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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Using Strain in the Vadose Zone During Sinusoidal-Rate Well Tests to Characterize an Aquifer

Well tests with sinusoidal variation in pumping rate are appealing because of the ability to filter competing signals and they also can be set up with no net removal of water, which is an advantage at contaminated sites. Current methods of interpreting sinusoidal-rate well tests analyze the phase lag and amplitude of pressure signals in the aquifer. This approach is restricted by the availability of monitoring wells. An alternative approach could be to measure the stain in the vadose zone instead of pressure in the aquifer. The goal of this research is to evaluate the feasibility of using signals from in-situ sensors in the vadose zone to characterize sinusoidal-rate well tests. Well tests with a variety of periods and amplitudes were performed using a well completed in an unconfined saprolite aquifer with a water table at 9m depth at our test site near Clemson, South Carolina. Vertical strain was measured every meter between 1 to 7 m using a distributed optical fiber sensing technique called coherence length gated microwave photonics interferometry (CMPI). A novel packaging system was designed to couple the optical fiber to the saprolite. The results show that strain measured in the vadose zone during sinusoidal-rate pumping varies periodically with amplitudes from 0.1 to 3 microstrain, depending on the amplitude of the sinusoidal pumping rate. Hydraulic heads at similar radial distances were also periodic with changing amplitudes ranging up to ±0.2 meters. The strain in the vadose zone responds to pressure in the underlying aquifer—the strain is tensile when the pressure is falling, and compressive when the pressure is rising. The phase lag between the pumping rate and the strain was 3 min with a pumping period of 15 minutes, and this gives a hydraulic diffusivity of 0.06 m2/s. This is the same diffusivity obtained by analyzing a constant rate pumping test, and it is slightly larger than the diffusivity (0.044 m2/s) obtained by analyzing the phase lag of the pressure in a nearby monitoring well. Strain measurements in the vadose zone could be made with much less cost and effort than installing a deep monitoring well. These results suggest that strain measurements in the vadose zone could be used to supplement monitoring wells, thereby increasing the resolution, and reducing costs of analyzing well tests.

well test, sinusoidal, periodic pumping, strain↗
DOE OSTI2022

Decomposition of high-rank factorized unitary coupled-cluster operators using ancilla and multiqubit controlled low-rank counterparts

The factorized form of the unitary coupled-cluster (UCC) approximation is one of the most promising methodologies to prepare trial states for strongly correlated systems within the variational quantum eigensolver framework. The factorized form of the UCC Ansatz can be systematically applied to a reference state to generate the desired entanglement. The difficulty associated with such an approach is the requirement of simultaneously entangling a growing number of qubits, which quickly exceeds the hardware limitations of today's quantum machines. In particular, while circuits for singles and double excitations can be performed on current hardware, higher-rank excitations require too many gate operations. In this work, we propose a set of schemes that trade off using extra qubits for a reduced gate depth to decompose high-rank UCC excitation operators into significantly lower depth circuits. These results will remain useful even when fault-tolerant machines are available to reduce the overall state-preparation circuit depth.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2026

Oxygen Vacancy Evolution at Li x V 2 O 5 /LiPON Solid State Electrochemical Interfaces Using Depth Resolved Cathodoluminescence Spectroscopy

The formation of oxygen vacancies at buried LiPON/ Li x V 2 O 5 interfaces has been observed on a near-nanometer scale and nondestructively using depth-resolved cathodoluminescence spectroscopy (DRCLS) and interfacial markers. Before electrochemical cycling, as-deposited LiPON/Li x V 2 O 5 exhibits a 1.6 eV defect optical emission, which density functional theory calculations identify as originating from oxygen vacancies. This defect appears first within a few nanometers of the buried LiPON/Li x V 2 O 5 interface without cycling, indicating that spontaneous O diffusion from the Li x V 2 O 5 lattice into LiPON may have caused these interface-localized oxygen vacancy defects. DRCLS measured the intensity and spatial distribution of this oxygen vacancy signal as a function of electrochemical cycling in a LiPON/Li x V 2 O 5 half-cell, showing oxygen vacancy signal increasing and moving deeper into the electrode with increased cycle number. Significant electrochemical irreversibility was also observed, with poor Coulombic efficiency and a 15% drop in capacity over 50 cycles. Theoretical simulations predict that the presence of oxygen vacancies increases the energy barrier for lithium diffusion significantly, indicating that this aggregation of oxygen vacancies could be another battery degradation mechanism accompanying lithiation induced phase changes.

