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At least 451 records · Page 25

Glass Veins in the Unequilibrated Eucrite Yamato 82202

The unequilibrated eucrite Yamato 82202 (Y82202) contains a network of glass veins, which are relatively thick (up to 1 mm in width) and are not devitrified. The host of the meteorite represents volcanic rock that crystallized >4.3 Gyr ago, probably as a lava flow on the surface of 4 Vesta. The impact event that formed the glass veins occurred at approx. 3.9 Gyr under conditions of low effective fo2 and very rapid cooling. A S-rich vapor probably was generated by impact vaporization of sulfides. The impact melt was not superheated and it retains some disordered structural characteristics of the original pyroxene and feldspar of the eucritic target lithology. The unequilibrated pyroxenes of this eucrite and the pristine character of the glass indicate that the meteorite experienced no significant metamorphism after initial crystallization. Hence, it was not buried to a significant depth or covered by a lava flow or hot layer of impact ejecta. The meteorite resided at a shallow level (though not at the surface) on 4 Vesta or on one of the vestoids until it was ejected and traveled to Earth, probably with other HED materials that have Ar-36 exposure ages of approx. 13 Myr.

Bogard, Donald↗

Physics-informed Bayesian machine learning case study: Integral blade rotors

This paper provides a physics-informed Bayesian machine learning (PIBML) description and case study. The PIBML approach applies three physics-based models to establish the initial beliefs before testing to determine the probability of milling stability (or prior). These include: receptance coupling substructure analysis (RCSA) prediction for the tool tip frequency response functions; finite element software prediction of the mechanistic force model coefficients; and a spindle speed-dependent power law model for process damping. Testing was then performed to identify optimal stable machining conditions using an expected improvement in material removal rate criterion. The prior probability of stability was updated using the test results to determine the posterior probability of stability. The test results were compared to the parameter recommendations provided by the endmill manufacturer. A demonstration integral blade rotor was machined at the optimal stable machining conditions for 304 stainless steel and 6061-T6 aluminum. Finally, the disagreement between manufacturer recommendations and milling performance in both materials tested emphasizes the need for broad implementation of PIBML approaches to increase machining productivity and efficiency.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Dolomites in hydrated fine-grained Antarctic micrometeorites: Effective tools for analyzing secondary processes

We report detailed transmission electron microscope (TEM) observations of carbonates from one hydrated fine-grained Antarctic micrometeorite (H-FgMM). These carbonates show the occurrence of complex chemical variations and microstructures that provide important evidence regarding the formation and evolution of rarely analyzed H-FgMMs. The chemical variations were identified at both micrometer and nanometer scales, indicating that these carbonates formed under localized fluid conditions that suggest a variable chemical microenvironment. Individual carbonates grew from isolated reservoirs of fluid. Moreover, these carbonates contain manganese amounts almost twice as high as those measured in CM chondrites but similar to those identified in CI chondrites. Their particular compositions indicate reducing and progressively evolving conditions in the fluid from which these carbonates precipitated, probably due to water consumption during phyllosilicates formation. In addition to the compositional variability, microstructural features are pervasive in these carbonates, similar to those described in heavily shocked meteorites indicating that these carbonates were probably modified during shock processes after their formation. Since carbonates are highly susceptible to shock metamorphism, we suggest that it is essential to investigate their structure in detail before interpreting the isotopic measurements related to the time of their formation. Additionally, associated with carbonates, ubiquitous phosphates were identified in the micrometeorite analyzed. Future studies of these mineral associations will provide us further insight into the formation and evolution of asteroids, especially since they were both identified in the surface materials of Ryugu and Bennu.

58 GEOSCIENCES↗

Ocean internal tides suppress tropical cyclones in the South China Sea

Abstract Tropical Cyclones (TCs) are devastating natural disasters. Analyzing four decades of global TC data, here we find that among all global TC-active basins, the South China Sea (SCS) stands out as particularly difficult ocean for TCs to intensify, despite favorable atmosphere and ocean conditions. Over the SCS, TC intensification rate and its probability for a rapid intensification (intensification by ≥ 15.4 m s −1 day −1 ) are only 1/2 and 1/3, respectively, of those for the rest of the world ocean. Originating from complex interplays between astronomic tides and the SCS topography, gigantic ocean internal tides interact with TC-generated oceanic near-inertial waves and induce a strong ocean cooling effect, suppressing the TC intensification. Inclusion of this interaction between internal tides and TC in operational weather prediction systems is expected to improve forecast of TC intensity in the SCS and in other regions where strong internal tides are present.

