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At least 451 records · Page 25

All sources NASA NTRS DOE OSTI

NASA NTRS2013

Olivine Weathering aud Sulfate Formation Under Cryogenic Conditions

High resolution photography and spectroscopy of the martian surface (MOC, HiRISE) from orbit has revolutionized our view of Mars with one of the most important discoveries being wide‐spread layered sedimentary deposits associated with sulfate minerals across the low to mid latitude regions of Mars. The mechanism for sulfate formation on Mars has been frequently attributed to playa‐like evaporative environments under prolonged warm conditions. An alternate view of the ancient martian climate contends that prolonged warm temperatures were never present and that the atmosphere and climate has been similar to modern conditions throughout most of its history. This view has had a difficult time explaining the sedimentary history of Mars and in particular the presence of sulfate minerals which seemingly need more water. We suggest here that mixtures of atmospheric aerosols, ice, and dust have the potential for creating small films of cryo‐concentrated acidic solutions that may represent an important unexamined environment for understanding weathering processes on Mars. This study seeks to test whether sulfate formation may be possible at temperatures well below 0degC in water limited environments removing the need for prolonged warm periods to form sulfates on early Mars. To test this idea we performed laboratory experiments to simulate weathering of mafic minerals under Mars‐like conditions. The weathering rates measured in this study suggest that fine grained olivine on Mars would weather into sulfate minerals in short time periods if they are exposed to H2SO4 aerosols at temperatures at or above ‐40degC. In this system, the strength of the acidic solution is maximized through eutectic freezing in an environment where the silicate minerals are extremely fine grained and have high surface areas. This provides an ideal environment despite the very low temperatures. On Mars the presence of large deposits of mixed ice and dust is undisputed. The presence of substantial sulfur‐rich volcanism, and sulfur‐rich surface deposits also makes it very likely that sulfate aerosols have also been an important component of the martian atmosphere. Thus mixtures of ice, dust, and sulfate aerosols are likely to have been common on the martian surface. Given the fact that it is not difficult to achieve surface temperatures above ‐40degC on Mars throughout its history, it seems likely that sulfate formation on Mars is controlled by the availability of sulfate aerosols and not by the martian climate. The current polar regions of Mars and Earth provide interesting analogs. Large regions of sulfaterich material have been detected on and around the modern north polar region of Mars. The prevalence of ice‐dust mixtures in this region and the existence of sulfates within the ice cap itself are strong evidence for the origin of the sulfates from inside the ice deposits. In addition sulfates have been found in ice deposits in Greenland and Mount Fuji on Earth that have been attributed to forming within the ice deposit. These sulfates can form either through interaction with dust particles in the atmosphere or through weathering inside the ice itself.

Niles, Paul B.↗

NASA NTRS2003

Obliquity Driven Climate Change in Mars' Recent Past

We use the NASA/Ames grid Mars general circulation model with an updated radiation code and cloud nlicrophysics scheme. To speed up the simulations, we run the model at fairly coarse resolution (7.5" latitude x 22.5" longitude). Radiation Code Fluxes and heating rates are calculated from a radiation code based on the two-stream solution to radiative transfer that fully accounts for multiple scattering in the presence of gaseous absorp- tion. The model has 12 spectral intervals. Dust and water ice scattering properties are included. For dust, we use the Ockert-Bell [9] values in the visible, and Forget [IO] values in the infrared. For ice, we can either compute them online as the cloud evolves, or we can specify them. Gaseous opacities for water vapor and CO2 are calculated from correlated k-distributions taken from full line-by-line models. Cloud Microphysics Our cloud scheme is based on momentlorder scheme in which the mass mixing ratio and number density of the cloud ensemble are the advected species. From these we obtain a mean particle size and an estimate or the particle size distribution assuming a variance) which we then divide into 8 bins. Cloud microphysics is performed in each of these bins and includes nucleation, condensation, and gravitational settling. Dust is treated as a tracer and serves as condensation nuclei. The altered size distribution is then converted back into a mean size, a mixing ratio, and a particle number density.

Haberle, R. M.↗

NASA NTRS1991

Propagation measurements in Alaska using ACTS beacons

The placement of an ACTS propagation terminal in Alaska has several distinct advantages. First is the inclusion of a new and important climatic zone to the global propagation model. Second is the low elevation look angle from Alaska to ACTS. These two unique opportunities also present problems unique to the location, such as extreme temperatures and lower power levels. These problems are examined and compensatory solutions are presented.

