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At least 451 records · Page 25

Ostwald ripening in a system with a high volume fraction of coarsening phase

The coarsening of Sn-rich and Pb-rich solid phases in contact with eutectic liquid in the volume fraction solid range above approximately 0.6, where the development of a solid skeletal structure inhibits sedimentation, is investigated. Particle intercept distributions are shown to be time independent when scaled by the average intercept. It is noted that the coarsening rate constants obtained exceed the values calculated from theory by factors ranging from about 2 to 5.

Hardy, S. C.↗

Naturally occurring continued fractions in the variation of Kepler's equation

A family of functions involving integrals of universal functions is introduced. These functions have some interesting mathematical properties including the fact that they may be expressed as Gaussian continued fractions. A unique method of performing the integration is demonstrated which indicates why these functions may be important in the variation of Kepler's equation.

Shepperd, Stanley W.↗

Effective-field-theory model for the fractional quantum Hall effect

Starting directly from the microscopic Hamiltonian, a field-theory model is derived for the fractional quantum Hall effect. By considering an approximate coarse-grained version of the same model, a Landau-Ginzburg theory similar to that of Girvin (1986) is constructed. The partition function of the model exhibits cusps as a function of density. It is shown that the collective density fluctuations are massive.

Zhang, S. C.↗

High alumina (HA) and very high potassium (VHK) basalt clasts from Apollo 14 breccias. II - Whole rock geochemistry - Further evidence for combined assimilation and fractional crystallization within the lunar crust

The understanding of basalt petrogenesis at the Apollo 14 site has increased markedly due to the study of 'new' samples from breccia 'pull-apart' efforts. Whole-rock compositions of 26 new high alumina (HA) and 7 very high potassium (VHK) basalts emphasize the importance of combined assimilation and fractional crystallization in a lunar regime. Previously formulated models for HA and VHK basalt petrogenesis are modified in order to accomodate these new data, although modeling parameters are essentially the same. The required range in HA basalt compositions is generated by the assimilation of KREEP by a 'primitive' parental magma. The VHK basalts can be generated by three parental HA basalts assimilating granite. Results indicate that VHK basalt compositions are dominated by the parental magma, and only up to 8 percent granite assimilation is required. This modeling indicates that at least three VHK basalt flows must be present at the Apollo 14 site.

Neal, C. R.↗

Basalts and gabbros from Mare Crisium - Evidence for extreme fractional crystallization

Petrographic and electron microprobe techniques were used to examine igneous fragments in Luna 24 samples 24088 and 24105. It is the complex chemistry of the pyroxenes that distinguishes the different rock types. Basaltic pyroxenes exhibit an Fe-enrichment trend; the evolutionary trends are more complex in the gabbros, with enrichments in both Fe and Ti and a depletion in Cr. These chemical evolutionary trends are displayed by a progressive variation in rock types from Mg-rich olivine-gabbro to olivine-gabbro, and to ferrogabbro and ferrotroctolite. The low TiO2 content of the primary melt, possibly represented by the least-evolved Mg-rich olivine-gabbro, retarded the formation of early ilmenite and spinel, such that 'Fenner Trend' Fe enrichment occurred. The ferrotroctolite is probably the end product of chemical evolution by extreme fractional crystallization, controlled primarily by olivine and pyroxene crystallization.

Lu, F.↗

Laboratory simulation of meteoritic noble gases. III - Sorption of neon, argon, krypton, and xenon on carbon - Elemental fractionation

The sorption of Ne, Ar, Kr, and Xe was studied in carbon black, acridine carbon, and diamond in an attempt to understand the origin of trapped noble gases in meteorites. The results support a model in which gases are physically adsorbed on interior surfaces formed by a pore labyrinth within amorphous carbons. The data show that: (1) the adsorption/desorption times are controlled by choke points that restrict the movement of noble gas atoms within the pore labyrinth, and (2) the physical adsorption controls the temperature behavior and elemental fractionation patterns.

Wacker, John F.↗

Injectant mole-fraction imaging in compressible mixing flows using planar laser-induced iodine fluorescence

A technique is described for imaging the injectant mole-fraction distribution in nonreacting compressible mixing flow fields. Planar fluorescence from iodine, seeded into air, is induced by a broadband argon-ion laser and collected using an intensified charge-injection-device array camera. The technique eliminates the thermodynamic dependence of the iodine fluorescence in the compressible flow field by taking the ratio of two images collected with identical thermodynamic flow conditions but different iodine seeding conditions.

Hartfield, Roy J., Jr.↗

Composition of dust from Comet P/Halley: The mineral fraction

The composition of dust from Comet Halley was investigated in situ during the Vega 1, Vega 2, and Giotto encounters by the PIA/PUMA impact mass spectrometers. More than 5000 meaningful spectra of individual dust particles were obtained, most in a compressed mode. The interpretation of these spectra in terms of elemental and mineralogical composition will be discussed. Accounting for these difficulties, the following conclusions can be derived for the mineral fraction of dust particles: (1) the observed compositions are compatible with the full range of observed meteoritic minerals (in particular mafic silicates, plagioclases, sulfides, oxides); and (2) within each mineralogical class, the spread in composition appears much wider and more uniform than in meteorites. The low overall density and very large excess of light elements will be discussed. These first direct results on cometary dust considerably strengthen the case for a comet sample return mission.

