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At least 451 records · Page 25

NEAR-INFRARED BAND STRENGTHS OF MOLECULES DILUTED IN N{sub 2} AND H{sub 2}O ICE MIXTURES RELEVANT TO INTERSTELLAR AND PLANETARY ICES

The relative abundances of ices in astrophysical environments rely on accurate laboratory measurements of physical parameters, such as band strengths (or absorption intensities), determined for the molecules of interest in relevant mixtures. In an extension of our previous study on pure-ice samples, here we focus on the near-infrared absorption features of molecules in mixtures with the dominant components of interstellar and planetary ices, H{sub 2}O and N{sub 2}. We present experimentally measured near-infrared spectral information (peak positions, widths, and band strengths) for both H{sub 2}O- and N{sub 2}-dominated mixtures of CO (carbon monoxide), CO{sub 2} (carbon dioxide), CH{sub 4} (methane), and NH{sub 3} (ammonia). Band strengths were determined during sample deposition by correlating the growth of near-infrared features (10,000-4000 cm{sup -1}, 1-2.5 {mu}m) with better-known mid-infrared features (4000-400 cm{sup -1}, 2.5-25 {mu}m) at longer wavelengths.

79 ASTRONOMY AND ASTROPHYSICS↗

Sensitivities of the West Greenland Current to Greenland Ice Sheet Meltwater in a Mesoscale Ocean/Sea Ice Model

Abstract Meltwater from the Greenland Ice Sheet can alter the continental shelf/slope circulation and cross-shelf freshwater fluxes and limit deep convection in adjacent basins through surface freshening. We explore the impacts on the West Greenland Current and eastern Labrador Sea with different vertical distributions of the meltwater forcing. In this study, we present the results from global coupled ocean/sea ice simulations, forced with atmospheric reanalysis, that are mesoscale eddy-active (∼2–3-km horizontal spacing) and eddy-permitting (∼6–7-km horizontal spacing) in the study region. We compare the West Greenland Current in mesoscale eddy-active and eddy-permitting without meltwater to highlight the role of small-scale features. The mesoscale eddy-active configuration is then used to assess the change in the eastern Labrador Sea when meltwater is added to the surface or vertically distributed to account for mixing within fjords. In both simulations with meltwater, the West Greenland and West Greenland Coastal Currents are faster than in the simulation with no meltwater; their mean surface speeds are the highest in the vertical distribution case. In the latter case, there is enhanced baroclinic conversion at the shelf break compared to the simulation with no meltwater. When meltwater is vertically distributed, there is an increase in baroclinic conversion at the shelf break associated with increased eddy kinetic energy. In addition, in the eastern Labrador Sea, the salinity is lower and the meltwater volume is greater when meltwater is vertically distributed. Therefore, the West Greenland Current is sensitive to how meltwater is added to the ocean with implications for the freshening of the Labrador Sea. Significance Statement Our goal is to understand how the flux of freshwater across the West Greenland continental slope into the Labrador Sea is modified by meltwater from the Greenland Ice Sheet. We compare the simulations of the ocean that capture key dynamics along the West Greenland continental slope that have no meltwater, meltwater added to the ocean surface, and meltwater distributed vertically to represent the mixing within fjords. When meltwater is added, the currents along the continental slope are faster, with the greatest increase when meltwater is vertically distributed. In that case, there is enhanced freshening of the Labrador Sea because modified density gradients generate more eddies. Proper representation of the vertical structure of meltwater is important for projecting the impact of freshwater on the subpolar North Atlantic.

58 GEOSCIENCES↗

Ice-shelf Dynamics Near the Front of Filchner-Ronne Ice Shelf, Antarctica, Revealed by SAR Interferometry: Model/Interferogram Comparison

We compare Earth Remote Sensing (ERS) satellite synthetic-aperture radar (SAR) interferograms with artificial interferograms constructed using output of a finite-element ice-shelf flow model to study the dynamics of Filchner-Ronne Ice Shelf (FRIS) near Hemmen Ice Rise (HIR) where the iceberg-calving front itersects Berkener Island (BI).