36 MATERIALS SCIENCE↗
DOE OSTI2021

A comparison of Raman and pyrometry dynamic temperature measurements of shocked cyclohexane

Optical pyrometry is a well-developed, broadly applicable method to determine temperature in dynamic compression experiments. However, it measures radiation from only the skin depth of the radiant material, is highly susceptible to spurious backgrounds, and requires an often-unmeasurable free parameter—the sample dynamic emissivity. Raman spectroscopy offers a method to determine temperature directly from fundamental theory, but it is practically limited in applications to a small subset of shock experiments. In this work, we describe an experiment allowing simultaneous application of Raman and pyrometric temperature techniques to benchmark a specific instance of pyrometry. We attempted both measurements on multiple experiments and compare the successful temperature results between the separate but highly repeatable shots. Here, we find that dynamic shock temperatures inferred from Raman spectroscopy and pyrometry generally agree within the uncertainties of each measurement, although those uncertainties are larger than typical for a specially designed pyrometry experiment on a shocked metal sample.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2020

Measurement of Kinetic-Scale Current Filamentation Dynamics and Associated Magnetic Fields in Interpenetrating Plasmas

Here, we present the first local, quantitative measurements of ion current filamentation and magnetic field amplification in interpenetrating plasmas, characterizing the dynamics of the ion Weibel instability. The interaction of a pair of laser-generated, counterpropagating, collisionless, supersonic plasma flows is probed using optical Thomson scattering (TS). Analysis of the TS ion-feature revealed anticorrelated modulations in the density of the two ion streams at the spatial scale of the ion skin depth c/ω pi = 120 μm, and a correlated modulation in the plasma current. The inferred current profile implies a magnetic field amplitude ~30 ± 6 T , corresponding to ~1% of the flow kinetic energy, indicating that magnetic trapping is the dominant saturation mechanism.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Ground-based Transmission Spectroscopy with VLT FORS2: Evidence for Faculae and Clouds in the Optical Spectrum of the Warm Saturn WASP-110b

We present a ground-based optical transmission spectrum for the warm Saturn-mass exoplanet WASP-110b from two transit observations made with the FOcal Reducer and Spectrograph on the Very Large Telescope. The spectrum covers the wavelength range from 4000–8333 Å, which is binned in 46 transit depths measured to an averaged precision of 220 parts per million (ppm) over an averaged 80 Å bin for a Vmag = 12.8 star. The measured transit depths are unaffected by a dilution from a close A-type field dwarf, which was fully resolved. The overall main characteristic of the transmission spectrum is an increasing radius with wavelength and a lack of the theoretically predicted pressure-broadened sodium and potassium absorption features for a cloud-free atmosphere. We analyze archival high-resolution optical spectroscopy and find evidence for low to moderate activity of the host star, which we take into account in the atmospheric retrieval analysis. Using the AURA retrieval code, we find that the observed transmission spectrum can be best explained by a combination of unocculted stellar faculae and a cloud deck. Transmission spectra of cloud-free and hazy atmospheres are rejected at a high confidence. With a possible cloud deck at its terminator, WASP-110b joins the increasing population of irradiated hot-Jupiter exoplanets with cloudy atmospheres observed in transmission.

47 OTHER INSTRUMENTATION↗
DOE OSTI2026

Electrically tunable nonlinear light generation in plasmonic tunnel junctions

Active and efficient control of nonlinear optical processes is essential for integrated photonics, with applications in signal processing, ultrafast switching, and quantum light manipulation. While nanophotonic structures are powerful for enhancing nonlinearities, achieving wide-range electrical tunability has remained a challenge. Plasmonic tunnel junctions offer a unique path to bridge this gap because they combine extreme optical field confinement with direct electrical control in a single nanoscale device. Here, we report the first, to our knowledge, demonstration of electrically tunable second-harmonic generation (SHG) in plasmonic tunnel junctions. Using ultra-stable epitaxial heterostructures, we achieve reproducible modulation of SHG with depths up to ∼500% and magnitudes above 1.3V −1 . We identify two mechanisms, electric-field-induced SHG (EFISH) and ion migration, that can either compete or cooperate depending on junction thickness and bias, enabling both broad tunability and ferroelectric-like hysteretic switching. These findings establish plasmonic tunnel junctions as a platform for electrically controlled nonlinear optics, with potential for nanoscale light sources, reconfigurable modulators, and neuromorphic photonic devices..