Mayer, Charles E.↗

DOE OSTI2022

Developing a Composite Vacuum Insulated Panel (VIP) Insulation/Vinyl Siding Composite Technology for Retrofitting Residential Walls

This paper reports on a project that has attempted to seize on an opportunity to take a giant leap forward in commercializing a technology that would address a key opportunity to achieve energy savings in the existing residential housing stock. It is typically very difficult to increase the R-value of the walls in existing residential housing as doing so from the inside is disruptive and there have not been good solutions to increase thermal envelope performance from the exterior through adding continuous insulation due to the additional work required to fit existing architectural features to the new wall thickness and to reclad the facade. A high thermal resistivity or R-value per inch product that can be used in these applications offers an excellent solution. This paper summarizes a three-year research project to a produce vacuum insulated panel (VIP)/vinyl siding that would have sufficient R-value to meet the continuous insulation requirements of the 2018 International Energy Conservation Code (IECC, 2018) in all climate zones and has a much thinner profile that will facilitate its application to existing residential homes without the need for expensive retrimming of the architectural details. The paper will supply information on the development of the technology, its thermal modelling, testing, voice of user sessions to solicit input from architects, designers, manufacturers, contractors, and installers, and a techno-economic analysis to gauge its competitiveness with existing product options.

Desjarlais, Andre↗

DOE OSTI2025

Integration of Electrolysis Systems Into Isolated Microgrid Systems at Extreme Cold Climates

Isolated microgrid systems are generally used to power communities in remote locations where transmission line installations are cost prohibitive. These systems are usually powered by diesel generators, delivering expensive energy with high carbon emissions. However, most of these communities have special geographic access to renewable energy. These special conditions make it interesting to investigate the deployment of renewable energies and storage solutions. Within this scope, this paper analyses the integration of water electrolysis systems into off-grid communities, simulating the electrolyzer as well as the whole electrical grid in real time.

digital real-time simulation↗

DOE OSTI2021

Recent Progress in Cathode Materials for Sodium-Metal Halide Batteries

Transitioning from fossil-fuels to renewable energy sources is a critical goal of greenhouse gas re-duction and climate control. Major improvements have made wind and solar power increasingly cost-competitive with fossil fuels. However, the inherent intermittency of renewable power sources such motivates pairing these resources with energy storage. Electrochemical energy storage in batteries is widely used in many fields and increasingly for grid-level storage, but current battery technologies still fall short of performance, safety, and cost. This review focuses on sodium metal halide (Na-MH) batteries, such as well-known Na-NiCl2 batteries, as a promising solution to safe and economical grid-level energy storage. Important features of conventional Na-MH batteries are discussed, and recent literature on the development of intermediate temperature, low-cost cathodes for Na-MH batteries is highlighted. By employing lower cost metal halides (e.g. FeCl2, ZnCl2, and CuCl2, etc.) in the cathode and operating at lower temperatures (e.g. 190 °C vs. 280 °C), new Na-MH batteries have the potential to offer comparable performance at much lower overall costs, providing an exciting alternative technology to enable widespread adoption of renewables plus storage for the grid.

Zhan, Xiaowen↗

DOE OSTI2025

Exploring Micro-Environmental Conditions of Urban Agrivoltaics: Advancing Sustainable Green Spaces and Agriculture in Temperate Cities

Agrivoltaics, the integrated land use combining renewable energy production and agriculture, can potentially address key challenges faced by urban communities, including limited access to vacant land, fresh produce, and electricity. However, urban agrivoltaics has rarely been considered a viable solution, primarily due to a lack of experimental systems demonstrating the functionality of urban food production or green spaces alongside solar energy production. To evaluate the potential of solar photovoltaics to help mitigate heat stress on urban agriculture and green spaces in a temperate climate, we examined the microclimatic changes introduced by an urban agrivoltaics system (UrAV) when combined with vegetable crops and turfgrass, respectively. Accordingly, we installed an experimental setup instrumented with environmental sensors to compare full-sun conditions with those of an agrivoltaics system designed for urban environments. We found minimal differences for both land cover types between the control and agrivoltaics sites in air and soil temperature. However, during periods of intensified summer heat, temperatures beneath the panels cooled due to reductions in wind speed and relative humidity, which impeded the movement of hot, moist air and reduced reference evapotranspiration. Further, soil moisture in UrAV was highly spatially heterogeneous, influenced by the layout of the photovoltaic panels and their support structure, which redistributed rainfall and controlled where solar radiation could penetrate and drive evapotranspiration. Overall, our results suggest that PV-induced environmental changes in temperate climates are compatible with cultivating turfgrass or appropriate crops. These findings can help planners and designers integrate agrivoltaics into community gardens, farms, and green spaces in temperate cities.

