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At least 451 records · Page 25

Sensitivity Studies of Premixed Flame Response to Transverse, High Frequency Disturbances

This study analyzes the response of premixed flames to high frequency transverse acoustic disturbances. A significant body of experiment, modeling and simulation efforts has been performed to understand the response of the spatially integrated heat release of premixed flames to low-frequency disturbances. These studies quantified this sensitivity through the Flame Transfer Function (FTF), as the global heat release is the key quantity influencing thermoacoustic stability for acoustically compact flames. Recent efforts have expanded these models to consider high-frequency acoustic disturbances, and the sensitivity of premixed flames through the Rayleigh integral (RI). The full Rayleigh Integral, as opposed to simply the spatially integrated heat release, must be considered in these cases where the flame is not acoustically compact. Prior modeling studies considered several effects - stability of axisymmetric flames centered in a cylindrical combustion chamber and the effect of flame offset from the combustor axis and the effect of mean flame asymmetries in the flame centered in the combustor. These studies showed that the flame's stability was sensitive to all these parameters, as well as to the transverse mode in question. In this paper, we quantify these different parametric sensitivities of premixed flame stability in the presence of high-frequency transverse acoustic modes - specifically sensitivity to flame length and nozzle location within the acoustic mode shape for 2 different transverse modes. The sensitivity of the RI to these control parameters provides an improved understanding of which flame parameters are critical to improve the overall thermoacoustic stability of the system.

Acharya, Vishal S.↗

The structure of the distanct geomagnetic tail during long periods of northward IMF

We have used a newly developed, parallelized, global MHD magnetosphere - ionosphere simulation model with a 400 R(sub E) long tail to study the evolution, structure, and dynamics of the distant magnetotail during extended periods of northward interplanetary magnetic field (IMF). We find that the tail evolves to a nearly time stationary structure about one solar wind transit time after the IMF turns northward. Four regions of different magnetic topology can be distinguished which extend at least to the end of the simulation box at 400 R(sub E). Besides lobe field lines and open solar wind field lines tailward of an X-line, there is a broad boundary layer of closed field lines which we call the tail flank boundary layer (TFBL). Just inside the TFBL there is a region of closed field loops. Besides the X-line we find two O-lines which are enclosed by the closed field loops and are roughly aligned with the tail axis. Together they form a U shaped separator between the northward and the southward plasma sheet fields.

Raeder, J.↗

Leaf area index (LAI), Teller site, Seward Peninsula, Alaska, 2022

Leaf area index (LAI) sampled from locations on the Teller MM27 NGEE-Arctic site, Seward Peninsula, Alaska. These data were collected in support of the ongoing NGEE-Arctic and NASA ABoVE data synthesis work. Samples were collected in July 2022 at 100 locations that cover the down slope half of Teller MM27 hillslope. This data package includes sample information and LAI data (.csv), an ESRI shape file (.shp) and Keyhole Markup Language (.kml) that define the location and area of each LAI measurement. Metadata files include data descriptions (_dd.csv) for tabular data, file level metadata (.csv), and methods and the instrument manual (.pdf). The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

MODIS Retrieval of Dust Aerosol

The MODerate resolution Imaging Spectroradiometer (MODIS) currently aboard both the Terra and Aqua satellites produces a suite of products designed to characterize global aerosol distribution, optical thickness and particle size. Never before has a space-borne instrument been able to provide such detailed information, operationally, on a nearly global basis every day. The three years of Terra-MODIS data have been validated by comparing with co-located AERONET observations of aerosol optical thickness and derivations of aerosol size parameters. Some 8000 comparison points located at 133 AERONET sites around the globe show that the MODIS aerosol optical thickness retrievals are accurate to within the pre-launch expectations. However, the validation in regions dominated by desert dust is less accurate than in regions dominated by fine mode aerosol or background marine sea salt. The discrepancy is most apparent in retrievals of aerosol size parameters over ocean. In dust situations, the MODIS algorithm tends to under predict particle size because the reflectances at top of atmosphere measured by MODIS exhibit the stronger spectral signature expected by smaller particles. This pattern is consistent with the angular and spectral signature of non-spherical particles. All possible aerosol models in the MODIS Look-Up Tables were constructed from Mie theory, assuming a spherical shape. Using a combination of MODIS and AERONET observations, in regimes dominated by desert dust, we construct phase functions, empirically, with no assumption of particle shape. These new phase functions are introduced into the MODIS algorithm, in lieu of the original options for large dust-like particles. The results will be analyzed and examined.

