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At least 451 records · Page 25

Collaboration on SBIR/TTO Phase II Project for Optical QC Device and Collaboration on SBIR/TTO Phase II-b Project for Advanced Quality Inspection Device Development: Cooperative Research and Development CRADA Number CRD-16-00652 (Final Report)

The overall goal of this program is to develop and commercialize a turnkey quality control solution for the entire PEM fuel cell manufacturing process including membrane, gas diffusion layers, catalyst, and assembled systems. This quality control solution is unique to each customer’s specific needs but includes a suite of in-line quality control systems for roll-to-roll manufacturing that can target thin, transparent membrane as well as opaque membrane, catalyst, and GDLs. The Phase II developed the CPNUVV system for thin, transparent membrane that operates using polarized filters to enhance defect resolution and determine thickness. However, PEM material manufacturers want a complete, turnkey solution for all components of the PEM fuel cell. In the Phase IIB, Mainstream will partner with NREL, and transition reflectance technology NREL developed (US Patent 9,234,843) to operate in real-time on a web-line to develop a total solution to PEM quality control. The device will identify and mark defects as well as monitor materials thickness in real-time to improve line efficiency and to reduce waste. The research performed at NREL under this CRADA increases the basis of knowledge about optical inspection methods, how they perform with regards to fuel cell component materials, and how they can be implemented in in-line, real-time configurations to provide quality inspection for roll-to-roll (R2R) manufacturing. Methods explored were found to be sensitive to catalyst loading in electrodes on both membrane and gas diffusion media substrates and to membrane thickness, across a broad range of thickness. The latter capability is novel and now patented and provides a previously unstudied and undemonstrated capability for R2R manufacturing of membranes.

30 DIRECT ENERGY CONVERSION↗

Use of Computed Tomography for Characterizing Materials Grown Terrestrially and in Microgravity

Computed Tomography (CT) has advanced considerably since being responsible for such dramatic advances in diagnostics within the medical field. It has become a major tool in non destructive evaluation (NDE), and is used in many fields as diverse as coal-mining to metal solidification to examination of rock cores. A review of industrial applications has been written by Dennis. It is only recently that the technique has been seriously used to determine composition through precise measurement of density. While such applications are restricted to cases when there is no ambiguity in the relationship of composition to density. Thus alloy solid solutions lend themselves to compositional analysis provided there is a large change in density with composition. The technique is most useful when rapid non-destructive evaluation is needed. Such cases will occur with samples returning from the International Space Station (ISS) when knowledge of the results could affect future strategies for processing of on-board samples. Experiments from those Principal Investigators (PI) that are most likely to benefit from early CT scanning are discussed. With a dearth of samples, the major emphasis in the first part of this project has been on preparing suitable standards, optimizing the CT technique for these applications, and using the CT system to determine density variations with temperature. An interesting application of CT has been in the examination of meteorites, which can be classified as space-grown materials and will certainly have solidified in a low gravity environment.

Gillies, Donald C.↗

Recommendations for UAS Crew Ratings. Pilot Ratings and Authorization Requirements for UAS

This position paper is intended to recommend the minimum certificate and rating requirements for a pilot to operate an Unmanned Aircraft System (UAS) in the National Airspace System. The paper will recommend the minimum requirements based on the Knowledge, Skills, and Abilities (KSA) required of a UAS pilot and show how those compare to the KSAs required by regulation for manned-aircraft pilots. The paper will provide substantiation based on studies conducted using analyses, simulation and flight experience. The paper is not yet complete; only initial working material is included. The material provided describes the body of work completed thus far and the plan for remaining tasks to complete the recommendation. The HSI Pilot KSA document provides an analysis of the knowledge, skills, and abilities required for UAS operation in the NAS. It is the source document used for the position paper.

Source record↗

The CAESAR New Frontiers Mission: Comet Surface Sample Acquisition and Preservation

NASA recently selected the Comet Astrobiology Exploration Sample Return (CAESAR) mission for Phase A study in the New Frontiers Program. This mission will acquire and return to Earth for laboratory analysis at least 80 g of surface material from the nucleus of comet 67P/Churyumov-Gerasimenko (hereafter 67P). CAESAR will characterize the surface region sampled, preserve the sample in a pristine state, and return evolved volatiles by capturing them in a separate gas reservoir. The system protects both volatile and non-volatile components from contamination or alteration thatwould hamper their scientific analysis. Laboratory analyses of comet samples provide unparalleled knowledge about the presolar history through the initial stages of planet formation to the origin of life.