Ice-shelf Filchner-Ronne Antarctica SAR Interferom↗

A New Ecosystem Model for Arctic Phytoplankton Phenology From Ice‐Covered to Open‐Water Periods: Implications for Future Sea Ice Retreat Scenarios

Abstract To predict ecosystem change in the Arctic Ocean, understanding Arctic phytoplankton phenology is essential. We develop a marine ecosystem model focusing on phytoplankton dynamics and the competition for multiple resources based on knowledge from in situ data obtained in the Chukchi Sea. The model is designed to include the unique ecological characteristics of the Arctic Ocean. To the best of our knowledge, this is the first model successfully simulating the current paradigm for Arctic phytoplankton phenology, including both under‐ice blooms and succession of phytoplankton groups. Sensitivity experiments show that the dominance of diatoms can be sustained by lateral transport of a high‐silicate water mass (Pacific Winter Water). Experiments for future scenarios show that sea ice retreat drives a decrease in large diatoms and an increase in the other relatively small non‐diatom groups. These results suggest that dominant phytoplankton groups can be shifted from diatoms to non‐diatoms under ongoing Arctic Ocean sea ice retreat.

Choi, Jang‐Geun↗

Plant, insect, and fungi fossils under the center of Greenland’s ice sheet are evidence of ice-free times

The persistence and size of the Greenland Ice Sheet (GrIS) through the Pleistocene is uncertain. This is important because reconstructing changes in the GrIS determines its contribution to sea level rise during prior warm climate periods and informs future projections. To understand better the history of Greenland’s ice, we analyzed glacial till collected in 1993 from below 3 km of ice at Summit, Greenland. The till contains plant fragments, wood, insect parts, fungi, and cosmogenic nuclides showing that the bed of the GrIS at Summit is a long-lived, stable land surface preserving a record of deposition, exposure, and interglacial ecosystems. Knowing that central Greenland was tundra-covered during the Pleistocene informs the understanding of Arctic biosphere response to deglaciation.

58 GEOSCIENCES↗

Ice rule breakdown and frustrated antiferrotoroidicity in an artificial colloidal Cairo ice

Abstract We combine experiments and numerical simulations to investigate the low energy states and the emergence of topological defects in an artificial colloidal ice in the Cairo geometry. This type of geometry is characterized by a mixed coordination ( z ), with coexistence of both z = 3 and z = 4 vertices. We realize this particle ice by confining field tunable paramagnetic colloidal particles within a lattice of topographic double wells at a one to one filling using optical tweezers. By raising the interaction strength via an applied magnetic field, we find that the ice rule breaks down, and positive monopoles with charge q = + 2 accumulate in the z = 4 vertices and are screened by negative ones ( q = − 1 ) in the z = 3. The resulting, strongly coupled state remains disordered. Further, via analysis of the mean chirality associated to each pentagonal plaquette, we find that the disordered ensemble for this geometry is massively degenerate and it corresponds to a frustrated antiferrotoroid.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Deviation from the dipole-ice model in the spinel spin-ice candidate MgEr 2 Se 4

In spin-ice research, small variations in structure or interactions drive a multitude of different behaviors, yet the collection of known materials relies heavily on the “227” pyrochlore structure. Here, we present thermodynamic, structural, and inelastic-neutron-scattering data on a spin-ice material, MgEr 2 Se 4 , which contributes to the relatively underexplored family of rare-earth spinel chalcogenides. X-ray and neutron diffraction confirm a normal spinel structure and place Er 3+ moments on an ideal pyrochlore sublattice. Measurement of crystal electric field excitations with inelastic neutron scattering confirms that the moments have perfect Ising character, and further identifies the ground-state Kramers doublet as having dipolar-octupolar form with a significant multipolar character. Heat capacity and magnetic neutron diffuse scattering have icelike features, but are inconsistent with Monte Carlo simulations of the nearest-neighbor and next-nearest-neighbor dipolar spin-ice (DSI) models. A significant remnant entropy is observed as T → 0 K, but again falls short of the full Pauling expectation for DSI, unless significant disorder is added. We show that these observations are fully in line with what has been recently reported for CdEr 2 Se 4 , and point to the importance of quantum fluctuations in these materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Ice at the Interface: Atmosphere-Ice-Ocean Boundary Layer Processes and Their Role in Polar Change (Workshop Report)

