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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25

Breaking adsorption-energy scaling limitations of electrocatalytic nitrate reduction on intermetallic CuPd nanocubes by machine-learned insights

The electrochemical nitrate reduction reaction (NO 3 RR) to ammonia is an essential step toward restoring the globally disrupted nitrogen cycle. In search of highly efficient electrocatalysts, tailoring catalytic sites with ligand and strain effects in random alloys is a common approach but remains limited due to the ubiquitous energy-scaling relations. With interpretable machine learning, we unravel a mechanism of breaking adsorption-energy scaling relations through the site-specific Pauli repulsion interactions of the metal d-states with adsorbate frontier orbitals. The non-scaling behavior can be realized on (100)-type sites of ordered B2 intermetallics, in which the orbital overlap between the hollow *N and subsurface metal atoms is significant while the bridge-bidentate *NO 3 is not directly affected. Among those intermetallics predicted, we synthesize monodisperse ordered B2 CuPd nanocubes that demonstrate high performance for NO 3 RR to ammonia with a Faradaic efficiency of 92.5% at –0.5 V RHE and a yield rate of 6.25 mol h –1 g –1 at –0.6 V RHE . This study provides machine-learned design rules besides the d-band center metrics, paving the path toward data-driven discovery of catalytic materials beyond linear scaling limitations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Optimal Low-Thrust Limited-Power Transfers between Arbitrary Elliptic Coplanar Orbits

In this work, a complete first order analytical solution, which includes the short periodic terms, for the problem of optimal low-thrust limited-power transfers between arbitrary elliptic coplanar orbits in a Newtonian central gravity field is obtained through Hamilton-Jacobi theory and a perturbation method based on Lie series.

daSilvaFernandes, Sandro↗

Numerical simulation of cometary nuclei. III - Internal temperatures of cometary nuclei

The thermal diffusion equation for the internal temperature of cometary nuclei is exactly solved by means of a one-dimensional numerical model in order to shed light on the complex behavior of these temperatures with varying orbital and thermal parameters and in order to consider possible cometary nucleus thermal evolution targets for comet rendezvous and/or sample-return missions. The concept of 'new' and 'old' comets, classified in terms of how many passages around the sun have been made, may take on new meaning in view of the present demonstration that differences in eccentricity between two comets having the same period and number of apparitions may yield significantly different internal temperature profiles.

Herman, Gary↗

Transfer trajectories for distant retrograde orbiters of the Earth

A new mission concept is introduced for future astrophysical observatories. This concept is to use a solar orbit that remains bounded to the Earth at a large distance on the order of several million kilometers. These orbits are termed here distant Retrograde Orbits (DRO's). This type of orbit is ideal for a space telescope that needs to be separated from the Earth by a large distance to avoid the near-Earth environmental effects, yet needs to remain bounded within some pre-defined distance for communication purposes. Another application is for a solar storm warning system that can provide warning times greater than those available from a similar system at the interior libration point of the Sun-Earth/Moon system. Several classes of DRO's in the Sun-Earth/Moon system are presented. The associated launch and insertion energies for impulsive and continuous thrust transfers from a low Earth parking orbit are investigated.

Ocampo, Cesar A.↗

Transfer trajectories for distant retrograde orbiters of the Earth

A new mission concept is introduced for future astrophysical observatories. This concept is to use a solar orbit that remains bounded to the Earth at a large distance on the order of several million kilometers. These orbits are termed here Distant Retrograde Orbits (DRO's). This type of orbit is ideal for a space telescope that needs to be separated from the Earth by large distance to avoid the near Earth environmental effects, yet needs to remain bounded within some predefined distance for communication purposes. Another application is for a solar storm warning system that can provide warning times greater than those available from a similar system at the interior libration point of the Sun-Earth/Moon system. Several classes of DRO's in the Sun-Earth/Moon system are presented. The associated launch and insertion energies for impulsive and continuous thrust transfers from a low Earth parking orbit are investigated.

Ocampo, Cesar A.↗

Horizon radiation reaction forces

Using Effective Field Theory (EFT) methods, we compute the effects of horizon dissipation on the gravitational interactions of relativistic binary black hole systems. We assume that the dynamics is perturbative, i.e it admits an expansion in powers of Newton’s constant (post-Minkowskian, or PM, approximation). As applications, we compute corrections to the scattering angle in a black hole collision due to dissipative effects to leading PM order, as well as the post-Newtonian (PN) corrections to the equations of motion of binary black holes in non-relativistic orbits, which represents the leading order finite size effect in the equations of motion. The methods developed here are also applicable to the case of more general compact objects, eg. neutron stars, where the magnitude of the dissipative effects depends on non-gravitational physics (e.g, the equation of state for nuclear matter).

