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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
NASA NTRS2008

Radiative Susceptibility of Cloudy Atmospheres to Droplet Number Perturbations: 1. Theoretical Analysis and Examples from MODIS

Theoretical and satellite-based assessments of the sensitivity of broadband shortwave radiative fluxes in cloudy atmospheres to small perturbations in the cloud droplet number concentration (N) of liquid water clouds under constant water conditions are performed. Two approaches to study this sensitivity are adopted: absolute increases in N, for which the radiative response is referred to as absolute cloud susceptibility, and relative increases in N or relative cloud susceptibility. Estimating the former is more challenging as it requires an assumed value for either cloud liquid water content or geometrical thickness; both susceptibilities require an assumed relationship between the droplet volume and effective radius. Expanding upon previous susceptibility studies, present radiative calculations include the effect of AN perturbations on droplet asymmetry parameter and single-scattering albedo, in addition to extinction. Absolute cloud susceptibility has a strong nonlinear dependence on the droplet effective radius as expected, while relative cloud susceptibility is primarily dependent on optical thickness. Molecular absorption and reflecting surfaces both reduce the relative contribution of the cloud to the top-of-atmosphere (TOA) flux and therefore also reduce the TOA albedo susceptibility. Transmittance susceptibilities are negative with absolute values similar to albedo susceptibility, while atmospheric absorptance susceptibilities are about an order of magnitude smaller than albedo susceptibilities and can be either positive or negative. Observation-based susceptibility calculations are derived from MODIS pixel-level retrievals of liquid water cloud optical thickness, effective radius, and cloud top temperature; two data granule examples are shown. Susceptibility quantifies the aerosol indirect effect sensitivity in a way that can be easily computed from model fields. As such, susceptibilities derived from MODIS observations provide a higher-order test of model cloud properties used for indirect effect studies. MODIS-derived global distributions of cloud susceptibility and radiative forcing calculations are presented in a companion paper.

Platnick, Steven↗
NASA NTRSDate not supplied

Characterization of Novel Spacecraft Materials aboard the Materials International Space Station Experiment-Flight Facility (Preliminary Results)

This work will encompass the preflight characterization of 15 novel and heritage materials currently under observation on the Materials International Space Station Experiment-Flight Facility (MISSE-FF). MISSE-FF has been upgraded to perform active reflectance measurements of the materials. Images taken in RGB/IR colors are compared to results from an extensive ground testing campaign to obtain quantitative on-orbit material evolution data. Identical materials samples are to be flown on the ram, wake, and zenith faces of MISSE-FF, enabling deconvolution of the energetic electron, proton, atomic oxygen, and ultraviolet damage pathways. Energy deposition from the space environment leads to chemical changes in the material that in turn alter the optical properties. The same chemical damage that manifests as changes in optical reflectance and absorptance also leads to changes in myriad physical properties such as mechanical strength, electrical conductivity, and chemical reactivity. Therefore, flight materials are able to be characterized based on their unique reflectance spectra by comparing on-orbit measurements of optical reflectance with extensive terrestrial experiments, which help to correlate changes in reflectance with respect to changes in other material properties. The MISSE program has been a part of the International Space Station National Laboratory for many years and has been instrumental in understanding space weather modification of material properties. However, MISSE-FF has been limited to passive experiments with only pre/post flight material studies possible. In advance of the MISSE-16 experiment, the flight facility has received a major upgrade to provide daily spectral observations by way of a RGB/IR camera and a tunable light source. The MISSE-16 mission launched in February 2022 and carries 15 material samples for 6 months of the low Earth orbital exposure. Identical materials samples are to be flown on the ram, wake, and zenith faces of MISSE-FF, enabling deconvolution of the energetic electron, proton, atomic oxygen, and ultraviolet damage pathways. This paper discusses the MISSE-16 experiment, highlights the first use of the facility upgrades, and presents results from the extensive preflight material characterization that includes directional hemispherical reflectance, bidirectional reflectance, AFM, SEM, and electrical conductivity. Additionally, data showing the modification of these properties by ground-based exposure to space-like electron and atomic oxygen flux will be discussed. Finally, updates on deployment and initial check-out of the experiment on MISSE-FF will be presented. It is the ultimate goal of this program to provide validation for the development of ground based space weather simulation facilities and techniques.