Remer, Lorraine A.↗

The Essential Role of Westerly Wind Bursts in ENSO Dynamics and Extreme Events Quantified in Model “Wind Stress Shaving” Experiments

Abstract Westerly wind bursts (WWBs)—brief but strong westerly wind anomalies in the equatorial Pacific—are believed to play an important role in El Niño–Southern Oscillation (ENSO) dynamics, but quantifying their effects is challenging. Here, we investigate the cumulative effects of WWBs on ENSO characteristics, including the occurrence of extreme El Niño events, via modified coupled model experiments within Community Earth System Model (CESM1) in which we progressively reduce the impacts of wind stress anomalies associated with model-generated WWBs. In these “wind stress shaving” experiments we limit momentum transfer from the atmosphere to the ocean above a preset threshold, thus “shaving off” wind bursts. To reduce the tropical Pacific mean state drift, both westerly and easterly wind bursts are removed, although the changes are dominated by WWB reduction. As we impose progressively stronger thresholds, both ENSO amplitude and the frequency of extreme El Niño decrease, and ENSO becomes less asymmetric. The warming center of El Niño shifts westward, indicating less frequent and weaker eastern Pacific (EP) El Niño events. Removing most wind burst–related wind stress anomalies reduces ENSO mean amplitude by 22%. The essential role of WWBs in the development of extreme El Niño events is highlighted by the suppressed eastward migration of the western Pacific warm pool and hence a weaker Bjerknes feedback under wind shaving. Overall, our results reaffirm the importance of WWBs in shaping the characteristics of ENSO and its extreme events and imply that WWB changes with global warming could influence future ENSO.

Meteorology & Atmospheric Sciences↗

Global metagenomics reveals plastid diversity and unexplored algal lineages

Photosynthetic organelles in eukaryotes originated through primary endosymbiosis with a cyanobacterium, an event that profoundly shaped the evolutionary landscape of the eukaryotic tree of life. Primary plastids in Archaeplastida, especially in cultivable plants and algae, contribute most to known plastid diversity. Secondary and higher-order endosymbiosis, involving eukaryotic hosts and algal endosymbionts, further spread photosynthesis among protists within the CASH lineages (Cryptophyta, Alveolata, Stramenopila, and Haptophyta). Despite various hypotheses explaining secondary plastid evolution and distribution, empirical support remains limited. Here, we employ cultivation-independent global metagenomics to expand plastid diversity and investigate plastid origins. We capture 1,027 plastid sequences, including 300 novel sequences belonging to previously unsequenced plastids and representing yet-to-be described microeukaryotes. This includes a new lineage that offers insights into plastid evolution in haptophytes and cryptophytes. Our results confirm that Archaeplastida plastids originate from an early branching cyanobacterial lineage closely related to Gloeomargaritales and identify the closest extant relative of Paulinella plastids. Additionally, our findings suggest two independent origins of secondary red-algal plastids, contributing to plastid diversity in CASH lineages and challenging the prevailing model of single secondary plastid origin. Our study highlights the importance of metagenomic data in uncovering biological diversity and advancing understanding of plastid relationships across photosynthetic eukaryotes.

