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At least 451 records · Page 25
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NASA NTRS1994

Venus climate stability and volcanic resurfacing rates

The climate of Venus is to a large degree controlled by the radiative properties of its massive atmosphere. In addition, outgassing due to volcanic activity, exospheric escape processes, and surface/atmosphere interactions may all be important in moderating the abundances of atmospheric CO2 and other volatiles. We have developed an evolutionary climate model for Venus using a systems approach that emphasizes feedbacks between elements in the climate system. Modules for atmospheric radiative transfer, surface/atmosphere interactions, tropospheric chemistry, and exospheric escape processes have so far been developed. Climate feedback loops result from interconnections between modules, in the form of the environmental parameters pressure, temperature, and atmospheric mixing ratios. The radiative transfer module has been implemented by using Rosseland mean opacities in a one dimensional grey radiative-convective model. The model has been solved for the static (time independent) case to determine climate equilibrium points. The dynamics of the model have also been explored by employing reaction/diffusion kinetics for possible surface atmosphere heterogeneous reactions over geologic timescales. It was found that under current conditions, the model predicts that the climate of Venus is at or near an unstable equilibrium point. The effects of constant rate volcanism and corresponding exsolution of volatiles on the stability of the climate model were also explored.

Bullock, M. A.↗
NASA NTRS1993

Heterogeneous reaction probabilities, solubilities, and the physical state of cold volcanic aerosols

On 19 January 1992, heterogeneous loss of HNO3, ClNO3, and HCl was observed in part of the Mount Pinatubo volcanic cloud that had cooled as a result of forced ascent. Portions of the volcanic cloud froze near 191 kelvin. The reaction probability of ClNO3 and the solubility of HNO3 were close to laboratory measurements on liquid sulfuric acid. The magnitude of the observed loss of HCl suggests that it underwent a heterogeneous reaction. Such reactions could lead to substantial loss of HCl on background sulfuric acid particles and so be important for polar ozone loss.

Toon, O.↗
NASA NTRS1994

Comparison of TOMS and AVHRR imagery of volcanic clouds

This project consisted of merging volcanic cloud data from initial studies from TOMS and AVHRR sensors. Because of the different data acquisition platforms and processing algorithms and formats, the combination of the two data required special consideration. Once the registration technique was perfected, several eruptions with data from both sensors were studied. The conclusion showed that, from the initial work, the positions of the volcanic clouds as detected by the two sensors are very similar. Because the AVHRR algorithm is now capable of retrieving masses of ash and sulfate aerosol, the capability of comparing data from the two sensors now allows changes in SO2, H2SO4, and silicated ash in drifting clouds to be described. The results of this study culminated in several presentations, and a master's thesis, which in turn was converted into a paper submitted to the Journal of Geophysical Research. Abstracts of two presentations are attached.

Rose, William I.↗
NASA NTRS1994

NO2 column changes induced by volcanic eruptions

Nitrogen dioxide slant column amounts measured by ground-based remote sensing from Lauder, New Zealand (45 deg S) and Campbell Island (53 deg S) during the second half of 1991 and early 1992 show anomalously low values that are attributed to the effects of volcanic eruptions. It is believed that the eruptions of Mount Pinatubo in the Philippines in June 1991 and possibly Mount Hudson in Chile in August 1991 are responsible for the stratospheric changes, which first became apparent in July 1991. The effects in the spring of 1991 are manifested as a reduction in the retrieved NO2 column amounts from normal levels by 35 to 45 percent, and an accompanying increase in the overnight decay of NO2. The existence of an accurate long-term record of column NO2 from the Lauder site enables us to quantify departures from the normal seasonal behavior with some confidence. Simultaneous retrievals of column ozone agree well with Dobson measurements, confirming that only part of the NO2 changes can be attributed to a modification of the scattering geometry by volcanic aerosols. Other reasons for the observed behavior are explored, including the effects of stratospheric temperature increases resulting from the aerosol loading and the possible involvement of heterogeneous chemical processes.

