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At least 451 records · Page 25

Investigation of Non-Nuclear Plowshare and Vela Uniform Sites - 20447

The Plowshare Program was initiated by the Atomic Energy Commission, a predecessor agency to the US Department of Energy (DOE), to investigate peaceful uses of nuclear devices. 'Vela Uniform,' part of the broader Project Vela, was designed to use nuclear and other explosions to increase the capability of the United States to detect nuclear tests through seismicity. There were underground nuclear tests conducted off the Nevada National Security Site (NNSS) as part of the Plowshare Program (e.g., the Gnome-Coach, New Mexico, Site) and the Vela Uniform Program (e.g., Project Shoal, Nevada, Site) at which the DOE Office of Legacy Management (LM) has been conducting long-term surveillance and maintenance since fiscal year (FY) 2006. There are many additional locations, particularly for the Plowshare Program, that were considered for nuclear tests or used for non-nuclear tests off the NNSS. Some were only named on paper, but at 30 sites, field work such as drilling test wells and conducting tests using conventional explosives was done. A Plowshare nuclear explosion had been proposed at Project Chariot but was canceled in 1962. In 1992, the discovery of soils contaminated with radionuclides from tracer experiments led to a cleanup by the DOE Office of Environmental Management (EM) of the Project Chariot, Alaska, Site, which was completed in 1994. Following the cleanup of the Project Chariot site, EM was concerned that there might be environmental liabilities at other Plowshare or Vela Uniform sites where field investigations were done, even if the nuclear test was never conducted. The EM Program at the Nevada Site Office began examining records and visiting selected locations that were evaluated for Plowshare and Vela Uniform non-nuclear tests. In total, 161 Plowshare and 14 Vela Uniform sites or proposed projects were identified. The Desert Research Institute (DRI) created summaries of the work carried out at these sites and developed a collection of unclassified documents for them. Preliminary investigations had been conducted at these sites by both LM and EM since the early 2000's. In 2016, in preparation for accepting responsibility for the sites, LM started a program to determine if there were any environmental or safety liabilities associated with them. In 2019, LM formally accepted responsibility for these sites off the NNSS where non-nuclear explosive tests were conducted or where underground nuclear tests were proposed as part of the Plowshare and Vela Uniform programs but were never conducted. LM responsibilities will include maintaining institutional knowledge of the sites, responding to public inquiries, and addressing any concerns at each site. To minimize risk associated with site management, LM has archived all historical records compiled by DRI and has performed limited investigations at sites identified by the prior studies as having a higher potential liability. Preserving records related to site operations reduces the risk of doing unnecessary site investigations in the future caused by the loss of institutional knowledge. During the investigations, some maintenance needs were identified and will be addressed by the end of FY 2021. At the end of FY 2021, investigations, maintenance, and archiving activities will be complete. Remnants of test activities found at sites include craters, mud pits, debris, and open boreholes. Open boreholes are being plugged and abandoned in accordance with state regulatory standards. Other issues are being addressed in accordance with land owner requests and preferences as well as state regulations. Archiving activities include the development of project summaries identifying key operational details and current condition to allow site managers to be easily briefed. The LM experience at non-nuclear Plowshare and Vela Uniform sites applies to other programs where there is the potential for liability associated with the non-nuclear aspects of nuclear programs. This may include support activities or early phases of planned nuclear projects. Preserving institutional knowledge enables land managers to adequately address any concerns associated with operations and lowers risk. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Implementing Mixed Reality Tools to Support Mission Delivery at Hanford - 20520