59 BASIC BIOLOGICAL SCIENCES↗

Rapid Process to Generate Beam Envelopes for Optical System Analysis

The task of evaluating obstructions in the optical throughput of an optical system requires the use of two disciplines, and hence, two models: optical models for the details of optical propagation, and mechanical models for determining the actual structure that exists in the optical system. Previous analysis methods for creating beam envelopes (or cones of light) for use in this obstruction analysis were found to be cumbersome to calculate and take significant time and resources to complete. A new process was developed that takes less time to complete beam envelope analysis, is more accurate and less dependent upon manual node tracking to create the beam envelopes, and eases the burden on the mechanical CAD (computer-aided design) designers to form the beam solids. This algorithm allows rapid generation of beam envelopes for optical system obstruction analysis. Ray trace information is taken from optical design software and used to generate CAD objects that represent the boundary of the beam envelopes for detailed analysis in mechanical CAD software. Matlab is used to call ray trace data from the optical model for all fields and entrance pupil points of interest. These are chosen to be the edge of each space, so that these rays produce the bounding volume for the beam. The x and y global coordinate data is collected on the surface planes of interest, typically an image of the field and entrance pupil internal of the optical system. This x and y coordinate data is then evaluated using a convex hull algorithm, which removes any internal points, which are unnecessary to produce the bounding volume of interest. At this point, tolerances can be applied to expand the size of either the field or aperture, depending on the allocations. Once this minimum set of coordinates on the pupil and field is obtained, a new set of rays is generated between the field plane and aperture plane (or vice-versa). These rays are then evaluated at planes between the aperture and field, at a desired number of steps perceived necessary to build up the bounding volume or cone shape. At each plane, the ray coordinates are again evaluated using the convex hull algorithm to reduce the data to a minimal set. When all of the coordinates of interest are obtained for every plane of the propagation, the data is formatted into an xyz file suitable for FRED optical analysis software to import and create a STEP file of the data. This results in a spiral-like structure that is easily imported by mechanical CAD users who can then use an automated algorithm to wrap a skin around it and create a solid that represents the beam.

Howard, Joseph↗

A Preliminary Analysis of Precipitation Properties and Processes during NASA GPM IFloodS

The Iowa Flood Studies (IFloodS) is a NASA Global Precipitation Measurement (GPM) ground measurement campaign, which took place in eastern Iowa from May 1 to June 15, 2013. The goals of the field campaign were to collect detailed measurements of surface precipitation using ground instruments and advanced weather radars while simultaneously collecting data from satellites passing overhead. Data collected by the radars and other ground instruments, such as disdrometers and rain gauges, will be used to characterize precipitation properties throughout the vertical column, including the precipitation type (e.g., rain, graupel, hail, aggregates, ice crystals), precipitation amounts (e.g., rain rate), and the size and shape of raindrops. The impact of physical processes, such as aggregation, melting, breakup and coalescence on the measured liquid and ice precipitation properties will be investigated. These ground observations will ultimately be used to improve rainfall estimates from satellites and in particular the algorithms that interpret raw data for the upcoming GPM mission's Core Observatory satellite, which launches in 2014. The various precipitation data collected will eventually be used as input to flood forecasting models in an effort to improve capabilities and test the utility and limitations of satellite precipitation data for flood forecasting. In this preliminary study, the focus will be on analysis of NASA NPOL (S‐band, polarimetric) radar (e.g., radar reflectivity, differential reflectivity, differential phase, correlation coefficient) and NASA 2D Video Disdrometers (2DVDs) measurements. Quality control and processing of the radar and disdrometer data sets will be outlined. In analyzing preliminary cases, particular emphasis will be placed on 1) documenting the evolution of the rain drop size distribution (DSD) as a function of column melting processes and 2) assessing the impact of range on ground‐based polarimetric radar estimates of DSD properties.

