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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Synthesis of cobalt grown from Co-S eutectic in high magnetic fields

Samples of Co were grown directly in the ferromagnetic state under equilibrium conditions using a cobalt sulfide flux. Magnetic fields up to 9 T were applied during growth, and isolated Co products exhibit progressively elongated morphologies, from cubes to rectangular rods to needle-like tendrils with poorly-defined facets. The degree of elongation of the major axis was found to correlate with magnetic field direction, strength, and gradient. Two-dimensional X-ray diffraction data indicate some level of polycrystalline-like samples, and quantitative analyses (Le Bail and Rietveld) of the one-dimensional data confirm the presence of hcp and fcc phases. The magnetic responses indicate a partial alignment of the magnetic easy-axis of the hcp phase along the magnetic field present during growth.

36 MATERIALS SCIENCE↗
NASA NTRS2001

An Overview of the Thermal Challenges of Designing Microgravity Furnaces

Marshall Space Flight Center is involved in a wide variety of microgravity projects that require furnaces, with hot zone temperatures ranging from 300 C to 2300 C, requirements for gradient processing and rapid quench, and both semi-conductor and metal materials. On these types of projects, the thermal engineer is a key player in the design process. Microgravity furnaces present unique challenges to the thermal designer. One challenge is designing a sample containment assembly that achieves dual containment, yet allows a high radial heat flux. Another challenge is providing a high axial gradient but a very low radial gradient. These furnaces also present unique challenges to the thermal analyst. First, there are several orders of magnitude difference in the size of the thermal 'conductors' between various parts of the model. A second challenge is providing high fidelity in the sample model, and connecting the sample with the rest of the furnace model, yet maintaining some sanity in the number of total nodes in the model. The purpose of this paper is to present an overview of the challenges involved in designing and analyzing microgravity furnaces and how some of these challenges have been overcome. The thermal analysis tools presently used to analyze microgravity furnaces and will be listed. Challenges for the future and a description of future analysis tools will be given.

Westra, Douglas G.↗
DOE OSTI2021

Vapor-Phase Intercalation of Cesium into Black Phosphorous

Cesium vapors were charged into black phosphorous (BP) flakes at varied times and at a temperature gradient of 150 °C. The X-ray diffraction (XRD) measurements of these samples suggest a reduction in the strength of van der Waal interactions between BP layers leading to the loss of coherence of out-of-plane peaks. At the same time, the three main Raman modes of BP (A g 1 , B 2 g , and A g 2 ) steadily redshifted as exposure times were increased, with modes B 2 g and A g 2 shifting faster than A g 1 . After initial rapid downshifts of active BP phonon modes, this intercalation strategy showed its limits following prolonged exposure times. Saturation of BP flakes by Cs vapors ensued and the kinetics was fitted with an exponential decay function. Furthermore, the thermoelectric power (TEP) of cesiated BP exhibited an inversion in sign from positive to negative around 400 K, lending credence to the transformation of as-prepared BP which is a p-type semiconductor to an n-type equivalent due to Cs atom intercalation driven shifting of the Fermi level toward the conduction band of BP and the donation of electrons from Cs. Furthermore, density functional theory (DFT) calculations were used to delve deeper into understanding Cs intercalation on the structural evolution of BP.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Soil carbon storage capacity of drylands under altered fire regimes

The determinants of fire-driven changes in soil organic carbon (SOC) across broad environmental gradients remains unclear, especially in global drylands. Here we combined datasets and field sampling of fire-manipulation experiments to evaluate where and why fire changes SOC and compared our statistical model to simulations from ecosystem models. Drier ecosystems experienced larger relative changes in SOC than humid ecosystems—in some cases exceeding losses from plant biomass pools—primarily explained by high fire-driven declines in tree biomass inputs in dry ecosystems. Many ecosystem models underestimated the SOC changes in drier ecosystems. Upscaling our statistical model predicted that soils in savannah–grassland regions may have gained 0.64 PgC due to net-declines in burned area over the past approximately two decades. Consequently, ongoing declines in fire frequencies have probably created an extensive carbon sink in the soils of global drylands that may have been underestimated by ecosystem models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

