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At least 451 records · Page 25

Development of a Rational Modeling Approach for the Design, and Optimization of the Multifiltration Unit

This thesis includes the development and verification of an adsorption model for analysis and optimization of the adsorption processes within the International Space Station multifiltration beds. The fixed bed adsorption model includes multicomponent equilibrium and both external and intraparticle mass transfer resistances. Single solute isotherm parameters were used in the multicomponent equilibrium description to predict the competitive adsorption interactions occurring during the adsorption process. The multicomponent equilibrium description used the Fictive Component Analysis to describe adsorption in unknown background matrices. Multicomponent isotherms were used to validate the multicomponent equilibrium description. Column studies were used to develop and validate external and intraparticle mass transfer parameter correlations for compounds of interest. The fixed bed model was verified using a shower and handwash ersatz water which served as a surrogate to the actual shower and handwash wastewater.

Hand, David W.↗

Nonequilibrium Ablation of Phenolic Impregnated Carbon Ablator

In previous work, an equilibrium ablation and thermal response model for Phenolic Impregnated Carbon Ablator was developed. In general, over a wide range of test conditions, model predictions compared well with arcjet data for surface recession, surface temperature, in-depth temperature at multiple thermocouples, and char depth. In this work, additional arcjet tests were conducted at stagnation conditions down to 40 W/sq cm and 1.6 kPa. The new data suggest that nonequilibrium effects become important for ablation predictions at heat flux or pressure below about 80 W/sq cm or 10 kPa, respectively. Modifications to the ablation model to account for nonequilibrium effects are investigated. Predictions of the equilibrium and nonequilibrium models are compared with the arcjet data.

Milos, Frank S.↗

Possible flyby measurements of Galilean satellite interior structure

Flyby encounters of the Galilean satellites from a Jupiter orbiter spacecraft could yield information about the second-degree gravity harmonics of these satellites. The expected values of these harmonics have been calculated for a range of plausible interior models in hydrostatic equilibrium. Because the satellites respond to comparable perturbations from rotation and tides, an independent test of hydrostatic equilibrium is feasible. For Io and Ganymede, the expected measurement accuracy from a nominal encounter should make possible an excellent discrimination from the ensemble of interior models. For Europa, a qualitative distinction between near-uniform and centrally condensed models seems feasible. Only for Callisto is the proposed experiment of marginal value.

Hubbard, W. B.↗

Experimental partitioning of rare earth elements and scandium among armalcolite, ilmenite, olivine and mare basalt liquid

An experimental study was carried out to measure partition coefficients for two rare-earth elements (Sm and Tm) and Sc among armalcolite, ilmenite, olivine and liquid coexisting in a system modeled on high-Ti mare basalt 74275. This 'primitive' sample was chosen for study because its major and trace element chemistry as well as its equilibrium phase relations at atmospheric pressure are known from previous studies. Beta-track analytical techniques were used so that partition coefficients could be measured in an environment whose bulk trace element composition is similar to that of the natural basalt. Partition coefficients for Cr and Mn were determined in the same experiments by microprobe analysis. The only equilibrium partial melting model appears to be one in which ilmenite is initially present in the source region but is consumed by melting before segregation of the high-Ti mare basalt liquid from the residue.

Irving, A. J.↗

Dynamical System Analysis of Reynolds Stress Closure Equations

In this paper, we establish the causality between the model coefficients in the standard pressure-strain correlation model and the predicted equilibrium states for homogeneous turbulence. We accomplish this by performing a comprehensive fixed point analysis of the modeled Reynolds stress and dissipation rate equations. The results from this analysis will be very useful for developing improved pressure-strain correlation models to yield observed equilibrium behavior.

Girimaji, Sharath S.↗

Physics of Solar Prominences: I-Spectral Diagnostics and Non-LTE Modelling

This review paper outlines background information and covers recent advances made via the analysis of spectra and images of prominence plasma and the increased sophistication of non-LTE (i.e. when there is a departure from Local Thermodynamic Equilibrium) radiative transfer models. We first describe the spectral inversion techniques that have been used to infer the plasma parameters important for the general properties of the prominence plasma in both its cool core and the hotter prominence-corona transition region. We also review studies devoted to the observation of bulk motions of the prominence plasma and to the determination of prominence mass. However, a simple inversion of spectroscopic data usually fails when the lines become optically thick at certain wavelengths. Therefore, complex

