Results for “alternative technologies” — Page 25

DOE OSTI2023

EXPERIMENTAL AND MODELING STUDY OF MOLECULAR TRANSPORT PHENOMENA IN COMPLEX LIQUID MIXTURES USING COVALENT ORGANIC FRAMEWORK MEMBRANES

Currently, 10-15% of the world’s energy is consumed by chemical separations, and more than 80% of that is used to purify organic liquids and recover rare earth elements and critical minerals. Membrane nanofiltration presents an energy-efficient, cost-effective, and eco-friendly alternative to current separation technologies. These complex liquid environments require high- performance, chemically-resistant membrane materials. Recently discovered Covalent Organic Frameworks (COFs) possess desirable properties as membrane materials for complex liquid separations. COFs are highly crystalline, chemically and thermally stable, with tunable size and charge. COFs, especially two-dimensional highly crystalline COFs, possess narrow pore-size distribution and controlled porous structures. Two-dimensional COFs are also resistant to swelling, another feature beneficial in complex liquid separations. Molecular interactions in complex liquid systems often dictate final membrane performance, resulting in a discrepancy between designed and apparent COF properties. Understanding and resolving this discrepancy is critical in utilizing COF membranes as a viable alternative to energy-intensive separations. The primary objective of this thesis was to use a commercially available COF TpPa-1 as a platform to investigate how mixed solvent environment affects COF membrane performance via experimental and molecular modeling studies. Specifically, the effects of solution pH, solvent- solvent-solute interactions in mixed solvents, and COF chemistry were carefully examined on apparent TpPa-1 pore size and permeability and targeted solute rejection of COF membranes for neat and mixed solvents. Experimental COF filtration performance was compared and corroborated with modeling predication. Findings from this study will provide guidance for future COF design, synthesis, and desired functional COF membrane performance.

Barnes, Anastasia↗

DOE OSTI2020

MEP: Mobility Energy Productivity Metric

In response to the need to assess fundamental improvements in mobility as technology provides new modes, methods, and opportunities in urban areas to connect people with goods, services, and employment, a mobility-energy productivity score (MEPS) has been developed. The MEPS fundamentally measures the potential of a multi-modal system to connect a person to a variety of services and activities that define a high-quality of life. The MEPS is measured relative to the convenience and energy needed to provide connectivity. Fundamentally derived from accessibility theory, the MEPS advances practice by using readily available travel time data (either from web-based APIs or outputs from an urban transportation model) combined with established parameters that reflect the energy intensity of various travel modes, and relative frequency of activity engagement. The construction of the MEPS allows for aggregation and disaggregation to the appropriate spatial, modal, and trip purpose resolution, as analysis needs dictate. The MEPS could be used to compare alternative futures related to technology, infrastructure investment, or policy, providing a much needed tool for planners, researchers, and analysts. In other words, the metric measures how efficiently connected a place is.

Hou, Yi↗

DOE OSTI2022

Thermal Process Intensification: Transforming the Way Industry Uses Thermal Process Energy (Workshop Report)

