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At least 451 records · Page 25

Continuous surface-to-distributed acoustic sensor snapshots explain reactivation of individual natural fractures during an unconventional reservoir stimulation

ABSTRACT Fiber-optic sensing technologies allow petroleum engineering teams to detect hydraulic fracture interaction with boreholes during unconventional reservoir stimulation. In combination with high-repeatability seismic sources, the same distributed acoustic sensors (DASs) enable vertical seismic profiling (VSP) of the fracture evolution away from the boreholes. We discovered clear signatures of seismic scattering on activated fractures during nine days of continuous seismic monitoring of the fracturing stages at the Austin Chalk/Eagle Ford Field Laboratory. The present study applies a novel approach for quantitative analysis of the scattering events in terms of the evolution of the geometry and elastic stiffness of individual fractures. Our characterization strategy sequentially refines the fracture models: from a stack of 1D soft layers to 3D rectangular inclusions. First, we estimate the number of fracture locations and reflectivity using a modified sparse-spike deconvolution of the stacked VSP traces. The fracture set consists of five fractures spaced by 15–30 m with a reflectivity of approximately 1%. Then, we develop a scattering integral method to refine these estimates along with an inversion of the fracture top and bottom for each monitoring vintage. We find that, initially, some of the fractures are located above the monitoring fiber with the height of approximately 100 m. Then we integrate the seismic interpretation with the low-frequency DAS and pressure and microseismic monitoring to reconstruct the activation process of the fractures. Most likely, some of the natural fractures slowly grew downward to the monitoring fiber as a result of fluid injections in the stimulated well. This led to bright strain anomalies but did not trigger seismicity. The top of the fractures remained almost constant and were limited by a lithologic boundary/stress barrier. To our knowledge, this is the first time VSP data enabled tracking of the fracture evolution with such high spatial and temporal resolution, which was previously only available for crosswell surveys and at a much smaller scale.

Glubokovskikh, Stanislav↗

Change-point Detection and Image Segmentation for Time Series of Astrophysical Images

Many astrophysical phenomena are time-varying, in the sense that their intensity, energy spectrum, and/or the spatial distribution of the emission suddenly change. This paper develops a method for modeling a time series of images. Under the assumption that the arrival times of the photons follow a Poisson process, the data are binned into 4D grids of voxels (time, energy band, and x-y coordinates), and viewed as a time series of non-homogeneous Poisson images. The method assumes that at each time point, the corresponding multiband image stack is an unknown 3D piecewise constant function including Poisson noise. It also assumes that all image stacks between any two adjacent change points (in time domain) share the same unknown piecewise constant function. The proposed method is designed to estimate the number and the locations of all of the change points (in time domain), as well as all of the unknown piecewise constant functions between any pairs of the change points. The method applies the minimum description length principle to perform this task. A practical algorithm is also developed to solve the corresponding complicated optimization problem. Simulation experiments and applications to real data sets show that the proposed method enjoys very promising empirical properties. Applications to two real data sets, the XMM observation of a flaring star and an emerging solar coronal loop, illustrate the usage of the proposed method and the scientific insight gained from it.

79 ASTRONOMY AND ASTROPHYSICS↗

Technical Performance and Cost Optimization of Unobtrusive Multi-static Serial LiDAR Imager (UMSLI) for Wide-area Surveillance and Identification of Marine Life at Marine Energy Installations