14 SOLAR ENERGY↗

DOE OSTI2020

Evaluating the efficacy and equity of environmental stopgap measures

Contemporary environmental policy is rife with measures that do not fully resolve a problem, but instead are proposed to “buy time” for the development and future implementation of more durable solutions. In this perspective, we define such measures as “stopgap measures,” and examine examples from wildfire risk management, hydrochlorofluorocarbon regulation, and Colorado River water management. We introduce an analytical framework to assess stopgaps, and apply this framework to solar geoengineering, a controversial stopgap for climate action. Studying stopgaps as a novel category of policy and management measures can help us understand the why stopgaps emerge, and weigh the equity and efficacy of stopgaps against other policy proposals

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Framework for Greenhouse Gas Emissions Reduction Planning: Building Portfolios

The goal of this framework for greenhouse gas (GHG) emissions reduction planning (ERP) is to provide guidance to organizations seeking to reduce GHG emissions for their building portfolios and vehicle fleets. The process described in this framework helps organizations develop an actionable plan that prioritizes emissions reduction measures, identifies solutions, and lays out a phased pathway to achieve deep emissions reductions. The plan aims to result in the achievement of Scope 1 and 2 GHG emissions reduction targets, in alignment with goals set within the U.S. Department of Energy’s (DOE’s) Better Climate Challenge, as well as longer term emissions reduction goals.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2023

Framework for Greenhouse Gas Emissions Reduction Planning: Building Portfolios

The goal of this Framework for greenhouse gas (GHG) emissions reduction planning (ERP) is to provide guidance to organizations seeking to reduce GHG emissions for their building portfolios and vehicle fleets. The process described in this framework helps organizations develop an actionable plan that prioritizes emissions reduction measures, identifies solutions, and lays out a phased pathway to achieve deep emissions reductions The plan aims to result in the achievement of Scope 1 and 2 GHG emissions reduction targets, in alignment with goals set within the U.S. Department of Energy’s (DOE’s) Better Climate Challenge, as well as longer term emissions reduction goals.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

NASA NTRS1993

The US Geological Survey, digital spectral reflectance library: version 1: 0.2 to 3.0 microns

We have developed a digital reflectance spectral library, with management and spectral analysis software. The library includes 500 spectra of 447 samples (some samples include a series of grain sizes) measured from approximately 0.2 to 3.0 microns. The spectral resolution (Full Width Half Maximum) of the reflectance data is less than or equal to 4 nm in the visible (0.2-0.8 microns) and less than or equal 10 nm in the NIR (0.8-2.35 microns). All spectra were corrected to absolute reflectance using an NBS Halon standard. Library management software lets users search on parameters (e.g. chemical formulae, chemical analyses, purity of samples, mineral groups, etc.) as well as spectral features. Minerals from sulfide, oxide, hydroxide, halide, carbonate, nitrate, borate, phosphate, and silicate groups are represented. X-ray and chemical analyses are tabulated for many of the entries, and all samples have been evaluated for spectral purity. The library also contains end and intermediate members for the olivine, garnet, scapolite, montmorillonite, muscovite, jarosite, and alunite solid-solution series. We have included representative spectra of H2O ice, kerogen, ammonium-bearing minerals, rare-earth oxides, desert varnish coatings, kaolinite crystallinity series, kaolinite-smectite series, zeolite series, and an extensive evaporite series. Because of the importance of vegetation to climate-change studies we have include 17 spectra of tree leaves, bushes, and grasses.