The US Department of Energy’s (DOE’s) Advanced Manufacturing Office held the virtual workshop entitled “Thermal Process Intensification: Transforming the Way Industry Uses Thermal Process Energy” in November and December 2020. The workshop brought together participants from universities/laboratories, industries, equipment manufacturers, technology vendors, nongovernmental organizations, and subject-matter experts to discuss transformative technologies and strategies to substantially improve the performance (e.g., energy productivity, thermal efficiency, reduced greenhouse gas [GHG] emissions, reduced number of process steps) of thermal processing systems in the industrial sector. The US industrial sector accounts for 32% of the nation’s primary energy use (including feedstocks), and refining, chemicals, pulp and paper, iron and steel, and food products represent the top energy-consuming sectors. Thermal processing or process heating represents the largest energy use category; it accounts for 63% of all energy use in manufacturing. Additionally, thermal processing is the largest contributor of carbon dioxide (CO2) generation, resulting from combustion of fuels and process related chemical reactions, such as in the case of cement and lime production. The challenge of achieving net-zero industrial GHG emissions is colossal considering the established industrial base that depends mainly on carbon-based processes and energy sources; the time frame and cost to replace carbon-based energy sources and feedstocks; and the long-term outlook for development with large-scale adaptation of alternative non carbon–based technologies. The goals of the DOE Advanced Manufacturing Office Thermal Process Intensification Workshop were as follows: (1) Identify R&D gaps and opportunities to facilitate transformative improvement in industrial thermal processes beyond current technologies and allow for entirely new methods for processing materials; (2) Gain insight into new and innovative approaches to thermally intensify processes, reduce heat demand, harness waste heat, and use fuels and hydrocarbon feedstocks more efficiently; (3) Identify the R&D pathways to thermal process intensification (TPI) with the highest potential for impact and adoption by the industrial sector; (4) Define areas of research, development, and demonstration (RD&D) activities to accelerate development and application of emerging and transformative technologies to intensify thermal processes in industry. The scope and focus of the workshop were defined to meet these goals. Based on the available data for energy use and GHG emissions, the industries that collectively use more than 80% of the total process heating energy consumption were selected as primary focus areas. The chosen industries were combined into the following four groups based on similarities in their thermal processes: high-temperature metal processing (iron and steel industry, alumina-aluminum industry); high-temperature nonmetal and mineral processing (cement and glass industry); medium- to low-temperature thermal processing (food processing and pulp and paper industry as part of forest products sector); and hydrocarbon processing (petroleum refining and chemical industry). Furthermore, all potential TPI technologies associated with the processes defined were considered as part of the workshop. Different types of TPI technologies possible in industrial in the document.

42 ENGINEERING↗

DOE OSTI2020

A Novel and Practical Method to Quantify the Quality of Mobility: The Mobility Energy Productivity Metric: Preprint

Recent technology innovations are enabling fundamental improvements in mobility systems, including options for new travel modes, methods, and opportunities to connect people with goods, services, and employment. A desire to quantify and compare both existing and emerging transportation options motivated development of the mobility energy productivity (MEP) metric described herein. The MEP metric fundamentally measures the potential of a city's transportation system to connect a person to a variety of services and activities that define a high-quality of life, relative to the convenience, cost and energy needed to provide these connections. Fundamentally derived from accessibility theory, the MEP advances practice by using readily available travel time data (either from web-based application programming interfaces (APIs) or outputs from an urban transportation model) combined with established parameters that reflect the energy intensity and cost of various travel modes, and relative frequency of activity engagement. The construction of the MEP metric allows for aggregation and disaggregation to the appropriate spatial, modal, and trip purpose resolution, as analysis needs dictate. The MEP could be used to compare alternative futures related to technology, infrastructure investment, or policy, providing a much-needed tool for planners, researchers, and analysts.

33 ADVANCED PROPULSION SYSTEMS↗

NASA NTRSDate not supplied

Advancements in Logistics Reduction for Exploration Missions

Management of logistics on exploration missions includes both looking for ways to minimize the quantities, mass and volume of various consumables, supplies, spares and equipment as well as ways to minimize the crew time needed for locating and handling those items. Also included are ways to minimize the waste, handling and resultant products from the processes of maintaining a crew on these missions. The Logistics Reduction project encompasses technologies for management of waste, trash, autonomous logistics, and clothing. This paper provides a status of work in these areas including recent accomplishments and challenges encountered. Future objectives will also be covered along with the work currently in progress. Specifically, the paper will cover technologies in waste management, namely, the Universal Waste Management System (UWMS) or exploration toilet and work on an alternative waste collection container, the Alternate Fecal Canister. Trash management technologies work on the Trash Compaction and Processing System (TCPS) and Trash to Gas (TtG) is summarized with progress to date as well as information on how Jettison as an option is related. Progress and summary of recent accomplishment on the RFID (Radio Frequency ID) Enabled Autonomous Logistics Management (REALM) and the Autonomous Logistics (AL) technologies is detailed. Advanced Clothing System (ACS) and work in the area of Systems Engineering and Integration (SE&I) is also included. Status of the technologies, accomplishments and how the focus areas inform program decisions will be addressed.