Mission Support Alliance's (MSA) Public Works and Information Systems organizations have been working with Microsoft Corporation to develop and implement mixed reality operational solutions using their HoloLens technology. This collaborative effort is intended to drive innovative solutions and significantly improve MSA's efficiency in performing work at the Hanford Site. HoloLens, a mixed reality tool, is a commercial off-the-shelf technology that combines a head-mounted viewing screen with applications to help people and organizations learn, communicate, and collaborate more effectively through the use of mixed reality. https://microsoft.com/en-us/hololens MSA's initial pilot successfully demonstrated its ability to use mixed reality utilizing HoloLens' advanced features in a variety of ways, illustrating the potential efficiency gains previously stated as goals of this pilot. These achievements include the development of proprietary technology that allows synchronization between a HoloLens device and a mobile device or alternate global positioning system (GPS) device. This synchronization enables the HoloLens device to access real time GPS location data anywhere on the Hanford Site. This real time location data, combined with MSA's improved Hanford Geographical Information System (GIS) data, enables the mixed reality pilot application to identify underground utility systems as well as related utility attributes. This ability will aid utility workers in several areas, including excavation activities, the placement of large cranes, identifying interactions and conflicts with future underground utility placements and, eventually, recognizing and de-conflicting tank waste transfer system valve alignments. The HoloLens mixed reality application is also able to provide full or small scale holographic images of a facility's digital twin. This feature will allow MSA's Water and Sewer Utilities team to train and validate procedures associated with the new water treatment facility virtually, before it is constructed. This reduces the amount of time it takes to complete the training and procedure validation, and accelerates the overall construction schedule. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Decade of Innovative Approaches to Treating and Dispositioning Radioactive Waste at the Savannah River Site - 20620

This year marks the 70. anniversary of the U.S. Department of Energy's (DOE) Savannah River Site (SRS), located near Aiken, South Carolina. SRS is a key industrial complex responsible for environmental stewardship, environmental cleanup, waste management, and disposition of nuclear materials. SRS also continues to have a role in critical defense-related activities and the reprocessing of used reactor fuel. The SRS encompasses 803 square kilometers (310 square miles) in parts of Aiken, Barnwell, and Allendale counties. The Liquid Waste Mission starts with the safe receipt and storage of radioactive liquid waste in the waste tanks, which principally includes Cold War legacy waste, but also waste from support of National Aeronautics Space Administration missions, medical isotope production, and research activities. This 133,000 cubic meters (m{sup 3}) (35 million gallons [Mgal]) of high-level radioactive waste (HLW) is currently held in 43 large underground waste tanks. The capacity of each of these tanks range from 2,800 m{sup 3} to 5,000 m{sup 3} (0.75 to 1.33 Mgal) and were placed in operation between 1954 and 1986. In July 2009, the DOE awarded a stand-alone contract to execute the Liquid Waste Mission at SRS. The Liquid Waste Contractor selected was Savannah River Remediation LLC1 (SRR), which is responsible for receipt, storage, retrieval and treatment of all HLW, disposal of the decontaminated low-activity waste fraction, as well as operationally closing cleaned HLW tanks. Since July 2009, SRR has successfully grouted and operationally closed six large underground tanks, poured 1,476 canisters of vitrified HLW (a stable glass waste form), treated approximately 34,200 m{sup 3} (9.0 Mgal) of HLW, and dispositioned over 41,200 m{sup 3} (10.9 Mgal) of decontaminated salt solution as low-level waste (LLW) into the Saltstone Disposal Units (SDUs) being constructed by SRR on site. The innovative work performed by SRR in the LLW portion of its mission has earned it the Richard S. Hodes Award. The work conducted by SRR is the same work championed by the late Richard S. Hodes, a respected physician, statesmen, and Chairman of the Southeast Compact Commission for Low-Level Radioactive Waste Management. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Deposition Behavior of Supersaturated Silicic Acid on the Surfaces of Chlorite and Sericite around Geological Repository - 20138

Around the repository for HLW underground, cementitious materials used for the repository may complicate the migration of radionuclides in the host rock by the alteration of groundwater to a high alkaline condition. Specially, the alkaline groundwater dissolves silicate minerals of host rocks but the plenty of silicic acid dissolved from host rocks in groundwater will become supersaturated and deposit on the surface of flow-paths after decreasing the pH value to about 8 with dispersion and dilution. The deposition of silicic acid is presumed to recover and improve the barrier performance of host rocks for the radionuclide migration because of the narrowing of flow paths and the decrease of the permeability. In this study, the deposition behavior of supersaturated silicic acid was examined by the deposition experiments and the deposition rate constants, k [m/s], were evaluated from the experimental data. As the minerals of the surface of flow-paths, this study focused on chlorite and sericite, hydrothermally-altered minerals distributed to fill fractures of granite. In the experiments, deposition behavior of silicic acid on the powder of chlorite or sericite was observed after the pH of the solution was adjusted to 8 in order to make the silicic acid supersaturated. The solution of CaCl{sub 2} and NaCl were added into a silicic acid to simulate Ca{sup 2+} from the cementitious materials of the repository, Na{sup +} of the saline groundwater in Japan. From the results, the value of k was estimated to be about the order of 10{sup -10}∼10{sup -9} m/s for both chlorite and sericite and the value was almost the same as those for amorphous silica in the previous study. Therefore, the deposition of silicic acid may be assessed by similar apparent deposition rate constants even in actual underground containing various silicate minerals. Moreover, the Damkoehler number which is the dimensionless number expressed by the ratio of characteristic time of mass transfer and chemical reaction was calculated to be 10{sup 4} or more from the value of k. This value shows that the deposition reaction of silicic acid was estimated as much more predominant than the groundwater flow under the situation simulated in this study. These results suggest that the deposition of supersaturated silicic acid on the flow paths composed with various silicate minerals will be able to retard the migration of radionuclides because of narrowing micro flow-paths. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Infrastructure and DFLAW Support at Hanford - 20443