Johnston, Paul V.↗
NASA NTRS1994

Modulations of stratospheric ozone by volcanic eruptions

We have used a time series of aerosol surface based on the measurements of Hofmann to investigate the modulation of total column ozone caused by the perturbation to gas phase chemistry by the reaction N2O5(gas) + H2O(aero) yields 2HNO3(gas) on the surface of stratospheric aerosols. We have tested a range of values for its reaction probability, gamma = 0.02, 0.13, and 0.26 which we compared to unperturbed homogeneous chemistry. Our analysis spans a period from Jan. 1974 to Oct. 1994. The results suggest that if lower values of gamma are the norm then we would expect larger ozone losses for highly enhanced aerosol content that for larger values of gamma. The ozone layer is more sensitive to the magnitude of the reaction probability under background conditions than during volcanically active periods. For most conditions, the conversion of NO2 to HNO3 is saturated for reaction probability in the range of laboratory measurements, but is only absolutely saturated following major volcanic eruptions when the heterogeneous loss dominates the losses of N2O5. The ozone loss due to this heterogeneous reaction increases with the increasing chlorine load. Total ozone losses calculated are comparable to ozone losses reported from TOMS and Dobson data.

Blanchette, Christian↗
NASA NTRS1994

Retrieval of sizes and total masses of particles in volcanic clouds using AVHRR bands 4 and 5

The advanced very high resolution radiometer (AVHRR) sensor on polar orbiting NOAA satellites can discriminate between volcanic clouds and meteorological clouds using two-band data in the thermal infrared. This paper is aimed at developing a retrieval of the particle sizes, optical depth, and total masses of particles from AVHRR two-band data of volcanic clouds. Radiative transfer calculations are used with a semi-transparent cloud model that is based on assumptions of spherical particle shape, a homogeneous underlying surface, and a simple thin cloud parallel to the surface. The model is applied to observed AVHRR data from a 13-hour old drifting cloud from the August 19, 1992, eruption of Crater Peak/Spurr Volcano, Alaska. The AVHRR data fit in the range of results calculated by the model, which supports its credibility. According to the model results, the average of effective particle radius in the test frame of this cloud is in the range of 2 to 2.5 micrometer, the optical depth at 12 micrometer is about 0.60 - 0.65. The total estimated mass of ash in the air amounts to 0.24 - 0.31 x 10(exp 6) tons, which is about 0.7-0.9% of the mass measured in the ashfall blanket. Sensitivity tests show that the mass estimate is more sensitive to the assumed ash size distribution than it is to the ash composition.

Wen, Shiming↗
NASA NTRS1994

Experimental reduction of lunar mare soil and volcanic glass

We have reduced high-titanium lunar mare soil and iron-rich lunar volcanic glass with hydrogen at temperatures of 900-1100 C. Ilmenite is the most reactive phase in the soil, exhibiting rapid and complete reduction at all temperatures. Ferrous iron in the glass is extensively reduced concurrent with partial crystallization. In both samples pyroxene and olivine undergo partial reduction along with chemical and mineralogical modifications. High-temperature reduction provides insight into the optical and chemical effects of lunar soil maturation, and places constraints on models of that process. Mare soil and volcanic glass are attractive feedstocks for lunar oxygen production, with achievable yields of 2-5 wt%.

Allen, Carlton C.↗
NASA NTRS1995

Post-entry and volcanic contaminant abundances of zinc, copper, selenium, germanium and gallium in stratospheric micrometeorites

Some fraction of Zn, Cu, Se, Ga and Ge in chondritic interplanetary dust particles (IDPs) collected in the lower stratosphere between 1981 May and 1984 June has a volcanic origin. I present a method to evaluate the extent of this unavoidable type of stratospheric contamination for individual particles. The mass-normalized abundances for Cu and Ge as a function of mass-normalized stratospheric residence time show their time-integrated stratospheric aerosol abundances. The Zn, Se and Ga abundances show a subdivision into two groups that span approximately two-year periods following the eruptions of the Mount St. Helens (1980 May) and El Chichon (1982 April) volcanoes. Elemental abundances in particles collected at the end of each two-year period indicate low, but not necessarily ambient, volcanic stratospheric abundances. Using this time-integrated baseline, I calculate the straospheric contaminant fractions in nine IDPs and show that Zn, SE and Ga abundances in chondritic IDPs derive in part from stratospheric aerosol contaminants. Post-entry elemental abundances (i.e., the amount that survived atmospheric entry heating of the IDP) show enrichments relative to the CI abundances but in a smaller number of particles than previously suggested.