human spaceflight↗

NASA NTRSDate not supplied

Advancements in Logistics Reduction Technologies for Exploration Missions

Management of logistics on exploration missions includes both looking for ways to minimize the quantities, mass and volume of various consumables, supplies, spares and equipment as well as ways to minimize the crew time needed for locating and handling those items. Also included are ways to minimize the waste, handling and resultant products from the processes of maintaining a crew on these missions. The Logistics Reduction project encompasses technologies for management of waste, trash, autonomous logistics, and clothing. This paper provides a status of work in these areas including recent accomplishments and challenges encountered. Future objectives will also be covered along with the work currently in progress. Specifically, the paper will cover technologies in waste management, namely, the Universal Waste Management System (UWMS) or exploration toilet and work on an alternative waste collection container, the Alternate Fecal Canister. Trash management technologies work on the Trash Compaction and Processing System (TCPS) and Trash to Gas (TtG) is summarized with progress to date as well as information on how Jettison as an option is related. Progress and summary of recent accomplishment on the RFID (Radio Frequency ID) Enabled Autonomous Logistics Management (REALM) and the Autonomous Logistics (AL) technologies is detailed. Advanced Clothing System (ACS) and work in the area of Systems Engineering and Integration (SE&I) is also included. Status of the technologies, accomplishments and how the focus areas inform program decisions will be addressed.

human spaceflight↗

NASA NTRSDate not supplied

Logistics Reduction Advancements and Future Plans for NASA's Exploration Missions

Management of logistics on exploration missions includes both looking for ways to minimize the quantities, mass and volume of various consumables, supplies, spares, and equipment as well as ways to minimize the crew time needed for locating and handling those items. Also included are ways to minimize the waste, handling, and resultant products from the processes of maintaining a crew on these missions. The Logistics Reduction project encompasses technologies for management of waste, trash, autonomous logistics, and clothing. This paper provides a status of work from 2023 in these areas including recent accomplishments and challenges encountered. Future objectives and plans for 2024 will also be covered along with the work currently in progress. Specifically, the paper will cover technologies in waste management, namely, the Universal Waste Management System (UWMS) or exploration toilet and work on an alternative waste collection container, the Alternate Fecal Canister. Trash management technologies work on the Trash Compaction Processing System (TCPS) and Trash to Gas (TtG) is summarized with progress to date as well as information on how Jettison as an option is related. Progress and summary of recent accomplishment on the RFID (Radio Frequency ID) Enabled Autonomous Logistics Management (REALM) and the Autonomous Logistics (AL) technologies is detailed. Advanced Clothing System (ACS) and work in the area of Systems Engineering and Integration (SE&I) is also included. Status of the technologies, accomplishments and how the focus areas inform program decisions will be addressed.

Toilet↗

NASA NTRSDate not supplied

Logistics Reduction Advancements and Future Plans for NASA's Exploration Missions

Management of logistics on exploration missions includes both looking for ways to minimize the quantities, mass and volume of various consumables, supplies, spares, and equipment as well as ways to minimize the crew time needed for locating and handling those items. Also included are ways to minimize the waste, handling, and resultant products from the processes of maintaining a crew on these missions. The Logistics Reduction project encompasses technologies for management of waste, trash, autonomous logistics, and clothing. This paper provides a status of work from 2023 in these areas including recent accomplishments and challenges encountered. Future objectives and plans for 2024 will also be covered along with the work currently in progress. Specifically, the paper will cover technologies in waste management, namely, the Universal Waste Management System (UWMS) or exploration toilet and work on an alternative waste collection container, the Alternate Fecal Canister. Trash management technologies work on the Trash Compaction Processing System (TCPS) and Trash to Gas (TtG) is summarized with progress to date as well as information on how Jettison as an option is related. Progress and summary of recent accomplishment on the RFID (Radio Frequency ID) Enabled Autonomous Logistics Management (REALM) and the Autonomous Logistics (AL) technologies is detailed. Advanced Clothing System (ACS) and work in the area of Systems Engineering and Integration (SE&I) is also included. Status of the technologies, accomplishments and how the focus areas inform program decisions will be addressed.