Florida Atlantic University developed an underwater optical monitoring system prototype - Unobtrusive Multi-static Serial LiDAR Imager (UMSLI) - suitable for marine energy full project lifecycle observation (baseline, commissioning, and decommissioning), with an automated real-time classification of marine animals. With precursor 2014 DOE funding (award DE-EE0006787), a prototype UMSLI was demonstrated in a controlled laboratory environment and achieved a TRL 6. This EERE DE-EE0007828 award aimed to both increase the TRL of the UMSLI by improving the technology performance (e.g., increase distance of marine animal target detection capability, add additional species classification capabilities, improve the system performance during the day, etc.) and reduce the cost. The UMSLI presents a novel application of underwater distributed Light Detection And Ranging (LiDAR), an advanced remote sensing method that uses light in the form of laser pulses for an application, this paired with an algorithm provides 360 degrees underwater detection, imaging, and classification of marine life. This solution for underwater monitoring of biota preserves the advantages of traditional optical and acoustic solutions while overcoming many associated disadvantages for marine energy site environmental monitoring, such as difficulties in species detection and classification in low light or night and turbid environments. This new approach is a purposefully designed, reconfigurable adaptation of an existing class 3B laser technology into one UMSLI instrument that can be easily mounted on or around different classes of marine energy equipment, such as devices to capture ocean current energy or wave energy. The system uses relatively low average power, utilizes far-red (> 635nm) laser illumination to be invisible and eye-safe to marine animals, is compact, and cost-effective. The equipment is designed for long-term, maintenance-free operations (i.e., current design is targeting more than 7 days continuous operation), to inherently generate a sparse primary dataset that only includes detected anomalies, and to allow robust real-time automated animal classification and identification with a low data bandwidth requirement. The technology’s overarching goal for application, is a system that can be deployed to collect pre-installation baseline species observations at a proposed marine energy deployment site with minimal post-processing overhead. The envisioned system will also produce high-resolution imagery of marine animals through a wide range of conditions and support automated tracking and notification of the presence of managed animals within established perimeters of marine energy equipment to satisfy deployed marine energy projects’ endangered and threatened species monitoring requirements. Through the current project, we demonstrated the UMSLI prototype in an operational environment and increased the UMSLI’s Technology Readiness Level from 6 to 7. The project resulted in many novel technologies, including: 1) an eye-safe red laser based, low-cost LiDAR system that can detect targets up to 10 meters distance; 2) the GAN-based machine learning underwater LiDAR image enhancement technique (this is the first known application of GAN technique in underwater LiDAR); 3) LiDAR-based real-time automated detection capabilities; and 4) a template matching based automated classification tool. These technologies build a solid foundation for future efforts to develop an extended range electro-optical monitoring system suitable for marine energy deployments. In addition to technology development, a key lesson learned is that addressing regulatory and safety requirements must be front and center in any marine energy monitoring applications.

16 TIDAL AND WAVE POWER↗

Template‐Directed Growth of Palladium Nanoparticles in Holey Single‐Layer Graphene for High‐Performance Room‐Temperature Hydrogen Sensing

Holey graphene (HG), formed by introducing nanoscale perforations into graphene sheets, combines the structural advantages of continuous sp 2 conjugation with the beneficial effects of high surface area and enhanced chemical reactivity associated with nanoscopic holes. Conventional HG fabrication methods often rely on harsh oxidative treatments that compromise graphene's intrinsic electronic properties by disrupting its sp 2 conjugation. A new approach is introduced to fabricate HG directly from single-layer graphene (SLG), using two-dimensional covalent organic frameworks (COFs) as a template followed by controlled oxygen plasma etching. This method preserves the integrity of the SLG's sp 2 network while producing well-defined holes with an average diameter of 2.7 nm. These hole edges act as reactive sites that facilitate the confined, autoreductive growth of palladium nanoparticles (PdNPs) without external reducing agents. The confined hole geometry prevents NP agglomeration and ensures a uniform size distribution. The resulting Pd@HG hybrid exhibits exceptional chemiresistive hydrogen sensing characteristics, including ultrahigh sensitivity, low detection limits, rapid response and recovery, and long-term stability under both dry and humid conditions. Mechanistic investigations reveal a two-step sensing process involving surface redox interactions and hydrogen absorption into the PdNP lattices. This strategy presents a scalable platform for integrating metal NPs within conductive carbon frameworks for advanced sensing applications.

chemical vapor deposition↗

Quantifying Moss Response to Metal Contaminant Exposure Using Laser-Induced Fluorescence