CAESAR↗

L’Ralph Integration and Testing

This paper describes the plans, flows, key facilities, components and equipment necessary to fully integrate, functionally test, qualify and calibrate the L’Ralph instrument on the Lucy observatory. Lucy is currently in the final design and fabrication phase (phase C) of mission development. It is scheduled to launch out of Cape Canaveral, Florida, in October 2021. Lucy will be the first space mission to study the Trojan asteroids associated with Jupiter, that are thought to be remnants of the primordial material that formed the outer planets. Lucy will fly by and carry out remote sensing on six different Trojan asteroids. The mission takes its name from the fossilized human ancestor (called “Lucy” by her discoverers) whose skeleton provided unique insight into humanity's evolution. Likewise, the Lucy mission will revolutionize our knowledge of planetary origins and the formation of the solar system. L’Ralph is one of the instruments on Lucy and it is provided by the NASA Goddard Space Flight Center (GSFC). L’Ralph is a combined multi-band visible imager (the Multi-spectral Visible Imaging Camera, MVIC, 0.4-0.85 microns) and wedge-filter infrared spectrometer (Linear Etalon Imaging Spectral Array, LEISA, 1-3.6 microns). LEISA will allow the team to look for the absorption lines that serve as the fingerprints for different silicates, ices and organics that likely will be on the surface of the Trojan asteroids. MVIC will take color images of the Trojan asteroid targets, and help determine how active they are. This paper will focus on the Integration and Test (I&T) activities for L’Ralph while it is at the NASA GSFC. L’Ralph has two assemblies, the telescope detector assembly (TDA) and main electronics box (MEB). The TDA is a single telescope feeding two focal planes, MVIC and LEISA. L’Ralph integration consists of assembly and alignment of the telescope, electronics box integration, thermal systems integration and the final assembly and testing. This I&T phase will be followed by the L’Ralph calibration and characterization, environmental tests which include electromagnetic interference (EMI)/electromagnetic compatibility (EMC), vibration with sine sweep, acoustics, shock, thermal balance, thermal vacuum, mass properties and center of gravity determination. This paper will briefly discuss L’Ralph shipment and delivery to the spacecraft vendor for observatory level I&T as well as some launch preparation activities.

Spaceflight Instruments↗

A Review of Extra-Terrestrial Regolith Excavation Concepts and Prototypes

Regolith is present on many extra-terrestrial bodies, and the crushed rock material it is made of contains many of the resources that are enabling for In-Situ Resource Utilization (ISRU). When extracted these resources can be used to provide consumables such as rocket propellant, human life support, working fluids and gases for industrial processes and feedstocks for manufacturing. In addition, the regolith can also be very beneficial for construction purposes as an aggregate which can be used for construction materials and shielding for radiation protection and micrometeorite impact. Binders for regolith concrete may also be made from geopolymers that may be in the regolith. The regolith can be melted and drawn out into glass fibers and used as reinforcements in a metal, polymer, or concrete matrix. In addition, there is tremendous scientific and geological knowledge that can only be obtained by studying samples of the regolith. However, none of these valuable activities can proceed without first acquiring the regolith granular material with some type of excavation device and method. Excavation is in the critical path of many workflows that will make up the capabilities required to establish a human and robotic presence in our solar system. While scientific in-situ sampling of regolith in small quantities has been achieved since the dawn of the space age in the 1960’s, large scale excavation for mining and construction on extra-terrestrial bodies has only been contemplated for many decades in works of scientific fact and also in fictional stories, but serious development and prototyping of excavation technologies for use in reduced gravity space environments was only started in the late 1990’s.This paper will review and document the evolution of extra-terrestrial excavation concepts and prototypes based on the available literature and the personal experience of the author who has been working on regolith excavation technology development since 1998.