Langevin, Y.↗

The influence of buoyant forces and volume fraction of particles on the particle pushing/entrapment transition during directional solidification of Al/SiC and Al/graphite composites

Directional solidification experiments in a Bridgman-type furnace were used to study particle behavior at the liquid/solid interface in aluminum metal matrix composites. Graphite or silicon-carbide particles were first dispersed in aluminum-base alloys via a mechanically stirred vortex. Then, 100-mm-diameter and 120-mm-long samples were cast in steel dies and used for directional solidification. The processing variables controlled were the direction and velocity of solidification and the temperature gradient at the interface. The material variables monitored were the interface energy, the liquid/particle density difference, the particle/liquid thermal conductivity ratio, and the volume fraction of particles. These properties were changed by selecting combinations of particles (graphite or silicon carbide) and alloys (Al-Cu, Al-Mg, Al-Ni). A model which consideres process thermodynamics, process kinetics (including the role of buoyant forces), and thermophysical properties was developed. Based on solidification direction and velocity, and on materials properties, four types of behavior were predicted. Sessile drop experiments were also used to determine some of the interface energies required in calculation with the proposed model. Experimental results compared favorably with model predictions.

Stefanescu, Doru M.↗

The equation of state for stellar envelopes. IV - Thermodynamic quantities and selected ionization fractions for six elemental mixes

The free-energy minimization technique in the form developed in the preceding papers in this series is employed to evaluate thermodynamic quantities and ionization fractions on a fine temperature and density grid for six astrophysical mixtures of 15 elements. The mixtures range from that appropriate to super-metal-rich stars, through solar abundance, to that for extreme Population II objects. In this paper, the results for solar abundances are summarized in a form that is illustrative and which facilitates comparison with the results from other equation of state calculations.

Mihalas, Dimitri↗

Coarsening in high volume fraction nickel-base alloys

The coarsening behavior of the gamma-prime precipitate has been examined in high volume fraction nickel-base alloys aged at elevated temperatures for times of up to 5000 h. Although the cube rate law was observed during coarsening, none of the presently available coarsening theories showed complete agreement with the experimental particle size distributions (PSDs). These discrepancies were thought to be due to elastic coherency strains which were not considered by the available models. Increasing the Mo content significantly influenced the PSDs and decreased the coarsening rate of the gamma-prime cubes, as a result of increasing the magnitude of the lattice mismatch. After extended aging times, the gamma-prime cubes underwent massive coalescence into plates at a rate which was much faster than the cuboidal coarsening rate. Once the gamma-prime plates were formed, further coarsening was not observed, and this stabilization of the microstructure was attributed to the development of dislocation networks at the gamma-gamma-prime interfaces.

Mackay, R. A.↗

Petrology and mineralogy of Type II, FeO-rich chondrules in Semarkona (LL3.0) - Origin by closed-system fractional crystallization, with evidence for supercooling

The petrology of type II porphyritic olivine chondrules in Semarkona (LL3.0) has been studied in detail. Olivines in these chondrules are euhedral, Fe-rich, and are strongly zoned from cores to rims of grains in FeO (Fa10-30), Cr2O3 (0.2-0.6 wt pct), MnO (0.2-0.7 wt pct), and CaO (0.1-0.4 wt pct). Interstitial mesostasis is rich in Si, Al, and Ca and is glassy with abundant microcrystallites. Minor minerals include troilite, Fe,Ni metal, and chromite. Some olivine grains contain euhedral, fayalite-rich cores that are probably produced during initial supercooling of the chondrule melt. Rare relict grains of forsteritic olivine have compositions very similar to olivines in type IA chondrules in Semarkona and may result from disaggregation of such chondrules. Apart from these relics, all properties of type II chondrules can be described by closed-system fractional crystallization of droplets which were essentially entirely molten. Type IA chondrules may have formed from type II chondrules by loss of Fe and volatiles. Alternatively, the two chondrule types may have formed in regions of considerable diversity in the solar nebula from precursor materials with different Fe/Mg ratios.

Jones, Rhian H.↗

An improved method for simultaneous determination of frictional pressure drop and vapor volume fraction in vertical flow boiling

The two-phase frictional pressure drop and vapor volume fraction in the vertical boiling and adiabatic flow of the refrigerant, R11, have been simultaneously measured by a liquid balancing column and differential magnetic reluctance pressure transducers. An account is given of the experimental apparatus and procedure, data acquisition and analysis, and error estimation employed. All values of two-phase multipliers evaluated on the basis of the measured frictional pressure drop data in vertical upflow fall in the range bounded by the predictions of the Chisholm correlation and the homogeneous model.