Tracing sources of contamination, including potentially toxic elements (PTEs), has historically been achieved through sampling and analysis of soil or biota, which are labor-intensive, costly, and destructive methods. Thus, availability of a non-destructive in situ remote sensing method for monitoring metals deposited in biota is of great interest. Laser-induced fluorescence (LIF) is an emerging spectroscopic and imaging technique that documents changes in molecular energy level in plants as a biological response to metal contamination. For a proof-of-concept study and preliminary experiment, moss was selected for experimentation due to its long history of use in tracing atmospheric deposition of PTEs. Consecutive treatments of copper chloride (CuCl2) were administered to three moss samples, simulating wet deposition every 48 h over 10 days until reaching cumulative Cu concentrations of 2.690 to 8.075 μmol/cm2. While these Cu amounts are above environmentally relevant concentrations, they allowed the best conditions for testing and fine tuning of the imaging and data processing protocols presented in this paper. Moss fluorescence was induced using both 532 nm green and 355 nm UV lasers. A CMOS camera captured images of the LIF response, and red–green–blue (RGB) decimal code values were extracted for each pixel in the images, and pixel densities of color channels from treated and untreated moss samples were compared. Results show a shift towards lower color decimal codes corresponding to increased Cu concentration. We developed and contrasted multiple quantitative analyses of color distributions and demonstrated that LIF shows great promise for remote sensing of Cu accumulation in moss at μmol/cm2 levels. Though currently, the method would be limited to highly toxic sites, it illustrates the possibility and provides a framework for development of higher-sensitivity methods to detect nmol/cm2 that are viable for urban contamination level monitoring.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Medium-Voltage Testbed for Comparing Advanced Power Line Sensors vs. Measurement Transformers with Electrical Grid Events

Electrical utilities have relied upon potential transformers (PTs) and current transformers (CTs) for very accurate metering and to provide reliable signals for protective relays. Less expensive alternative sensing technologies offer the possibility of wider deployment, particularly in grids that employ distributed energy resources. In this work, the performance of an advanced medi-um-voltage sensor is compared with a reference PT and CT and experimentally evaluated for different power grid scenarios on an advanced outdoor power line sensor testbed at the US De-partment of Energy’s Oak Ridge National Laboratory. The sensor is based on a capacitive divider for voltage monitoring and a Rogowski coil with integrator for current monitoring. The advanced outdoor power line sensor testbed has a real-time simulator that was used to generate transient scenarios (e.g., electrical faults, capacitor bank operation, service restoration), while the analog signals were recorded by the same high resolution power meter. The behavior of analog signals, harmonic components, total harmonic distortion, and crest factors were assessed for this power line sensor compared with the reference PT/CT, because of the absence for testing standards for advanced outdoor power line sensors.

Piesciorovsky, Emilio↗

Ensemble Estimation of Historical Evapotranspiration for the Conterminous U.S.

Abstract Evapotranspiration (ET) is the largest component of the water budget, accounting for the majority of the water available from precipitation. ET is challenging to quantify because of the uncertainties associated with the many ET equations currently in use, and because observations of ET are uncertain and sparse. In this study, we combine information provided by available ET data and equations to produce a new monthly data set for ET for the conterminous U.S. (CONUS). These maps are produced from 1895 to 2018 at an 800 m spatial scale, marking a finer resolution than currently available products over this time period. In our approach, the relative performance of a suite of ET equations is assessed using water balance, flux tower, and remotely sensed ET estimates. At the observation locations, we use error distributions to quantify relative weights for the equations and use these in a modified Bayesian model averaging weighted ensemble approach. The relative weights are spatially generalized using a random forest regression, which is applied to wall‐to‐wall explanatory variable maps to generate CONUS‐wide relative weight maps and ensemble estimates. We assess the performance of the ensemble using a reserved subset of the observations and compare this performance against other national‐scale map products for historical to modern ET. The ensemble ET maps are shown to provide an improved accuracy over the alternative comparison products. These ET maps could be useful for a variety of hydrologic modeling and assessment applications that benefit from a long record, such as the study of periods of water scarcity through time.

