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At least 451 records · Page 25

An Approach to Shape Parameterization Using Laboratory Hypervelocity Impact Experiments

NASA’s Orbital Debris Program Office relies on laboratory-based impact tests to supplement the measurement data of on-orbit events that defines the orbital debris environment. These experiments provide information that is essential to interpreting the radar and optical measurements of orbital fragmentation events into useful metrics, such as characteristic size of the debris, and to providing a better understanding of the distributions of fragment populations in terms of their masses, material constituents, fragment densities, cross-sectional areas, area-to-mass ratios, shapes, etc. The Satellite Orbital Debris Characterization Impact Test (SOCIT) was a notable laboratory impact experiment conducted in 1992 using a surplus U.S. Navy Transit navigation satellite of the 1960s. The data from this ground-based experiment were combined with on-orbit measurements to develop the NASA Standard Satellite Breakup Model (SSBM). To account for advancements in satellite design and construction since, a new impact test series – DebriSat – was conducted in 2014. This test utilized a high-fidelity mock-up spacecraft that better represents the materials and construction techniques used to design and manufacture modern spacecraft. Together, these tests offer valuable data to model an orbital debris environment composed of legacy and modern spacecraft. This paper presents an overview of the two laboratory impact tests, comparing their fragment parameter distributions with each other and with relevant distributions from the NASA SSBM. The categorization and descriptions of fragment shapes are of significant interest for future work, yet there are marked differences in the definitions of shape categories between each dataset. The categorizations of constituent materials, and the measurement techniques employed to populate these two datasets, are also different. New rubrics simplify and equate the categorizations between datasets to aid comparative analyses and to facilitate the potential use of both datasets in tandem with future environmental debris models. A preferred approach to classifying shape across disparate datasets uses the characteristic-length dimensions, and a simplified shape classification based on physical, solid-body dimensions, to mathematically construct an encapsulating right-circular cylinder that represents the fragment. The ratio of cylinder length-to-diameter (L:D) then provides a single continuum value for shape that is strongly correlated with its designated shape and size. This metric can then be used to further assess the distribution of shape with populations of other fragment characteristics within these datasets. The shape parameterization using the L:D ratios of right-circular cylinders is discussed.

John H Seago↗

Research on design feasibility of high-power light-weight dc-to-dc converters for space power applications

Utilizing knowledge gained from past experience with experimental current-or-voltage step-up dc-to-dc converter power stages operating at output powers up to and in excess of 2 kW, a new experimental current-or-voltage step-up power stage using paralleled bipolar junction transistors (BJTs) as the controlled power switch, was constructed during the current reporting period. The major motivation behind the construction of this new experimental power stage was to improve the circuit layout so as to reduce the effects of stray circuit parasitic inductances resulting from excess circuit lead lengths and circuit loops, and to take advantage of the layout improvements which could be made when some recently-available power components, particularly power diodes and polypropylene filter capacitors, were incorporated into the design.

Wilson, T. G.↗

Entropy condition satisfying approximations for the full potential equations of transonic flow

A class of conservative difference approximations for the steady full potential equation was presented. They are, in general, easier to program than the usual density biasing algorithms, and in fact, differ only slightly from them. Rigorous proof indicated that these new schemes satisfied a new discrete entropy inequality, which ruled out expansion shocks, and that they have sharp, steady, discrete shocks. A key tool in the analysis is the construction of a new entropy inequality for the full potential equation itself. Results of some numerical experiments using the new schemes are presented.

Osher, S.↗

Entropy condition satisfying approximations for the full potential equation of transonic flow

A class of conservative difference approximations for the steady full potential equation was presented. They are, in general, easier to program than the usual density biasing algorithms, and in fact, differ only slightly from them. Rigorous proof indicated that these new schemes satisfied a new discrete entropy inequality, which ruled out expansion shocks, and that they have sharp, steady, discrete shocks. A key tool in the analysis is the construction of a new entropy inequality for the full potential equation itself. Results of some numerical experiments using the new schemes are presented.

