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At least 451 records · Page 25

A novel micro-Raman technique to detect and characterize 4H-SiC stacking faults

A novel Micro-Raman technique was designed and used to detect extended defects in 4H-SiC homoepitaxy. The technique uses above band-gap high-power laser densities to induce a local increase of free carriers in undoped epitaxies (n < 10{sup 16} at/cm{sup −3}), creating an electronic plasma that couples with the longitudinal optical (LO) Raman mode. The Raman shift of the LO phonon-plasmon-coupled mode (LOPC) increases as the free carrier density increases. Crystallographic defects lead to scattering or recombination of the free carriers which results in a loss of coupling with the LOPC, and in a reduction of the Raman shift. Given that the LO phonon-plasmon coupling is obtained thanks to the free carriers generated by the high injection level induced by the laser, we named this technique induced-LOPC (i-LOPC). This technique allows the simultaneous determination of both the carrier lifetime and carrier mobility. Taking advantage of the modifications on the carrier lifetime induced by extended defects, we were able to determine the spatial morphology of stacking faults; the obtained morphologies were found to be in excellent agreement with those provided by standard photoluminescence techniques. The results show that the detection of defects via i-LOPC spectroscopy is totally independent from the stacking fault photoluminescence signals that cover a large energy range up to 0.7 eV, thus allowing for a single-scan simultaneous determination of any kind of stacking fault. Combining the i-LOPC method with the analysis of the transverse optical mode, the micro-Raman characterization can determine the most important properties of unintentionally doped film, including the stress status of the wafer, lattice impurities (point defects, polytype inclusions) and a detailed analysis of crystallographic defects, with a high spectral and spatial resolution.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Characterizing Oxygen Local Environments in Paramagnetic Battery Materials via 17 O NMR and DFT Calculations

Experimental techniques that probe the local environment around O in paramagnetic Li-ion cathode materials are essential in order to understand the complex phase transformations and O redox processes that can occur during electrochemical delithiation. While Li NMR is a well-established technique for studying the local environment of Li ions in paramagnetic battery materials, the use of 17 O NMR in the same materials has not yet been reported. In the work reported here, we present a combined 17 O NMR and hybrid density functional theory study of the local O environments in Li 2 MnO 3 , a model compound for layered Li-ion batteries. After a simple 17 O enrichment procedure, we observed five resonances with large 17 O shifts ascribed to the Fermi contact interaction with directly bonded Mn 4+ ions. The five peaks were separated into two groups with shifts at 1600 to 1950 ppm and 2100 to 2450 ppm, which, with the aid of first-principles calculations, were assigned to the 17 O shifts of environments similar to the 4i and 8j sites in pristine Li 2 MnO 3 , respectively. The multiple O environments in each region were ascribed to the presence of stacking faults within the Li 2 MnO 3 structure. From the ratio of the intensities of the different 17 O environments, the percentage of stacking faults was found to be ca. 10%. The methodology for studying 17 O shifts in paramagnetic solids described in this work will be useful for studying the local environments of O in a range of technologically interesting transition metal oxides.

25 ENERGY STORAGE↗

Bonneville, Power Administration Timing System

Time is an integral part of the Bonneville Power Administration's (BPA) operational systems. Generation and power transfers are planned in advance. Utilities coordinate with each other by making these adjustments on a timed schedule. Price varies with demand, so billing is based on time. Outages for maintenance are scheduled to assure they do not interrupt reliable power delivery. Disturbance records are aligned with recorded timetags for analysis and comparison with related information. Advanced applications like traveling wave fault location and real-time phase measurement require continuous timing with high precision. Most of BPA is served by a Central Time System (CTS) at the Dittmer Control Center near Portland, OR. This system keeps time locally and supplies time to both the control center systems and field locations via a microwave signal. It is kept synchronized to national standard time and coordinated with interconnected utilities. It is the official BPA time. Powwer system control and operation is described, followed by a description of BPA timing systems including CTS, the Fault Location Acquisition Reporter, time dissemination, and phasor measurements. References are provided for further reading.