A synthesis of bacterial and archaeal phenotypic trait data

A synthesis of phenotypic and quantitative genomic traits is provided for bacteria and archaea, in the form of a scripted, reproducible workflow that standardizes and merges 26 sources. The resulting unified dataset covers 14 phenotypic traits, 5 quantitative genomic traits, and 4 environmental characteristics for approximately 170,000 strain-level and 15,000 species-aggregated records. It spans all habitats including soils, marine and fresh waters and sediments, host-associated and thermal. Trait data can find use in clarifying major dimensions of ecological strategy variation across species. They can also be used in conjunction with species and abundance sampling to characterize trait mixtures in communities and responses of traits along environmental gradients.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Ab initio molecular dynamics on quantum computers

Ab initio molecular dynamics (AIMD) is a valuable technique for studying molecules and materials at finite temperatures where the nuclei evolve on potential energy surfaces obtained from accurate electronic structure calculations. In this work, we present an approach to running AIMD simulations on noisy intermediate-scale quantum (NISQ)-era quantum computers. The electronic energies are calculated on a quantum computer using the variational quantum eigensolver (VQE) method. Algorithms for computation of analytical gradients entirely on a quantum computer require quantum fault-tolerant hardware, which is beyond NISQ-era. Therefore, we compute the energy gradients numerically using finite differences, the Hellmann-Feynman theorem, and a correlated sampling technique. This method only requires additional classical calculations of electron integrals for each degree of freedom without any additional computations on a quantum computer beyond the initial VQE run. As a proof of concept, AIMD simulations are demonstrated for the H-2 molecule on IBM quantum devices. In addition, we demonstrate the validity of the method for larger molecules using full configuration interaction wave functions. As quantum hardware and noise mitigation techniques continue to improve, the method can be utilized for studying larger molecular systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Wavefront shaping with a Hadamard basis for scattering soil imaging

Here, soil is a scattering medium that inhibits imaging of plant-microbial-mineral interactions that are essential to plant health and soil carbon sequestration. However, optical imaging in the complex medium of soil has been stymied by the seemingly intractable problems of scattering and contrast. Here, we develop a wavefront shaping method based on adaptive stochastic parallel gradient descent optimization with a Hadamard basis to focus light through soil mineral samples. Our approach allows a sparse representation of the wavefront with reduced dimensionality for the optimization. We further divide the used Hadamard basis set into subsets and optimize a certain subset at once. Simulation and experimental optimization results demonstrate our method has an approximately seven times higher convergence rate and overall better performance compared to that with optimizing all pixels at once. The proposed method can benefit other high-dimensional optimization problems in adaptive optics and wavefront shaping.

47 OTHER INSTRUMENTATION↗
NASA NTRS1982

Electrohydrodynamics and other hydrodynamic phenomena in continuous flow electrophoresis

The process known as continuous flow electrophoresis employs an electric field to separate the constituents of particulate samples suspended in a liquid. Complications arise because the electric field generates temperature gradients due to Joule heating and derives an electrohydrodynamic crossflow. Several aspects of the flow are discussed including entrance effects, hydrodynamic stability and a flow restructuring due to the combined effects of buoyancy and the crossflow.

Saville, D. A.↗
NASA NTRS1987

Directional solidification of flake and spheroidal graphite cast iron in low and normal gravity environment

A NASA KC-135 research aircraft, flying repeated low-g trajectories that yield 20-30 sec of 0.1-0.001 g microgravity, has been used to study microgravity solidification's elimination of sedimentation and convection (with formation of unique and advantageous microstructures) for the case of eutectic-composition cast irons. The solidification interface of hypereutectic flake and spheroidal graphite cast irons has been slowly advanced through a 4 mm-diameter rod sample. Sample solidification rates have been correlated with accelerometer data, while independently controlling thermal gradients and solidification rates.