Klausner, J. F.↗

Use of narrow-band spectra to estimate the fraction of absorbed photosynthetically active radiation

A novel approach is proposed for using high-spectral resolution imagers to estimate the fraction of photosynthetically active radiation adsorbed, f(apar), by vegetated land surfaces. In comparison to approaches using broad-band vegetation indices, the proposed method appears to be relatively insensitive to the reflectance of nonphotosynthetically active material beneath the canopy, such as leaf litter or soil. The method is based on a relationship between the second derivative of the reflectance vs wavelength function for terrestrial vegetation and f(apar). The relationship can be defined by the second derivatives in either of two windows, one in the visible region centered at 0.69 micron, another in the near-infrared region centered at 0.74 micron.

Hall, Forrest G.↗

Comparison of ground and satellite based measurements of the fraction of photosynthetically active radiation intercepted by tall-grass prairie

The fraction, of photosynthetically active radiation absorbed by vegetation, F sub ipar, is an important requirement for estimating vegetation biomass productivity and related quantities. This was an integral part of a large international effort; the First ISLSCP Field Experiment (FIFE). The main objective of FIFE was to study the effects of vegetation on the land atmosphere interactions and to determine if these interactions can be assessed from satellite spectral measurements. The specific purpose of this experiment was to find out how well measurements of F sub ipar relate to ground, helicopter, and satellite based spectral reflectance measurements. Concurrent measurements of F sub ipar and ground, helicopter, and satellite based measurements were taken at 13 tall grass prairie sites in Kansas. The sites were subjected to various combinations of burning and grazing managements.

Demetriades-Shah, T. H.↗

Comparison of ground and satellite based measurements of the fraction of photosynthetically active radiation intercepted by tall-grass prairie

The fraction, of photosynthetically active radiation intercepted by vegetation, F(sub ipar) is an important parameter for modeling the interactions between the land-surface and atmosphere and for estimating vegetation biomass productivity. This study was; therefore, an integral part of FIFE. The specific purpose of this experiment was to find out how well definitive measurements of F(sub ipar) on the ground relate to near-ground and satellite based spectral reflectance measurements. Concurrent measurements of F(sub ipar) and ground, helicopter, and satellite based reflectance measurements were taken at thirteen tall-grass prairie sites within the FIFE experimental area. The sites were subjected to various combinations of burning and grazing managements. The ground and helicopter based reflectance measurements were taken on the same day or few days from the time of the overpass of LANDSAT and SPOT satellites. Ground-based reflectance measurements and sun photometer readings taken at the times of the satellite overpasses were used to correct for atmospheric attenuation. Hand-held radiometer spectral indices were strongly correlated with helicopter and satellite based values (r=0.94 for helicopter, 0.93 for LANDSAT Thematic Mapper, and 0.86 for SPOT). However, the ground, helicopter, and satellite based normalized difference spectral vegetation indices showed low sensitivity to changes in F(sub ipar). Reflectance measurements were only moderately well correlated with measurements of F(sub ipar) (r=0.82 for hand-held radiometer, 0.84 for helicopter measurements, and 0.75 for the LANDSAT Thematic Mapper and SPOT). Improved spectral indices which can compensate for site differences are needed in order to monitor F(sub ipar) more reliably.

Demetriades-Shah, T. H.↗

A fractional step solution method for the unsteady incompressible Navier-Stokes equations in generalized coordinate systems

The time-dependent, three-dimensional incompressible Navier-Stokes equations are presently solved in generalized coordinate systems by means of a fractional-step method whose primitive variable formulation uses as dependent variables, in place of the Cartesian components of the velocity: (1) pressure (defined at the center of the computational cell), and (2) volume fluxes across the faces of the cells. The momentum equations are solved by means of an approximate factorization method. A novel 'ZEBRA' scheme incorporating four-color ordering efficiently solves the Poisson equation. Illustrative two- and three-dimensional laminar flow test cases are computed and evaluated relative to extant numerical and experimental results, and good agreement is obtained.

Rosenfeld, Moshe↗

La/Sm ratios in mare basalts as a consequence of mafic cumulate fractionation from an initial lunar magma

A model is constructed for the La/Sm ratio and the abundance of chrondrite-normalized La in different proportions of partial melts of a mafic cumulate source that might have settled to the bottom of an initial lunar magma ocean prior to any plagioclase separation. It is proposed that La/Sm ratios and chrondrite-normalized La abundances of common mare basalts are found in partial melts only if: the mafic cumulate consists mostly of clinopyroxene, a very low fraction of the cumulate melts, and the cumulate represents a moderate to high proportion of the crystallization of the initial magma ocean. Only if the partitioning of clinopyroxene is forced to mimic plagioclase (DLa is greater than DSm) do the present modeling results become compatible with the scenario for producing appropriate parent melts of mare basalts from mafic cumulates. It is found unlikely that parent melts of mare basalts were produced from mafic cumulates of an initial lunar magma ocean that had not had any plagioclase crystallization.

Shaffer, E. E.↗