Carey, Lawrence↗

Enabling the Assimilation of CrIS Shortwave Infrared Observations in Global NWP at NOAA. Part II: OSEs and Results

The assimilation of data from hyperspectral infrared sounders in global data assimilation systems has historically been focused on observations in the longwave infrared (LWIR) region of the spectrum (650-1100 cm−1), despite the often concurrent availability of measurements from the shortwave infrared (SWIR) region of the spectrum (2150-2550 cm−1), because issues (like solar effects) have generally prevented the assimilation of SWIR observations. Recent advances in radiative transfer models have worked to address some of the previous challenges in simulating SWIR observations, and the assimilation of SWIR data (e.g. from potential future small-satellites) is now a feasible prospect. Still, a better understanding of how these observations perform in a data assimilation system and impact resulting analyses and NWP forecasts is necessary. In this study, the value of SWIR observations in global NWP is assessed by assimilating SWIR observations from the Cross-track Infrared Sounder (CrIS) in NOAA’s Global Data Assimilation System (GDAS). The methodologies used to enable the assimilation of these observations, including the implementation of a scene-dependent observation error and the enhancement of quality control procedures, are discussed, as are the results of Observing System Experiments (OSEs) conducted to evaluate the impact of assimilating SWIR observations on forecast skill. The overall results show that SWIR assimilation produces similar forecast impacts to LWIR assimilation. The ability to demonstrate that the assimilation or SWIR observations in NWP is a realistic prospect may help to shape future constellations of small-satellites to serve as a beneficial complement to the current constellation if hyperspectral IR sounders.

Erin Jones↗

Magnetopause Reconnection as Influenced by the Dipole Tilt Under Southward IMF Conditions: Hybrid Simulation and MMS Observation

Abstract Using a three‐dimensional (3‐D) global‐scale hybrid code, the Magnetospheric Multiscale (MMS) reconnection event around 02:13 UT on 18 November 2015, highlighted in the Geospace Environment Modeling (GEM) Dayside Kinetic Challenge, is simulated, in which the interplanetary magnetic field (IMF) points southward and the geomagnetic field has a −27° dipole tilt angle. Strong southward plasma jets are found near the magnetopause as a result of the dayside reconnection. Our results indicate that the subsolar magnetopause reconnection X line shifts from the subsolar point toward the Northern Hemisphere due to the effect of the tilted geomagnetic dipole angle, consistent with the MMS observation. Subsequently, the reconnection X lines or sites and reconnection flux ropes above the equator propagate northward along the magnetopause. The formation and global distribution of the X lines and the structure of the magnetopause reconnection are investigated in detail with the simulation. Mirror mode waves are also found in the middle of the magnetosheath downstream of the quasi‐perpendicular shock where the plasma properties are consistent with the mirror instability condition. As a special outcome of the GEM challenge event, the spatial and temporal variations in reconnection, the electromagnetic power spectra, and the associated D‐shaped ion velocity distributions in the simulated reconnection event are compared with the MMS observation.

Guo, Zhifang↗

Charge radii in covariant density functional theory: A global view

A systematic global investigation of differential charge radii has been performed within the CDFT framework for the first time. Theoretical results obtained with conventional covariant energy density functionals and the separable pairing interaction of Tian et al. [Phys. Lett. B 676, 44 (2009)] are compared with experimental differential charge radii in the regions of the nuclear chart in which available experimental data crosses the neutron shell closures at N=28,50,82, and 126. The analysis of absolute differential radii of different isotopic chains and their relative properties indicate clearly that such properties are reasonably well described in model calculations in the cases when the mean-field approximation is justified. However, while the observed clusterization of differential charge radii of different isotopic chains is well described above the N=50 and N=126 shell closures, it is more difficult to reproduce it above the N=28 and N=82 shell closures because of possible deficiencies in the underlying single-particle structure. The impact of the latter has been evaluated for spherical shapes and it was shown that the relative energies of the single-particle states and the patterns of their occupation with increasing neutron number have an appreciable impact on the evolution of the δ$\langle$r2$\rangle$N,N' values. These factors also limit the predictive power of model calculations in the regions of high densities of the single-particle states of different origin. It is shown that the kinks in the charge radii at neutron shell closures are due to the underlying single-particle structure and due to weakening or collapse of pairing at these closures. The regions of the nuclear chart in which the correlations beyond mean field are expected to have an impact on charge radii are indicated; the analysis shows that the assignment of a calculated excited prolate minimum to the experimental ground state allows us to understand the trends of the evolution of differential charge radii with neutron number in many cases of shape coexistence even at the mean-field level. It is usually assumed that pairing is a dominant contributor to odd-even staggering (OES) in charge radii. Our analysis paints a more complicated picture. It suggests a new mechanism in which the fragmentation of the single-particle content of the ground state in odd-mass nuclei due to particle-vibration coupling provides a significant contribution to OES in charge radii.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Higher-Order Theory for Functionally Graded Materials

