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At least 451 records · Page 25

Vapor-deposited platinum as a fuel-cell catalyst

Electrodes are prepared by vacuum deposition of platinum on nickel substrate with conventional vapor-deposition apparatus. Amount of platinum loaded on substrate can be veried by changing exposure time during deposition. These electrodes are significantly more effective than conventional oxygen electrodes.

Asher, W. J.↗

Determination of Optical Constants of in Bi from Reflectance Measurements

A fall in reflectance was noted from values obtained for a freshly cleaved sample to values obtained after periods of exposure of the surface to air. The decrease in reflectance with increased exposure time is attributed to formation of a surface layer insoluble in Freon or ethyl alcohol; it is assumed to be a tarnish layer. Computer processing was employed to calculate optical constants from reflectance data.

Martin, F. E.↗

Study of the detail content of Apollo orbital photography

The results achieved during a study of the Detail Content of Apollo Orbital Photography are reported. The effect of residual motion smear or image reproduction processes upon the detail content of lunar surface imagery obtained from the orbiting command module are assessed. Data and conclusions obtained from the Apollo 8, 12, 14 and 15 missions are included. For the Apollo 8, 12 and 14 missions, the bracket-mounted Hasselblad camera had no mechanism internal to the camera for motion compensation. If the motion of the command module were left totally uncompensated, these photographs would exhibit a ground smear varying from 12 to 27 meters depending upon the focal length of the lens and the exposure time. During the photographic sequences motion compensation was attempted by firing the attitude control system of the spacecraft at a rate to compensate for the motion relative to the lunar surface. The residual smear occurring in selected frames of imagery was assessed using edge analyses methods to obtain and achieved modulation transfer function (MTF) which was compared to a baseline MTF.

Kinzly, R. E.↗

Short term hearing loss in general aviation operations, phase 1, part 1

The effects of light aircraft noise on six subjects during flight operations were investigated. The noise environment in the Piper Apache light aircraft was found to be capable of producing hearing threshold shifts. The following are the principal findings and conclusions: (1) Through most of the frequency range for which measurements were taken (500 to 6000 Hz), there was a regular progression showing increased loss of auditory acuity as a function of increased exposure time. (2) Extensive variability was found in the results among subjects, and in the measured loss at discrete frequencies for each subject. (3) The principal loss of hearing occurred at the low frequencies, around 500 Hz.

Parker, J. F., Jr.↗

Metallurgical evaluation of factors influencing the ductility of aged T-111

The metallurgical factors influencing the ductility of T-111 (Ta-8W-2Hf) alloy following long-time exposures of GTA welds and tubing in the temperature range 982 C (1800 F) through 1316 C (2400 F) were evaluated by means of scanning and transmission electron microscopy, Auger electron emission spectroscopy, and optical metallographic procedures. No classical aging response occurs in the alloy over the temperature range studied. The ductility impairment implied by previous investigations is not the result of microstructural response of the alloy to thermal exposures. Intergranular failure in the GTA sheet welds appears the result of random contamination by silicon, potassium, and/or fluorine at the grain boundaries of the fusion zones. Exposure to lithium at high temperatures had no adverse effects on the ductility of T-111 tubing. These materials were, however, sensitive to post-age handling and testing procedures.

Gold, R. E.↗

Photogrammetry and altimetry. Part A: Apollo 16 laser altimeter

The laser altimeter measures precise altitudes of the command and service module above the lunar surface and can function either with the metric (mapping) camera or independently. In the camera mode, the laser altimeter ranges at each exposure time, which varies between 20 and 28 sec (i.e., 30 to 43 km on the lunar surface). In the independent mode, the laser altimeter ranges every 20 sec. These altitude data and the spacecraft attitudes that are derived from simultaneous stellar photography are used to constrain the photogrammetric reduction of the lunar surface photographs when cartographic products are generated. In addition, the altimeter measurements alone provide broad-scale topographic relief around the entire circumference of the moon. These data are useful in investigating the selenodetic figure of the moon and may provide information regarding gravitational anomalies on the lunar far side.