Environmental Sciences & Ecology↗

A viscoelastic model for seismic attenuation using fractal mechanical networks

SUMMARY Seismic attenuation (quantified by the quality factor Q) has a significant impact on the seismic waveforms, especially in the fluid-saturated rocks. This dissipative process can be phenomenologically represented by viscoelastic models. Previous seismological studies show that the Q value of Earth media exhibits a nearly frequency-independent behaviour (often referred to as constant-Q in literature) in the seismic frequency range. Such attenuation can be described by the mathematical Kjartansson constant-Q model, which lacks of a physical representation in the viscoelastic sense. Inspired by the fractal nature of the pore fluid distribution in patchy-saturated rocks, here we propose two fractal mechanical network (FMN) models, that is, a fractal tree model and a quasi-fractal ladder model, to phenomenologically represent the frequency-independent Q behaviour. As with the classic viscoelastic models, the FMN models are composed of mechanical elements (spring and dashpots) arranged in different hierarchical patterns. A particular parametrization of each model can produce the same complex modulus as in the Kjartansson model, which leads to the constant-Q. Applying the theory to several typical rock samples, we find that the seismic attenuation signature of these rocks can be accurately represented by either one of the FMN models. Besides, we demonstrate that the ladder model in particular exhibits the realistic multiscale fractal structure of the saturated rocks. Therefore, the FMN models as a proxy could provide a new way to estimate the microscopic rock structure property from macroscopic seismic attenuation observation.

Geochemistry & Geophysics↗

On-chip sensing of hotspots in superconducting terahertz emitters

Intrinsic Josephson junctions in high-temperature superconductor Bi 2 Sr 2 CaCu 2 O 8+δ (BSCCO) are known for their capability to emit high-power terahertz photons with widely tunable frequencies. Hotspots, as inhomogeneous temperature distributions across the junctions, are believed to play a critical role in synchronizing the gauge-invariant phase difference among the junctions, so as to achieve coherent strong emission. In this paper, we demonstrate an on-chip in situ sensing technique that can characterize hotspot distributions on BSCCO. This is achieved by fabricating a series of micro-nanosized "sensor" junctions on top of an "emitter" junction and measuring the critical current on the sensors versus the bias current applied to the emitter. Furthermore, this fully electronic on-chip design can enable efficient close-loop control of hotspots in BSCCO junctions and significantly enhance the functionality of superconducting terahertz emitters.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

A recyclable self-healing composite with advanced sensing property

Polymer-based composites frequently encounter damage, often lurking beneath the surface and proving challenges to their early detection and repair. While material-based sensors show promise for encoding self-sensing properties within these composites, their in situ healing and reprocessability remain significant challenges. Therefore, the overarching goal of this study is the creation of a reprocessable polymeric composite encoded with self-healing attributes and the ability to autonomously sense damage. At the core of this innovation are vitrimers, a polymeric material characterized by a covalently adaptive dynamic network responsive to external factors such as heat. They combine thermoset-like resilience with thermoplastic-like flowability on demand under external stimuli. We nanoengineer a polyester-based vitrimeric polymer by incorporating piezoresistive carbon nanotubes (CNTs) as reinforcing elements that not only enhance its mechanical strength but also create a percolation network within the composite, thereby enabling piezoresistive self-sensing properties, all the while preserving the intrinsic self-healing capabilities offered by the vitrimeric matrix. The fabrication process of the composite involves a solvent-free in situ polymerization method that combines epoxy and anhydride-containing monomers with ~ 0.1 wt.% of CNTs. Once it was established that the introduction of CNTs into the polymeric matrix did not compromise the mechanical properties of the composite, their strain-sensing properties were characterized by applying cyclic loading while measuring their electrical resistance. Strikingly, CNT-enhanced vitrimer composite consistently retains its mechanical and sensing properties through repeated cycles of reshaping and reprocessing, underscoring its potential as a robust distributed strain sensor. This polyester-based vitrimeric composite is also easily recyclable without harsh chemical treatments. Preliminary findings from this study conclusively demonstrate that the bulk composite boasts both self-sensing capabilities and in situ detect healing properties, charting a promising course towards the development of a mechanically resilient multifunctional composite that seamlessly integrates selfsensing and healing capabilities.