Manhattan Project era infrastructure systems are degrading at an accelerated pace across the Department of Energy's (DOE) Environmental Management complex. Revitalizing, rejuvenating and right-sizing these systems to ensure reliability for ongoing cleanup missions is a major focus at the 580-square- mile Hanford Site in southeast Washington State. The push to complete construction, commissioning, startup, and operation of facilities and systems in the Direct-Feed Low-Activity Waste (DFLAW) program at Hanford by 2023 requires considerable coordination among site contractors and a significant investment in infrastructure. The passage of time also poses a challenge. It has been about 75 years since facilities were first operated at the site, and approximately 40 years of plutonium production created a legacy of unidentified active and abandoned underground obstacles and waste sites that must be avoided when building and upgrading the infrastructure. Converting infrastructure systems originally built to support plutonium production from the 1940's to the 1980's and upgrading those systems to optimize technology is an ever-changing balance of funding profiles, available resources and execution strategies. The DOE Richland Operations Office (RL) has long recognized the need for increased investment in Hanford Site infrastructure to support the future processing of approximately 56 million gallons of waste currently stored in large underground tanks. When DFLAW is fully operational, safe and reliable infrastructure systems will be needed to ensure continuity of operations around the clock, 365 days a year. These include roadways, water, power, sewer, information technology systems and facilities. To ensure the readiness of Hanford's infrastructure to support treating tank waste in the next three years, 15 projects were identified with a combined value of $133.8 million. Through calendar year 2019, 7 infrastructure projects have been substantially completed and the remaining 8 projects, with a remaining value of $103.8 million, are scheduled to be completed by December 2023. RL and its site services/infrastructure contractor, Mission Support Alliance (MSA), regularly evaluate the needs of the DFLAW program and other Hanford Site missions to ensure the highest priority systems are addressed. In addition to a fast-approaching deadline for round-the-clock treatment operations, RL and MSA face another significant infrastructure challenge. As cleanup is being completed in a 220-square-mile area called the River Corridor, most of the cleanup operations going forward will occur in a 20-square-mile area in the center of the Hanford Site, known as the Central Plateau. Infrastructure systems are becoming more congested in an already overcrowded area. This paper/presentation will outline some of the challenges Hanford faces while executing infrastructure reliability projects. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A History of Hanford Tank Waste, Implications for Waste Treatment and Disposal

More than 40 years of plutonium processing have left almost 56 million gallons of mixed radioactive waste sequestered in 177 underground tanks on the Hanford Site. Three different processing technologies were employed for plutonium purification in addition to uranium scavenging and fission product removal from the tank waste. All of these chemical processes have contributed to a complex waste stream that varies from tank to tank that presents downstream processing challenges to render the waste into a safe form for long-term storage. The current disposition pathway for Hanford tank waste is vitrification. To maximize waste loading and minimize the number of high-level waste canisters stored in a geologic repository, pretreatment of the waste is required. Both pretreatment and vitrification operations are impacted by the waste composition.