Hendrix, J. C.↗
NASA NTRS1992

Influence of the preshock temperature on shock effects in quartz

Shock metamorphic features are the prime indicators for recognizing impact phenomena on Earth and other planetary bodies. Although the pressure dependence of shock features is well known, information about the influence of the preshock temperature is almost lacking. Especially in the case of large-scale impacts like Sudbury, it is expected that deep-seated crustal rocks were subjected to shock at elevated temperatures. Therefore, we continued to perform shock experiments at elevated temperatures on less than 0.5-mm thin disks of single crystal quartz cut parallel to the (1010) face. All recovered quartz samples were investigated by universal stage, spindle stage, and a newly developed density gradient technique. Errors of refractive index and density measurements are +/- 0.0005 and +/- 0.002 g/cu cm respectively. Our investigations indicate that shock metamorphic features are strongly dependent on the preshock temperature. This statement has far-reaching implications with respect to shock wave barometry that is based on data from recovery experiments at room temperature. These datasets might be applicable only to low-temperature target rocks. Moreover, this study demonstrates that shock recovery experiments are definitely required for understanding the complete pressure-temperature regime of shock metamorphism on planetary bodies.

Langenhorst, F.↗
NASA NTRS1992

Morphological, anatomical, and chemical characteristics of needle and branch samples of Siberian fir (Abies Siberica)

In August, 1991, needle and branch samples of Siberian fir were collected from undisturbed forest stands along an elevation gradient ranging from 2300 ft to 4450 ft. Four study sites were selected on west-facing slopes, and a standard set of measurements and collections was made. First-, second-, and third-year needles were collected for anatomical assessment. A visual assessment of the forest stand conditions at each site included an evaluation of canopy morphology needle, coloration, increment growth, and the state of health of a specific type of lichen. The heaviest damage to forest stands (extensive foliar loss, needle discoloration, dieback of terminal growth) occurs at an intermediate elevation site (3400 ft/1037 m). The least amount of damage was recorded at the lowest elevation site (2300 ft/701 m). Only slight damage occurs at the highest elevation site (4450 ft/1357 m). Some degree of flagging occurs at all sites. Several lines of evidence suggest that the damage occurring in this area is recent in origin (incipient).

Rock, B. N.↗
NASA NTRSDate not supplied

Three-dimensional in Situ Observations of Polycrystalline Microstructure Evolution During Directional Solidification of Transparent Alloys Aboard the ISS and Quantitative Comparison with Numerical Modeling

Cellular/dendritic microstructures formed during solidification have a crucial influence on the mechanical properties of a wide range of structural alloys. By minimizing the amount of gravity-induced convection in the liquid, directional solidification experiments using transparent organic alloys conducted in the DECLIC-DSI onboard the International Space Station have provided unique 3D in situ observations of the spatiotemporal evolution of the solid-liquid interface during the formation of cellular and dendritic microstructures under purely diffusive growth conditions in polycrystalline samples containing several grains with a small misorientation with respect to the temperature gradient. Those observations have made it possible to perform benchmark quantitative comparisons with the predictions of state-of-the-art phase-field simulations of microstructure formation in 3D on experimentally relevant length and time scales. This talk will report quantitative comparisons between microgravity experiments and phase-field simulations in succinonitrile-camphor alloys of two different compositions that shed new light on the role of subgrain boundaries in the spatiotemporal evolution of the primary cellular spacing and the selection of dendritic array structures.