Toilet↗

NASA NTRS2024

Logistics Reduction Advancements and Future Plans for NASA's Exploration Missions

Management of logistics on exploration missions includes both looking for ways to minimize the quantities, mass and volume of various consumables, supplies, spares, and equipment as well as ways to minimize the crew time needed for locating and handling those items. Also included are ways to minimize the waste, handling, and resultant products from the processes of maintaining a crew on these missions. The Logistics Reduction project encompasses technologies for management of waste, trash, autonomous logistics, and clothing. This paper provides a status of work from 2023 in these areas including recent accomplishments and challenges encountered. Future objectives and plans for 2024 will also be covered along with the work currently in progress. Specifically, the paper will cover technologies in waste management, namely, the Universal Waste Management System (UWMS) or exploration toilet and work on an alternative waste collection container, the Alternate Fecal Canister. Trash management technologies work on the Trash Compaction Processing System (TCPS) and Trash to Gas (TtG) is summarized with progress to date as well as information on how Jettison as an option is related. Progress and summary of recent accomplishment on the RFID (Radio Frequency ID) Enabled Autonomous Logistics Management (REALM) and the Autonomous Logistics (AL) technologies is detailed. Advanced Clothing System (ACS) and work in the area of Systems Engineering and Integration (SE&I) is also included. Status of the technologies, accomplishments and how the focus areas inform program decisions will be addressed.

Toilet↗

DOE OSTI2024

Emerging Technologies Review: Carbon Capture and Conversion to Methane and Methanol

Project 69643 Task 10 - The Air Force Civil Engineer Center has tasked Pacific Northwest National Laboratory with investigating emerging technologies to inform the Air Force’s understanding of the technology and to guide key considerations for implementing technologies that are resilient and alternative sources to the traditional methods used in the Air Force today. This report this report describes the emerging technology to capture carbon as a waste product and convert this to methane and methanol for deployment as a fuel on Air Force installations.

09 BIOMASS FUELS↗

DOE OSTI2022

Safety-Related Instrumentation and Control Pilot Upgrade: Initial Scoping Phase Implementation and Lessons Learned

In May 2016, the U.S. Nuclear Regulatory Commission (NRC) staff provided a digital instrumentation and control (I&C) regulatory infrastructure integrated action plan to the NRC for approval. One of the objectives of that plan was to establish a clear regulatory structure with reduced regulatory uncertainty to enable the expanded safe use of digital I&C in commercial nuclear reactors while continuing to ensure safety and security. To achieve this end, the NRC, with collaboration from industry, developed a streamlined License Amendment Request Alternate Review (AR) process for safety-related (SR) digital I&C upgrades. In spite of this effort, the industry has remained reluctant to perform such I&C upgrades because of perceived regulatory and financial risks associated with being the first or an early adopter of the AR process for SR I&C upgrades. The U.S. Department of Energy Light Water Reactor Sustainability Program at the Idaho National Laboratory performed Initial Scoping Phase research to help break this impasse by supporting a SR I&C Pilot Upgrade, working with MPR Associates, ScottMadden Inc., and Exelon Generation. Exelon’s Limerick Generating Station (LGS) was selected as the target for this research. This paper summarizes the Initial Scoping Phase engineering and operations, licensing, and project management activities necessary to bound the scope, schedule, and estimated cost of the project sufficiently to enable utility management authorization of Conceptual Design Phase activities. These efforts and associated products are intended to provide a template to support larger industry efforts to perform similar upgrades as a foundation stone for a digital transformation that will improve plant safety, reliability, and operational performance while lowering plant total cost of ownership. As a result of the combined effort of Exelon Generation and research participants, Conceptual Design Phase activities for the subject upgrade at LGS were approved by Exelon. Further, the U.S. Department of Energy also awarded a $50 million cost share award to Exelon in order to pave the way for SR I&C modernization and associated control room upgrades across the U.S. nuclear fleet. Additional research reports are planned for the Conceptual Design Phase, Detailed Design Phase, and the Implementation Phase of the LGS project to document the process followed and promulgate lessons learned to industry.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

