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Instrumentation Working Group Summary

The Instrumentation Working Group compiled a summary of measurement techniques applicable to gas turbine engine aerosol precursors and particulates. An assessment was made of the limits, accuracy, applicability, and technology readiness of the various techniques. Despite advances made in emissions characterization of aircraft engines, uncertainties still exist in the mechanisms by which aerosols and particulates are produced in the near-field engine exhaust. To adequately assess current understanding of the formation of sulfuric acid aerosols in the exhaust plumes of gas turbine engines, measurements are required to determine the degree and importance of sulfur oxidation in the turbine and at the engine exit. Ideally, concentrations of all sulfur species would be acquired, with emphasis on SO2 and SO3. Numerous options exist for extractive and non-extractive measurement of SO2 at the engine exit, most of which are well developed. SO2 measurements should be performed first to place an upper bound on the percentage of SO2 oxidation. If extractive and non-extractive techniques indicate that a large amount of the fuel sulfur is not detected as SO2, then efforts are needed to improve techniques for SO3 measurements. Additional work will be required to account for the fuel sulfur in the engine exhaust. Chemical Ionization Mass Spectrometry (CI-MS) measurements need to be pursued, although a careful assessment needs to be made of the sampling line impact on the extracted sample composition. Efforts should also be placed on implementing non-intrusive techniques and extending their capabilities by maximizing exhaust coverage for line-of-sight measurements, as well as development of 2-D techniques, where feasible. Recommendations were made to continue engine exit and combustor measurements of particulates. Particulate measurements should include particle size distribution, mass fraction, hydration properties, and volatile fraction. However, methods to ensure that unaltered samples are obtained need to be developed. Particulate speciation was also assigned a high priority for quantifying the fractions of carbon soot, PAH, refractory materials, metals, sulfates, and nitrates. High priority was also placed on performing a comparison of particle sizing instruments. Concern was expressed by the workshop attendees who routinely make particulate measurements about the variation in number density measured during in-flight tests by different instruments. In some cases, measurements performed by different groups of researchers during the same flight tests showed an order of magnitude variation. Second priority was assigned to measuring concentrations of odd hydrogen and oxidizing species. Since OH, HO2, H2O2, and O are extremely reactive, non-extractive measurements are recommended. A combination of absorption and fluorescence is anticipated to be effective for OH measurements in the combustor and at the engine exit. Extractive measurements of HO2 have been made in the stratosphere, where the ambient level of OH is relatively low. Use of techniques that convert HO2 to OH for combustor and engine exit measurements needs to be evaluated, since the ratio of HO2/OH may be 1% or less at both the combustor and engine exit. CI-MS might be a viable option for H2O2, subject to sampling line conversion issues. However, H2O2 is a low priority oxidizing species in the combustor and at the engine exit. Two candidates for atomic oxygen measurements are Resonance Enhanced Multi-Photon Ionization (REMPI) and Laser-Induced Fluorescence (LIF). Particulate measurement by simultaneous extractive and non-extractive techniques was given equal priority to the oxidizer measurements. Concern was expressed over the ability of typical ground test sampling lines to deliver an unaltered sample to a remotely located instrument. It was suggested that the sampling probe and line losses be checked out by attempting measurements using an optical or non-extractive technique immediately upstream of the sampling probe. This is a possible application for Laser Induced Incandescence (LII) as a check on the volume fraction of soot. Optical measurements of size distribution are not well developed for ultrafine particles less than about 20 nm in diameter, so a non-extractive technique for particulate size distribution cannot be recommended without further development. Carbon dioxide measurements need to be made to complement other extractive measurement techniques. CO2 measurements enable conversion of other species concentrations to emission indices. Carbon monoxide, which acts as a sink for oxidizing species, should be measured using non-extractive techniques. CO can be rapidly converted to CO2 in extractive probes, and a comparison between extractive and non-extractive measurements should be performed. Development of non-extractive techniques would help to assess the degree of CO conversion, and might be needed to improve the concentration measurement accuracy. Measurements of NO(x) will continue to be critical due to the role of NO and NO2 in atmospheric chemistry, and their influence on atmospheric ozone. Time-resolved measurements of temperature, velocity, and species concentrations were included on the list of desired measurement. Thermocouples are typically adequate for engine exit measurements. PIV and LDV are well established for obtaining velocity profiles. The techniques are listed in the accompanying table; are divided into extractive and non-extractive techniques. Efforts were made to include a measurement uncertainty for each technique. An assessment of the technology readiness was included.