54 ENVIRONMENTAL SCIENCES↗

Bounds on galaxy stochasticity from halo occupation distribution modeling

The joint probability distribution of matter overdensity and galaxy counts in cells is a powerful probe of cosmology, and the extent to which variance in galaxy counts at fixed matter density deviates from Poisson shot noise is not fully understood. The lack of informed bounds on this stochasticity is currently the limiting factor in constraining cosmology with the galaxy–matter probability distribution function (PDF). We investigate stochasticity in the conditional distribution of galaxy counts along lines of sight with fixed matter density, and we present a halo occupation distribution (HOD)-based approach for obtaining plausible ranges for stochasticity parameters. To probe the high-dimensional space of possible galaxy–matter connections, we derive a set of HODs that conserve the galaxies’ linear bias and number density to produce RED M A G I C-like galaxy catalogs within the A BACUS S UMMIT suite of N -body simulations. We study the impact of individual HOD parameters and cosmology on stochasticity and perform a Monte Carlo search in HOD parameter space subject to the constraints on bias and density. In mock catalogs generated by the selected HODs, shot noise in galaxy counts spans both sub-Poisson and super-Poisson values, ranging from 80% to 133% of Poisson variance for cells with mean matter density. Nearly all of the derived HODs show a positive relationship between local matter density and stochasticity. For galaxy catalogs with higher stochasticity, modeling galaxy bias to second order is required for an accurate description of the conditional PDF of galaxy counts at fixed matter density. The presence of galaxy assembly bias also substantially extends the range of stochasticity in the super-Poisson direction. This HOD-based approach leverages degrees of freedom in the galaxy–halo connection to obtain informed bounds on nuisance model parameters and can be adapted to study other parametrizations of shot noise in galaxy counts, in particular to motivate prior ranges on stochasticity for cosmological analyses.

Britt, Dylan (ORCID:000000019905601X)↗

Asymptotic consistency of the WSINDy algorithm in the limit of continuum data

In this work we study the asymptotic consistency of the weak-form sparse identification of nonlinear dynamics algorithm (WSINDy) in the identification of differential equations from noisy samples of solutions. We prove that the WSINDy estimator is unconditionally asymptotically consistent for a wide class of models that includes the Navier–Stokes, Kuramoto–Sivashinsky and Sine–Gordon equations. We thus provide a mathematically rigorous explanation for the observed robustness to noise of weak-form equation learning. Conversely, we also show that, in general, the WSINDy estimator is only conditionally asymptotically consistent, yielding discovery of spurious terms with probability one if the noise level exceeds a critical threshold σ c . We provide explicit bounds on σ c in the case of Gaussian white noise and we explicitly characterize the spurious terms that arise in the case of trigonometric and/or polynomial libraries. Furthermore, we show that, if the data is suitably denoised (a simple moving average filter is sufficient), then asymptotic consistency is recovered for models with locally-Lipschitz, polynomial-growth nonlinearities. Our results reveal important aspects of weak-form equation learning, which may be used to improve future algorithms. We demonstrate our findings numerically using the Lorenz system, the cubic oscillator, a viscous Burgers-growth model and a Kuramoto–Sivashinsky-type high-order PDE.

asymptotic consistency↗

Impact of Carbon Support Structure on the Durability of PtCo Electrocatalysts

High performing, low-Pt content fuel cell membrane electrode assemblies (MEAs) are critical to the economic viability of proton exchange membrane fuel cells (PEMFCs) for the transportation industry. Considerable research has been conducted to reduce the Pt content in fuel cells, leading to the development of transition metal alloys, such as Platinum-Cobalt (PtCo). The degree of degradation of PtCo catalysts can be impacted by not only the composition and morphology of the catalyst particle itself, but also its interactions with the carbon support. In this study several low-PtCo MEAs were fabricated, with various combinations of porous and solid carbon cathode catalyst supports. The MEAs were subjected to an accelerated stress test (AST), and the catalyst degradation characterized using electrochemical, X-ray scattering, and electron microscopy techniques. Porous supports retain more of their electrochemically-active surface area (ECSA) and demonstrate higher performance after the AST. This is believed to be due to the ability of the porous supports to trap the metal particles within the pores, slowing their dissolution/precipitation, and agglomeration. However porous supports also exhibit greater increases in transport resistance probably associated with enhanced Co leaching under the AST conditions.