Wollenhaupt, W. R.↗

Snow survey and vegetation growth in high mountains (Swiss Alps)

The author has identified the following significant results. A method for mapping snow over large areas was developed combining the possibilities of a Quantimet (QTM 72) to evaluate the exact density level of the snow cover for each individual image (or a selected section of the photo) with the higher resolution of photographic techniques. The density level established on the monitor by visual control is used as reference for the exposure time of a lithographic film, producing a clear tonal separation of all snow- and ice-covered areas from uncovered land in black and white. The data is projected onto special maps 1:500,000 or 1:100,000 showing the contour lines and the hydrographic features only. The areal extent of the snow cover may be calculated directly with the QTM 720 or on the map. Bands 4 and 5 provide the most accurate results for mapping snow. Using all four bands a separation of an old melting snow cover from a new one is possible. Regional meteorological studies combining ERTS-1 imagery and conventional sources describe synoptical evolution of meteorological systems over the Alps.

Haefner, H.↗

Manual for 70 mm hand-held photography from Skylab

A manual and atlas used on the Skylab mission for hand-held photography are presented. The manual covers terrain, environmental, meteorological, and dim light photography while the atlas covers sections from the Army Map Service 1:40.000,000 world map, a glossary of geologic terms, geologic maps, and recommended exposure times.

Lowman, P. D., Jr.↗

Breakdown phenomena in reverse biased silicon solar cells.

Solar cell reverse current-voltage characteristics have been found to vary widely and to be generally unstable. At reverse voltages greater than approximately 20 V and at cell power dissipations of more than 4 W, the probability of permanent breakdown, resulting in cell short-circuit failure, was found to increase with increasing voltage and exposure time. Shorted cells showed evidence of cell contact material and silicon melting in very localized areas with lava-like flow patterns and channels bridging the p and n contacts.

Rauschenbach, H. S.↗

Analysis of sublimation-cooled coated mirrors in convective and radiative environments.

Analytical solutions were obtained for the thermal response of a transpiration- or sublimation-cooled spherical mirror coating exposed to convective and radiative heating. The solutions allow unlimited spectral detail to be accounted for. Results indicate that transpiration-cooled thick coatings (1 cm) may withstand up to 10 kW/sq cm on a steady basis without excessive temperature rise for quartzlike materials with an internal absorption coefficient of 0.01 per cm. On a transient basis, fluxes up to 20 kW/sq cm can be accommodated for a second (cW laser exposure time), 4 kW/sq cm for 5 sec (planetary entry heating time), and of the order of MW/sq cm for millisecond times (short-duration laser bursts) without transpiration cooling for a material with an absorption coefficient of 0.1 per cm. Proportionately higher fluxes can be accommodated with lower absorption coefficients. Thermal stresses produced by the heat pulse are found to be high but within the strength of the materials. The regime in which meaningful solutions may be obtained is mapped in detail.

Howe, J. T.↗

Apollo 14 soils - Size distribution and particle types.

Particle size characteristics are discussed together with particle types, abundances, variation in the soils, questions of soil maturity, coarse fines, and ropy glasses. It is found that agglutinates are formed primarily by micrometeorite impact into lunar soil. Agglutinates appear to be the major particle type now being formed on the lunar surface. Agglutinate content of a soil increases with particle track densities and with surface exposure time.

Mckay, D. S.↗

Particle track record of the Luna missions.

Measurements are reported of particle-track densities in 100 to 200-micron crystalline grains taken from one level of the soil column returned from the lunar highlands between Mare Fecunditatis and Mare Crisium by Luna 20 and from two levels in the soil column from Mare Fecunditatis by Luna 16. Ninety-three percent of the grains from Luna 16 have very high densities, greater than 10 to the 8th power per cu cm and the lower-track density grains are all in the deeper soil level. In contrast, most Luna 20 grains show densities less than 10 to the 8th power per cu cm. Track density gradients and exposure times have been measured for six Luna 16 grains with a wide spread in absolute track densities. The more extensive track counts in crystals strengthens an earlier conclusion that the Luna 16 soil has received long irradiations very close to the surface. Two possible histories are that the highly irradiated soil blanket at the Luna 16 site is either well mixed and thin, or else has accumulated by transport from surrounding higher regions.