Martin, Kenneth E.↗

Stress-dependent χ phase transformation in a Ni-based superalloy

The ongoing push to elevate operating temperatures in aerospace gas turbine engines – driven by goals of enhanced fuel efficiency and reduced CO 2 emissions – mandates advancements in the creep resistance of Ni- and Co-based superalloys, which are integral for critical engine components. This study elucidates the role of stress assisted localized phase transformations in the creep properties of these alloys. By leveraging chemo-mechanical coupling, self-healing γ′ precipitates are designed to immobilize planar defects, thereby increasing creep resistance. Employing advanced characterization techniques such as high-resolution Scanning Transmission Electron Microscopy (HR-STEM), in conjunction with atomistic simulations and thermodynamic calculations, novel deformation pathways facilitated by χ local phase transformation (LPT) strengthening have been uncovered; notably, the formation of χ nano-laths through microtwinning and superlattice intrinsic stacking fault (SISF) shearing. This study highlights critical insights into the compositional boundaries necessary for optimizing LPT strengthening while avoiding deleterious bulk formation of η/χ phases. These advancements will guide the design of new alloys maximizing high-temperature creep strength for advanced aerospace applications.

Egan, Ashton J. [Friedrich-Alexander University Er↗

Tectonic escape in the evolution of the continental crust

The continental crust originated by processes similar to those operating today and continents consist of material most of which originated long ago in arc-systems that have later been modified, especially at Andean margins and in continental collisions where crustal thickening is common. Collision-related strike-slip motion is a general process in continental evolution. Because buoyant continental (or arc) material generally moves during collision toward a nearby oceanic margin where less buoyant lithosphere crops out, the process of major strike-slip dominated motion toward a 'free-face' is called 'tectonic escape'. Tectonic escape is and has been an element in continental evolution throughout recorded earth-history. It promotes: (1) rifting and the formation of rift-basins with thinning of thickened crust; (2) pervasive strike-slip faulting late in orogenic history which breaks up mountain belts across strike and may juxtapose unrelated sectors in cross-section; (3) localized compressional mountains and related foreland-trough basins.

Burke, K.↗

Introduction to Tools and Techniques for Surface Sampling on Europa

The NASA Jet Propulsion Laboratory (JPL) is studying excavation and collection of a sample from an icy surface for a potential landed mission to Europa. Europa presents unique challenges in planetary sampling. Very little is known about the local topography and material composition of the surface. The environmental conditions of being cryogenically cold (80-130K), low gravity (~1/7th Earth), no atmosphere, low lighting conditions, and limited ground in the loop opportunities have forced JPL to look at sampling differently than past missions. Interacting with the surface of the Jovian moon requires a sampling system that is robust to local topography on the scale of the lander and/or the tool. In addition, the sampling system must be capable both of detecting faults and automatically adjusting to them to achieve the mission objectives without ground in the loop feedback. Presented here is an overview of a sampling system concept that involves a two-stage approach for collecting a sample. The first stage uses an excavation tool to prepare the surface site for sample collection by removing the top layer of irradiated material and clearing tailings from the hole. The second stage then generates and collects a sample for delivery to instruments on-board a lander. Also presented is an introduction for how autonomy and sensing technologies might be employed to enable mission success.

Tevere, Erica L.↗

Co-scheduling of network resource provisioning and host-to-host bandwidth reservation on high-performance network and storage systems

A cross-domain network resource reservation scheduler configured to schedule a path from at least one end-site includes a management plane device configured to monitor and provide information representing at least one of functionality, performance, faults, and fault recovery associated with a network resource; a control plane device configured to at least one of schedule the network resource, provision local area network quality of service, provision local area network bandwidth, and provision wide area network bandwidth; and a service plane device configured to interface with the control plane device to reserve the network resource based on a reservation request and the information from the management plane device. Corresponding methods and computer-readable medium are also disclosed.