25 ENERGY STORAGE↗

Long-Term Performance of Ag/AgCl Reference Electrodes for Corrosion Potential Monitoring in Radioactive Tank Waste at the Hanford Site

This work studied the exposure effects of radioactive tank waste on the long-term performance of single junction Ag/AgCl reference electrodes for corrosion potential monitoring at the Hanford Site. Electrodes from three manufacturers with very different designs were studied using open-circuit potential and electrochemical impedance measurements in radioactive tank waste. Post-test analyses were conducted on some failed electrodes using destructive and nondestructive techniques. The intrusion of the aggressive and radioactive chemicals in tank waste through the porous frit materials was the primary mechanism that led to the clogging of frit, physical and chemical degradation of AgCl bonded to Ag wire, and alteration of the internal electrolyte. Radiolytic chemical species such as H2O2 and HNO3 may have also induced the degradation of the Ag wire. The extent of electrode degradation and failure probability highly depended on the electrode design and environmental conditions. Chemicals in tank waste had stronger effects than radiation on the long-term performance of the Ag/AgCl reference electrodes.

Materials Science↗

A translational velocity command system for VTOL low speed flight

A translational velocity flight controller, suitable for very low speed maneuvering, is described and its application to a large class of VTOL aircraft from jet lift to propeller driven types is analyzed. Estimates for the more critical lateral axis lead to the conclusion that the controller would provide a jet lift (high disk loading) VTOL aircraft with satisfactory "hands off" station keeping in operational conditions more stringent than any specified in current or projected requirements. It also seems likely that ducted fan or propeller driven (low disk loading) VTOL aircraft would have acceptable hovering handling qualities even in high turbulence, although in these conditions pilot intervention to maintain satisfactory station keeping would probably be required for landing in restricted areas.

Merrick, V. K.↗

A near-optimum receiver structure for the detection of M-ary optical PPM signals

A class of receivers called conditionally nulling receivers is defined for quantum noise limited optical communications. These receivers have the ability to decide at each moment in time whether or not to coherently combine a predetermined local oscillator field with the received optical field, prior to performing an energy measurement (photodetection) on the combined field. Conditionally nulling receivers are applicable to pulse position modulation and related modulation schemes, which have the property that, at each moment in time, the transmitted signal is in one of only two states, on or off. The local oscillator field which may or may not be added by the receiver is an exact replica of the negative of the received on field; hence, the receiver can exactly null the on signal if the on signal is present and the receiver chooses to use the local field. An ideal conditionally nulling receiver achieves very nearly the same error probability (within a multiplicative factor varying froom 1 to 2.15) as the optimum quantum measurement for quantum noise limited detection of M-ary PPM signals. In contrast, other known receiving methods, such as direct, heterodyne, and homodyne detection, are exponentially suboptimum.

Dolinar, S. J., Jr.↗

Combustion characteristics in the transition region of liquid fuel sprays

A number of important effects have been observed in the droplet size transition region in spray combustion systems. In this region, where the mechanism of flame propagation is transformed from diffusive to premixed dominated combustion, the following effects have been observed: (1) maxima in burning velocity; (2) extension of flammability limits; (3) minima in ignition energy; and (4) minima in NOx formation. A monodisperse aerosol generator has been used to form and deliver a well controlled liquid fuel spray to the combustion test section where measurements of ignition energy have been made. The ignition studies were performed on monodisperse n-heptane sprays at atmospheric pressure over a range of equivalence ratios and droplet diameters. A capacitive discharge spark ignition system was used as the ignition source, providing independent control of spark energy and duration. Preliminary measurements were made to optimize spark duration and spark gap, optimum conditions being those at which the maximum frequency or probability of ignition was observed. Using the optimum electrode spacing and spark duration, the frequency of ignition was determined as a function of spark energy for three overall equivalence ratios (0.6, 0.8, and 1.0) and for initial droplet diameters of 25, 40, 50, 60, and 70 micro m.

Cernansky, N. P.↗

Moments of catchment storm area

The portion of a catchment covered by a stationary rainstorm is modeled by the common area of two overlapping circles. Given that rain occurs within the catchment and conditioned by fixed storm and catchment sizes, the first two moments of the distribution of the common area are derived from purely geometrical considerations. The variance of the wetted fraction is shown to peak when the catchment size is equal to the size of the predominant storm. The conditioning on storm size is removed by assuming a probability distribution based upon the observed fractal behavior of cloud and rainstorm areas.