Separations, filtration, ion exchange↗

Risk-based area of review estimation in overpressured reservoirs to support injection well storage facility permit requirements for CO 2 storage projects

This paper by the Energy & Environmental Research Center presents a workflow and modeling approach for delineating a risk-based area of review (AOR) to support a U.S. Environmental Protection Agency (EPA) Class VI permit for a carbon dioxide (CO 2 ) storage project. The approach combines semianalytical solutions for estimating formation fluid leakage through a hypothetical leaky wellbore with the results of numerical reservoir simulations to define the AOR. The modeling utilizes 1) semianalytical solutions from the peer-reviewed literature for formation fluid leakage through abandoned wellbores by Raven (1990) and Avci (1994), 2) a FORTRAN model compiled and described in Cihan et al. (2011, 2012) called ASLMA (Analytical Solution for Leakage in Multilayered Aquifers), and 3) a computational framework for estimating a risk-based AOR first proposed by Oldenburg et al. (2014, 2016). Therefore, the approach builds upon well-established research and underlying hydrogeological principles that have been upheld for nearly three decades. Moreover, the ASLMA model has been broadly applied to an array of storage projects. The work presented herein extends these earlier works using a custom wrapper written in the software environment, R (R Core Team, 2020), which was developed to perform multiple runs of the ASLMA model using given ranges for one or more input parameters. In addition, the current work simulates the pressure buildup within the storage reservoir in response to CO 2 injection using a compositional simulator to better accommodate the temporospatial evolution of pressure buildup within the storage reservoir that is more accurately modeled using a heterogeneous geologic model and a compositional simulator that accounts for the multiphase interactions. The workflow is demonstrated using a case study for a 180,000-metric-ton-per-year storage project located in the PCOR (Plains CO 2 Reduction) Partnership region. For the storage project evaluated here, under the scenario where the leaky wellbore is open to a saline aquifer (thief zone) between the overlying seal (cap rock) and the underground sources of drinking water (USDW), the risk-based AOR essentially collapses to the areal extent of the CO 2 plume in the storage reservoir because the pressure buildup in the storage reservoir beyond the CO 2 plume is insufficient to drive formation fluids up a hypothetical leaky wellbore into the USDW. However, even under the conservative assumption that the leaky wellbore is not open to a thief zone, beyond the areal extent of the CO 2 plume, the incremental leakage is less than 400 m 3 over 20 years, which represents ~0.0001% or less of the total volume of water contained within the USDW rock volume. As discussed in the text, the threshold criterion for defining the risk-based AOR is site-specific and should be informed by the results of the sensitivity analysis and available site characterization data. The approach outlined in this paper is designed to be protective of USDWs and, therefore, comply with the Safe Drinking Water Act requirements and provisions for the U.S. EPA Class VI Underground Injection Control (UIC) Program (Class VI Rule) and North Dakota Administrative Code Chapter 43-05-01.

54 ENVIRONMENTAL SCIENCES↗

Study of cosmogenic activation above ground for the DarkSide-20k experiment

The activation of materials due to exposure to cosmic rays may become an important background source for experiments investigating rare event phenomena. DarkSide-20k, currently under construction at the Laboratori Nazionali del Gran Sasso, is a direct detection experiment for galactic dark matter particles, using a two-phase liquid-argon Time Projection Chamber (TPC) filled with 49.7 tonnes (active mass) of Underground Argon (UAr) depleted in 39 Ar. Despite the outstanding capability of discriminating γ / β background in argon TPCs, this background must be considered because of induced dead time or accidental coincidences mimicking dark-matter signals and it is relevant for low-threshold electron-counting measurements. Here, the cosmogenic activity of relevant long-lived radioisotopes induced in the experiment has been estimated to set requirements and procedures during preparation of the experiment and to check that it is not dominant over primordial radioactivity; particular attention has been paid to the activation of the 120 t of UAr used in DarkSide-20k. Expected exposures above ground and production rates, either measured or calculated, have been considered in detail. From the simulated counting rates in the detector due to cosmogenic isotopes, it is concluded that activation in copper and stainless steel is not problematic. The activity of 39 Ar induced during extraction, purification and transport on surface is evaluated to be 2.8% of the activity measured in UAr by DarkSide-50 experiment, which used the same underground source, and thus considered acceptable. Other isotopes in the UAr such as 37 Ar and 3 H are shown not to be relevant due to short half-life and assumed purification methods.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Experimental study on nanoparticle injection by using a lab-scale wellbore system

After long-term underground storage of CO 2 gas, leakage generated from the cement annulus in the wellbore system is often detected due to unbalanced pressure, chemical attack, etc. Here in this paper, nanoparticle injection technology is introduced to inject different types of nanoparticles into the cementitious material for repairing the leakage paths through electrochemical means. The pressure vessel is designed and built to provide a realistic underground environment with high pressure and high temperature. The testing results are evaluated by the saturate-drying method, charge-passed method, and X-ray microscopy (XRM) test. The results consistently show that all types of nanoparticles tested in this paper can be successfully driven into the cement annulus within the wellbore system. The pressure (6.89 MPa) and temperature (80 °C) in the pressure vessel, and the surrounding rock can directly affect the injection effectiveness. The nanoparticle injection technology is proven to be beneficial to the cracked cement annulus for preventing the leakage of CO 2 gas through the lab-scale wellbore system.