ISRU↗

A Review of Extra-Terrestrial Regolith Excavation Concepts and Prototypes

Regolith is present on many extra-terrestrial bodies, and the crushed rock material it is made of contains many of the resources that are enabling for In-Situ Resource Utilization (ISRU). When extracted, these resources can be used to provide consumables such as rocket propellant, human life support, working fluids and gases for industrial processes and feedstocks for manufacturing. In addition, the regolith can also be very beneficial for construction purposes as an aggregate which can be used for construction materials and shielding for radiation protection and micrometeorite impact. Binders for regolith concrete may also be made from geopolymers that may be in the regolith. The regolith can be melted and drawn out into glass fibers and used as reinforcements in a metal, polymer, or concrete matrix. In addition, there is tremendous scientific and geological knowledge that can only be obtained by studying samples of the regolith. However, none of these valuable activities can proceed without first acquiring the regolith granular material with some type of excavation device and method. Excavation is in the critical path of many workflows that will make up the capabilities required to establish a human and robotic presence in our solar system. While scientific in-situ sampling of regolith in small quantities has been achieved since the dawn of the space age in the 1960’s, large scale excavation for mining and construction on extra-terrestrial bodies has only been contemplated, for many decades, but serious development and prototyping of excavation technologies for use in reduced gravity space environments was only started in the late 1990’s. This paper will review and document the evolution of extra-terrestrial excavation concepts and prototypes based on the available literature and the personal experience of the author who has been working on regolith excavation technology development since 1998.

Regolith↗

A Review of Extra-Terrestrial Regolith Excavation Concepts and Prototype

Regolith is present on many extra-terrestrial bodies, and the crushed rock material it is made of contains many of the resources that are enabling for In-Situ Resource Utilization (ISRU). When extracted, these resources can be used to provide consumables such as rocket propellant, human life support, working fluids and gases for industrial processes and feedstocks for manufacturing. In addition, the regolith can also be very beneficial for construction purposes as an aggregate which can be used for construction materials and shielding for radiation protection and micrometeorite impact. Binders for regolith concrete may also be made from geopolymers that may be in the regolith. The regolith can be melted and drawn out into glass fibers and used as reinforcements in a metal, polymer, or concrete matrix. In addition, there is tremendous scientific and geological knowledge that can only be obtained by studying samples of the regolith. However, none of these valuable activities can proceed without first acquiring the regolith granular material with some type of excavation device and method. Excavation is in the critical path of many workflows that will make up the capabilities required to establish a human and robotic presence in our solar system. While scientific in-situ sampling of regolith in small quantities has been achieved since the dawn of the space age in the 1960’s, large scale excavation for mining and construction on extra-terrestrial bodies has only been contemplated, for many decades, but serious development and prototyping of excavation technologies for use in reduced gravity space environments was only started in the late 1990’s. This paper will review and document the evolution of extra-terrestrial excavation concepts and prototypes based on the available literature and the personal experience of the author who has been working on regolith excavation technology development since 1998.

Regolith↗

Best of both worlds: Enforcing detailed balance in machine learning models of transition rates

The slow microstructural evolution of materials often plays a key role in determining material properties. When the unit steps of the evolution process are slow, direct simulation approaches such as molecular dynamics become prohibitive and Kinetic Monte-Carlo (kMC) algorithms, where the state-to-state evolution of the system is represented in terms of a continuous-time Markov chain, are instead frequently relied upon to efficiently predict long-time evolution. The accuracy of kMC simulations however relies on the complete and accurate knowledge of reaction pathways and corresponding kinetics. This requirement becomes extremely stringent in complex systems such as concentrated alloys where the astronomical number of local atomic configurations makes the a priori tabulation of all possible transitions impractical. Machine learning models of transition kinetics have been used to mitigate this problem by enabling the efficient on-the-fly prediction of kinetic parameters. While conventional KMC methods based on transition state theory naturally yield reversible dynamics that exactly obey the detailed balance criterion, providing strong guarantees on the properties of the stationary distribution, many recently-proposed ML-based approaches to barrier predictions provide no such guarantees. In this study, we derive conditions under which physics-informed ML architectures exactly enforce the detailed balance condition by construction, even when relying on non-extensive descriptions of states in terms of local environments around mobile defects. In conclusion, using the diffusion of a vacancy in a concentrated alloy as an example, we show that such ML architectures also exhibit superior performance in terms of prediction accuracy, demonstrating that the imposition of physical constraints can facilitate the accurate learning of barriers at no increase in computational cost.