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Experimental investigation of beam-ion losses induced by magnetic perturbations using the light ion beam probe technique in the ASDEX Upgrade tokamak

The impact of externally applied magnetic perturbations (MPs) on fast-ion losses has been investigated by means of the light ion beam probe (LIBP) technique in the ASDEX Upgrade tokamak. The LIBP technique allows to experimentally infer the fast-ion orbit displacement induced by MPs via first-orbit losses using scintillator based fast-ion loss detector (FILD) measurements. The fast-ion orbit displacement against different applied MP spectra has been studied. These shots were conducted in ELM mitigated H-mode plasmas. A rigid rotation of the MP coils was applied with a frequency of 1 Hz, with an n = 2 configuration and changing the differential phase between the upper and lower set of coils (ΔΦ ul ) on a shot-to-shot basis. Beam sources Q7 (tangential) and Q8 (radial) were used to probe different fast-ion orbits with FILD1. The measured fast-ion orbit displacement ranges from 3 to 20 mm approximately, and no qualitative difference is observed between ions from beam sources Q7 and Q8. The minimum is found for a ΔΦ ul ~ 50°, which is shifted with respect to the minimum of the plasma boundary displacement, found at ΔΦ ul ~ 0°. A first attempt to validate the orbit following code ASCOT—including the plasma response calculated with the MARS-F code—against these experimental measurements is performed. Finally, while the dependence of the first-orbit fast-ion displacement with ΔΦ ul does not match the experimental measurements, these simulations do capture other features such as the order of magnitude of the orbit displacement and the importance of the toroidal spectrum of the applied perturbation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Dawn Orbit Determination Team: Trajectory Modeling and Reconstruction Processes at Vesta

The Dawn spacecraft spent over a year in orbit around Vesta from July 2011 through August 2012. In order to maintain the designated science reference orbits and enable the transfers between those orbits, precise and timely orbit determination was required. Challenges included low-thrust ion propulsion modeling, estimation of relatively unknown Vesta gravity and rotation models, track-ing data limitations, incorporation of real-time telemetry into dynamics model updates, and rapid maneuver design cycles during transfers. This paper discusses the dynamics models, filter configuration, and data processing implemented to deliver a rapid orbit determination capability to the Dawn project.

low thrust↗

A First Look at Orbit Determination for the Cassini Mission, Part 2: Saturn Tour

This is the second of two papers which summarize orbit determination analysis accoumpliched to date as part of navigation studies for the Cassini mission. The thrust of the analysis has been to characterize orbit determination accuracy to first order for selected phases of the mission.

Cassini orbiter Huygens probe VVEJGA trajectory Ju↗

On plasma disturbances caused by the motion of the Space Shuttle and small satellites - A comparison of in situ observations

Recent results regarding the interactions between a body and its environmental space plasma, made by charged particle probes mounted in the bay of the Space Shuttle Orbiter Columbia (STS 3 mission), are compared with earlier results, obtained from small ionospheric satellites, in an attempt to widen our scope of knowledge and understanding regarding such interactions. The objective is to work toward a unified model of body-space plasma interactions in the solar system covering a variety of plasma and body conditions. The comparisons focus mainly on (1) the (wake/ram) current ratio; (2) the generation of charged particle density fluctuations (indicative of plasma turbulence) around the body; and (3) the increase in electron temperature ahead and in the wake of the satellite. The main results of the comparison are that (1) the (wake/ram) current ratio (or current depletion in the wake) for the Orbiter is 1 to 2 orders of magnitude larger than the ratio for small ionospheric satellites; and (2) fluctuations in density (or turbulence) are observed for both 'large body' (Shuttle Orbiter) and 'smaller body' (standard ionospheric satellites). However, the cause of the turbulence may not be the same for both cases; (3) the results for the electronic temperature enhancement due to the Shuttle Orbiter are in contrast with measurements from smaller ionospheric satellites. A path to follow in future Shuttle experiments is suggested and caution that care be taken in interpreting local particle and field measurements.

Samir, U.↗

Eccentricity and argument of perigee control for orbits with repeat ground tracks

In order to gain an understanding into the problem of eccentricity (e) and argument of perigee (omega) control for TOPEX/Poseidon, the two cases where the highest latitude crossing time and one of the equator crossings are held constant are investigated. Variations in e and omega cause a significant effect on the satellite's ground-track repeatability. Maintaining e and omega near their frozen values will minimize this variation. Analytical expressions are found to express this relationship while keeping an arbitrary point of the ground track fixed. The initial offset of the ground track from its nominal path determines the subsequent evolution of e and omega about their frozen values. This long-term behavior is numerically determined using an earth gravitational field including the first 17 zonal harmonics. The numerical results are plotted together with the analytical constraints to see if the later values of e and omega cause unacceptable deviation in the ground track.

Vincent, Mark A.↗

On-Orbit Calibration of Satellite Gyroscopes

In order to maneuver satellites accurately from one attitude to another, onboard rate sensing gyroscopes usually must be calibrated after launch. Several algorithms have been used to determine gyro biases, misalignments, and scale factors. This paper describes algorithms that have been used in the past, discusses their advantages and limitations, and describes a new algorithm and the gyro calibration results obtained using this new algorithm. The new algorithm has significant operational advantages in addition to being at least as accurate as other algorithms.