NASA NTRS2012

Next Generation Life Support Project: Development of Advanced Technologies for Human Exploration Missions

Next Generation Life Support (NGLS) is one of several technology development projects sponsored by the National Aeronautics and Space Administration s Game Changing Development Program. NGLS is developing life support technologies (including water recovery, and space suit life support technologies) needed for humans to live and work productively in space. NGLS has three project tasks: Variable Oxygen Regulator (VOR), Rapid Cycle Amine (RCA) swing bed, and Alternative Water Processing. The selected technologies within each of these areas are focused on increasing affordability, reliability, and vehicle self sufficiency while decreasing mass and enabling long duration exploration. The RCA and VOR tasks are directed at key technology needs for the Portable Life Support System (PLSS) for an Exploration Extravehicular Mobility Unit (EMU), with focus on prototyping and integrated testing. The focus of the Rapid Cycle Amine (RCA) swing-bed ventilation task is to provide integrated carbon dioxide removal and humidity control that can be regenerated in real time during an EVA. The Variable Oxygen Regulator technology will significantly increase the number of pressure settings available to the space suit. Current spacesuit pressure regulators are limited to only two settings while the adjustability of the advanced regulator will be nearly continuous. The Alternative Water Processor efforts will result in the development of a system capable of recycling wastewater from sources expected in future exploration missions, including hygiene and laundry water, based on natural biological processes and membrane-based post treatment. The technologies will support a capability-driven architecture for extending human presence beyond low Earth orbit to potential destinations such as the Moon, near Earth asteroids and Mars.

Barta, Daniel J.↗

DOE OSTI2024

The Toughness of Interlocking Metasurfaces

Interlocking metasurfaces (ILMs) are arrays of autogenous latching unit cells patterned across a surface. These create structural joints similar to bioinspired suture joints but patterned over a 2D surface rather than a 1D seam. This enables ILMs to be an alternative to conventional joining technologies such as bolts, welds, and adhesives. However, compared to conventional joining methods, relatively little is known of the engineering considerations for designing structural ILMs. Herein, the interfacial toughness of an archetypal ILM is examined for the first time. Under the conditions studied here, the ILM is substantially tougher than the material from which it is made, in this case, exhibiting up to a 50% increase in interfacial crack initiation energy over the solid base material, a photocured 3D‐printed polymer. Through experimental tests using in‐situ digital image correlation along with complementary computational analyses, the mechanism of toughening in the ILM structure and the origins of toughness anisotropy are revealed. The increase in toughness is associated with cross‐cell interactions, that is, load‐sharing across unit cells, which give rise to a finite process zone length with different effective material properties. In this way, ILM toughening is analogous to crack blunting in ductile materials or fiber bridging in composites; yet here, the ILM is composed of a single‐phase base material and so the architected toughening is geometric in nature and hence amenable to future topological optimization.

fracture↗

DOE OSTI2021

Preventing Electrolyte Decomposition on a Ca Metal Electrode Interface Using an Artificial Solid‐Electrolyte Interphase

Abstract Calcium ion batteries are gaining attention as alternatives to lithium‐ion technology because they offer comparable properties at reduced cost and improved safety. However, progress has been limited because of the inability to efficiently and reversibly plate and strip Ca metal anodes in organic electrolytes. Moreover, the inorganic components of the solid‐electrolyte interphase (SEI) that form via decomposition of the electrolyte often do not allow for the diffusion of Ca ions. In this work, an approach combining density functional theory and ab initio molecular dynamics (AIMD) simulations is utilized to show that the use of a preformed artificial SEI layer of amorphous can potentially prevent electrolyte decomposition. First, Ca is shown to be able to intercalate into an amorphous layer (up to Ca 1.5 Al 2 O 3 ) and diffuse through on a reasonable time scale. Through calculation of the density of states, the system is found to remain insulating up to the equilibrium stoichiometry. Finally, AIMD simulations with a realistic organic electrolyte environment are used to show that this calcinated layer completely prevents the decomposition of solvent molecules. This approach can provide a route to efficient rechargeable Ca ion batteries, paving the way for cheap large‐scale energy storage.