Comstock, G. M.↗

Radiative property degradation of water impinging on thermally-controlled surfaces under space conditions.

Review of the results of an investigation aimed at determining experimentally the directional monochromatic reflectance changes caused under high-vacuum space conditions by a water spray impinging on thermally controlled surfaces consisting of three paint specimens (Z93, S13G, and 92-007) and an aluminum foil. The first two paints and the aluminum foil suffered considerable physical damage, but only small changes resulted in the reflectance of the paints while the reflectance of the aluminum foil decreased with increase in exposure time to the water jet. Only the 92-007 Dow Corning paint retained the same physical and reflective characteristics.

Maples, D.↗

Mechanical erasure of particle tracks - A tool for lunar microstratigraphic chronology.

Mechanical erasure of particle tracks caused by impact deformation is shown to be a common feature of lunar soil grains. Etching of lunar pyroxenes reveals deformation markings that are evidence of prior impact events. The soil microstratigraphic chronology can be derived if it is assumed that the minimum track density in a thin soil layer is commonly found in grains where such erasure was caused by the impact that deposited the soil. With Apollo 12 core samples as examples, the minimum track density found in each layer is used to calculate the longest exposure that layer could have received since it was last disturbed. By summing the upper limits on the exposure times of the different layers, a lower limit on the average deposition rate was estimated to be 0.35 cm/m.y.

Fleischer, R. L.↗

Development of coatings to control electroosmosis in zero gravity electrophoresis

A major problem confronting the operation of free fluid electrophoresis in zero gravity is the control of electrokinetic phenomena and, in particular, electroosmosis. Due to the severity of counter flow, as a result of electroosmosis, the electrical potential developed at the surface of shear must be maintained at near, or as close to, zero millivolts as possible. Based upon this investigation, it has been found that the amount of bound water or the degree of hydroxylation plays a major role in the control of this phenomena. Of necessity, factors, such as adhesion, biocompatibility, protein adsorption, and insolubility were considered in this investigation because of the long buffer-coating exposure times required by present space operations. Based upon tests employing microcapillary electrophoresis, it has been found that gamma amino propyl trihydroxysilane produced a coating which provides the lowest potential (minus 3.86 mv) at the surface of shear between the stationary and mobile layers. This coating has been soaked in both borate and saline buffers, up to three months, in a pH range of 6.5 to 10 without deleterious effects or a change in its ability to control electrokinetic effects.

Krupnick, A. C.↗

Apollo window meteoroid experiment

Apollo command module heat shield windows were examined for meteoroid impacts to obtain information about (1) the flux of meteoroids with masses of 10 to the -7th g and less, (2) dynamic and physical properties of meteoroids, and (3) correlations with lunar-rock-crater studies. The results of examining Apollo 17, and nine prior Apollo windows are tabulated. The window exposure time, number of impacts, crater diameter, flux, energy, and mass are shown.

Cour-Palais, B. G.↗

Resin/graphite fiber composites

Techniques were developed that provided thermo-oxidatively stable A-type polyimide/graphite fiber composites using the approach of in situ polymerization of monomeric reactants directly on reinforcing fibers, rather than employing separately prepared prepolymer varnish. This was accomplished by simply mixing methylene dianiline and two ester-acids and applying this solution to the fibers for subsequent molding. Five different formulated molecular weight resins were examined, and an optimized die molding procedure established for the 1500 formulated molecular weight system. Extensive ultrasonic inspection of composites was successfully utilized as a technique for monitoring laminate quality. Composite mechanical property studies were conducted with this polyimide resin at room temperature and after various time exposures in a thermo-oxidative environment at 561 K (550 F), 589 K (600 F) and 617 K (650 F). It was determined that such composites have a long term life in the temperature range of 561 K to 589 K. The final phase involved the fabrication and evaluation of a series of demonstration airfoil specimens.

Cavano, P. J.↗