Hashmall, Joseph A.↗

Modal control of an unstable periodic orbit

Floquet theory is applied to the problem of designing a control system for a satellite in an unstable periodic orbit. Expansion about a periodic orbit produces a time-periodic linear system, which is augmented by a time-periodic control term. It is shown that this can be done such that (1) the application of control produces only inertial accelerations, (2) positive real Poincareexponents are shifted into the left half-plane, and (3) the shift of the exponent is linear with control gain. These developments are applied to an unstable orbit near the earth-moon L(3) point pertubed by the sun. Finally, it is shown that the control theory can be extended to include first order perturbations about the periodic orbit without increase in control cost.

Wiesel, W.↗

Repartitioned Brillouin-Wigner perturbation theory with a size-consistent second-order correlation energy

Second-order Møller-Plesset perturbation theory (MP2) often breaks down catastrophically in small-gap systems, leaving much to be desired in its performance for myriad chemical applications such as noncovalent interactions, thermochemistry, and dative bonding in transition metal complexes. This divergence problem has reignited interest in Brillouin-Wigner perturbation theory (BWPT), which is regular at all orders but lacks size consistency and extensivity, severely limiting its application to chemistry. In this work, we propose an alternative partitioning of the Hamiltonian that leads to a regular BWPT perturbation series that, through the second order, is size-extensive, size-consistent (provided its Hartree–Fock reference is also), and orbital invariant. Here, our second-order size-consistent Brillouin-Wigner (BW-s2) approach can describe the exact dissociation limit of H 2 in a minimal basis set, regardless of the spin polarization of the reference orbitals. More broadly, we find that BW-s2 offers improvements relative to MP2 for covalent bond breaking, noncovalent interaction energies, and metal/organic reaction energies, although rivaling coupled-cluster with single and double substitutions for thermochemical properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Stationkeeping Approach for the Microwave Anisotropy Probe (MAP)

The Microwave Anisotropy Probe was successfully launched on June 30, 2001 and placed into a Lissajous orbit about the L2 Sun-Earth-Moon libration point. However, the L2 libration point is unstable which necessitates occasional stationkeeping maneuvers in order to maintain the spacecraft s Lissajous orbit. Analyses were performed in order to develop a feasible L2 stationkeeping strategy for the MAP mission. The resulting strategy meets the allotted fuel budget, allowing for enough fuel to handle additional he1 taxes, while meeting the attitude requirements for the maneuvers. Results from the first two stationkeeping maneuvers are included.

Rohrbaugh, Dave↗

On the nature of the interaction of the Jovian magnetosphere with the icy Galilean satellites

The effects of plasma and micrometeoroid bombardment of each satellite are considered in the case of interactions between the Jovian magnetosphere and Europa, Ganymede, and Callisto, in an attempt to understand the influences of these exogenic processes on the surface properties of each of the three moons. Sublimated and sputtered H2O results in a net O2 atmosphere on each of the three moons, and the effectiveness of such an atmosphere in preventing the Jovian plasma from reaching each satellite surface is considered for a variety of magnetospheric conditions. Also studied are the effects of possible satellite magnetic field magnitude and orientation, in order to estimate satellite magnetosphere properties, and the orbits of charged micrometeroids in the Jupiter magnetosphere, in order to determine the relative flux of these particles over the satellite surfaces.

Wolff, R. S.↗

Intercontinental Bistatic Radar Test Observation of Asteroid 1998 WT24

We describe the first intercontinental planetary radar test performed in Italy observing the near Earth asteroid (NEA) 33342 (1998 WT24) in December 2001 by means of the bistatic configurations Goldstone (California, USA)-Medicina (Italy) and Evpatoria (Ukraine)-Medicina. The experiment goal was to characterize the system for realtime radar follow-up observations of NEAs and artificial orbiting debris, in the framework of a feasibility study which aims at using the Sardinia Radio Telescope, at present under construction, also as a planetary radar facility. We report the preliminary results of the radar observations carried out by the IRA-CNR (Instituto di Radioastronomia - Consiglio Nazionale delle Ricerche) and the OATo (Osservatorio Astronomico di Torino) groups, aimed at exploring the scientific potentials of a new space radar program, using the existing facilities in Italy. The planetary radar technique is uniquely capable of investigating geometry and surface properties of various solar system objects, demonstrating advantages over the optical methods in its high spatial resolution and ability to obtain three-dimensional images. A single radar detection allows to obtain extremely accurate orbital elements, improving the instantaneous positional uncertainties by orders of magnitude with respect to an optically determined orbit. Radar is a powerful means to spatially resolve NEAs by measuring the distribution of the echo power in time delay (range) and Doppler frequency (line-of-sight velocity) with extreme precision in each coordinate, as it provides detailed information about the target physical properties like size, shape, rotation, near-surface bulk density and roughness and internal density distribution. The Medicina 32m antenna had been successfully used for the first time as the receiving part of a bistatic configuration during a test experiment (September 2001) held to check the capabilities of the entire data acquisition system. This test was possible thanks to the collaboration undertaken with the Evpatoria radar station, and consisted in the observation of the ETALON-1 low orbit satellite

Righini, S.↗