Rohewal, Sargun Singh↗

Quantum Sensing for Energy Applications: Review and Perspective

On its revolutionary threshold, quantum sensing is creating potentially transformative opportunities to exploit intricate quantum mechanical phenomena in new ways to make ultrasensitive measurements of multiple parameters. Concurrently, growing interest in quantum sensing has created opportunities for its deployment to improve processes pertaining to energy production, distribution, and consumption. Safe and secure utilization of energy is dependent upon addressing challenges related to material stability and function, secure monitoring of infrastructure, and accuracy in detection and measurement. A summary of well-established and emerging quantum sensing materials and techniques, as well as the corresponding sensing platforms that have been developed for their deployment is provided here. Specifically, the enhancement of existing advanced sensing technologies with quantum methods and materials is focused on, enabling the realization of an unprecedented level of sensitivity, placing an emphasis on relevance to the energy industry. The review concludes with a discussion on high-value applications of quantum sensing to the energy sector, as well as remaining barriers to sensor deployment.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Comparative Study of Hydrology and Icemelt in Three Nepal River Basins Using the Glacio-Hydrological Degree-Day Model (GDM) and Observations From the Advanced Scatterometer (ASCAT)

An assessment of the water supply and its seasonal and annual changes over the century in the High Mountain Asia (HMA) region is of increasing interest due to its potential impact on one-sixth of the global population. In order to understand the changing hydrology and snow and ice melt, we used remotely sensed Advanced Scatterometer (ASCAT) observations of glacier melt (GM) and a distributed and gridded Glacio-hydrological Degree-day Model (GDM) in three river basins: Tamor, Trishuli and Marsyangdi. The GDM-estimated contribution of snowmelt, icemelt, rainfall and baseflow in river flows is found to be most accurate in the Trishuli River basin, with Nash-Sutcliffe efficiency (NSE) between the estimated and observed discharges of 0.81 and volume differences of -0.5%, and reasonably accurate in the Tamor River basin, with NSE of 0.69 and volume difference of -7.51%. Similarly, NSE of 0.81 and volume difference of 4.64% in Marsyangdi River basin. We find strong similarities in the timing of glacier melting using the GDM and from observations from the ASCAT GM, determining the seasonal start of glacier melting to within 6 days on average. In all basins ASCAT GM observes melting at higher elevations relative to GDM, average of 5,328 m a.s.l. Systematic differences in glacier melting area determined by modeling and satellite observations indicate ASCAT may have suboptimal resolution, view geometry and/or polarimetry for delineating glacier melting at the process-scale in complex topography, especially in the ablation zone. This is the first step in examining the remote sensing products that could potentially be incorporated into hydrologic models to increase the accuracy of the hydrologic flow as well as the ability to estimate river discharge in other basins with limited data.

54 ENVIRONMENTAL SCIENCES↗

High-Resolution PM2.5 Concentrations Estimation Based on Stacked Ensemble Learning Model Using Multi-Source Satellite TOA Data

Nepal has experienced severe fine particulate matter (PM2.5) pollution in recent years. However, few studies have focused on the distribution of PM2.5 and its variations in Nepal. Although many researchers have developed PM2.5 estimation models, these models have mainly focused on the kilometer scale, which cannot provide accurate spatial distribution of PM2.5 pollution. Based on Gaofen-1/6 and Landsat-8/9 satellite data, we developed a stacked ensemble learning model (named XGBLL) combined with meteorological data, ground PM2.5 concentrations, ground elevation, and population data. The model includes two layers: a XGBoost and Light GBM model in the first layer, and a linear regression model in the second layer. The accuracy of XGBLL model is better than that of a single model, and the fusion of multi-source satellite remote sensing data effectively improves the spatial coverage of PM2.5 concentrations. Besides, the spatial distribution of the daily mean PM2.5 concentrations in the Kathmandu region under different air conditions was analyzed. The validation results showed that the monthly averaged dataset was accurate (R2 = 0.80 and root mean square error = 7.07). In addition, compared to previous satellite PM2.5 datasets in Nepal, the dataset produced in this study achieved superior accuracy and spatial resolution.