Osher, S.↗

Uncovering New Physics in the Cosmic Microwave Background: Developing Novel Theoretical Models and Machine-Learning-Powered Constraints

The search for evidence of new physics via its signatures in the cosmos is a cornerstone goal of the Office of High Energy Physics in the DOE Office of Science. Indeed, the current concordance cosmological model provides intriguing hints for beyond-the-standard-model (BSM) physics, such as dark matter and dark energy. Recently, a potential breakdown has appeared in this model, which could be initial evidence toward a further important revision in our fundamental theoretical understanding of cosmology. This breakdown is reflected in disagreements between inferences of the current expansion rate of the universe, H 0 (the Hubble constant), based on indirect, cosmological data (e.g., from the early universe) and based on direct, local measurements. Despite significant effort, a compelling new concordance cosmological model has yet to be found; achieving significant progress on this front was the first major focus of the project. Theoretical considerations indicate that if the observational discrepancies are not due to systematic errors, they strongly suggest new physics operating in the redshift range just prior to recombination, when cosmic microwave background (CMB) photons last scattered. Crucially, almost all such models produce unique signatures in the CMB temperature and polarization power spectra, which will be measured with unprecedented precision by ongoing and upcoming experiments, including the DOE-supported CMB-S4 project. However, these subtle hints of new physics must be uncovered from beneath a swath of Galactic and extragalactic foreground contamination. Current CMB analysis methods, although powerful, do not optimally infer the CMB power spectrum in the presence of non-Gaussian foregrounds. There is thus scope for theoretical improvement in this foundational challenge of cosmological inference, which formed the second major focus of the project. The primary objectives of the project were two-fold: (1) to develop new theoretical models in cosmology that can restore concordance amongst the full suite of cosmological data sets, thereby potentially providing evidence of novel BSM physics; (2) to develop new theoretical machinery to enable significant sensitivity improvements in searches for new physics in cosmology, particularly via the CMB power spectrum. The two objectives are intertwined, as the analysis methodology improvements in (2) will enable the tightest possible constraints on the signatures of new physics predicted by the novel scenarios in (1). The theoretical approaches to restore concordance focused on models involving novel scalar field dynamics in the pre-recombination universe (the “early dark energy” scenario and modifications thereof), as well as couplings between this field and other components in the standard cosmological model, such as dark matter. We also studied a model featuring a generalization of the decaying dark matter scenario, in which a sub-component of dark matter converts into dark radiation at late times in cosmic history. While these ideas are mostly driven by phenomenological considerations, this tactic has proven extremely successful in cosmology throughout the past few decades, including in the early history of evidence for dark matter and dark energy. The new theoretical machinery envisioned in (2) is undergirded by developments in signal processing and machine learning, which will enable improvements in CMB power spectrum estimation in the presence of non-Gaussian foreground contaminants. In turn, this will yield optimal sensitivity in searches for new physics in the CMB, by maximizing the cosmological information that is extracted from this observable. The most ambitious outcome of this work would be the construction of a new cosmological model that restores concordance amongst data sets. Although the individual models studied here did not fully achieve that goal, significant progress in narrowing down the model space was made, as described below. Moreover, the outcome of the methodological improvements in (2) will significantly impact a wide range of theoretical cosmology, by enabling the tightest possible constraints on any model that leaves novel signatures in the CMB temperature and polarization power spectra.

79 ASTRONOMY AND ASTROPHYSICS↗

Crewbot Suspension Design

Planetary Surface Robot Work Crews (RWC) represent a new class of construction robots for future deployment in planetary exploration. Rovers currently being used for the RWC platform lack the load carrying capabilities required in regular work. Two new rovers, dubbed CrewBots, being designed in JPL's Planetary Robotics Lab specifically for RWC applications greatly increase the load carrying capabilities of the platform. A major component of the rover design was the design of the rocker type suspension, which increases rover mobility. The design of the suspension for the Crewbots departed from the design of recent rovers. While many previous rovers have used internal bevel gear differentials, the increased load requirements of the Crewbots calls for a more robust system. The solution presented is the use of an external modified three-bar, slider-linkage, rocker-style suspension that increases the moment arm of the differential. The final product is a suspension system capable of supporting the extreme loading cases the RWC platform presents, without consuming a large portion of the Crewbots' internal space.