Ryan Hoffman↗
NASA NTRS1990

The 27-28 October 1986 FIRE IFO cirrus case study: Comparison of satellite and aircraft derived particle size

Theoretical calculations predict that cloud reflectance in near infrared windows such as those at 1.6 and 2.2 microns should give lower reflectances than at visible wavelengths. The reason for this difference is that ice and liquid water show significant absorption at those wavelengths, in contrast to the nearly conservative scattering at wavelengths shorter than 1 micron. In addition, because the amount of absorption scales with the path length of radiation through the particle, increasing cloud particle size should lead to decreasing reflectances at 1.6 and 2.2 microns. Measurements at these wavelengths to date, however, have often given unpredicted results. Twomey and Cocks found unexpectedly high absorption (factors of 3 to 5) in optically thick liquid water clouds. Curran and Wu found expectedly low absorption in optically thick high clouds, and postulated the existence of supercooled small water droplets in place of the expected large ice particles. The implications of the FIRE data for optically thin cirrus are examined.

Wielicki, Bruce A.↗
NASA NTRS1976

Effect of radiant and convective heating on the optical and thermochemical properties of reusable surface insulation

A correlation between the morphology, chemistry, and optical properties of space shuttle candidate reusable surface insulation coatings were made to determine the proper test environment for flight evaluation studies. The optical properties (solar absorption coefficient and total hemispherical emittance) for each coating were obtained as a function of exposure to radiant and convectively heated environments since these parameters define the surface temperature of the material during flight. Results are presented which show these optical properties differ in the two environments and can be related to the coating's surface and bulk chemistry.

Stewart, D. A.↗
NASA NTRS1991

High quality flame deposited diamond films for infrared optical windows

The IR absorption in polycrystalline diamond films deposited in oxygen-acetylene flames is characterized using FTIR. The one-phonon absorption coefficient in the region from 7 to 12 microns that is related to extrinsic defects in the diamond films shows a strong dependence on the flame conditions as well as the substrate temperature. A high degree of diamond crystalline perfection, as judged from the undetectable one-phonon absorption, is achieved under the optimized deposition conditions for our flame setup. This is further supported by the sharp Raman peak at 1332/cm as well as the high purity in crystal orientation according to the X-ray diffraction pattern measured for the high quality diamond films.

Tzeng, Y.↗
NASA NTRS1976

Improvement of black nickel coatings

Selectively absorbing black nickel coatings are among the most optically efficient low cost coatings for use on flat plate solar collectors. However, a current Ni-Zn-S-O coating in use is quite susceptible to a humid environment, degrading badly in less than ten days at 38 C (100 F) at 95 percent relative humidity. Therefore, a black nickel formula was developed which can withstand such exposures with no loss of optical efficiency, solar absorption of 0.92 and an infrared emittance (at 100 C) of 1.00 were still present after 14 days of humidity exposure. This compares to a solar absorptance of only 0.72 for the previous formula after a similar time period. The electroplating bath and conditions were changed to obtain the more stable coating configuration. The effect of bath composition, temperature, pH, and plating current density and time on the coating composition, spectral optical properties and durability were investigated systematically.

Peterson, R. E.↗
NASA NTRS1989

Spectroscopic study of combustion diagnostics on hydroxyl radicals

Experimental observations of propane/air flames have been carried out. Measurements of hydroxyl (OH) radical concentration have been made using resonance line absorption techniques. A microwave-pumped low pressure discharge in argon and water vapor is employed to produce strong OH radical band radiation in the 308 nm region. This radiation is transmitted through the plume and absorption data is taken at various radial positions using an optical multichannel analyzer. This absorption data is used to compute OH number density using a model for the absorption band characteristics as a function of temperature based on an atlas of line strengths. A numerical computation of flow fields, temperature profile, OH number density and water vapor mass fraction profiles was carried out by using a technique of computational fluid dynamics (CFD). The results of CFD computation are compared with experimental observation with a good agreement.