42 ENGINEERING↗
DOE OSTI2026

Depth-Resolved X-Ray Nanoimaging of Coherent and Incoherent Energy Transport in Silicon Carbide

Understanding lattice dynamics is crucial for optimizing the process of creating functional structures, such as laser writing of color-center defects. However, existing structural probes have difficulty measuring structural dynamics with submicrometer depth sensitivity. Here, in this study, a depth-resolved ultrafast X-ray nanodiffraction technique is developed to track the lattice dynamics of silicon carbide (SiC) in three dimensions. Upon laser excitation of an aluminum layer that acts as a heat and strain transducer, a specular Bragg peak of SiC shows an overall increase in the X-ray diffraction intensity rather than a peak shift. The relaxation dynamics of the increased intensity are significantly different when probed on and off the Bragg peak. The fast subnanosecond relaxation probed at the maximum of the Bragg peak is a result of the propagation of a coherent strain wave along the depth direction, while a slow relaxation probed at the wings of the Bragg peak reflects a localized incoherent lattice heating. To further visualize these processes, spatiotemporal maps were obtained by scanning the relative position and delay between the laser pump and X-ray probe beams, which capture the propagation of the strain wave, as well as a stationary structural distortion close to the aluminum/SiC interface. These depth-resolved structural measurements disentangle energy dissipation mechanisms in laser-excited SiC, and they open opportunities for finer control of, for example, the formation of optically addressable defect complexes central to quantum information applications.

X-ray nanodiffraction↗
DOE OSTI2025

Replenishing liquid sheet targets to enable high-intensity high-repetition-rate laser–plasma interactions for ion-beam technology

We report on the development of a robust microfluidic nozzle capable of generating replenishing liquid sheet targets with sub-micron thickness at up to kHz repetition rates, a λ/20 surface flatness over areas of at least 100 μm 2 , and in-vacuum dimensions of 6 × 1.5 mm 2 . The platform was evaluated for stability under hundreds of 4.3 J laser shots at 0.5 Hz and 6 × 10 20 W/cm 2 peak intensity, delivered in burst mode, totaling 2.9 kJ on the target. The key metrics of the platform, including sheet characteristics, nozzle aperture morphology, and proton spectra, showed no measurable degradation in the performance of the liquid sheet platform following this experiment. Beyond its application to ion beam technology, we outline a pathway to further develop the capabilities of the platform into a high-repetition-rate plasma mirror.

depth profiling techniques↗
DOE OSTI2022

Temperature Mapping of Stacked Silicon Dies from X-Ray-Diffraction Intensities

Increasing power densities in integrated circuits have led to an increased prevalence of thermal hotspots in integrated circuits. Tracking these thermal hotspots is imperative to prevent circuit failures. In three- dimensional (3D) integrated circuits, conventional surface techniques like infrared thermometry are unable to measure the 3D temperature distribution, and optical and magnetic resonance techniques are difficult to apply due to the presence of metals and large current densities. X-rays offer a high penetration depth and can be used to probe 3D structures. We report a method utilizing the temperature dependence of x-ray-diffraction intensity via the Debye-Waller factor to simultaneously map the temperature of individual silicon dies in a stack. Here, utilizing beamline 1-ID-E at the Advanced Photon Source (Argonne), we demonstrate, for each individual silicon die, a temperature resolution of 3 K, a spatial resolution of 100 × 400 μm 2 , and a temporal resolution of 20 s. Utilizing a sufficiently high-intensity laboratory source, e.g., from a liquid-anode source, this method can be scaled down to laboratories for noninvasive temperature mapping of 3D integrated circuits.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

Enhanced Bottom Anode Monitoring in DC Electric Arc Furnaces Using Fiber-Optic Sensors