Wood, Nathan A.↗

Lunar surface chemistry - A new imaging technique

Detailed chemical maps of the lunar surface have been constructed by applying a new weighted-filter imaging technique to Apollo 15 and Apollo 16 X-ray fluorescence data. The data quality improvement is amply demonstrated by (1) modes in the frequency distribution, representing highland and mare soil suites, which are not evident before data filtering, and (2) numerous examples of chemical variations which are correlated with small-scale (about 15 kilometer) lunar topographic features.

Andre, C. G.↗

Structural Dynamic Assessment of the GN2 Piping System for NASA's New and Powerful Reverberant Acoustic Test Facility

The National Aeronautics and Space Administration (NASA) Glenn Research Center (GRC) has led the design and build of the new world-class vibroacoustic test capabilities at the NASA GRC's Plum Brook Station in Sandusky, Ohio, USA from 2007 to 2011. SAIC-Benham has completed construction of a new reverberant acoustic test facility to support the future testing needs of NASA's space exploration program and commercial customers. The large Reverberant Acoustic Test Facility (RATF) is approximately 101,000 cubic feet in volume and was designed to operate at a maximum empty chamber acoustic overall sound pressure level (OASPL) of 163 dB. This combination of size and acoustic power is unprecedented amongst the world s known active reverberant acoustic test facilities. Initial checkout acoustic testing was performed on March 2011 by SAIC-Benham at test levels up to 161 dB OASPL. During testing, several branches of the gaseous nitrogen (GN2) piping system, which supply the fluid to the noise generating acoustic modulators, failed at their T-junctions connecting the 12 in. supply line to their respective 4 in. branch lines. The problem was initially detected when the oxygen sensors in the horn room indicated a lower than expected oxygen level from which was inferred GN2 leaks in the piping system. In subsequent follow up inspections, cracks were identified in the failed T-junction connections through non-destructive evaluation testing. Through structural dynamic modeling of the piping system, the root cause of the T-junction connection failures was determined. The structural dynamic assessment identified several possible corrective design improvements to the horn room piping system. The effectiveness of the chosen design repairs were subsequently evaluated in September 2011 during acoustic verification testing to 161 dB OASPL.

McNelis, Mark E.↗

Studying Type II supernovae as cosmological standard candles using the Dark Energy Survey

ABSTRACT Despite vast improvements in the measurement of the cosmological parameters, the nature of dark energy and an accurate value of the Hubble constant (H0) in the Hubble–Lemaître law remain unknown. To break the current impasse, it is necessary to develop as many independent techniques as possible, such as the use of Type II supernovae (SNe II). The goal of this paper is to demonstrate the utility of SNe II for deriving accurate extragalactic distances, which will be an asset for the next generation of telescopes where more-distant SNe II will be discovered. More specifically, we present a sample from the Dark Energy Survey Supernova Program (DES-SN) consisting of 15 SNe II with photometric and spectroscopic information spanning a redshift range up to 0.35. Combining our DES SNe with publicly available samples, and using the standard candle method (SCM), we construct the largest available Hubble diagram with SNe II in the Hubble flow (70 SNe II) and find an observed dispersion of 0.27 mag. We demonstrate that adding a colour term to the SN II standardization does not reduce the scatter in the Hubble diagram. Although SNe II are viable as distance indicators, this work points out important issues for improving their utility as independent extragalactic beacons: find new correlations, define a more standard subclass of SNe II, construct new SN II templates, and dedicate more observing time to high-redshift SNe II. Finally, for the first time, we perform simulations to estimate the redshift-dependent distance-modulus bias due to selection effects.

79 ASTRONOMY AND ASTROPHYSICS↗

Modulating Energy Level on an A‐D‐A′‐D‐A‐Type Unfused Acceptor by a Benzothiadiazole Core Enables Organic Solar Cells with Simple Procedure and High Performance

Unfused‐ring acceptors (UFAs) have gained considerable research attention as they offer simple chemical structures through simplified synthesis methods, which would boost the commercialization of organic solar cells (OSCs). Recently, a new small molecule acceptor (SMA) named Y6 was reported, yielding high‐performance OSCs. Herein, the Y6‐like A‐DA′D‐A framework is developed to A‐D‐A′‐D‐A‐type backbone adopted in constructing UFAs. Two new Y6‐like UFAs are synthesized within four steps and the effect of noncovalent atoms at the central electron‐deficient core on material properties and device performances is studied. It is found that the introduction of fluorine atoms can bring larger red‐shift in the absorption spectra and better aggregation of the resulting UFA film states compared with those of oxygen atoms. Interestingly, the variations in the noncovalent interaction atoms induce different intermolecular charge transfer between donors and UFAs. When blended with another economical donor, PTQ10, F substitution at the benzothiadiazole ring is more effective than O substitution, leading to the increased short‐circuit current density ( J SC ) and higher efficiency of over 12%, among the best performances of UFA‐based OSCs. This contribution demonstrates the appropriate introduction of noncovalent interaction is a promising method for tuning energy levels, absorption, and aggregation of UFAs for high‐performance OSCs.