Eskridge, Richard↗
NASA NTRS1990

Spectroscopic study of combustion diagnostics on hydroxyl radicals

Experimental observations of propane-air flames were performed. Measurements of hydroxyl (OH) radical concentration were made using resonance line absorption techniques. A microwave-pumped low pressure discharge in argon and water vapor is employed to produce strong OH radical band radiation in the 308 nm region. This radiation is transmitted through the plume and absorption data are taken at various radical positions using an optical multichannel analyzer. This absorption data is used to compute OH number density using a model for the absorption band characteristics as a function of temperature based on an atlas of line strengths. A numerical computation of flow fields, temperature profile and OH number density is carried out by using a technique of computational fluid dynamics (CFD). The results of CFD computation are good compared with experimental observation with a good agreement.

Hung, R. J.↗
NASA NTRS2011

Locating the Accretion Footprint on a Herbig Ae Star: MWC 480

Accretion is a fundamental process which establishes the dynamics of the protoplanetary disk and the final properties of the forming star. In solar-type stars, the star-disk coupling is determined by the magnetic field structure, which is responsible for funneling material from the disk midplane to higher latitudes on the star. Here, we use pan-chromatic data for the Herbig Ae star MWC 480 to address whether similar processes occur in intermediate-mass stars. MWC 480 has X-ray emission typical of actively accreting Herbig Ae stars, but with 5-9 x more photoelectric absorption than expected from optical and FUV data. We consider 3 sources for the absorption: the disk absorption in a wind or jet, and accretion. While we detect the disk in scattered light in are-analysis of archival HST data. the data are consistent with grazing illumination of the dust disk. We find that MWC 480's disk is stratified, geometrically thin, and is not responsible for the observed photoelectric absorption. MWC 480 drives a bipolar jet, but with a mass loss rate which is low compared to other Herbig Ae stars, where the outflow is more favorably oriented and enhanced photoelectric absorption is not seen. This excludes a jet or wind origin for the enhanced photoelectric absorption. We compare MWC 480's 0 VI emission with other Herbig Ae stars. The distribution of the emission in inclination, and lack of a correlation of profile shape and system inclination excludes equatorially-confined accretion for the FUSE Herbig Ae stars. The photoelectric absorption data further suggest that the accretion footprint on MWC 480 and other Herbig Ae stars is located at high temperate, rather than polar, latitudes. These findings support the presence of funneled accretion in MWC 480 and Herbig Ae stars, strengthening the parallel to T Tauri stars.

Grady, C. A.↗
NASA NTRS2015

Secured Optical Communications Using Quantum Entangled Two-Photon Transparency Modulation

A system and method is disclosed wherein optical signals are coded in a transmitter by tuning or modulating the interbeam delay time (which modulates the fourth-order coherence) between pairs of entangled photons. The photon pairs are either absorbed or not absorbed (transparent) by an atomic or molecular fluorescer in a receiver, depending on the inter-beam delay that is introduced in the entangled photon pairs. Upon the absorption, corresponding fluorescent optical emissions follow at a certain wavelength, which are then detected by a photon detector. The advantage of the disclosed system is that it eliminates a need of a coincidence counter to realize the entanglement-based secure optical communications because the absorber acts as a coincidence counter for entangled photon pairs.