Functionally graded materials (FGM's) are a new generation of engineered materials wherein the microstructural details are spatially varied through nonuniform distribution of the reinforcement phase(s). Engineers accomplish this by using reinforcements with different properties, sizes, and shapes, as well as by interchanging the roles of the reinforcement and matrix phases in a continuous manner (ref. 1). The result is a microstructure that produces continuously or discretely changing thermal and mechanical properties at the macroscopic or continuum scale. This new concept of engineering the material's microstructure marks the beginning of a revolution both in the materials science and mechanics of materials areas since it allows one, for the first time, to fully integrate the material and structural considerations into the final design of structural components. Functionally graded materials are ideal candidates for applications involving severe thermal gradients, ranging from thermal structures in advanced aircraft and aerospace engines to computer circuit boards. Owing to the many variables that control the design of functionally graded microstructures, full exploitation of the FGM's potential requires the development of appropriate modeling strategies for their response to combined thermomechanical loads. Previously, most computational strategies for the response of FGM's did not explicitly couple the material's heterogeneous microstructure with the structural global analysis. Rather, local effective or macroscopic properties at a given point within the FGM were first obtained through homogenization based on a chosen micromechanics scheme and then subsequently used in a global thermomechanical analysis.

Aboudi, J.↗

Comparison of PARASOL Observations with Polarized Reflectances Simulated Using Different Ice Habit Mixtures

Insufficient knowledge of the habit distribution and the degree of surface roughness of ice crystals within ice clouds is a source of uncertainty in the forward light scattering and radiative transfer simulations required in downstream applications involving these clouds. The widely used MODerate Resolution Imaging Spectroradiometer (MODIS) Collection 5 ice microphysical model assumes a mixture of various ice crystal shapes with smooth-facets except aggregates of columns for which a moderately rough condition is assumed. When compared with PARASOL (Polarization and Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar) polarized reflection data, simulations of polarized reflectance using smooth particles show a poor fit to the measurements, whereas very rough-faceted particles provide an improved fit to the polarized reflectance. In this study a new microphysical model based on a mixture of 9 different ice crystal habits with severely roughened facets is developed. Simulated polarized reflectance using the new ice habit distribution is calculated using a vector adding-doubling radiative transfer model, and the simulations closely agree with the polarized reflectance observed by PARASOL. The new general habit mixture is also tested using a spherical albedo differences analysis, and surface roughening is found to improve the consistency of multi-angular observations. It is suggested that an ice model incorporating an ensemble of different habits with severely roughened surfaces would potentially be an adequate choice for global ice cloud retrievals.