Labrosse, N.↗

Estimating Irrigation Water Requirements using MODIS Vegetation Indices and Inverse Biophysical Modeling

An inverse process approach using satellite-driven (MODIS) biophysical modeling was used to quantitatively assess water resource demand in semi-arid and arid agricultural lands by comparing the carbon and water flux modeled under both equilibrium (in balance with prevailing climate) and non-equilibrium (irrigated) conditions. Since satellite observations of irrigated areas show higher leaf area indices (LAI) than is supportable by local precipitation, we postulate that the degree to which irrigated lands vary from equilibrium conditions is related to the amount of irrigation water used. For an observation year we used MODIS vegetation indices, local climate data, and the SiB2 photosynthesis-conductance model to examine the relationship between climate and the water stress function for a given grid-cell and observed leaf area. To estimate the minimum amount of supplemental water required for an observed cell, we added enough precipitation to the prevailing climatology at each time step to minimize the water stress function and bring the soil to field capacity. The experiment was conducted on irrigated lands on the U.S. Mexico border and Central Asia and compared to estimates of irrigation water used.

Imhoff, Marc L.↗

An analysis of CH in the solar atmosphere.

CH molecule solar spectral observations interpreted using several upper photosphere models and assuming local thermodynamic equilibrium approximation

THERMODYNAMIC EQUILIBRIUM↗

Steady state and dynamical structure of a cosmic-ray-modified termination shock

A hydrodynamic model is developed for the structure of a cosmic-ray-modified termination shock. The model is based on the two-fluid equations of diffuse shock acceleration (Drury and Volk, 1981). Both the steady state structure of the shock and its interaction with outer heliospheric disturbances are considered. Under the assumption that the solar wind is decelerated by diffusing interstellar cosmic rates, it is shown that the natural state of the termination shock is a gradual deceleration and compression, followed by a discontinuous jump to a downstream state which is dominated by the pressure contribution of the cosmic rays. A representative model is calculated for the steady state which incorporates both interstellar cosmic ray mediation and diffusively accelerated anomalous ions through a proposed thermal leakage mechanism. The interaction of large-scale disturbances with the equilibrium termination shock model is shown to result in some unusual downstream structure, including transmitted shocks and cosmic-ray-modified contact discontinuities. The structure observed may be connected to the 2-kHz outer heliospheric radio emission (Cairns et al., 1992a, b). The time-dependent simulations also demonstrate that interaction with solar wind compressible turbulence (e.g., traveling interplanetary shocks, etc.) could induce the termination shock to continually fluctuate between cosmic-ray-dominated and gas-dynamic states. This fluctuation may represent a partial explanation of the galactic cosmic ray modulation effect and illustrates that the Pioneer and Voyager satellites will encounter an evolving shock whose structure and dynamic properties are strongly influence by the mediation of interstellar and anomalous cosmic rays.

Donohue, D. J.↗

Addition of equilibrium air to an upwind Navier-Stokes code and other first steps toward a more generalized flow solver

An upwind three-dimensional volume Navier-Stokes code is modified to facilitate modeling of complex geometries and flow fields represented by proposed National Aerospace Plane concepts. Code enhancements include an equilibrium air model, a generalized equilibrium gas model and several schemes to simplify treatment of complex geometric configurations. The code is also restructured for inclusion of an arbitrary number of independent and dependent variables. This latter capability is intended for eventual use to incorporate nonequilibrium/chemistry gas models, more sophisticated turbulence and transition models, or other physical phenomena which will require inclusion of additional variables and/or governing equations. Comparisons of computed results with experimental data and results obtained using other methods are presented for code validation purposes. Good correlation is obtained for all of the test cases considered, indicating the success of the current effort.