36 MATERIALS SCIENCE↗

Modeling the corrosion of steel casing and the damage of well cement in a borehole system

This work presents the effect of chloride-induced corrosion in an underground borehole system, specifically considering the steel casing and further damage to the surrounding cement. In the past four decades, oil well cement has been successfully used for underground construction. However, high concentrations of chloride ions gradually degrade the functionality and durability of well cement. Gasses and liquids can leak from deterioration caused by chloride ions, and thus motivate this study. The chemo-mechanical coupling diffusion model and a classical fracture mechanics model are applied. The model is validated with OPC concrete corrosion data from literature, and then applied to well cement using experimentally obtained material property data. The time when crack initiation, peak pressure, and complete fracture is reached in the model of the cement sheath provides a quantification of the expected service life of the borehole system.

36 MATERIALS SCIENCE↗

Experimental and theoretical study of the restrained shrinkage cracking of early age well cement

The shrinkage cracking occurring in oil & gas well cement material is a major factor that reduces the cement sheath integrity and impairs the durability of an underground well. Shrinkage mainly takes place in the early hydration period of the cement, and the resulting restrained shrinkage cracking can form a leaking network for oil & gas or carbon dioxide stored in an underground reservoir. It is thus important to understand the early age behavior of well cement and the leaking pathway formation in the well. This study describes the application of the digital image correlation (DIC) method as a tool to measure the strain development and crack distributions of well cement in the lab during early phase changes. A theoretical model is presented to calculate the stress distribution built up in the cement sheath during early ages of well cement hydration, which helps to interpret the experimental observations and determine the major factors influencing the cracking sequences. This study presents the whole hydration – drying shrinkage – and cracking mechanism of early age well cement under restrained ring conditions experimentally and theoretically. Finally, the results offer useful insights on the key material and geometric parameters which control the fracture of a well cementing structure.

36 MATERIALS SCIENCE↗

Deep-learning-enhanced assessment of wellbore barrier effectiveness in geologic storage systems with intermediate aquifers

For geologic systems where carbon dioxide (CO 2 ) is injected underground, existing wells represent potential pathways for fluid migration. Here, this study introduces a novel deep learning model to quantify the likelihood and potential magnitude of fluid migration through wellbores at sites with intermediate aquifers or thief zones between the injection units and underground drinking water sources. Synthetic datasets, generated using reservoir simulations, captured a wide range of subsurface conditions, well attributes, operational parameters, and fluid migration scenarios. Among the regression models developed to predict brine and CO 2 leakage rates and CO 2 saturations along leaky wellbores, convolutional neural network (CNN) outperformed both Light Gradient Boosting Machine and deep neural network. Additionally, a CNN-based classification model was created to predict whether brine and CO 2 would leak along a wellbore, further improving performance over regression alone. The best models were integrated into the National Risk Assessment Partnership Open-source Integrated Assessment Model for rapid, stochastic assessment of storage system containment and leakage risks. A case study demonstrated the model’s ability to simulate fluid migration through existing wells with multiple intermediate aquifers. This computationally efficient wellbore model offers value in support of site performance evaluation and risk-informed decision making by stakeholders.

CO2 leakage↗

Microwave-enhanced methane cracking for clean hydrogen production in shale rocks

Here, steam methane reforming (SMR) generates about 95% of hydrogen (H 2 ) in the U.S. using natural gas as a main feedstock. However, this technology also generates a large amount of carbon dioxide (CO 2 ), a major greenhouse gas causing global warming. Carbon capture and storage (CCS) technique is required, but the cost and safety of storing CO 2 underground are a concern. Here we propose a new approach using microwave/electromagnetic irradiation to produce clean hydrogen from unrecovered hydrocarbons within petroleum reservoirs. Solid carbon or CO 2 produced during this process will be simultaneously sequestrated underground without involving CCS. In this paper, we perform a series of experiments to investigate the in-situ hydrogen production from shale gas (methane) conversion by passing a methane stream through a packed shale rock sample heated by microwave. We found that methane conversion was significantly enhanced in the presence of Fe and Fe 3 O 4 particles as catalysts, with a conversion of 40.5% and 100% at reaction temperature of 500 °C and 600 °C, respectively. Methane conversion is promoted at a lower reaction temperature by the catalytic effect of minerals in shale. Additionally, the influences of catalysts, shale rock, and methane flow rate are characterized.