A pin style bottom anode employs conductive steel rods that serve as the pathway for the high electrical power through rammed refractory at the bottom of a DC Electric Arc Furnace (EAF). Anode wear during operation is important to monitor, as anode replacement is expensive and impacts EAF productivity. Liquid steel penetration into the un-sintered refractory layer can result from rapid electrical power ramp-up, dips in furnace temperature, or operating the anode for too long between EAF campaigns. In extreme cases, the liquid steel may penetrate the bottom of the furnace when anode wear progresses too close to the bottom shell, which is extremely dangerous and must be avoided. The current state of the art for monitoring bottom anode wear employs thermocouples imbedded in the anode pins at points in the anode. However, this approach is not sensitive enough to detect localized damage to the anode, especially when cracking occurs. Here, the present work utilizes fiber optic sensors to monitor the health of the anode, by creating a real-time spatially distributed temperature map of the anode. Unlike the traditional thermocouples, these sensors can be mounted at significantly greater depths, provide distributed temperature measurements, and can withstand temperatures of up to 900°C. Additionally, they are able to perform temperature measurements with a spatial resolution of 1.3 mm at a 5 Hz acquisition rate, providing unprecedented high-density real time monitoring of anode health and increasing the efficiency, and safety of EAF operation.

Bottom Anode↗
DOE OSTI2025

Atomic Coherence of 2 Minutes and Instability of 1.5 × 10 −18 at 1 s in a Wannier-Stark Lattice Clock

We explore the limits of atomic coherence and measurement precision in a 87 Sr optical lattice clock. We perform a detailed characterization of key effects, including lattice Raman scattering and atomic collisions in a shallow lattice configuration, determining a 174(28) s 3 𝑃 0 clock state lifetime. Investigation of atomic coherence across a range of lattice depths and atomic densities reveals decoherence mechanisms related to photon scattering and atomic interaction. At a reduced density, we observe a coherence time of 118(9) s, approaching the fundamental limit set by spontaneous emission. Guided by this coherence understanding, we demonstrate a clock instability for an atomic ensemble of 1.5 × 10 −18 at 1 s in fractional frequency units. Our results are important for further advancing the state of the art of an optical lattice clock for fundamental physics applications.

atomic, optical, & lattice clocks↗
DOE OSTI2024

Probing elemental diffusion and radiation tolerance of perovskite solar cells via non-destructive Rutherford backscattering spectrometry

Mixed organic–inorganic halide perovskite-based solar cells have attracted interest in recent years due to their potential for both terrestrial and space applications. Analysis of interfaces is critical to predicting device behavior and optimizing device architectures. Most advanced tools to study buried interfaces are destructive in nature and can induce further degradation. Ion beam techniques, such as Rutherford backscattering spectrometry (RBS), is a useful non-destructive method to probe an elemental depth profile of multilayered perovskite solar cells (PSCs) as well as to study the inter-diffusion of various elemental species across interfaces. Additionally, PSCs are becoming viable candidates for space photovoltaic applications, and it is critical to investigate their radiation-induced degradation. RBS can be simultaneously utilized to analyze the radiation effects induced by He+ beam on the device, given their presence in space orbits. In the present work, a 2 MeV He+ beam was used to probe the evidence of elemental diffusion across PSC interfaces with architecture glass/ITO/SnO2/Cs0.05(MA0.17FA0.83)0.95Pb(I0.83Br0.17)3/spiro-OMeTAD/MoO3/Au. During the analysis, the device active area was exposed to an irradiation equivalent of up to 1.62 × 1015 He+/cm2, and yet, no measurable evidence (with a depth resolution ∼1 nm) of beam-induced ion migration was observed, implying high radiation tolerance of PSCs. On the other hand, aged PSCs exhibited indications of the movement of diverse elemental species, such as Au, Pb, In, Sn, Br, and I, in the active area of the device, which was quantified with the help of RBS.