Yu, Han↗

14 MeV DT Neutron Test Facility at the Sandia Ion Beam Laboratory

A recently completed LDRD project has provided a new facility at Sandia for testing effects of energetic neutrons on electronic components. 14 MeV neutrons are produced with a deuterium ion beam onto a thin-film tritide target. The goal of the project was to increase the neutron fluence to levels needed for radiation effects testing and qualification. This goal was achieved through two technical advances. First, a new multi-layer target concept was developed to reduce the rate of tritium loss from the target by isotope exchange, thereby reducing tritium usage and increasing target lifetime. The second advance was the construction of a new test chamber designed to maximize neutron flux at test locations. Together, these increased the available neutron fluence by several orders of magnitude. This new capability is being used in tests for Sandia nuclear weapon programs, evaluation of commercial parts such as highly-scaled CMOS SRAM lCs, and tests of new devices under development at Sandia such as lll-V HBTs, gallium nitride high-voltage diodes, and for fundamental studies of physical mechanisms of device failure.

36 MATERIALS SCIENCE↗

LLNS Request for Variance From 10 CFR 851 for Construction of LLNL Emergency Operations Center

Lawrence Livermore National Security, LLC (LLNS) is submitting the following variance application requesting the use of the State of California’s Occupational Safety and Health Administration (Cal/OSHA) Regulations in lieu of Title 10 Code of Federal Regulations Part 851 (10 CFR 851, the Rule), Worker Safety and Health Program, Subpart B (Program Requirements), Subpart C (Specific Program Requirements), and Appendix A (Worker Safety and Health Functional Areas), solely with respect to the construction of the new Lawrence Livermore National Laboratory (LLNL) Emergency Operations Center (EOC) facility. The request is in support of the National Nuclear Security Administration (NNSA) “pilot” to streamline the delivery of commercial-like line item construction projects under $50 million. This pilot is aligned with the approved NA-50 safety approach for the projects in the pilot. This pilot is to test and demonstrate innovation leading to a reduced cost of construction for building commercial type structures at Department of Energy (DOE)/NNSA facilities. The variance proposes to permit local/regional construction businesses contracted to Management & Operation contractor operated facilities to bid, operate, execute, and comply with safety and health standards they utilize in their business outside of the DOE Complex. This will permit compliance to standards that are as safe and healthful as those in 10 CFR 851 without confusion, additional cost, and inefficiencies associated with the burden of compliance to an unfamiliar regulatory spectrum.