97 MATHEMATICS AND COMPUTING↗

The 1974 Ethiopian rift geodimeter survey

The field techniques and methods of data reduction for five successive geodimeter surveys in the Ethiopian rift valley are enlarged upon, with the considered conclusion that there is progressive accumulation of upper crustal strain, consonant with on-going rift extension. The extension is restricted to the Quaternary volcanotectonic axis of the rift, namely the Wonji fault belt, and is occurring at rates of 3 to 6 mm/yr in the northern sector of the rift valley. Although this concurs with the predictions of platetectonic analysis of the Afar triple junction, it is considered premature to endorse such a concurrence on the basis of only 5 years of observations. This is underlined by the detection of local tectonic contractions and expansions associated with geothermal and gravity anomalies in the central sector of the rift valley. There is a hint of a component of dextral slip along some of the rift-floor fault zones, both from geological evidence and from the strain patterns detected in the present geodetic surveys.

Mohr, P.↗

Multi-Source Data Aggregation and Real-Time Anomaly Classification and Localization in Power Distribution Systems

This paper proposes a real-time anomaly location and classification framework for power distribution systems to simultaneously determine the type of anomaly (i.e., short-circuit fault, cyber attack, DER switching) and its location. The proposed framework employs the data aggregation module to collect the measurement data from multiple field devices operating at different sampling rates, such as protection relays and D-PMUs. The output of the data aggregation is then fed into a multi-task learning-based long-based short-term memory (MTL-LSTM) to classify the type of anomaly and the location in two separate tasks. The proposed MTL-LSTM approach can be utilized in real-time operation in order to distinguish between normal and several anomalous operations and locate the anomaly. The proposed framework is tested on a modified IEEE 33-bus test feeder benchmark that integrates solar generation and energy storage. Furthermore, the results show that the proposed framework can locate and classify anomalies for several operation conditions with more than 96% accuracy. Further experiments highlight the impact of aggregating multiple sources of data on the performance of the proposed model.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Soil Moisture Active and Passive (SMAP) White-Painted Expanded Polystyrene (EPS) Radome Survivability Test

NASA's SMAP Mission launched in January 2015 into a 685 km near-polar, sun-synchronous orbit. The SMAP instrument architecture incorporates an L-band radar and radiometer which share a common feedhorn and mesh reflector. The instrument rotates about the nadir axis at approximately 15 rpm, thereby providing a conically scanning wide swath antenna beam that is capable of achieving global coverage within three days. The radiometer and its associated electronics have tight thermal stability requirements in order to meet the required surface emittance measurement precision from space. Maintaining the thermal stabilities is quite challenging because the radiometer is located on a spinning platform that can either be in full sunlight or eclipse, and thus exposed to a highly transient environment. Stability requirements were met by integrating a light-weight Expanded Polystyrene (EPS) radome into the design to prevent solar illumination of the feed horn interior. The radome was painted white since the thermo-optical properties of bare sunlit EPS degrade rapidly over the three-year mission. Milling of the EPS and solvent within the white paint created cavities on the EPS surface which may introduce localized hot spots possibly violating the EPS glass transition temperature of 96degC and leading to structural integrity concerns. A three-day thermal test was conducted in a vacuum chamber to verify survivability of the radome during a simulated non-spin fault condition at end of mission. A portable solar simulator illuminated the test article and the beam irradiance was kept nearly constant during the entire 50 hour test, except during the first hour which simulated the expected 79degC on-orbit surface temperature of the radome. The test article survived based on the established pass criteria for three separate metrics: dimensional, optical property, and color. If any hot spots exist locally, they did not cause any observable permanent deformation when compared to pre- and post-test images. The test results increase confidence that there is a high probability that the radome will survive the worst-case scenario of a no-spin fault condition at the end of mission.