08 HYDROGEN↗

Determination of permeability for hydrocarbon release due to excavation-induced stress redistribution in rock salt

Due to a stress redistribution after the excavation of an underground tunnel for radioactive waste disposal, an Ed/DZ (excavation disturbed/damaged zone) will be generated in the near field of the opening, resulting in significant changes in the hydraulic and mechanical properties of the rock mass in the zone. Initially more or less randomly distributed hydrocarbons at grain boundaries in rock salt, which sometimes can only be observed with ultraviolet light, can then be mobilised and migrate at a potentially significant rate towards the excavation. Within the international cooperative project DECOVALEX 2019, the migration mechanism of such fluid inclusions in rock salt is being studied intensively. Specifically, a multi-scale modelling strategy has been developed. A macroscale coupled hydro-mechanical modelling of an underground excavation was performed to determine hydraulic and time-dependent deviatoric stress conditions, by taking into account the rock salt creep behaviour. Under the obtained macro-scale constraints, micro-scale modelling of a pathway dilation along halite grain boundaries was performed using different model strategies: a) coupled hydromechanical modelling with a consideration of hydraulic pressure-induced dilatant deformation, b) nonlinear dynamic model taking account of fluid migration, stress-dependent grain boundary wetting and shear-induced dilatancy of salt, and c) phase-field modelling of flow pathway propagation. The permeability increase resulting from the pathway dilation is estimated to be as high as two orders of magnitude. Based on the permeability determined, a series of pressure buildups measured from a borehole with a high hydrocarbon release rate, a total of 430 build-ups within a monitoring time of 938 days, can be simulated with a macro-scale compressible flow model accounting for different zones around the opening.

58 GEOSCIENCES↗

Low-stress creep behavior of multiple salt caverns under cyclic operations

Here, the use of multiple salt caverns for large-scale underground hydrogen storage offers a strategic solution to the growing demand for efficient and flexible energy storage, due to the inherent low permeability, high mechanical strength, and self-healing properties of the salt formation. Despite these advantages, the long-term geomechanical response of salt caverns under cyclic injection and withdrawal remains a significant challenge for ensuring operational stability. This mechanistic study highlights the critical role of low-stress creep, also known as pressure solution creep, in governing deformation of salt caverns during cyclic operations. Unlike conventional creep mechanisms that dominate under high-stress conditions, low-stress creep becomes particularly relevant under the moderate stress changes induced by repeated injection and withdrawal, which provides a previously underexplored control on cavern closure. Our three-dimensional computational model integrates the low-stress creep mechanism into the Munson–Dawson creep equation across a spectrum of operational scenarios including variations in cavern pressure cycles, injection-withdrawal frequencies, and caprock mechanical property. The low-stress creep components accelerate the cavern creep closure, which is amplified with shorter cycle frequency and larger pressure difference. Sensitivity analyses capture the complex interactions between multiple caverns and surround formations at the field scale that allows for a quantitative assessment of deformation patterns and closure rates over time and thereby informs the design and operation of sustainable underground hydrogen storage system.

Cyclic operation↗

Comparison of near-background concentrations of Argon-37 and Xenon-133 in the Atmosphere

Radioisotopes of noble gases xenon and argon can be important indicators of underground nuclear explosions. The Comprehensive Nuclear-Test-Ban Treaty (CTBT) includes monitoring capabilities to identify potential nuclear explosions conducted in violation of the CTBT. This monitoring currently focuses on measurement of the xenon isotopes 133Xe, 135Xe, 131mXe and 133mXe. However, it is predicted that within 100 days of an underground nuclear explosion (UNE) 37Ar would be released to the atmosphere at higher concentrations than xenon isotopes (Haas et al. 2010) and with a higher signal to background ratio, depending on the radioxenon background levels. Therefore, inclusion of 37Ar measurement capabilities at atmospheric International Monitoring System (IMS) stations may represent an improvement in the capability to detect a nuclear explosion. At an IMS station, it could be difficult to determine what constitutes an elevated concentration as a result of an UNE without first understanding the expected range of background concentrations. This work describes our analysis of atmospheric samples for 37Ar to evaluate the range of background concentrations. Samples were collected at multiple locations, with approximately half coming from a sampler co-located with an IMS xenon monitoring station (RN75). The range of 37Ar concentrations measured in atmospheric air samples was relatively narrow; for samples considered detectable, the minimum and maximum measured concentrations were 0.56 and 2.3 mBq/m3, respectively. Comparison of 37Ar and 133Xe concentrations measured at the IMS station indicated some correlation between the measured concentrations. The results presented here demonstrate the capability to detect background concentrations of 37Ar in atmospheric air and provide a basis for potential implementation of 37Ar monitoring at IMS stations.