99 GENERAL AND MISCELLANEOUS↗

NASA Lunar Mining and Construction Activities and Plans

The Space Exploration Policy enacted by the US Congress in 2005 calls for the US National Aeronautics and Space Administration (NASA) to implement a sustained and affordable human and robotic program to explore the solar system and beyond; Extend human presence across the solar system, starting with a human return to the Moon by the year 2020, in preparation for human exploration of Mars and other destinations; Develop the innovative technologies, knowledge, and infrastructures both to explore and to support decisions about the destinations for human exploration; and Promote international and commercial participation in exploration to further U.S. scientific, security, and economic interests. In 2006, NASA released the Lunar Architecture Study, which proposed establishing a lunar Outpost on the Moon with international participation to extend human presence beyond Earth's orbit, pursue scientific activities, use the Moon to prepare for future human missions to Mars, and expand Earth s economic sphere. The establishment of sustained human presence on the Moon for science and exploration combines the design, integration, and operation challenges experienced from both the short Apollo lunar missions and the build-up and sustained crew operations of the International Space Station (ISS). Apollo experience reminds developers and mission planners that hardware must operate under extremely harsh environmental and abrasive conditions and every kilogram of mass and payload must be critical to achieve the mission s objectives due to the difficulty and cost of reaching the lunar surface. Experience from the ISS reminds developers and mission planners that integration of all hardware must be designed and planned from the start of the program, operations and evolution of capabilities on a continuous basis are important, and long-term life-cycle costs and logistical needs are equally or more important than minimizing early development and test costs. Overarching all of this is the need to implement efforts that are sustainable and affordable. One area NASA is developing that can significantly change how systems required for sustained human presence are designed and integrated, as well as potentially break our reliance on Earth supplied logistics, is In-Situ Resource Utilization (ISRU). ISRU, also known living off the land, involves the extraction and processing of local resources into useful products. In particular, the ability to make propellants, life support consumables, fuel cell reagents, and radiation shielding can significantly reduce the cost, mass, and risk of sustained human activities beyond Earth. Also, the ability to modify the lunar landscape for safer landing, transfer of payloads from the lander an outpost, dust generation mitigation, and infrastructure placement and buildup are also extremely important for long-term lunar operations. While extra-terrestrial excavation, material handling and processing, and site preparation and construction may be new to NASA and other space agencies, there is extensive terrestrial hardware and commercial experience that can be leveraged. This paper will provide an overview of current NASA activities in lunar ISRU mining and construction and how terrestrial experience in these areas are important to achieving the goal of affordable and sustainable human exploration.

Sanders, Gerald B.↗

Sorafenib derivatives-functionalized gold nanoparticles confer protection against tumor angiogenesis and proliferation via suppression of EGFR and VEGFR-2

Sorafenib is a multi-kinase inhibitor that has been highlighted as a tumor suppressor due to its anti-proliferative and anti-angiogenic properties, whereas the clinical application of Sorafenib is restricted by the side effects it may cause. The past decade has witnessed the development of a series of sorafenib derivatives to improve the clinical performance of sorafenib. Gold nanoparticles (AuNPs) have been widely utilized in drug delivery systems due to their unique properties, including biocompatible nature, simple preparation, and easy surface modification. Herein, this study is aimed to investigate the anti-tumor effects of new sorafenib derivatives-capped gold nanoparticles (AuNPs-New Sor) in tumor formation and metastasis as well as the underlying mechanisms. Initially, new sorafenib derivatives were constructed and combined with AuNPs to form AuNPs-New Sor, and the properties of synthesized AuNPs-New Sor were identified in a mouse model of tumorigenesis. The effect of AuNPs-New Sor on tumor vascular normalization was investigated by assessing vascular permeability and perfusion rate. Next, we evaluated the effect of AuNPs-New Sor on migration and viability of tumor cells and human umbilical vein endothelial cells (HUVECs) as well as on HUVEC angiogenesis in vitro. A melanoma mouse model was further established for in vivo substantiation of the anti-tumor effect of AuNPs-New Sor. According to the results, AuNPs could deliver new sorafenib derivatives into tumor tissues and downregulate the expression of epidermal growth factor receptor (EGFR) and vascular endothelial growth factor receptor-2 (VEGFR-2), thereby suppressing tumor migration, EMT, and angiogenesis in vitro. In addition, AuNPs-New Sor displayed competitive anti-tumor activities in vivo. Taken together, AuNPs-New Sor may attenuate tumor development and angiogenesis through downregulation of EGFR and VEGFR-2.

60 APPLIED LIFE SCIENCES↗

Life Cycle Assessment and Design of LignoBlock: A Lignin Bound Block on the Path Towards a Green Transition of the Construction Industry

Lignin-based biopolymer-bound soil composites (BSCs) are a new class of sustainable construction materials that utilize a bio-based biopolymer — lignin — as a binder. Prior use of lignin suggests that lignin is a promising candidate for the development of bio-based construction materials. Inspired by these applications, lignin-based BSCs were developed using lignoboost lignin, lignoforce lignin, alkali lignin, and hydrolysis lignin. Uni-axial compressive testing of lignin-based BSC shows that the compressive strength for these BSCs range from 1.6–8.1 MPa, which makes them appropriate for low compressive strength construction applications. We performed a life cycle assessment (LCA) of lignin-based BSC, with the functional unit being a CMU-sized block ( V =6423 cm -3 ). The major advantage of BSC lies in the elimination of ordinary portland cement, which is common to many construction materials, including many forms of concrete. Furthermore, the use of lignin in lignin-based BSC results in carbon sequestration (lignin ≈ 60 wt% carbon), potentially making construction materials made from lignin-based BSC carbon negative. Additionally, a design guide for estimating the life cycle carbon footprint of lignin-based BSC for a required compressive strength was developed. By utilizing the results from material tests and the LCA, designers are now able to use lignin effectively in construction applications, as they can now design lignin-based BSC for a target compressive strength with a full understanding of the life cycle carbon footprint implications.