Mikhaylov, Rebecca↗

Impacts of hydrogeological characteristics on groundwater-level changes induced by earthquakes

Changes in groundwater level during earthquakes have been reported worldwide. In this study, field observations of co-seismic groundwater-level changes in wells under different aquifer conditions and sampling intervals due to near-field earthquake events in Taiwan are presented. Sustained changes, usually observed immediately after earthquakes, are found in the confined aquifer. Oscillatory changes due to the dynamic strain triggered by passing earthquake waves can only be recorded by a high-frequency data logger. While co-seismic changes recover rapidly in an unconfined aquifer, they can sustain for months or longer in a confined aquifer. Three monitoring wells with long-term groundwater-level data were examined to understand the association of co-seismic changes with local hydrogeological conditions. The finite element software ABAQUS is used to simulate the pore-pressure changes induced by the displacements due to fault rupture. The calculated co-seismic change in pore pressure is related to the compressibility of the formation. The recovery rate of the change is rapid in the unconfined aquifer due to the hydrostatic condition at the water table, but slow in the confined aquifer due to the less permeable confining layer. Fracturing of the confining layer during earthquakes may enhance the dissipation of pore pressure and induce the discharge of the confined aquifer. The study results indicated that aquifer characteristics play an important role in determining groundwater-level changes during and after earthquakes.

58 GEOSCIENCES↗

Multiscale analysis of nanoindentation-induced defect structures in gum metal

Using ex-situ transmission electron microscopy and the recently developed nanoprobe diffraction (NPD) technique, we characterize a nanoindented solution treated gum metal. Lattice rotations are resolved at a 1.2 nm length-scale and shown to be continuous within the nanoindentation pit; further, it is revealed that these can be accommodated by a reasonable number of geometrically necessary dislocations at a density of ~10 15 /m 2 . We furthermore provide direct evidence that dislocations within the nanoindent, rather than secondary phase nanoparticles, can serve as potent barriers to dislocation motion. We also demonstrate that plasticity in these alloys under nanoindentation can be accommodated solely by dislocation nucleation and propagation, with no competing deformation mechanisms present. Conventional transmission electron microscopy and “ g•b ” analysis reveal the presence of dislocations on &lang;$ \bar{1}11 $&rang;{110} slip systems and highly localized plastic deformation in the form of shear bands on <111>{$ \bar{1} \bar{1}2 $} slip systems, similar to previously observed “giant faults”.

36 MATERIALS SCIENCE↗

BESPOKV: Application Tailored Scale-Out Key-Value Stores

Enterprise KV stores are not well suited for HPC applications, and entail customization and cumbersome end-to-end KV design to extract the HPC application needs. To this end, in this paper we present BESPOKV, an adaptive, extensible, and scale-out KV store framework. BESPOKV decouples the KV store design into the control plane for distributed management and the data plane for local data store. BESPOKV takes as input a single-server KV store, called a datalet, and transparently enables a scalable and fault-tolerant distributed KV store service. The resulting distributed stores are also adaptive to consistency or topology requirement changes and can be easily extended for new types of services. Experiments show that BESPOKV-enabled distributed KV stores scale horizontally to a large number of nodes, and performs comparably and sometimes better than the state-of-the-art systems.

Anwar, Ali↗

CO2 Push-Pull Dual (Conjugate) Faults Injection Simulations

This submission contains datasets and a final manuscript associated with a project simulating carbon dioxide push-pull into a conjugate fault system modeled after Dixie Valley- sensitivity analysis of significant parameters and uncertainty prediction by data-worth analysis. Datasets include: (1) Forward simulation runs of standard cases (push & pull phases), (2) Local sensitivity analyses (push & pull phases), and (3) Data-worth analysis (push & pull phases).