Rosen, Bruce S.↗

A Theory for Rapid Charging Events on the International Space Station

The Floating Potential Measurement Unit (FPMU) has detected high negative amplitude rapid charging events (RCEs) on the International Space Station (ISS) at the morning terminator. These events are larger and more rapid than the ISS morning charging events first seen by the Floating Potential Probe (FPP) on ISS in 2001. In this paper, we describe a theory for the RCEs that further elucidates the nature of spacecraft charging in low Earth orbit (LEO) in a non-equilibrium situation. The model accounts for all essential aspects of the newly discovered phenomenon, and is amenable to testing on-orbit. Predictions of the model for the amplitude of the ISS RCEs for the full set of ISS solar arrays and for the coming solar cycle are given, and the results of modeling by the Environments WorkBench (EWB) are compared to the observed events to show that the phenomenon can be explained by solar array driven charging. The situation is unique because the coverglasses have not yet reached equilibrium with the surrounding plasma during the RCEs. Finally, a prescription for further use of the ISS for investigating fundamental plasma physics in LEO is given. Already, plasma and charging monitoring instruments on ISS have taught us much about spacecraft interactions with the dense LEO plasma, and we expect they will continue to yield more valuable science when the Japanese Experiment Module (JEM) is in place.

Ferguson, Dale C.↗

Molecular Hydrogen in Diffuse Interstellar Clouds of Arbitrary Three-Dimensional Geometry

We have constructed three-dimensional models for the equilibrium abundance of molecular hydrogen in diffuse interstellar clouds of arbitrary geometry that are illuminated by ultraviolet radiation. The position-dependent photodissociation rate of H2 in such clouds was computed with a 26 ray approximation to model the attenuation of the incident ultraviolet radiation field by dust and by H2 line absorption. We have applied our modeling technique to the isolated diffuse cloud G236+39, assuming that the cloud has a constant density and that the thickness of the cloud along the line of sight is at every point proportional to the 100 micron continuum intensity measured by IRAS. We find that our model can successfully account for observed variations in the ratio of 100 micron continuum intensity to H I column density, with larger values of that ratio occurring along lines of sight in which the molecular hydrogen fraction is expected to be the largest. Using a standard chi square analysis to assess the goodness of fit of our models, we find (at the 60 a level) that a three-dimensional model is more successful in matching the observational data than a one-dimensional model in which the geometrical extent of the cloud along the line of sight is assumed to be much smaller than its extent in the plane of the sky. If D is the distance to G236 + 39, and given standard assumptions about the rate of grain-catalyzed H2 formation, we find that the cloud has an extent along the line of sight that is 0.9 +/- 0.1 times its mean extent projected onto the plane of the sky and a gas density of 53 +/- 8 (100 pc/D) H nuclei/cc and is illuminated by a radiation field of 1.1 +/- 0.2 (100 pc/D) times the mean interstellar radiation field. The derived 100 micron emissivity per nucleon is 1.13 +/- 0.06 x 10(exp -20) MJy/sr sq cm.

Spaans, Marco↗

Descartes Mountains and Cayley Plains - Composition and provenance

Trace element compositions of petrographically characterized 2-4 mm lithic fragments from Apollo 16 soil samples are used to calculate initial REE concentrations in liquids in equilibrium with lunar anorthosites and to discuss the provenance of the Cayley Formation. Lithic fragments may be subdivided into four groups: (1) ANT rocks, (2) K- and SiO2-rich mesostasis-bearing rocks, (3) poikiloblastic rocks, and (4) (spinel) troctolites. Model liquids in equilibrium with essentially monominerallic anorthosites have initial REE concentrations 5-8 times those of chondrites. The REE contents of K- and SiO2-rich mesostasis-bearing rocks and poikiloblastic rocks are dominated by the mesostasis phases. ANT rocks appear to be more abundant in the Descartes Mountains, while poikiloblastic rocks appear to be more abundant in the Cayley Plains. Poikiloblastic rocks have intermediate to high LIL-element concentrations yet the low gamma-ray activity of Mare Orientale implies low LIL-element concentrations. Consequently, it is unlikely that the Cayley Formation is Orientale ejecta. A local origin as ejecta from smaller impacts is a more plausible model for the deposition of the Cayley Formation.

Drake, M. J.↗

Relaxation to photochemical equilibrium of charged species within displaced air parcels in the D-region

The effects of the relaxation to photochemical equilibrium are investigated for the electrons and NO(+) ions in the upper D-region and for the electrons and several species of positive and negative ions present in the lower D-region. In the upper D-region the photochemical model includes electrons, nitric oxide, and NO(+). A self-consisting model of the equilibrium concentrations is developed for the lower D-region, which includes electrons, nitric oxide, O2(-), heavy negative and positive ions, and the oxygen species O, O3, and O2(1 delta g). At altitudes of 75 and 80 km the time dependence of the oxygen species has a significant effect on the equilibration of the electron and O2(-) concentrations. The relaxation to photochemical equilibrium proceeds by five e-folding time scales in the lower D-region, where the time required for final equilibration due to recombination is very long.