14 SOLAR ENERGY↗
DOE OSTI2023

CRADA Number NFE-19-07847 with MantaPoole Technologies (CRADA Final Report)

As the world becomes more automated, smart and autonomous systems that utilize advanced 3D machine vision are becoming ever more prevalent. To function autonomously, these smart machines need to be able to identify the “what” and “where” of their application by capturing color and depth information. The color information provides the needed contrast information to identify the “what” of a scene while the depth information allows the smart machine to identify “where” an object in a 3D environment is. To capture both the color and depth information using only a single sensor, MantaPoole Technologies (MPT) is developing a new type of 3D light field camera. The approach leverages MPT’s active micro-optics technology which when aligned and placed over an imaging detector are designed to act as an advanced optical filter that controls the direction of light that reaches the underlying pixels.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Depth Thermography: Noninvasive 3D Temperature Profiling Using Infrared Thermal Emission

Here, we introduce a technique based on infrared thermal emission, termed depth thermography, that can remotely measure the temperature distribution beneath the surface of certain objects. Depth thermography utilizes the thermal-emission spectrum in the semitransparent spectral region of the target object to extract its temperature as a function of depth, in contrast with conventional thermography, which uses the spectrally integrated thermally emitted power to measure the surface temperature. Coupled with two-dimensional imaging, for example using an infrared hyperspectral camera or scanning a single-pixel spectrometer, this technique can yield volumetric temperature distributions. Furthermore, we carried out a proof-of-concept experiment on an asymmetrically heated fused-silica window, extracting the temperature distribution throughout the sample. Depth thermography may enable noncontact volumetric temperature measurements of microscopic objects such as multilayer electronic devices or macroscopic volumes of liquids and gases, as well as simultaneous all-optical measurements of optical and thermal properties of materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Next-generation perovskite photovoltaics: improving, stabilizing, and lead-sealing of record-setting laboratory solar cells towards commercialization

Summary: In the proposed program we plan to improve perovskite photovoltaic performance by developing (1) orientational control of 3D/2D perovskite heterostructures to simplify device architectures, thus improving device efficiencies and stability; (2) high-throughput optical measurements and real-time device simulations for device optimization; (3) robust, dual-pronged lead-sealing and oxygen/moisture/UV barrier films for long-term stability. Specifically, we seek to develop an in-depth understanding of the perovskite film formation, interface passivation, device stability, and environmentally friendly encapsulation, which together will lead to perovskite devices with PCE of over 28%, stability of T80 at 85/85 (85% humidity at 85 degrees C) for 10,000, expected to be equivalent to T90 of 100 hours), and architectures that would satisfy the U.S. EPA and RoHS limits of lead-leaching. The knowledge generated with this project will be applicable to tandem devices with wider-bandgap perovskites.

14 SOLAR ENERGY↗
DOE OSTI2025

Model of photoemission and framework for relating quantum efficiency to stoichiometry

Simulating the quantum efficiency (QE) from photocathodes used in accelerators and photoinjectors requires accounting for the properties of the photoemissive material, the optical properties, scattering coefficients, and doping concentrations of which are dependent upon the stoichiometry. We present a rapid and flexible optical model that can be used to investigate the consequences of changes in the dielectric properties and their impact on the QE through such factors as reflectivity and laser penetration depth. Differences in materials can then be characterized by changes to parameters used to evaluate the dielectric function in a Lorentz–Drude–Resonant model. A method to characterize data is motivated by the example of copper and vetted by application to an exact analytical model. The effects of changes in parameters describing the resonant terms, which aggregate in the visible and UV regions of the spectrum, are shown.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Utilisation of spatial derivative measurements in circular diffuse optical tomographic imaging to improve image resolution and contrast

The resolution of images recovered using diffuse optical tomography without spatial prior information is inherently limited due to the diffusive nature of light transport in scattering dominated biological tissue. Several studies have previously reported an improvement in depth sensitivity in near infrared spectroscopy by considering the subtraction of two neighbouring measurements. A nearest neighbour, spatial derivative based algorithm is presented, in which the difference between neighbouring source-sharing source – detector pairs is considered for tomographic reconstruction. Using a circular, inward-facing optode geometry, it is shown that deeper abnormalities in oxyhaemoglobin, deoxyhaemoglobin and water can be recovered with better localisation and contrast as compared to reconstructing using absolute values of multi-wavelength data. Relative improvements of up to 25 % in quantitative accuracy of recovered physiological values are demonstrated at better resolution for cancerous tissue in a heterogeneous breast model, when using this proposed spatial derivative based parameter reconstruction. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