Young, Joshua↗

DOE OSTI2022

Toward Fast Screening of Organic Solar Cell Blends

Explore the source record for details and available documents.

99 GENERAL AND MISCELLANEOUS↗

DOE OSTI2023

Expanding Linker Dimensionality in Metal‐organic Frameworks for sub‐Ångstrom Pore Control for Separation Applications

Abstract Metal‐organic frameworks (MOFs) are a class of porous materials with high surface areas, which are acquiring rapid attention on an exponential basis. A significant characteristic of MOFs is their ability to act as adsorbents to selectively separate component mixtures of similar size, thereby addressing the technological need for an alternative approach to conventional distillation methods. Recently, MOFs comprising a 3‐Dimensional (3D) linker have shown outstanding capabilities for difficult separations compared to the parent 2‐Dimensional (2D) analogue. 3D‐linkers with a polycyclic core are underrepresented in the MOF database due to the widespread preferred use of 2D‐linkers and the misconceived high‐cost of 3D linkers. We summarize the recent research of 3D‐linker MOFs and highlight their beneficial employment for selective gas and hydrocarbon adsorption and separation. Furthermore, we outline forecasts in this area to create a platform for widespread adoption of 3D‐linkers in MOF synthesis.

Macreadie, Lauren K.↗

DOE OSTI2023

Expanding Linker Dimensionality in Metal‐organic Frameworks for sub‐Ångstrom Pore Control for Separation Applications

Abstract Metal‐organic frameworks (MOFs) are a class of porous materials with high surface areas, which are acquiring rapid attention on an exponential basis. A significant characteristic of MOFs is their ability to act as adsorbents to selectively separate component mixtures of similar size, thereby addressing the technological need for an alternative approach to conventional distillation methods. Recently, MOFs comprising a 3‐Dimensional (3D) linker have shown outstanding capabilities for difficult separations compared to the parent 2‐Dimensional (2D) analogue. 3D‐linkers with a polycyclic core are underrepresented in the MOF database due to the widespread preferred use of 2D‐linkers and the misconceived high‐cost of 3D linkers. We summarize the recent research of 3D‐linker MOFs and highlight their beneficial employment for selective gas and hydrocarbon adsorption and separation. Furthermore, we outline forecasts in this area to create a platform for widespread adoption of 3D‐linkers in MOF synthesis.

Macreadie, Lauren K.↗

DOE OSTI2025

Correlated X‐Ray and Electron Microscopies of a Single Biphasic GaAs Nanowire

Engineering the properties of semiconductors by changing their crystalline phase is a technologically and economically relevant alternative to doping using foreign elements, with strong potential for photonic and electronic applications. Although major advances have been reported recently for crystal‐phase engineering of III‐V and group IV semiconductor nanowires, interfacing two mismatched crystalline phases in a nanostructure induces several deformation mechanisms, which remain largely unexplored. Here, using state‐of‐the‐art synchrotron X‐ray nanobeam diffraction and transmission electron microscopy, subtle twisting and bending is unveiled within an individual GaAs nanowire containing cubic and hexagonal segments. Their role is discussed in accommodating the inter‐reticular spacing fluctuations, and their variations are correlated to the nanoscale phase distribution and to the effect of the NW support. This study brings direct evidence of a complex combination of deformation mechanisms in biphasic nanowires, which opens a new path to tune the nanowire properties with appealing perspectives for device engineering in nanophotonics and nanomechanics.

III-V semiconductors↗