Kojima, Jun↗
NASA NTRS2010

Using Whispering-Gallery-Mode Resonators for Refractometry

A method of determining the refractive and absorptive properties of optically transparent materials involves a combination of theoretical and experimental analysis of electromagnetic responses of whispering-gallery-mode (WGM) resonator disks made of those materials. The method was conceived especially for use in studying transparent photorefractive materials, for which purpose this method affords unprecedented levels of sensitivity and accuracy. The method is expected to be particularly useful for measuring temporally varying refractive and absorptive properties of photorefractive materials at infrared wavelengths. Still more particularly, the method is expected to be useful for measuring drifts in these properties that are so slow that, heretofore, the properties were assumed to be constant. The basic idea of the method is to attempt to infer values of the photorefractive properties of a material by seeking to match (1) theoretical predictions of the spectral responses (or selected features thereof) of a WGM of known dimensions made of the material with (2) the actual spectral responses (or selected features thereof). Spectral features that are useful for this purpose include resonance frequencies, free spectral ranges (differences between resonance frequencies of adjacently numbered modes), and resonance quality factors (Q values). The method has been demonstrated in several experiments, one of which was performed on a WGM resonator made from a disk of LiNbO3 doped with 5 percent of MgO. The free spectral range of the resonator was approximately equal to 3.42 GHz at wavelengths in the vicinity of 780 nm, the smallest full width at half maximum of a mode was approximately equal to 50 MHz, and the thickness of the resonator in the area of mode localization was 30 microns. In the experiment, laser power of 9 mW was coupled into the resonator with an efficiency of 75 percent, and the laser was scanned over a frequency band 9 GHz wide at a nominal wavelength of approximately equal to 780 nm. Resonance frequencies were measured as functions of time during several hours of exposure to the laser light. The results of these measurements, plotted in the figure, show a pronounced collective frequency drift of the resonator modes. The size of the drift has been estimated to correspond to a change of 8.5 x 10(exp -5) in the effective ordinary index of refraction of the resonator material.

Matsko, Andrey↗
NASA NTRS2008

Black Carbon Concentration from Worldwide Aerosol Robotic Network (AERONET)

Worldwide black carbon concentration measurements are needed to assess the efficacy of the carbon emissions inventory and transport model output. This requires long-term measurements in many regions, as model success in one region or season does not apply to all regions and seasons. AERONET is an automated network of more than 180 surface radiometers located throughout the world. The sky radiance measurements obtained by AERONET are inverted to provide column-averaged aerosol refractive indices and size distributions for the AERONET database, which we use to derive column-averaged black carbon concentrations and specific absorptions that are constrained by the measured radiation field. This provides a link between AERONET sky radiance measurements and the elemental carbon concentration of transport models without the need for an optics module in the transport model. Knowledge of both the black carbon concentration and aerosol absorption optical depth (i.e., input and output of the optics module) will enable improvements to the transport model optics module.

Schuster, Greg↗
NASA NTRS1978

Ground-to-space optical power transfer

Using laser radiation as the energy input to a rocket, it is possible to consider the transfer of large payloads economically between low initial orbits and higher energy orbits. In this paper we will discuss the results of an investigation to use a ground-based High Energy Laser (HEL) coupled to an adaptive antenna to transmit multi-megawatts of power to a satellite in low-earth orbit. Our investigation included diffraction effects, atmospheric transmission efficiency, adaptive compensation for atmospheric turbulence effects, including the servo bandwidth requirements for this correction, and the adaptive compensation for thermal blooming. For these evaluations we developed vertical profile models of atmospheric absorption, strength of optical turbulence (CN2), wind, temperature, and other parameters necessary to calculate system performance. Our atmospheric investigations were performed for CO2, 12C18O2 isotope, CO and DF wavelengths. For all of these considerations, output antenna locations of both sea level and mountain top (3.5 km above sea level) were used. Several adaptive system concepts were evaluated with a multiple source phased array concept being selected. This system uses an adaption technique of phase locking independent laser oscillators. When both system losses and atmospheric effects were assessed, the results predicted an overall power transfer efficiency of slightly greater than 50%.

Mevers, G. E.↗
NASA NTRS2012

Ground and Airborne Methane Measurements with an Optical Parametric Amplifier

We report on ground and airborne atmospheric methane measurements with a differential absorption lidar using an optical parametric amplifier (OPA). Methane is a strong greenhouse gas on Earth and its accurate global mapping is urgently needed to understand climate change. We are developing a nanosecond-pulsed OPA for remote measurements of methane from an Earth-orbiting satellite. We have successfully demonstrated the detection of methane on the ground and from an airplane at approximately 11-km altitude.