36 MATERIALS SCIENCE↗

Statistical analysis and degradation pathway modeling of photovoltaic minimodules with varied packaging strategies

Degradation pathway models constructed using network structural equation modeling (netSEM) are used to study degradation modes and pathways active in photovoltaic (PV) system variants in exposure conditions of high humidity and temperature. This data-driven modeling technique enables the exploration of simultaneous pairwise and multiple regression relationships between variables in which several degradation modes are active in specific variants and exposure conditions. Durable and degrading variants are identified from the netSEM degradation mechanisms and pathways, along with potential ways to mitigate these pathways. A combination of domain knowledge and netSEM modeling shows that corrosion is the primary cause of the power loss in these glass/backsheet PV minimodules. We show successful implementation of netSEM to elucidate the relationships between variables in PV systems and predict a specific service lifetime. The results from pairwise relationships and multiple regression show consistency. This work presents a greater opportunity to be expanded to other materials systems.

electrical measurements↗

Indefinite and bidirectional near-infrared nanocrystal photoswitching

Materials whose luminescence can be switched by optical stimulation drive technologies ranging from superresolution imaging, nanophotonics, and optical data storage, to targeted pharmacology, optogenetics, and chemical reactivity. Furthermore, these photoswitchable probes, including organic fluorophores and proteins, can be prone to photodegradation and often operate in the ultraviolet or visible spectral regions. Colloidal inorganic nanoparticles can offer improved stability, but the ability to switch emission bidirectionally, particularly with near-infrared (NIR) light, has not, to our knowledge, been reported in such systems. Here, we present two-way, NIR photoswitching of avalanching nanoparticles (ANPs), showing full optical control of upconverted emission using phototriggers in the NIR-I and NIR-II spectral regions useful for subsurface imaging. Employing single-step photodarkening and photobrightening, we demonstrate indefinite photoswitching of individual nanoparticles (more than 1,000 cycles over 7 h) in ambient or aqueous conditions without measurable photodegradation. Critical steps of the photoswitching mechanism are elucidated by modelling and by measuring the photon avalanche properties of single ANPs in both bright and dark states. Unlimited, reversible photoswitching of ANPs enables indefinitely rewritable two-dimensional and three-dimensional multilevel optical patterning of ANPs, as well as optical nanoscopy with sub-Å localization superresolution that allows us to distinguish individual ANPs within tightly packed clusters.

36 MATERIALS SCIENCE↗

Many routes to ferroelectric HfO 2 : A review of current deposition methods

Although 10 years have passed since the initial report of ferroelectricity in hafnia (HfO 2 ), researchers are still intensely fascinated by this material system and the promise it holds for future applications. A wide variety of deposition methods have been deployed to create ferroelectric HfO 2 thin films such as atomic layer deposition, chemical solution deposition, and physical vapor deposition methods such as sputtering and pulsed laser deposition. Process and design parameters such as deposition temperature, precursor choice, target source, vacuum level, reactive gases, substrate strain, and many others are often integral in stabilizing the polar orthorhombic phase and ferroelectricity. We examine processing parameters across four main different deposition methods and their effect on film microstructure, phase evolution, defect concentration, and resultant electrical properties. The goal of this review is to integrate the process knowledge collected over the past 10 years in the field of ferroelectric HfO 2 into a single comprehensive guide for the design of future HfO 2 -based ferroelectric materials and devices.