Clark, Roger N.↗

DOE OSTI2021

An industrial policy framework for transforming energy and emissions intensive industries towards zero emissions

The target of zero emissions sets a new standard for industry and industrial policy. Industrial policy in the twenty-first century must aim to achieve zero emissions in the energy and emissions intensive industries. Sectors such as steel, cement, and chemicals have so far largely been sheltered from the effects of climate policy. A major shift is needed, from contemporary industrial policy that mainly protects industry to policy strategies that transform the industry. For this purpose, we draw on a wide range of literatures including engineering, economics, policy, governance, and innovation studies to propose a comprehensive industrial policy framework. The policy framework relies on six pillars: directionality, knowledge creation and innovation, creating and reshaping markets, building capacity for governance and change, international coherence, and sensitivity to socio-economic implications of phase-outs. Complementary solutions relying on technological, organizational, and behavioural change must be pursued in parallel and throughout whole value chains. Current policy is limited to supporting mainly some options, e.g. energy efficiency and recycling, with some regions also adopting carbon pricing, although most often exempting the energy and emissions intensive industries. An extended range of options, such as demand management, materials efficiency, and electrification, must also be pursued to reach zero emissions. New policy research and evaluation approaches are needed to support and assess progress as these industries have hitherto largely been overlooked in domestic climate policy as well as international negotiations.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2014

The Ancient Martian Climate System

Today Mars is a cold, dry, desert planet. The atmosphere is thin and liquid water is not stable. But there is evidence that very early in its history it was warmer and wetter. Since Mariner 9 first detected fluvial features on its ancient terrains researchers have been trying to understand what climatic conditions could have permitted liquid water to flow on the surface. Though the evidence is compelling, the problem is not yet solved. The main issue is coping with the faint young sun. During the period when warmer conditions prevailed 3.5-3.8 Gy the sun's luminosity was approximately 25% less than it is today. How can we explain the presence of liquid water on the surface of Mars under such conditions? A similar problem exists for Earth, which would have frozen over under a faint sun even though the evidence suggests otherwise. Attempts to solve the "Faint Young Sun Paradox" rely on greenhouse warming from an atmosphere with a different mass and composition than we see today. This is true for both Mars and Earth. However, it is not a straightforward solution. Any greenhouse theory must (a) produce the warming and rainfall needed, (b) have a plausible source for the gases required, (c) be sustainable, and (d) explain how the atmosphere evolved to its present state. These are challenging requirements and judging from the literature they have yet to be met. In this talk I will review the large and growing body of work on the early Mars climate system. I will take a holistic approach that involves many disciplines since our goal is to present an integrated view that touches on each of the requirements listed in the preceding paragraph. I will begin with the observational evidence, which comes from the geology, mineralogy, and isotopic data. Each of the data sets presents a consistent picture of a warmer and wetter past with a thicker atmosphere. How much warmer and wetter and how much thicker is a matter of debate, but conditions then were certainly different than what they are today. I will then discuss the origin and evolution of the early atmosphere from accretion and core formation to the end of the late heavy bombardment, including estimates of the volatile inventory, outgassing history, and potential escape mechanisms. This sets the stage for a comprehensive look at the climate system of early Mars and the attempts to solve the faint young sun problem. I will review the basic physics involved and then step through the different ideas highlighting their strengths and weaknesses. I will then conclude with a summary and a discussion of potentially promising avenues of future research

Mars↗

DOE OSTI2021

Exploring thermal state in mixed immersive virtual environments

Combining immersive virtual environment (IVE) with a controlled environment is a potential solution for analyzing human thermal experience during building design. Existing studies in this field have not adequately analyzed scenarios involving stabilized comfortable and uncomfortable temperature conditions using both thermal state votes and physiological responses, or the influence of the seasons. By combining IVE with a climate chamber, called mixed IVE (MIVE) in this study, experiments were conducted to test the hypothesis that participants' virtual experience did not significantly alter their thermal experience compared to their in-situ experience. Response variables were the control temperature distribution, the thermal state vote (at temperature steps 18.3 °C, 23.8 °C, and 29.4 °C), and physiological responses (heart rate and skin temperature). The results show that the first two response variables were not significantly different between the MIVE and in-situ settings (except for one case). Due to the heat development of the head mounted display device, the mean forehead skin temperature in the MIVE experiments was significantly higher than that in the in-situ experiments in most cases. Furthermore, such difference in skin temperature did not seem to affect general thermal state votes. In addition, significant skin temperature differences at some locations were also observed between the MIVE and in-situ settings.