Numata, Kenji↗
NASA NTRSDate not supplied

Quantum Mechanical Simulations of Dynamics of Electronic Excitations in Low-Dimensional Photovoltaics Materials

Dynamics of electronically excited states including exciton generation and relaxation, exciton-exciton interaction, and charge/energy transfer and transport, are critical to understanding and optimizing photovoltaic materials. Although considerable progress has been made, accurate experimental characterization of such crucial dynamics remains extremely challenging, especially in low-dimensional materials. In this talk, I will discuss how the advancement of quantum mechanical simulations of the dynamics of electronic excitations can reveal the physical mechanisms hindering or improving solar energy harvest. Specifically, we find that surface dangling-bond defects on silicon quantum dots cause rapid charge recombination and low carrier mobility in the inorganic-organic PV cells. Although small quantum dots are essentially free of defects, their optical gaps are too large. To solve this issue, a full-spectrum-light-absorption scheme is computationally designed, taking advantage of complexity and flexibility of low-dimensional materials consisting of different characteristics and dimensions. In this scheme the multifunctional ligands are used to (1) passivate against oxidation, (2) facilitate interfacial charge transfer, and (3) improve both charge transport and optical absorption. A joint theoretical and experimental study has demonstrated the feasibility of this approach. Finally, I will briefly talk about how this scheme and the well-tested quantum mechanical simulations can be employed to help improve energy-conversion efficiency in perovskite photovoltaics including perovskite-based tandem cells.

Zhigang Wu↗
NASA NTRS2001

Remote Sensing of Aerosol and Non-Aerosol Absorption

Remote sensing of aerosol from the new satellite instruments (e.g. MODIS from Terra) and ground based radiometers (e.g. the AERONET) provides the opportunity to measure the absorption characteristics of the ambient undisturbed aerosol in the entire atmospheric column. For example Landsat and AERONET data are used to measure spectral absorption of sunlight by dust from West Africa. Both Application of the Landsat and AERONET data demonstrate that Saharan dust absorption of solar radiation is several times smaller than the current international standards. This is due to difficulties of measuring dust absorption in situ, and due to the often contamination of dust properties by the presence of air pollution or smoke. We use the remotely sensed aerosol absorption properties described by the spectral sin le scattering albedo, together with statistics of the monthly optical thickness for the fine and coarse aerosol derived from the MODIS data. The result is an estimate of the flux of solar radiation absorbed by the aerosol layer in different regions around the globe where aerosol is prevalent. If this aerosol forcing through absorption is not included in global circulation models, it may be interpreted as anomalous absorption in these regions. In a preliminary exercise we also use the absorption measurements by AERONET, to derive the non-aerosol absorption of the atmosphere in cloud free conditions. The results are obtained for the atmospheric windows: 0.44 microns, 0.66 microns, 0.86 microns and 1.05 microns. In all the locations over the land and ocean that were tested no anomalous absorption in these wavelengths, was found within absorption optical thickness of +/- 0.005.

Kaufman, Y. J.↗
NASA NTRS1993

Total ozone and aerosol optical depths inferred from radiometric measurements in the Chappuis absorption band

A second-derivative smoothing technique, commonly used in inversion work, is applied to the problem of inferring total columnar ozone amounts and aerosol optical depths. The application is unique in that the unknowns may be solved for directly without employing standard inversion methods. It is shown, however, that by employing inversion constraints, better solutions are normally obtained. The method is quite versatile and able to deal with varying total ozone and various aerosol size distributions. The technique is applied first in simulation, then to 119 days of measurements taken in Tucson, Arizona, that are compared to TOMS values for the same dates. The technique is also applied to two measurements taken at Mauna Loa, Hawaii, for which Dobson ozone values are available in addition to the TOMS values, and the results agree to within 15 percent. It is also shown through simulations that additional information can be obtained from measurements outside the Chappuis band. This approach reduces the bias and spread of the estimated total ozone and is unique in that it uses measurements from both the Chappuis and Huggins absorption bands.

Flittner, D. E.↗
NASA NTRS1972

The interaction of infrared radiation with the eye: A review of the literature

A compilation of data concerning the effects of infrared radiation on the eye is presented. Information in the following areas is included: (1) transmission and absorption of infrared radiation by the ocular tissues, (2) range of infrared radiation which is harmful to the ocular tissues, (3) infrared radiation thresholds of the various oscular tissues, and (4) infrared radiation transmission and absorption of current optic materials.

Turner, H. S.↗