Cole, Benjamin H.↗

On Study of Air/Space-borne Dual-Wavelength Radar for Estimates of Rain Profiles

In this study, a framework is discussed to apply air/space-borne dual-wavelength radar for the estimation of characteristic parameters of hydrometeors. The focus of our study is on the Global Precipitation Measurements (GPM) precipitation radar, a dual-wavelength radar that operates at Ku (13.8 GHz) and Ka (35 GHz) bands. As the droplet size distributions (DSD) of rain are expressed as the Gamma function, a procedure is described to derive the median volume diameter (D(sub 0)) and particle number concentration (N(sub T)) of rain. The correspondences of an important quantity of dual-wavelength radar, defined as deferential frequency ratio (DFR), to the D(sub 0) in the melting region are given as a function of the distance from the 0 C isotherm. A self-consistent iterative algorithm that shows a promising to account for rain attenuation of radar and infer the DSD without use of surface reference technique (SRT) is examined by applying it to the apparent radar reflectivity profiles simulated from the DSD model and then comparing the estimates with the model (true) results. For light to moderate rain the self-consistent rain profiling approach converges to unique and correct solutions only if the same shape factors of Gamma functions are used both to generate and retrieve the rain profiles, but does not converges to the true solutions if the DSD form is not chosen correctly. To further examine the dual-wavelength techniques, the self-consistent algorithm, along with forward and backward rain profiling algorithms, is then applied to the measurements taken from the 2nd generation Precipitation Radar (PR-2) built by Jet Propulsion Laboratory. It is found that rain profiles estimated from the forward and backward approaches are not sensitive to shape factor of DSD Gamma distribution, but the self-consistent method is.

Liao, Liang↗

CRADA Final Report: CRADA Number NFE-22-09330 with General Fusion

General Fusion is developing a magnetized target fusion (MTF) approach that involves compressing an initial magnetically confined plasma inside a cavity formed in liquid metal. This approach builds from concepts initially developed under the Linus program at the U.S. Naval Research Laboratory and combines it with advances from compact toroid experiment (CTX) and sustained spheromak plasma experiment (SSPX) in compact toroid plasmas and coaxial Marshall gun systems. Modeling the tokamak during compression is central to designing a successful MTF device. The plasma is formed by coaxial helicity injection in the General Fusion device. Immediately after formation, the plasma has a diverted tokamak configuration with a single null. As the wall moves inwards, the plasma is repelled from the conducting surface and driven inwards by currents induced by its magnetic field in the liquid metal wall. As the liquid metal closes (or bridges) the opening of the coaxial plasma injector, the magnetic field topology alters to remove the null. Due to this, the plasma moves from a diverted to a wall-limited configuration. The liquid metal liner continues to close in and change shape, reducing in radius by a factor of ten at the peak of plasma compression. A model of the MTF plasma must be able to handle this continually varying geometry, and to be predictive, it must faithfully include the real imperfections arising in the process. In this project, we pursued a Monte Carlo approach to closures for MHD by computing kinetic electron trajectories in an MHD plasma background from simulations of GF devices. This requires enhancing the capabilities of the KORC-T code for running large ensembles of kinetic trajectories by porting it to GPU architectures and enabling workflows for large ensembles on OLCF machines. With these capabilities, it is possible to produce a large library of kinetic calculations of electron orbits evolving in plasma configurations spanning the magnetic configurations and plasma density profiles, including non-axisymmetry, arising in the General Fusion’s existing PI3 spherical tokamak device. Using ensembles will capture particles passing a single point in space in a given magnetic configuration, and the entire dataset will cover a range of global magnetic field geometries. By sampling around many starting points, this dataset will capture the spatial dependence of the plasma parameters. From this large dataset, it is possible to produce a reduced model for the kinetic effects not captured in MHD.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Effects of RAM Exposure on a Low Earth Orbit BroadBand Radiometer (BBR): CERES Experience and Implications for EarthCARE

In order to best detect real changes in the Earth's climate system it is estimated that space based instrumentation measuring the global Earth Radiation Budget (ERB) must remain calibrated with a stability of 0.3% per decade. This level of stability is beyond the specified accuracy of existing ERB programs such as the Clouds and the Earth's Radiant Energy System (CERES, using three broadband radiometric scanning channels: the shortwave (SW 0.3 - 5?m), total (0.3 - >100 micron), and window (8 - 12 micron)). When in low earth orbit, it has been shown that optical response to blue-UV radiance can be reduced significantly (> 3%) due to UV hardened contaminants deposited on the surface of the optics. Evidence suggests that exposure of telescope optics to the forward looking ram direction is the primary cause of this contamination build up. With typical onboard calibration lamps emitting very low energy in the blue-UV region, this darkening is not directly measurable using standard internal calibration techniques. This paper describes a study using a model of ram exposure induced contaminant deposition and darkening, in conjunction standard established in-flight vicarious and internal calibration techniques to derive the spectral shape of the darkening to which a broadband instrument is subjected. The results of the model when applied to the CERES instruments are shown. These findings are of great importance to the EarthCARE project, whose BBR uses one broadband telescope permanently looking forward at 45 degrees, with continual exposure to the ram direction. Specific attention may therefore be needed in the design of BBR optics and on-board calibration in order to prevent or compensate for the spectral darkening seen in the CERES project.