36 MATERIALS SCIENCE↗

Obtaining Public Opinion about sUAS Activity in an Urban Environment

The Unmanned Aircraft Systems (UAS) Traffic Management (UTM) research project has been developing and testing concept ideas for enabling small UAS (sUAS) operations in low altitude airspace (ground to 400 feet). To do this, a series of flight test demonstrations were organized over five years at seven test sites. Technology Capability Level-4 (TCL4), the most complex flight tests, were conducted in Texas, USA, during August 2019. This testing resulted in over 400 data collection flights using eight live rotorcraft, with nine flight crews flying pre-planned scenarios in the urban downtown and waterfront areas of Corpus Christi, Texas. Test scenarios were designed to include a variety of elements, including live and simulated vehicles, and personnel in many different roles, including flight crews and mission personnel. One group of people who did not have a role in the flight tests but will be affected by UAS operations as they become more ubiquitous, are the general public. What do the public think about sUAS operations in urban areas? In order to obtain a reference point that noted the public's view of the operations in the TCL4 demonstration, a short survey was developed and offered to members of the public who wished to comment on the sUAS activities they saw in their city during two weeks in August, 2019.Forty five people completed the online public opinion survey. Participants volunteered to take it, creating a self-selected sample. The survey included eleven questions that asked participants about their level of comfort and concerns with UAS activity; their knowledge of UAS operations; and, whether a traffic management system like UTM would increase their confidence in urban UAS activity. The general public in Corpus Christi showed a good level of knowledge of sUAS regulations, with almost half of their responses to the knowledge portion of the survey being correct. They expressed a moderate level of concern (x = 4.7 out of 7) at urban sUAS activity and, of those who cited a concern, the majority reported this was about privacy (54%), which are all responses in line with those reported in earlier research on public opinion. Views on UTM were mixed, with respondents indicating they thought the introduction of UTM will improve safety somewhat (5.2 out of 7) but it will also increase their concern a little (4.6 out of 7). This would indicate there needs to be more information and educational material about the UTM concept made available to the public with the aim to reduce public concerns about the system.

Caterina Grossi↗

Obtaining Public Opinion About sUAS Activity in an Urban Environment

The Unmanned Aircraft Systems (UAS) Traffic Management (UTM) research project has been developing and testing concept ideas for enabling small UAS (sUAS) operations in low altitude airspace (ground to 400 feet). To do this, a series of flight test demonstrations were organized over five years at seven test sites. Technology Capability Level-4 (TCL4), the most complex flight tests, were conducted in Texas, USA, during August 2019. This testing resulted in over 400 data collection flights using eight live rotorcraft, with nine flight crews flying pre-planned scenarios in the urban downtown and waterfront areas of Corpus Christi, Texas. Test scenarios were designed to include a variety of elements, including live and simulated vehicles, and personnel in many different roles, including flight crews and mission personnel. One group of people who did not have a role in the flight tests but will be affected by UAS operations as they become more ubiquitous, are the general public. What do the public think about sUAS operations in urban areas? In order to obtain a reference point that noted the public’s view of the operations in the TCL4 demonstration, a short survey was developed and offered to members of the public who wished to comment on the sUAS activities they saw in their city during two weeks in August, 2019. Forty five people completed the online public opinion survey. Participants volunteered to take it, creating a self-selected sample. The survey included eleven questions that asked participants about their level of comfort and concerns with UAS activity; their knowledge of UAS operations; and, whether a traffic management system like UTM would increase their confidence in urban UAS activity. The general public in Corpus Christi showed a good level of knowledge of sUAS regulations, with almost half of their responses to the knowledge portion of the survey being correct. They expressed a moderate level of concern (x = 4.7 out of 7) at urban sUAS activity and, of those who cited a concern, the majority reported this was about privacy (54%), which are all responses in line with those reported in earlier research on public opinion. Views on UTM were mixed, with respondents indicating they thought the introduction of UTM will improve safety somewhat (5.2 out of 7) but it will also increase their concern a little (4.6 out of 7). This would indicate there needs to be more information and educational material about the UTM concept made available to the public with the aim to reduce public concerns about the system.

UTM↗

USSR Space Life Sciences Digest, issue 7

This is the seventh issue of NASA's USSR Space Life Sciences Digest. It contains abstracts of 29 papers recently published in Russian language periodicals and bound collections and of 8 new Soviet monographs. Selected abstracts are illustrated with figures and tables from the original. Additional features include two interviews with the Soviet Union's cosmonaut physicians and others knowledgable of the Soviet space program. The topics discussed at a Soviet conference on problems in space psychology are summarized. Information about English translations of Soviet materials available to readers is provided. The topics covered in this issue have been identified as relevant to 29 areas of aerospace medicine and space biology. These areas are adaptation, biospherics, body fluids, botany, cardiovascular and respiratory systems, developmental biology, endocrinology, enzymology, exobiology, genetics, habitability and environment effects, hematology, human performance, immunology, life support systems, mathematical modeling, metabolism, microbiology, morphology and cytology, musculoskeletal system, neurophysiology, nutrition, perception, personnel selection, psychology, radiobiology, and space medicine.