Rietmeijer, Frans J. M.↗
NASA NTRS1994

Carbonate-sulfate volcanism on Venus?

Venusian canali, outflow channels, and associated volcanic deposits resemble fluvial landforms more than they resmeble volcanic features on Earth and Mars. Some canali have meandering habits and features indicative of channel migration that are very similar to meandering river channels and flood plains on Earth, venusian outflow channels closely resemble water-carved outflow channels on Mars and the Channeled Scabland in Washington, collapsed terrains at the sources of some venusian channels resemble chaotic terrains at the sources of martian outflow channels, venusian lava deltas are similar to bird's-foot deltas such as the Mississippi delta, and venusian valley networks indicate sapping. We have developed an alternative possibility that the lava had a water-like rheology and a melting point slightly greater than Venus' surface temperature, thus accounting for the unusual behavior of the lava. Unlike silicate lavas, some carbonatites (including carbonate-sulfate-rich liquids) have these properties; thus they can flow great distances while retaining a high fluidity, significant mechanical erosiveness, and substantial capacity to transport and deposit sediment. Venusian geochemistry and petrology are consistent with extensive eruptions of carbonatite lavas, which could have crustal and/or mantle origins. Venus' atmosphere (especially CO2, HCl, and HF abundances) and rocks may be in local chemical equilibrium, which suggests that the upper crust contains large amounts of calcite, anhydrite, and other salts. Chemical analyses indicate, according to some models, that Venusian rocks may contain 4-19% calcite and anhydrite. Mixtures of crustal salts could melt at temperatures a few tens to a few hundred Kelvins higher than Venus' surface temperature; hence, melting may be induced by modest endogenetic or impact heating. Salts may have many of the same geologic roles on Venus as water and ice have on Mars. A molten salt (carbonatite) 'aquifer' may exist beneath a few hundred meters to several kilometers of solidified salt-rich 'permafrost.' Many geologic features can be explained by carbonatite magmatism: (1) impact melting of crustal salts can explain crater outflows, (2) small, sustained eruptions from molten salt aquifers can explain sapping valleys, (3) large, sustained eruptions may explain canali and their flood plans, and (4) catastrophic outbursts amy have formed outflow channels and chaotic terrain. Landforms created by carbonate-rich lavas would be thermally stable on Venus' surface, though some minerals may weather to other solid substances.

Kargel, Jeffrey S.↗
NASA NTRS1996

Mapping Volcanic Gas Emissions in the Mammoth Mountain Area Using AVIRIS

The Long Valley Caldera located in the eastern Sierra Nevada (California) shows new signs of volcanic activity. This renewed activity is expressed by gas emissions, hydrothermal activity and frequent earthquakes. Analysis of the gas composition regarding the percentage biogenic carbon and the He-3/He-4 ratio revealed that the gas source is the magma body approximately 7 km beneath the Long Valley Caldera. The gas from the magma body surfaces not only via the fumaroles but also emerges along geological faults. Some of the spots where gas surfaces are marked by dead or stressed trees. Other spots may not yet be identified. It is only recently known, from research at 'Vulcano Island' in southern Italy, that volcanoes release abundant carbon dioxide from their flanks as diffuse soil emanations. Mammoth Mountain seems to behave in a similar manner. The research described in this paper is designed to determine whether AVIRIS (Airborne Visible/Infrared Imaging Spectrometer) can be used to identify areas of volcanic gas emissions.

deJong, Steven M.↗
NASA NTRS1998

Volcanism, Cold Temperature, and Paucity of Sunspot Observing Days (1818-1858): A Connection?