Eagleson, P. S.↗

Ignition characteristics of rich n-heptane fuel sprays in the transition region

Ignition studies were performed on monodisperse n-heptane sprays at atmospheric pressure over a range of equivalence ratios and droplet diameters. A capacitive discharge spark ignition system was used as the ignition source, providing independent control of spark energy and duration. Preliminary measurements were made to optimize spark duration and spark gap, optimum conditions being those at which the maximum frequency or probability of ignition was observed. Using the optimum electrode spacing and spark duration, the frequency of ignition was determined as a function of spark energy for three overall equivalence ratios (0.6, 0.8, and 1.0) and for initial droplet diameters of 25, 40, 50, 60, and 70 microns. An LDA system was used to determine the actual equivalence ratio at the spark gap, which varied from 1.5 to 4.7. The spark energy at which the frequency of ignition was 90 percent was defined as the minimum ignition energy. These data indicated that the ignitability of the sprays was enhanced as the equivalence ratio was increased, but was diminished as the droplet size was increased. The increase in minimum ignition energy with increasing droplet size and fixed equivalence ratio was nearly linear over the range of parameters studied. However, the effect became smaller with increasing equivalence ratio.

Danis, A. M.↗

Interstellar lines in the spectrum of supernova 1987a

The primary interest was to analyze the interstellar lines produced by gases along the line of sight which resides in the galactic plane and halo, as well as material in the Large Magellanic Cloud or the immediate environment of the supernovae. The ionization and fine-structure excitation of assorted atoms were intrepreted. The goal was to learn more about conditions in various regions of space and identify the probable origins for some velocity components whose locations were uncertain.

Jenkins, Edward B.↗

Descent strategy comparisons for TNAV-equipped aircraft under airplane-preferred operating conditions

Three 4-D descent strategies were evaluated which were employed by TNAV-equipped aircraft in an advanced metering air traffic control environment. The Flow Management Evaluation Model (FMEM) was used to assess performance using three criteria when traffic enters the simulation under preferred cruise operating conditions (altitude and speed): throughput, fuel usage, and conflict probability. In comparison to an evaluation previously performed under NASA contract, the current analysis indicates that the optimal descent strategy is preferred over the clean-idle and constant descent angle (CFPA) strategies when all three criteria are considered.

Izumi, K. H.↗

The isolation limits of stochastic vibration

The vibration isolation problem is formulated as a 1D kinematic problem. The geometry of the stochastic wall trajectories arising from the stroke constraint is defined in terms of their significant extrema. An optimal control solution for the minimum acceleration return path determines a lower bound on platform mean square acceleration. This bound is expressed in terms of the probability density function on the significant maxima and the conditional fourth moment of the first passage time inverse. The first of these is found analytically while the second is found using a Monte Carlo simulation. The rms acceleration lower bound as a function of available space is then determined through numerical quadrature.

Knopse, C. R.↗

Scaling, soil moisture and evapotranspiration in runoff models

The effects of small-scale heterogeneity in land surface characteristics on the large-scale fluxes of water and energy in the land-atmosphere system has become a central focus of many of the climatology research experiments. The acquisition of high resolution land surface data through remote sensing and intensive land-climatology field experiments (like HAPEX and FIFE) has provided data to investigate the interactions between microscale land-atmosphere interactions and macroscale models. One essential research question is how to account for the small scale heterogeneities and whether 'effective' parameters can be used in the macroscale models. To address this question of scaling, the probability distribution for evaporation is derived which illustrates the conditions for which scaling should work. A correction algorithm that may appropriate for the land parameterization of a GCM is derived using a 2nd order linearization scheme. The performance of the algorithm is evaluated.

Wood, Eric F.↗

Observed climatic activity pertaining to the evolution of the northern plains

Although most of the landforms observed by Viking were probably formed long before the advent of present climatic conditions, it is possible that some modifications occurred more recently and may continue to the present. Also, present climate activity provides another dataset for hypothesizing earlier climatic conditions. Observations of climatic activity in the northern plains from 1905 to 1993 are summarized. Data from Earthbound telescopes and from spacecraft, including the Hubble Space Telescope (HST), were used.

Martin, L. J.↗