42 ENGINEERING↗

DOE OSTI2023

CFL Optimized Forward–Backward Runge–Kutta Schemes for the Shallow-Water Equations

Abstract We present the formulation and optimization of a Runge–Kutta-type time-stepping scheme for solving the shallow-water equations, aimed at substantially increasing the effective allowable time step over that of comparable methods. This scheme, called FB-RK(3,2), uses weighted forward–backward averaging of thickness data to advance the momentum equation. The weights for this averaging are chosen with an optimization process that employs a von Neumann–type analysis, ensuring that the weights maximize the admittable Courant number. Through a simplified local truncation error analysis and numerical experiments, we show that the method is at least second-order in time for any choice of weights and exhibits low dispersion and dissipation errors for well-resolved waves. Further, we show that an optimized FB-RK(3,2) can take time steps up to 2.8 times as large as a popular three-stage, third-order strong stability-preserving Runge–Kutta method in a quasi-linear test case. In fully nonlinear shallow-water test cases relevant to oceanic and atmospheric flows, FB-RK(3,2) outperforms SSPRK3 in admittable time step by factors roughly between 1.6 and 2.2, making the scheme approximately twice as computationally efficient with little to no effect on solution quality. Significance Statement The purpose of this work is to develop and optimize time-stepping schemes for models relevant to oceanic and atmospheric flows. Specifically, for the shallow-water equations we optimize for schemes that can take time steps as large as possible while retaining solution quality. We find that our optimized schemes can take time steps between 1.6 and 2.2 times larger than schemes that cost the same number of floating point operations, translating directly to a corresponding speedup. Our ultimate goal is to use these schemes in climate-scale simulations.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2022

Interrogating organo-mineral interactions by Py-GC/MS and ToF-SIMS

Soil organic matter (SOM) is crucial to soil fertility and agricultural sustainability in the face of climate change, and organo-mineral interactions are a key mechanism for stabilizing SOM. The stability of mineral-associated organic matter (MAOM) can be approximated by the strength of bonds between biomolecules and mineral surfaces. We hypothesized that factors such as mineral reactivity and solution pH would impact bonding strength. To test these factors, sorption isotherms were performed on minerals differing in particle size, morphology, and reactivity (quartz, goethite, gibbsite, kaolinite, montmorillonite), under two pH conditions (4 and 6), and across a range of tannic acid concentration (0-1400 ppm). The quantity and quality of organo-mineral bonds was assessed by quantifying post-sorption solution compounds using an absorbance plate reader and assessing the thermal energy needed to break bonds using evolved gas analysis (EGA) on a pyrolysis gas chromatograph-mass spectrometer (Py-GC/MS). Organo-mineral surfaces were also interrogated using Time-of-flight secondary ion mass spectrometry (ToF-SIMS). Sorption experiments revealed an asymptotic relationship between sorbed tannic acid and increasing initial concentrations which suggests our concentration range saturated available mineral surfaces. Results indicated that mineral identity, chiefly surface area and native pH, impacted the amount of compound sorbed to mineral surfaces. Evolved gas analyses of organo-mineral samples uncovered increased thermal stability of sorbed compounds compared to our tannic acid standard particularly on the iron oxide, goethite. ToF-SIMS revealed that goethite surface ions were covered by increasing concentrations of adsorbed tannic acid with the replacement of chlorine and sulfate ions by tannic acid related ions. Our results indicate that Py-GC/MS and ToF-SIMS are useful techniques to determine the nature and strength of organo-mineral bonds and are steppingstones to understanding controls on carbon sequestration in terrestrial systems.

58 GEOSCIENCES↗

DOE OSTI2024

Depot Charging Schedule Optimization for Medium- and Heavy-Duty Battery-Electric Trucks

Charge management, which lowers charging costs for fleets and prevents straining the electrical grid, is critical to the successful deployment of medium- and heavy-duty battery-electric trucks (MHD BETs). This study introduces an energy demand and cost management framework that optimizes depot charging for MHD BETs by combining an energy consumption machine learning model and a linear program optimization model. The framework considers key factors impacting real-world MHD BET operations, including vehicle and charger configurations, duty cycles, use cases, geographic and climate conditions, operation schedules, and utilities’ time-of-use (TOU) rates and demand charges. The framework was applied to a hypothetical fleet of 100 MHD BETs in California under three different utilities for 365 days, with results compared to unmanaged charging. The optimized charging solution avoided more than 90% of on-peak charging, reduced fleet charging peak load by 64–75%, and lowered fleet energy variable costs by 54–64%. This study concluded that the proposed charge management framework significantly reduces energy costs and peak loads for MHD BET fleets while making recommendations for fleet electrification infrastructure planning and the design of utility TOU rates and demand charges.

Song, Shuhan↗

NASA NTRS2013

Experimental Evidence for Weathering and Martian Sulfate Formation Under Extremely Cold Weather-Limited Environments

Niles, Paul B.↗