Lignin↗

The upgrade of the ALICE TPC with GEMs and continuous readout

The upgrade of the ALICE TPC will allow the experiment to cope with the high interaction rates foreseen for the forthcoming Run 3 and Run 4 at the CERN LHC. In this article, we describe the design of new readout chambers and front-end electronics, which are driven by the goals of the experiment. Gas Electron Multiplier (GEM) detectors arranged in stacks containing four GEMs each, and continuous readout electronics based on the SAMPA chip, an ALICE development, are replacing the previous elements. The construction of these new elements, together with their associated quality control procedures, is explained in detail. Finally, the readout chamber and front-end electronics cards replacement, together with the commissioning of the detector prior to installation in the experimental cavern, are presented. After a nine-year period of R&D, construction, and assembly, the upgrade of the TPC was completed in 2020.

47 OTHER INSTRUMENTATION↗

Interfacial Fabrication of Supramolecular Polymer Networks Using Mussel-Inspired Catechol–Iron Complexes

The liquid–liquid interface provides a promising platform to construct supramolecular polymers and materials with advanced functions. However, supramolecular polymerization at the interface usually requires monomers with different or even orthogonal solubilities, which significantly limit the number of usable monomers. Here, in this work, we report a new strategy to construct supramolecular polymer networks at the oil–water interface using a water-soluble catechol–iron complex and an oil-soluble diend-functionalized polymer. Owing to the dynamic catechol–iron coordination bond and imine bond, the resulting supramolecular polymer networks demonstrate excellent dynamic features and responsiveness to different stimuli including the pH, redox, competing ligands, and temperature. With a supramolecular polymer network serving as a building block, emulsions and 2D films can be generated that have potential applications in encapsulation, release, and molecular separation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

VLBI: A Fascinating Technique for Geodesy and Astrometry

Since the 1970s Very Long Baseline Interferometry (VLBI) has proven to be a primary space-geodetic technique by determining precise coordinates on the Earth, by monitoring the variable Earth rotation and orientation with highest precision, and by deriving many other parameters of the Earth system. VLBI provides an important linkage to astronomy through, for instance, the determination of very precise coordinates of extragalactic radio sources. Additionally, it contributes to determining parameters of relativistic and cosmological models. After a short review of the history of geodetic VLBI and a summary of recent results, this paper describes future perspectives of this fascinating technique. The International VLBI Service for Geodesy and Astrometry (IVS), as a service of the International Association of Geodesy (IAG) and the International Astronomical Union (IAU), is well on its way to fully defining a next generation VLBI system, called VLBI2010. The goals of the new system are to achieve on scales up to the size of the Earth an accuracy of 1 mm in position and of 0.1 mm/year in velocity. Continuous observations shall be carried out 24 h per day 7 days per week in the future with initial results to be delivered within 24 h after taking the data. Special sessions, e.g. for monitoring the Earth rotation parameters, will provide the results in near real-time. These goals require a completely new technical and conceptual design of VLBI measurements. Based on extensive simulation studies, strategies have been developed by the IVS to significantly improve its product accuracy through the use of a network of small (approx 12 m) fast-slewing antennas. A new method for generating high precision delay measurements as well as improved methods for handling biases related to radio source structure, system electronics, and deformations of the antenna structures has been developed. Furthermore, as of January 2012, the construction of ten new VLBI2010 sites has been funded, with good prospects for one dozen more antennas, which will improve the geographical distribution of geodetic VLBI sites on Earth and provide an important step toward a global VLBI2010 network. Within this paper, the Global Geodetic Observing System (GGOS) of the IAG will also be introduced and the contribution of VLBI to GGOS will be described.

Geodesy↗