Environmental Sciences & Ecology↗

Cyber‐physical system testbed for power system monitoring and wide‐area control verification

The electric power system is intrinsically a cyber‐physical system (CPS) with power flowing inthe physical system and information flowing in the cyber‐network. Testbeds arecrucial for understanding the cyber‐physical interactions and provideenvironments for prototyping novel applications. This study proposes afour‐layer architecture for CPS testbeds with emphases on communication networkemulation and networked physical components. A configurable software‐definednetwork is employed to bridge physical components with wide‐area applicationsfor closed‐loop control. In order to distribute physically coupled devices intomultiple software simulations, this study proposes a data broker setup based ona distributed messaging environment to achieve low‐latency data streaming. Thedecoupled design with data streaming allows for building testbed components asmodules and running them in a distributed manner. Case studies verify the databroker setup for low‐latency sensing and actuation, as well as the communicationemulation setup for the desired network latency. Also illustrated is a replayattack scenario using synchrophasors in the Western Electricity CoordinatingCouncil (WECC) 181‐bus system for demonstrating the closed‐loop cyber‐physicalsimulation capability of the testbed.

Cui, Hantao↗

Synchronization-Based Guaranteed-Performance Formation Design for Swarm Systems

Guaranteed-performance formation control for swarm systems with the second-order dynamics is investigated based on the synchronization control strategy. Firstly, a new formation protocol is presented, where the weights of connected edges are adaptively regulated and the performance constraint is imposed. Then, on the basis of the Riccati inequality, sufficient conditions for synchronization-based guaranteed-performance formation are proposed, and an explicit expression of the guaranteed-performance cost is shown, where it is fully distributed to design gain matrices of the formation protocol in the sense that it is independent of global information of swarm systems. Moreover, the whole motion of a swarm system is determined, which is associated with initial states of all agents and formation control vectors. Finally, two numerical examples are shown to demonstrate theoretical conclusions, where the static whole motion and the dynamic whole motion are considered, respectively.

Dang, Hongtao↗

A new data-driven map predicts substantial undocumented peatland areas in Amazonia

Tropical peatlands are among the most carbon-dense terrestrial ecosystems yet recorded. Collectively, they comprise a large but highly uncertain reservoir of the global carbon cycle, with wide-ranging estimates of their global area (441 025–1700 000 km 2 ) and below-ground carbon storage (105–288 Pg C). Substantial gaps remain in our understanding of peatland distribution in some key regions, including most of tropical South America. Here we compile 2413 ground reference points in and around Amazonian peatlands and use them alongside a stack of remote sensing products in a random forest model to generate the first field-data-driven model of peatland distribution across the Amazon basin. Our model predicts a total Amazonian peatland extent of 251 015 km 2 (95th percentile confidence interval: 128 671–373 359), greater than that of the Congo basin, but around 30% smaller than a recent model-derived estimate of peatland area across Amazonia. The model performs relatively well against point observations but spatial gaps in the ground reference dataset mean that model uncertainty remains high, particularly in parts of Brazil and Bolivia. For example, we predict significant peatland areas in northern Peru with relatively high confidence, while peatland areas in the Rio Negro basin and adjacent south-western Orinoco basin which have previously been predicted to hold Campinarana or white sand forests, are predicted with greater uncertainty. Similarly, we predict large areas of peatlands in Bolivia, surprisingly given the strong climatic seasonality found over most of the country. Very little field data exists with which to quantitatively assess the accuracy of our map in these regions. Data gaps such as these should be a high priority for new field sampling. This new map can facilitate future research into the vulnerability of peatlands to climate change and anthropogenic impacts, which is likely to vary spatially across the Amazon basin.

54 ENVIRONMENTAL SCIENCES↗