The atmosphere-ocean boundary layer in which sea ice resides includes many complex processes that require a more realistic treatment in GCMs, particularly as models move toward full earth system descriptions. The primary purpose of the workshop was to define and discuss such coupled processes from observational and modeling points of view, including insight from both the Arctic and Antarctic systems. The workshop met each of its overarching goals, including fostering collaboration among experimentalists, theorists and modelers, proposing modeling strategies, and ascertaining data availability and needs. Several scientific themes emerged from the workshop, such as the importance of episodic or extreme events, precipitation, stratification above and below the ice, and the marginal ice zone, whose seasonal Arctic migrations now traverse more territory than in the past.

54 ENVIRONMENTAL SCIENCES↗

An investigation of the astronomical theory of the ice ages using a simple climate-ice sheet model

The astronomical theory of the Quaternary ice ages is incorporated into a simple climate model for global weather; important features of the model include the albedo feedback, topography and dynamics of the ice sheets. For various parameterizations of the orbital elements, the model yields realistic assessments of the northern ice sheet. Lack of a land-sea heat capacity contrast represents one of the chief difficulties of the model.

Pollard, D.↗

A method of predicting flow rates required to achieve anti-icing performance with a porous leading edge ice protection system

A proposed method of analytically predicting the minimum fluid flow rate required to provide anti-ice protection with a porous leading edge system on a wing under a given set of flight conditions is presented. Results of the proposed method are compared with the actual results of an icing test of a real wing section in the NASA Lewis Icing Research Tunnel.

Kohlman, D. L.↗

A method of predicting flow rates required to achieve anti-icing performance with a porous leading edge ice protection system

An analytical method was developed for predicting minimum flow rates required to provide anti-ice protection with a porous leading edge fluid ice protection system. The predicted flow rates compare with an average error of less than 10 percent to six experimentally determined flow rates from tests in the NASA Icing Research Tunnel on a general aviation wing section.

Kohlman, D. L.↗

The dynamic tensile strength of ice and ice-silicate mixtures

The dynamic tensile strength of icy media is measured at strain rates on the order of 10,000/sec to aid in the understanding of impact and cratering phenomena. Compressed samples consisting of ice and ice-silicate mixtures with 5 and 30 wt % sand were impacted at temperatures between 230 and 250 K by projectile plexiglas plates imparting the required strain rates in less than 0.75 microsec. Taking the tensile stress corresponding to the transition from intact to spalled or fragmented samples as the dynamic tensile strength, strengths of 17, 20 and 22 MPa were obtained for the pure ice, 5 wt % sand, and 30 wt % sand specimens, respectively. The values lie considerably above those observed in static testing. A continuum fracturing model is used to obtain relations between tensile strength and stress rate as well as to derive stress and damage histories during tensile loading and the size distribution of icy fragments as a function of strain rate.

Lange, M. A.↗

Ice-rich moons and the physical properties of ice

Many of the moons of the outer planets in the solar system consist to a substantial degree of water and other ices. Such ices are thought to make up at least half, by mass, of all condensed material in the outer solar system. The surfaces and interiors of these icy satellites have undergone considerable geologic evolution, and in some cases may still be active today. So that these processes can be understood, certain critical data on the behavior of water and other ices at low (ca. 100 K) temperatures and high (ca. 10 kbar) pressures are needed. Given such data, various techniques for modeling planetary interiors can be tested to see which models best describe the conditions observed on these bodies; such models may then be used to study larger, terrestrial planets.

Consolmagno, G. J.↗

Characteristics of Arctic Ocean ice determined from SMMR data for 1979 - Case studies in the seasonal sea ice zone

Sea ice data derived from the Scanning Multichannel Microwave Radiometer are examined for sections of the Arctic Ocean during early summer 1979. The temporary appearance of spuriously high multiyear ice fractions in the seasonal ice zones of the Kara and Barents Seas is a result of surface melt phenomena and the relative responses of the different channels to these effects. These spurious signatures can provide early identification of melt onset and additional information on surface characteristics.

Anderson, M. R.↗