Hill, R. J.↗

Ablator Response Model Development: From Flight Data Back to Fundamental Experiments

The successful Mars atmospheric entry by the Mars Science Laboratory (MSL-Curiosity) combined with the success of the Earth atmospheric entry by the Stardust capsule have established PICA as a major Thermal Protection Systems (TPS) material. We expect that this class of materials will be on the short list selected by NASA for any atmospheric entry missions and that it will be the lead of that list of materials in any planning, feasibility studies or flight readiness studies. In addition to NASAs successes, the Dragon capsule, the successful commercial space vehicle built by SpaceX, uses PICA-X, while the European Space Agency is considering ASTERM for its exploration missions that involve atmospheric entries, both of these materials are of the same family as PICA. In the talk, a high-fidelity model will be detailed and discussed. The model tracks the chemical composition of the gases produced during pyrolysis. As in the conventional models, it uses equilibrium chemistry to determine the recession rate at high temperatures but switches to in-volume finite-rate ablation for lower temperatures. It also tracks the time evolution of the porosity of the material. Progress in implementing this high-fidelity model in a code will be presented. In addition, a set of basic experimental data being supported for model validation will be summarized. The validation process for the model development will be discussed. Preliminary results will be presented for a case where detailed pyrolysis product chemistry is computed. Finally, a wish list for a set of validation experiments will be outlined and discussed.

Mansour, Nagi N.↗

Construction of an Exact Pressure-Equilibrium Scheme for the Five-Equation Two-Phase Flow Model With Thermal Relaxation

Numerical simulation of compressible multiphase flows based on the four-equation (homogeneous relaxation) model is known to suffer from two fundamental difficulties with (a) wave propagation and (b) pressure equilibrium preservation. First, the mixture sound speed exhibits non-monotonic dependency with respect to the volume fraction, which leads to robustness issues in the resolution of shocks and acoustic wave propagation across two-phase regions. This difficulty can be mitigated by solving Allaire’s five-equation model augmented with infinitely fast phasic temperature equilibrium, from which solutions of the four-equation model can be recovered. However, when temperature is non-uniform, this augmented five-equation formulation still fails to preserve pressure equilibrium across material interfaces. In this work, we propose a fully conservative numerical scheme that exactly preserves pressure equilibrium at the discrete level for the augmented five-equation model, for arbitrary initial distributions of temperature and volume fraction. Combined with the monotonic sound speed property of the five-equation formulation, the proposed pressure-equilibrium preserving scheme significantly improves robustness in the presence of strong multiphase interactions, including shock–interface interactions and advection of material interfaces.

ESG↗

Scale resolving simulations of the NASA Juncture Flow Model using the LAVA solver

Two distinct simulation methodologies: Delayed Detached Eddy Simulation (DDES) and stress based Wall-modelled Large Eddy Simulation (WMLES) are evaluated using structured overset curvilinear grids for the NASA juncture flow model. While both methodologies are shown to mitigate the primary shortcomings of steady state Reynolds Averaged Navier Stokes(RANS) simulations, several unresolved aspects are identified. Strong sensitivity to RANS-typegrid refinement is observed in the DDES with a substantial deterioration of the solution quality with increasing spatial resolution associated with deficiencies in the shielding function. Mean profiles for attached boundary layers on the fuselage show spurious inflections suggesting modelled stress depletion on finer grids. Lower numerical dissipation in terms of spatial discretization and time step size is seen to improve the solution quality, and the advantage of using RC and QCR2000 corrections in the underlying RANS closure is demonstrated for DDES on RANS-type meshes. Equilibrium Wall-Modelled LES used grids that resolved the tripping dots over the fuselage nose and the wing leading edge, consistent with the experiment setup. These simulations resulted in a cost-competitive approach compared to DDES on RANS-type grids. Although the agreement between WMLES predictions of first and second order single point statistics with experimental measurements is promising, a fundamental shortcoming is noted in terms of an overshoot in streamwise momentum in corner regions of the wing-fuselage juncture. This excess momentum subsequently delays the onset of separation,thereby resulting in an underprediction in length of the separation bubble. Some quantitative sensitivity to numerical discretization is observed; lowering of numerical dissipation shows better agreement with the experiment.

T^3↗