Hooke, L. R.↗

Potassium Isotopic Compositions of NIST Potassium Standards and 40Ar/39Ar Mineral Standards

Knowledge of the isotopic ratios of standards, spikes, and reference materials is fundamental to the accuracy of many geochronological methods. For example, the 238U/235U ratio relevant to U-Pb geochronology was recently re-determined [1] and shown to differ significantly from the previously accepted value employed during age determinations. These underlying values are fundamental to accurate age calculations in many isotopic systems, and uncertainty in these values can represent a significant (and often unrecognized) portion of the uncertainty budget for determined ages. The potassium isotopic composition of mineral standards, or neutron flux monitors, is a critical, but often overlooked component in the calculation of K-Ar and 40Ar/39Ar ages. It is currently assumed that all terrestrial materials have abundances indistinguishable from that of NIST SRM 985 [2]; this is apparently a reasonable assumption at the 0.25per mille level (1σ) [3]. The 40Ar/39Ar method further relies on the assumption that standards and samples (including primary and secondary standards) have indistinguishable 40K/39K values. We will present data establishing the potassium isotopic compositions of NIST isotopic K SRM 985, elemental K SRM 999b, and 40Ar/39Ar biotite mineral standard GA1550 (sample MD-2). Stable isotopic compositions (41K/39K) were measured by the peak shoulder method with high resolution MC-ICP-MS (Thermo Scientific NEPTUNE Plus), using the accepted value of NIST isotopic SRM 985 [2] for fractionation [4] corrections [5]. 40K abundances were measured by TIMS (Thermo Scientific TRITON), using 41K/39K values from ICP-MS measurements (or, for SRM 985, values from [2]) for internal fractionation corrections. Collectively these data represent an important step towards a metrologically traceable calibration of 40K concentrations in primary 40Ar/39Ar mineral standards and improve uncertainties by ca. an order of magnitude in the potassium isotopic compositions of standards.

Morgan, Leah↗

Selection of Cultivars for use in Controlled Environment Life Support System (CELSS) Human Rated Test Facility (HRTF) Trials

The aims under this training grant, as under the subsequent fellowship, were to elaborate the theory and technique of cultivar evaluation for specialized controlled environments, then to employ the technique on selected crops, ultimately conducting cultivar trials, and making the knowledge gained available for use in NASA's space program. We undertook a comprehensive search of the Cornell agricultural library (Mann library) and its data-bases for any and all material relating to cultivar evaluation of vegetable crops, and also developed the logic of how to go about narrowing down the field of contending cultivars when undertaking cultivar trials. The results of this work, the principal outcome of the grant, are reflected in his MS thesis, particularly in Chapter 2, "Commercial and Scientific Literature," and even more so in Chapter 8, "Selecting cultivars and lines for screening." David also attended annual conferences of vegetable crop plant breeders, annual yield trials and breeding trials for vegetable crops, as well as relevant professional conferences such as the ASHS annual meetings, and the others.

Langhans, Robert W.↗

The Renazzo-like Carbonaceous Chondrites as Resources to Understand the Origin, Evolution, and Exploration of the Solar System

We present here a review of the characteristics of CR carbonaceous chondrite meteorites. Over the past three decades, our knowledge and understanding of the scientific value of the CR chondrites have increased dramatically, as more samples from cold and hot deserts have become available for analysis. Based on a variety of compositional, mineralogical, isotopic, and spectroscopic studies, we have come to understand that CR chondrites are excellent samples of asteroidal meteorites to look for virtually unaltered solar nebula material and to observe asteroidal processes in progress. This paper summarizes these investigations, their similarities, and differences with other chondritic groups, their relationships to asteroids, and the questions yet to be addressed

N. M. Abreu↗