Matthews, Grant↗

Composition Reanalyses at NASA’s Global Modeling and Assimilation Office

Scientific Assessments of Ozone Depletion 2018 and 2022 report the recovery of Antarctic ozone, consistent with diminishing concentrations of halogens in the stratosphere. Both the size and the depth of the springtime ozone holes exhibit downward trends, particularly in September. Superimposed on the recovery trend are significant year-to-year fluctuations arising from dynamical variability potentially influenced by climate forcing and volcanic eruptions. Since 2018 the Antarctic stratosphere has experienced a wild parade of austral spring seasons with a sudden stratospheric warming and exceptionally high ozone in 2019 followed by large and long-lasting ozone holes in the following years, prompting questions about the speed and detectability of Antarctic ozone recovery and its potential connections to human-induced climate change. From the Australian New Years’ wildfires of 2020 to volcanic aerosols to the unprecedented injection of water vapor by the Hunga volcanic eruption, recent scientific literature on the subject investigates many factors that may or may not have contributed to this remarkable interannual variability. This presentation summarizes dynamical influences on springtime Antarctic stratospheric ozone in recent years and discusses these results in the context of long-term trends. In particular, this work seeks to isolate dynamical and chemical contributions to the Antarctic springs since 2019 using a consistent methodological framework. Our analysis uses constituent and meteorological fields from the MERRA-2 Stratospheric Composition Reanalysis of Aura MLS (M2-SCREAM) in combination with data from the Atmospheric Chemistry Experiment – Fourier Transform Spectrometer and from ozone sondes. Using the high spatial and temporal resolution of M2-SCREAM, we analyze the daily evolution of southern polar ozone, HCl, N2O, and water vapor in dynamical flow-following coordinates relative to the location, size, and shape of the polar vortex. For vertically integrated stratospheric ozone we emphasize the importance of the wave-influenced geometry of the polar vortex and its vertical alignment. The ultimate purpose of this project is to contribute to the quantification of the speed of the Antarctic ozone recovery and associated uncertainties.

Krzysztof Wargan↗

Chemical and structural characterization of particulate fallout isolated from air-filters

We report particulate nuclear fallout is the radioactive byproduct of a nuclear event formed by the mixture of proximate environmental materials with vaporized bomb debris. The fallout debris can be transported into the atmosphere during cloud rise, raining out locally and dispersing globally constituting a radiation hazard and contributing to the distribution of anthropogenic radionuclides in the environment. Questions remain on how entrainment of environmental material in the fireball affects fallout formation processes and radionuclide incorporation and distribution during cooling. To inform the characterization of fallout including the development of fallout size distributions and how radionuclides are incorporated into fallout debris where entrainment plays a role, we analyzed an archived historic US air-filter collected by aircraft in the aftermath of ground interacting nuclear tests. Particulate fallout collected on the filter was isolated and analyzed using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and NanoSIMS (Secondary Ion Mass Spectrometry) to determine chemistry, structure, morphology, and size of the particles. Results demonstrate that the particles isolated from the filter have spherical shape, display complex internal structures, and are mainly composed of Fe and Si oxides. In these spherical particles, Pu is preferentially associated with Fe-rich composition. The characterization of fallout particulate samples can provide information on nucleation and particle growth from the vapor phase to improve modeling and simulation of fallout hazards.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