During the interval of 1818-1858, several curious decreases in the number of sunspot observing days per year are noted in the observing record of Samuel Heinrich Schwabe, the discoverer of the sunspot cycle, and in the reconstructed record of Rudolf Wolf, the founder of the now familiar relative sunspot number. These decreases appear to be nonrandom in nature and often extended for 13 yr (or more). Comparison of these decreases with equivalent annual mean temperature (both annual means and 4-yr moving averages). as recorded at Armagh Observatory (Northern Ireland), indicates that the temperature during the years of decreased number of observing days trended downward near the start of' each decrease and upward (suggesting some sort of recovery) just before the end of each decrease. The drop in equivalent annual mean temperature associated with each decrease, as determined from the moving averages, measured about 0.1-0.7 C. The decreases in number of observing days are found to be closely related to the occurrences of large, cataclysmic volcanic eruptions in the tropics or northern hemisphere. In particular, the interval of increasing number of observing days at the beginning of the record (i.e., 1818-1819) may be related to the improving atmospheric conditions in Europe following the 1815 eruption of Tambora (Indonesia; 8 deg. S), which previously, has been linked to "the year without a summer" (in 1816) and which is the strongest eruption in recent history, while the decreases associated with the years of 1824, 1837, and 1847 may, be linked, respectively, to the large, catacivsmic volcanic eruptions of Galunggung (Indonesia; 7 deg. S) in 1822, Cosiguina (Nicaragua) in 1835, and, perhaps, Hekla (Iceland; 64 deg. N) in 1845. Surprisingly, the number of observing days per year, as recorded specifically b), SchAabe (from Dessau, Germany), is found to be linearly correlated against the yearly mean temperature at Armagh Observatory (r = 0.5 at the 2 percent level of significance); thus. years of fewer sunspot observing days in the historical record seem to indicate years of probable cooler clime, while years (if many sunspot observing days seem to indicate years of probable warmer clime (and Vice versa). Presuming this relationship to be real, one infers that the observed decrease in the number of observing days near 1830 (i.e., during "the lost record years" of 1825 to 1833) provides a strong indication that temperatures at Armagh (and, perhaps, most of Europe, as well) were correspondingly cooler. If true, then, the inferred cooling may have resulted from the eruption of Kliuchevsoi(Russia; 56 deg. N) in 1829.

Wilson, Robert M.↗
NASA NTRS1999

Near-Polar Cratered Cones on Mars: Mola Measurements and Implications for Volcanic Origins

Near-polar craterforms have been observed on Mars since Mariner 9. Hodges and Moore [1,2] described the implications of these apparently volcanic features and suggested that several were formed as a consequence of magma-ice or magma-water interactions. Indeed, they proposed that the feature illustrated in Fig. I represents a hydromagmatic explosion crater or maar, indicating interaction of ground-ice and/or water with magma in the higher Northern hemisphere latitudes of Mars. The advent of Mars Orbiter Laser Altimeter (MOLA) topographic information 161 for several of the putative volcanic craterforms described in [1,2] allows a reconsideration of their formation mechanisms. We have exploited MOLA's near-centerline cross-sections from the Science Phasing Orbit phase of the Mars Global Surveyor (MGS) mission to analyze the geometric properties of these features as constraints on their modes of origin and subsequent modification histories. From our preliminary analyses, we believe there is evidence these features may have been formed by effusive, lava shield building eruptions, and not hydromagmatic events. Furthermore, geometrical constraints indicate that some of the near-polar craterforms are geologically youthful.

