaps as colloid-like particles. These two observations may provide insight into the nature of fire-fountaining and vesiculation on the Moon.

Colson, R. O.↗

Effects of thermal-solutal convection on temperature and solutal fields under various gravitational orientations

Semiconductor crystals such as Hg(1-x)CD(x)Te grown by unidirectional solidification Bridgmann method have shown compositional segregations in both the axial and radial directions. Due to the wide separation between the liquidus and the solidus of its pseudobinary phase diagram, there is a diffusion layer of higher HgTe content built up in the melt near the melt-solid interface which gives a solute concentration gradient in the axial direction. The value of effective diffusion coefficient calculated from fitting of the data to 1D model varies with Hg(1-x)Cd(x)Te growth conditions. This indicates that the growth condition of the Hg(1-x)Cd(x)Te is not purely diffusion controlled. Because of the higher thermal conductivity in the melt than that in the crystal in the growth system, there is a thermal leakage through the fused silica crucible wall near the melt-solid interface. This gives a thermal gradient in the radial direction. Hart, and Thorpe, Hutt and Soulsby have shown that under such conditon a fluid will become convectively unstable as a result of different diffusitivities of temperature and solute. It is quite important to understand the effects of this thermosolute convection on the compositonal segregation in both axial and radial directions in the unidirectionally solidified crystals under various gravitational directions. To reach this goal, we start with a simplified problem to study the effects of thermal-solutal convection on the temperature and solutal fields under various gravitional orientations. We begin by reviewing model governing equations.

Wang, Jai-Ching↗

Gravitational evidence for an undifferentiated Callisto

Before the arrival of the Galileo spacecraft at Jupiter, models for the interior structure of the four galilean satellites--Io, Europa, Ganymede and Callisto-ranged from uniform mixtures of rock and ice (that is, undifferentiated objects) or rocky cores surrounded by a mantle of water ice. Now it appears that Io has a large metallic core and that Ganymede is strongly differentiated, most probably into a three-layer structure consisting of a metallic core, a silicate mantle and a deep outer layer of ice. Direct information on the interior structure of Callisto determined from previous spacecraft fly-bys was essentially limited to an estimate of the mean density being intermediate between pure ice and pure rock. Here we report measurements of Callisto's gravitational field which reveal that, in contrast to Io and Ganymede, this galilean satellite is most probably a homogeneous object consisting of a solar mixture of 40% compressed ice and 60% rock (including iron and iron sulphide). Callisto's undifferentiated state is consistent with the apparent lack of an intrinsic magnetic field, and indicates that the outermost galilean satellite has not experienced a heating phase sufficiently high to separate its rock and metal components from the lighter ices.

unmanned↗

A Solar Constant Model for Sun-climate Studies: 1600-2000AD

Discussed here is the solar constant model published recently (Schatten, 1988), but with a modified phasing and amplitude. This model enables the known solar constant variations to be calculated from known active region and quiet region solar parameters. The features which can be modelled are sunspots and faculae, the only two features which mark the photospheric continuum with their unusual contrast behavior. They include both the active region features (sunspots and faculae) and the quiet region features (global faculae). Although the direct influences of sunspots upon the solar constant leads to short term decreases, an opposite, nearly in phase, 11 year variation in the solar constant is modelled, thereby agreeing with the Active Cavity Radiometer Irradiance Monitor (ACRIM) and Earth Radiation Budget (ERB) secular trends observed. This opposite behavior results primarily from global faculae (polar, network, and active region). The main contributors to the global behavior are the network faculae. The model attributes the observed variations in the solar constant entirely to magnetic features in the solar atmosphere. The present model serves purely to model the secular (long term) trend in the solar constant. The model suggests a change of approx. 0.5 W/sq m for the differences between the late twentieth century solar constant and the 17th century solar constant. This supports Eddy's view that this difference could give rise to the glacial increase during the little ice age of the 17th century. Important for present day climate studies, is that it shows the recent peak activity (peaking in 1958) is associated with an atypically high value of the solar constant, with respect to the past few hundred years.

Schatten, Kenneth H.↗