Fritz, Brad G.↗

Examining the potential for detecting simultaneous noble gas and aerosol samples in the international monitoring system radionuclide network

The purpose of the Comprehensive Nuclear-Test-Ban Treaty (CTBT) is to establish a legally binding ban on nuclear weapon test explosions or any other nuclear explosions. The Preparatory Commission for the CTBT Organization (CTBTO PrepCom) is developing the International Monitoring System (IMS) that includes a global network of 80 stations to monitor for airborne radionuclides upon entry into force of the CTBT. All 80 radionuclide stations will monitor for particulate radionuclides and at least half of the stations will monitor for radioxenon. The airborne radionuclide monitoring is an important verification technology both for the detection of a radionuclide release and in the determination of whether the release event originates from a nuclear explosion as opposed to an industrial use of nuclear materials. Nuclear power plants and many medical isotope production facilities release radioxenon into the atmosphere. Low levels of a few particulate isotopes, such as iodine, may also be released. Detections of multiple isotopes are useful for screening the radionuclide samples for relevance to the Treaty. This paper examines the anticipated joint detections in the IMS of noble gas and particulate isotopes from underground nuclear explosions where breaches in the underground containment vents from low levels to up to 1% of the radionuclide inventory of the resulting fission products to the atmosphere. Detection probabilities are based on 844 simulated release events spaced out at 17 release locations and one year in time. Six different release (venting) scenarios, including two fractionated scenarios, were analyzed. When ranked by detection probability, 11 particulate isotopes and one noble gas isotope ( 133 Xe) appear in the top 20 isotopes for all six release scenarios. Using the 11 particulate isotopes and the one noble gas isotope, the IMS has nearly the same detection probability as when 45 particulate and 4 noble gas isotopes are used. Thus, a limited list of relevant radionuclides may be sufficient for treaty verification purposes. The probability that at least one particulate and at least one radioxenon isotope would be detected in the IMS from the release events ranged from 0.15 to 0.86 depending on the release scenario.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Curating a comprehensive set of enzymatic reaction rules for efficient novel biosynthetic pathway design

Enzyme substrate promiscuity has significant implications for metabolic engineering. The ability to predict the space of possible enzymatic side reactions is crucial for elucidating underground metabolic networks in microorganisms, as well as harnessing novel biosynthetic capabilities of enzymes to produce desired chemicals. Reaction rule-based cheminformatics platforms have been implemented to computationally enumerate possible promiscuous reactions, relying on existing knowledge of enzymatic transformations to inform novel reactions. However, past versions of curated reaction rules have been limited by a lack of comprehensiveness in representing all possible transformations, as well as the need to prune rules to enhance computational efficiency in pathway expansion. To this end, we curated a set of 1224 most generalized reaction rules, automatically abstracted from atom-mapped MetaCyc reactions and verified to uniquely cover all common enzymatic transformations. Additionally, we developed a framework to systematically identify and correct redundancies and errors in the curation process, resulting in a minimal, yet comprehensive, rule set. These reaction rules were capable of reproducing more than 85% of all reactions in the KEGG and BRENDA databases, for which a large fraction of reactions is not present in MetaCyc. Our rules exceed all previously published rule sets for which reproduction was possible in this coverage analysis, which allows for the exploration of a larger space of known enzymatic transformations. By leveraging the entire knowledge of possible metabolic reactions through generalized enzymatic reaction rules, we are able to better utilize underground metabolic pathways and accelerate novel biosynthetic pathway design to enable bioproduction towards a wider range of new molecules.

59 BASIC BIOLOGICAL SCIENCES↗