Kaihua Ji↗
NASA NTRS2019

FIGS: spectral fitting constraints on the star formation history of massive galaxies since the cosmic noon

We constrain the stellar population properties of a sample of 52 massive galaxies – with stellar mass log (M(s)/M(⊙)) ≳ 10.5 – over the redshift range 0.5 < z < 2 by use of observer-frame optical and near-infrared slitless spectra from Hubble Space Telescope’s ACS and WFC3 grisms. The deep exposures (∼100 ks) allow us to target individual spectra of massive galaxies to F160W = 22.5 AB. Our spectral fitting approach uses a set of six base models adapted to the redshift and spectral resolution of each observation, and fits the weights of the base models, including potential dust attenuation, via a Markov Chain Monte Carlo method. Our sample comprises a mixed distribution of quiescent (19) and star-forming galaxies (33). We quantify the width of the age distribution (Δt) that is found to dominate the variance of the retrieved parameters according to principal component analysis. The population parameters follow the expected trend towards older ages with increasing mass, and Δt appears to weakly anticorrelate with stellar mass, suggesting a more efficient star formation at the massive end. As expected, the redshift dependence of the relative stellar age (measured in units of the age of the Universe at the source) in the quiescent sample rejects the hypothesis of a single burst (aka monolithic collapse). Radial colour gradients within each galaxy are also explored, finding a wider scatter in the star-forming subsample, but no conclusive trend with respect to the population parameters.

Ignacio Ferreras↗
NASA NTRSDate not supplied

Global Analysis of Nonlinear Second-Mode Development in a Mach-6 Boundary Layer From High-Speed Schlieren Data

The second-mode instability on a 7◦ half-angle sharp cone at Mach 6 is analyzed using high-speed calibrated schlieren imagery at a frame rate near the expected fundamental frequency. Experiments were conducted in the NASA Langley 20-Inch Mach 6 facility at unit Reynolds number between 6.56×106 and 9.71×106 m−1. Time-resolved pixel intensity signals throughout the boundary layer are reconstructed using spatially available data in the schlieren images to recover an effective sampling rate of over 10 MHz; these are then converted to quantitative density gradients using a thin-lens-based calibration technique. A global analysis is performed on the schlieren data to investigate the nonlinear growth of the second-mode fundamental and harmonic content. Point-wise measures of the auto-bicoherence are used to identify specific triadic interactions and the locations of their highest levels of quadratic phase coupling. Significant resonance interactions between the second-mode fundamental and harmonic instabilities were found along with interactions between these and the mean flow. Bispectral mode decomposition is employed to educe the flow structures associated with these interactions. A similar analysis is performed for the power spectrum, with power spectral densities computed for each pixel’s time-series and spectral proper orthogonal decomposition employed to derive the modal structure and energy of the flow at specific frequencies. Comparisons between the bispectral quantities and second-mode power show that nonlinear interactions, particularly resonance interactions, are closely correlated with space-time modulation of disturbances during the nonlinear stage of transition.

boundary layer transition↗
NASA NTRS2020

Atmospheric Carbon Cycle Dynamics Over the Above Domain: an Integrated Analysis Using Aircraft Observations (Arctic-CA) and Model Simulations (GEOS)

The Arctic Carbon Atmospheric Profiles (Arctic-CAP) project conducted six airborne surveys of Alaska and northwestern Canada between April and November 2017 to capture the spatial and temporal gradients of northern high-latitude carbon dioxide (CO2), methane (CH4) and carbon monoxide (CO) as part of NASA's Arctic-Boreal Vulnerability Experiment (ABoVE). The Arctic-CAP sampling strategy involved acquiring vertical profiles of CO2, CH4 and CO from the surface to 5 km altitude at 25 sites around the ABoVE domain on a 4- to 6-week time interval. We observed vertical gradients of CO2, CH4 and CO that vary by eco-region and duration of the sampling period, which spanned the majority of the seasonal cycle. All Arctic-CAP measurements were compared to a global simulation using the Goddard Earth Observing System (GEOS) modeling system. Comparisons with GEOS simulations of atmospheric CO2, CH4 and CO highlight the potential of these multi-species observations to inform improvements in surface flux estimates and the representation of atmospheric transport. GEOS simulations provide estimates of the near surface average CO2 and CH4 enhancements that are well correlated with aircraft observations (R=0.74 and R=0.60 respectively), suggesting that GEOS has reasonable fidelity over this complex and heterogeneous region. This model-data comparison over the ABoVE domain reveals that while current state-of-the-art models and flux estimates are able to capture broadscale spatial and temporal patterns in near-surface CO2 and CH4 concentrations, more work is needed to resolve fine-scale flux features that are observed. The study also provides a framework for benchmarking a global model at regional scales, which is needed to use climate models as tools to investigate high-latitude carbon-climate feedbacks.