15 GEOTHERMAL ENERGY↗

Discovering Blind Geothermal Systems in the Great Basin Region: An Integrated Geologic and Geophysical Approach for Establishing Geothermal Play Fairways: All Phases

Most geothermal resources in the Great Basin region of the western USA are blind, and thus the discovery of new commercial-grade systems requires synthesis of favorable characteristics for geothermal activity. The geothermal play fairway concept involves integration of multiple parameters indicative of geothermal activity to identify promising areas for new development. This project integrated multiple datasets to apply the play fairway concept and assess geothermal potential in a large region of the Great Basin in Nevada. It is therefore referred to as the Nevada play fairway project. This project was a strong collaborative effort between several organizations, led by the Nevada Bureau of Mines and Geology at the University of Nevada, Reno, but with key support from the U.S. Geological Survey, ATLAS Geosciences, Inc,, Hi-Q Geophysical, Inc., Lawrence Berkeley National Laboratory, Utah Geological Survey, and Innovative Geothermal Ltd. In Budget Period 1 of this project, available data for nine geologic, geochemical, and geophysical parameters were initially synthesized to produce a new detailed geothermal potential map of 96,000 km2 from west-central to eastern Nevada. These parameters were grouped into subsets and individually weighted to delineate rankings for local permeability, intermediate permeability, regional permeability, and thermal potential, which collectively defined geothermal play fairways (i.e., most likely locations for significant geothermal fluid flow). This initial work was aimed at reducing the risks in regional exploration and therefore facilitating discovery of new commercial-grade systems in blind settings, as well as in areas with surface expressions of geothermal activity. Budget Period 2 of the project involved detailed analysis of some of the most promising areas identified in Phase 1. Twenty-four highly prospective areas, including both known undeveloped systems and previously undiscovered potential blind systems, were identified for further analysis. After reconnaissance of these areas, five of the most promising sites were selected for detailed studies. Multiple techniques were employed in the detailed studies, including geologic mapping, shallow temperature surveys, gravity surveys, Lidar, geochemical studies, seismic reflection analysis, and 3D modeling. The goal of the detailed studies was to identify specific areas with the highest likelihood for high permeability and thermal fluids, such that drill sites could be targeted. Three main sets of predictive maps were generated for each detailed study area: 1) play fairway maps, 2) play fairway error maps, and 3) direct evidence maps. Local- and intermediate-scale permeability models were revised to reflect results of the detailed geologic, geophysical, and geochemical analyses. Budget Period 3 of the project involved more detailed geophysical analyses and temperature-gradient (TG) drilling in southeastern Gabbs Valley and northern Granite Springs Valley, deemed the two most promising sites, with the goal of providing preliminary validation of the play fairway methodology. In southeastern Gabbs Valley, the collocation of a favorable structural setting (displacement transfer zone and fault intersections), Quaternary faults, intersecting and terminating gravity gradients, magnetic low, shallow (2 m) temperature anomaly, low resistivity anomaly, and promising geothermometry from nearby water wells provided evidence for a blind system. Drilling of six TG holes defines an apparent geothermal system at this locality with temperatures as high as 124°C at 152 m. This system is blind, with no surface hot springs, fumaroles, or paleo-geothermal deposits. For northern Granite Springs Valley, a favorable structural setting (termination of a major Quaternary normal fault), terminating gravity gradient, magnetic gradient, newly discovered sinter deposits, nearby warm water wells, previously drilled TG holes in the vicinity, and promising geothermometry suggest a hidden system. Drilling of six new TG holes yields temperatures of ~96°C at ~250 m, suggesting the presence of a geothermal system. Major lessons learned in the course of this project include: 1) initially identified sites commonly include multiple favorable structural settings at a finer scale; 2) promising sites in Cenozoic basins cannot be recognized without detailed geophysical surveys; and 3) play fairway analysis should be refined as the exploration program vectors into the most promising sites and finer-scale data are acquired. In addition to producing copious amounts of data, this project resulted in 16 published papers, 10 abstracts, more than 40 presentations across the U.S. and abroad (including several keynote addresses), 2 Masters theses, and 7 media reports.