Garvin, J. B.↗
NASA NTRS1998

Ozone Depletion at Mid-Latitudes: Coupling of Volcanic Aerosols and Temperature Variability to Anthropogenic Chlorine

Satellite observations of total ozone at 40-60 deg N are presented from a variety of instruments over the time period 1979-1997. These reveal record low values in 1992-3 (after Pinatubo) followed by partial but incomplete recovery. The largest post-Pinatubo reductions and longer-term trends occur in spring, providing a critical test for chemical theories of ozone depletion. The observations are shown to be consistent with current understanding of the chemistry of ozone depletion when changes in reactive chlorine and stratospheric aerosol abundances are considered along with estimates of wave-driven fluctuations in stratospheric temperatures derived from global temperature analyses. Temperature fluctuations are shown to make significant contributions to model calculated northern mid-latitude ozone depletion due to heterogeneous chlorine activation on liquid sulfate aerosols at temperatures near 200-210 K (depending upon water vapor pressure), particularly after major volcanic eruptions. Future mid-latitude ozone recovery will hence depend not only on chlorine recovery but also on temperature trends and/or variability, volcanic activity, and any trends in stratospheric sulfate aerosol.

Solomon, S.↗
NASA NTRS1999

Variation of Surface Air Temperature in Relation to El Nino and Cataclysmic Volcanic Eruptions, 1796-1882

During the contemporaneous interval of 1796-1882 a number of significant decreases in temperature are found in the records of Central England and Northern Ireland. These decreases appear to be related to the occurrences of El Nino and/or cataclysmic volcanic eruptions. For example, a composite of residual temperatures of the Central England dataset, centering temperatures on the yearly onsets of 20 El Nino of moderate to stronger strength, shows that, on average, the change in temperature varied by about +/- 0.3 C from normal being warmer during the boreal fall-winter leading up to the El Nino year and cooler during the spring-summer of the El Nino year. Also, the influence of El Nino on Central England temperatures appears to last about 1-2 years. Similarly, a composite of residual temperatures of the Central England dataset, centering temperatures on the month of eruption for 26 cataclysmic volcanic eruptions, shows that, on average, the change in temperature decreased by about 0.1 - 0.2 C, typically, 1-2 years after the eruption, although for specific events, like Tambora, the decrease was considerably greater. Additionally, tropical eruptions appear to produce greater changes in temperature than extratropical eruptions, and eruptions occurring in boreal spring-summer appear to produce greater changes in temperature than those occurring in fall-winter.

Wilson, Robert M.↗
NASA NTRS2000

Global to Microscale Evolution of the Pinatubo Volcanic Aerosol Derived from Diverse Measurements and Analyses

We assemble data on the Pinatubo aerosol from space, air, and ground measurements, develop a composite picture, and assess the consistency and uncertainties of measurement and retrieval techniques. Satellite infrared spectroscopy, particle morphology, and evaporation temperature measurements agree with theoretical calculations in showing a dominant composition of H2SO4-H20 mixture, with H2SO4 weight fraction of 65-80% for most stratospheric temperatures and humidities. Important exceptions are (1) volcanic ash, present at all heights initially and just above the tropopause until at least March 1992, and (2) much smaller H2SO4 fractions at the low temperatures of high-latitude winters and the tropical tropopause. Laboratory spectroscopy and calculations yield wavelength- and temperature-dependent refractive indices for the H2SO4-H20 droplets. These permit derivation of particle size information from measured optical depth spectra, for comparison to impactor and optical-counter measurements. All three techniques paint a generally consistent picture of the evolution of R(sub eff), the effective radius. In the first month after the eruption, although particle numbers increased greatly, R(sub eff) outside the tropical core was similar to preeruption values of approx. 0.1 to 0.2 microns, because numbers of both small (r < 0.2 microns) and large (r > 0.6 microns) particles increased. In the next 3-6 months, extracore R(sub eff) increased to approx. 0.5 microns, reflecting particle growth through condensation and coagulation. Most data show that R(sub eff) continued to increase for about 1 year after the eruption. R(sub eff) values up to 0.6 - 0.8 microns or more are consistent with 0.38 - 1 micron optical depth spectra in middle to late 1992 and even later. However, in this period, values from in situ measurements are somewhat less. The difference might reflect in situ undersampling of the very few largest particles, insensitivity of optical depth spectra to the smallest particles, or the inability of flat spectra to place an upper limit on particle size. Optical depth spectra extending to wavelengths lambda > 1 micron are required to better constrain R(sub eff), especially for R(sub eff) > 0.4 microns. Extinction spectra computed from in situ size distributions are consistent with optical depth measurements; both show initial spectra with lambda(sub max) <= 0.42 microns, thereafter increasing to 0.78 <= lambda(sub max) <= 1 micron. Not until 1993 do spectra begin to show a clear return to the preeruption signature of lambda(sub max) <= 0.42 microns. The twin signatures of large R(sub eff) (> 0.3 microns) and relatively flat extinction spectra (0.4 - 1 microns) are among the longest-lived indicators of Pinatubo volcanic influence. They persist for years after the peaks in number, mass, surface area, and optical depth at all wavelengths <= 1 microns. This coupled evolution in particle size distribution and optical depth spectra helps explain the relationship between global maps of 0.5- and 1.0-micron optical depth derived from the Advanced Very High Resolution Radiometer (AVHRR) and Stratospheric Aerosol and Gas Experiment (SAGE) satellite sensors. However, there are important differences between the AVHRR and SAGE midvisible optical thickness products. We discuss possible reasons for these differences and how they might be resolved.