C Sweeney↗
NASA NTRS1992

Experimental results and numerical modeling of solidification during aircraft high-g arcs

The question of how the Coriolis and gravity gradient forces during high-gravity maneuvers compare to that for common centrifuges is addressed. Microstructural examination of samples solidified during high-gravity arcs reveals no evidence of convection dampening. As a first approximation, the high-gravity arc is modeled as a centrifuge with a radius of 20,480 ft and angular speed of 0.318 rpm. Scaling analysis indicates that the Coriolis and gravity gradient expected on the aircraft high gravity arc are less than that for the centrifuges by a factor of 100. Detailed Navier-Stokes analysis of the fluid flow and thermal fields during solidification of aluminum and Cd-Te during KC-135 high gravity show that convective flows of about 1 mm/s are induced. The thermal field is only slightly modified by the convection. Coriolis and gravity gradient during solidification in KC-135 high-gravity arcs, even at accelerations that have been shown to produce significant convective flow dampening in the centrifuge systems, are found to have no significant influence on the melt thermal and flowfields.

Curreri, P. A.↗
NASA NTRS1979

General purpose rocket furnace

A multipurpose furnace for space vehicles used for material processing experiments in an outer space environment is described. The furnace contains three separate cavities designed to process samples of the widest possible range of materials and thermal requirements. Each cavity contains three heating elements capable of independent function under the direction of an automatic and programmable control system. A heat removable mechanism is also provided for each cavity which operates in conjunction with the control system for establishing an isothermally heated cavity or a wide range of thermal gradients and cool down rates. A monitoring system compatible with the rocket telemetry provides furnace performance and sample growth rate data throughout the processing cycle.

Aldrich, B. R.↗
DOE OSTI2022

Dissolved oxygen sensor in an automated hyporheic sampling system reveals biogeochemical dynamics

Many river corridor systems frequently experience rapid variations in river stage height, hydraulic head gradients, and residence times. The integrated hydrology and biogeochemistry of such systems is challenging to study, particularly in their associated hyporheic zones. Here we present an automated system to facilitate 4-dimensional study of dynamic hyporheic zones. It is based on combining real-time in-situ and ex-situ measurements from sensor/sampling locations distributed in 3-dimensions. A novel dissolved oxygen (DO) sensor was integrated into the system during a small scale study. We measured several biogeochemical and hydrologic parameters at three subsurface depths in the riverbed of the Columbia River in Washington State, USA, a dynamic hydropeaked river corridor system. During the study, episodes of significant DO variations (~+/- 4 mg/l) were observed, with minor variation in other parameters (e.g., <~+/-0.15 mg/l NO 3 ). DO concentrations were related to hydraulic head gradients, showing both hysteretic and non-hysteretic relationships with abrupt (hours) transitions between the two types of relationships. The observed relationships provide a number of hypotheses related to the integrated hydrology and biogeochemistry of dynamic hyporheic zones. We suggest that preliminary high-frequency monitoring is advantageous in guiding the design of long term monitoring campaigns. The study also demonstrated the importance of measuring multiple parameters in parallel, where the DO sensor provided the key signal for identifying/detecting transient phenomena.

54 ENVIRONMENTAL SCIENCES↗