15 GEOTHERMAL ENERGY↗

Application of ERTS and EREP images to geologic investigations of the basin and range: Colorado plateau boundary in northwestern and north-central Arizona

The author has identified the following significant results. In the course of the ERTS investigation in the Cataract Creek Basin of the Coconino Plateau it was recognized that shallow perched ground water associated with the Kaibab Limestone could be discovered by means of drilling guided by geologic mapping aided by the use of ERTS imagery. At the Globe Ranch, the perched water table is only 5 meters beneath the surface at the site of the original, hand dug well. Recharge occurs from local runoff and from direct precipitation on the outcrop belt of the sandstone. This well provides water for the ranch at the rate of about 1,000 gallons a week. In order to explore the possibility of further developing this aquifer, unit 5 was mapped over an area of about 50 square miles in the vicinity of the hand-dug well, with negative results. A new location was then picked for drilling based on the occurrence of unit 5 in a favorable structural setting. This location was along a normal fault, and it was anticipated that water might be structurally trapped within the down-dropped block of the fault. Four shallow testholes were drilled and all encountered water. These four water-bearing holes are currently being monitored and will be tested to determine potential production of water from the local sandstone aquifer.

Goetz, A. F. H.↗

A Structural Model Decomposition Framework for Systems Health Management

Systems health management (SHM) is an important set of technologies aimed at increasing system safety and reliability by detecting, isolating, and identifying faults; and predicting when the system reaches end of life (EOL), so that appropriate fault mitigation and recovery actions can be taken. Model-based SHM approaches typically make use of global, monolithic system models for online analysis, which results in a loss of scalability and efficiency for large-scale systems. Improvement in scalability and efficiency can be achieved by decomposing the system model into smaller local submodels and operating on these submodels instead. In this paper, the global system model is analyzed offline and structurally decomposed into local submodels. We define a common model decomposition framework for extracting submodels from the global model. This framework is then used to develop algorithms for solving model decomposition problems for the design of three separate SHM technologies, namely, estimation (which is useful for fault detection and identification), fault isolation, and EOL prediction. We solve these model decomposition problems using a three-tank system as a case study.

Roychoudhury, Indranil↗

Rapid Ice Mass Loss: Does It Have an Influence on Earthquake Occurrence in Southern Alaska?

The glaciers of southern Alaska are extensive, and many of them have undergone gigatons of ice wastage on time scales on the order of the seismic cycle. Since the ice loss occurs directly above a shallow main thrust zone associated with subduction of the Pacific-Yakutat plate beneath continental Alaska, the region between the Malaspina and Bering Glaciers is an excellent test site for evaluating the importance of recent ice wastage on earthquake faulting potential. We demonstrate the influence of cumulative glacial mass loss following the 1899 Yakataga earthquake (M=8.1) by using a two dimensional finite element model with a simple representation of ice fluctuations to calculate the incremental stresses and change in the fault stability margin (FSM) along the main thrust zone (MTZ) and on the surface. Along the MTZ, our results indicate a decrease in FSM between 1899 and the 1979 St. Elias earthquake (M=7.4) of 0.2 - 1.2 MPa over an 80 km region between the coast and the 1979 aftershock zone; at the surface, the estimated FSM was larger but more localized to the lower reaches of glacial ablation zones. The ice-induced stresses were large enough, in theory, to promote the occurrence of shallow thrust earthquakes. To empirically test the influence of short-term ice fluctuations on fault stability, we compared the seismic rate from a reference background time period (1988-1992) against other time periods (1993-2006) with variable ice or tectonic change characteristics. We found that the frequency of small tectonic events in the Icy Bay region increased in 2002-2006 relative to the background seismic rate. We hypothesize that this was due to a significant increase in the rate of ice wastage in 2002-2006 instead of the M=7.9, 2002 Denali earthquake, located more than 100km away.

Sauber, Jeanne M.↗