Russell, P. B.↗
NASA NTRS2000

Volcanic Signatures in Estimates of Stratospheric Aerosol Size, Distribution Width, Surface Area, and Volume Deduced from Global Satellite-Based Observations

Volcanic signatures in the stratospheric aerosol layer are revealed by two independent techniques which retrieve aerosol information from global satellite-based observations of particulate extinction. Both techniques combine the 4-wavelength Stratospheric Aerosol and Gas Experiment (SAGE) II extinction measurements (0.385 <= lambda <= 1.02 microns) with the 7.96 micron and 12.82 micron extinction measurements from the Cryogenic Limb Array Etalon Spectrometer (CLAES) instrument. The algorithms use the SAGE II/CLAES composite extinction spectra in month-latitude-altitude bins to retrieve values and uncertainties of particle effective radius R(sub eff), surface area S, volume V and size distribution width sigma(sub R). The first technique is a multi-wavelength Look-Up-Table (LUT) algorithm which retrieves values and uncertainties of R(sub eff) by comparing ratios of extinctions from SAGE II and CLAES (e.g., E(sub lambda)/E(sub 1.02) to pre-computed extinction ratios which are based on a range of unimodal lognormal size distributions. The pre-computed ratios are presented as a function of R(sub eff) for a given sigma(sub g); thus the comparisons establish the range of R(sub eff) consistent with the measured spectra for that sigma(sub g). The fact that no solutions are found for certain sigma(sub g) values provides information on the acceptable range of sigma(sub g), which is found to evolve in response to volcanic injections and removal periods. Analogous comparisons using absolute extinction spectra and error bars establish the range of S and V. The second technique is a Parameter Search Technique (PST) which estimates R(sub eff) and sigma(sub g) within a month-latitude-altitude bin by minimizing the chi-squared values obtained by comparing the SAGE II/CLAES extinction spectra and error bars with spectra calculated by varying the lognormal fitting parameters: R(sub eff), sigma(sub g), and the total number of particles N(sub 0). For both techniques, possible biases in retrieved-parameters caused by assuming a unimodal functional form are removed using correction factors computed from representative in situ measurements of bimodal size distributions. Some interesting features revealed by the LUT and PST retrievals include: (1) Increases in S and V (but not R(sub eff)) after the Ruiz and Kelut injections, (2) Increases in S, V, R(sub eff) after Pinatubo, (3) Post-Pinatubo increases in S, V, and R(sub eff) that are more rapid in the tropics than elsewhere, (4) Mid-latitude post-Pinatubo increases in R(sub eff) that lag increases in S and V, (5) S and V returning to pre-Pinatubo values sooner than R(sub eff) does, (6) Sharp increases in sigma(sub g), after Pinatubo and slight increases in sigma(sub g) after Ruiz, Etna, Kelut, Spurr and Rabaul, and (7) Gradual declines in the heights at which R(sub eff), S and V peak after Pinatubo.

Bauman, J. J.↗