Zaller, Michelle↗

Advances in Scientific Balloon Thermal Modeling

The National Aeronautics and Space Administration's Balloon Program office has long acknowledged that the accurate modeling of balloon performance and flight prediction is dependant on how well the balloon is thermally modeled. This ongoing effort is focused on developing accurate balloon thermal models that can be used to quickly predict balloon temperatures and balloon performance. The ability to model parametric changes is also a driver for this effort. This paper will present the most recent advances made in this area. This research effort continues to utilize the "Thrmal Desktop" addition to AUTO CAD for the modeling. Recent advances have been made by using this analytical tool. A number of analyses have been completed to test the applicability of this tool to the problem with very positive results. Progressively detailed models have been developed to explore the capabilities of the tool as well as to provide guidance in model formulation. A number of parametric studies have been completed. These studies have varied the shape of the structure, material properties, environmental inputs, and model geometry. These studies have concentrated on spherical "proxy models" for the initial development stages and then to transition to the natural shaped zero pressure and super pressure balloons. An assessment of required model resolution has also been determined. Model solutions have been cross checked with known solutions via hand calculations. The comparison of these cases will also be presented. One goal is to develop analysis guidelines and an approach for modeling balloons for both simple first order estimates and detailed full models. This papa presents the step by step advances made as part of this effort, capabilities, limitations, and the lessons learned. Also presented are the plans for further thermal modeling work.

Bohaboj, T.↗

Low-Temperature Plasma-Based Metrology of Lithium-Ion Battery Electrode Materials (CRADA Final Report)

As part of the Cyclotron Road program, SirenOpt Inc. evaluated its low-temperature plasma-based metrology sensor prototype for measuring multiple critical properties of lithium-ion battery electrode materials in parallel and in real-time. Cost-effective, minimal-waste manufacturing of high-performance battery electrode materials will be vital for achieving society’s net-zero carbon emission goals. Because existing electrode metrology sensors cannot operate within most sections of manufacturing lines, manufacturers often complete hundreds of processing steps before they can test their products and detect problems. When manufacturers perform these offline tests, they typically only test a small portion of the manufactured products. Current electrode manufacturing thus often yields many low-quality products, or off-spec products that must be thrown away all together. For example, at least 6% of the total lithium-ion battery manufacturing cost (i.e., over $250 million/year for the average gigafactory) is devoted to processing defective electrodes that are not scrapped until performance tests are failed during late-stage quality control checks. Electrode variability also leads manufacturers to build extra cells into battery packs to reduce the risk of poor performance. For example, many electric vehicle (EV) manufacturers include up to 10% more cells than needed, which substantially increases the cost and weight of the final EV product. The SirenOpt sensor can potentially enable early detection of poorly manufactured electrodes and allow them to be removed earlier from manufacturing lines, which can save battery manufacturers (hundreds of) millions of dollars per year. The sensor can further be used to improve product quality by accelerating R&D and process optimization, improving quality control, and enabling real-time process control. Overall, a real-time, in-situ metrology strategy can create unprecedented opportunities for implementation of smart manufacturing practices and advanced quality and process control solutions to realize higher battery electrode throughput and performance.

25 ENERGY STORAGE↗

The Gravity Probe B `Niobium bird' experiment: Verifying the data reduction scheme for estimating the relativistic precession of Earth-orbiting gyroscopes

Gravity Probe B (GP-B) is a relatively gyroscope experiment begun at Stanford University in 1960 and supported by NASA since 1963. This experiment will check, for the first time, the relativistic precession of an Earth-orbiting gyroscope that was predicted by Einstein's General Theory of Relativity, to an accuracy of 1 milliarcsecond per year or better. A drag-free satellite will carry four gyroscopes in a polar orbit to observe their relativistic precession. The primary sensor for measuring the direction of gyroscope spin axis is the SQUID (superconducting quantum interference device) magnetometer. The data reduction scheme designed for the GP-B program processes the signal from the SQUID magnetometer and estimates the relativistic precession rates. We formulated the data reduction scheme and designed the Niobium bird experiment to verify the performance of the data reduction scheme experimentally with an actual SQUID magnetometer within the test loop. This paper reports the results from the first phase of the Niobium bird experiment, which used a commercially available SQUID magnetometer as its primary sensor, and adresses the issues they raised. The first phase resulted in a large, temperature-dependent bias drift in the insensitive design and a temperature regulation scheme.

Uemaatsu, Hirohiko↗

On the Observed Changes in Upper Stratospheric and Mesospheric Temperatures from UARS HALOE

Temperature versus pressure or T(p) time series from the Halogen Occultation Experiment (HALOE) on the Upper Atmosphere Research Satellite (UARS) have been extended and re-analyzed for the period of 1991-2005 and for the upper stratosphere and mesosphere in 10-degree wide latitude zones from 60S to 60N. Even though sampling from a solar occultation experiment is somewhat limited, it is shown to be quite adequate for developing both the seasonal and longer-term variations in T(p). Multiple linear regression (MLR) techniques were used in the re-analyses for the seasonal and the significant interannual, solar cycle (SC-like or decadal-scale), and linear trend terms. A simple SC-like term of 11-yr period was fitted to the time series residuals after accounting for the seasonal and interannual terms. Highly significant SC-like responses were found for both the upper mesosphere and the upper stratosphere. The phases of these SC-like terms were checked for their continuity with latitude and pressure-altitude, and in almost all cases they are directly in-phase with that of standard proxies for the solar flux variations. The analyzed, max minus min, responses at low latitudes are of order 1 K, while at middle latitudes they are as large as 3 K in the upper mesosphere. Highly significant, linear cooling trends were found at middle latitudes of the middle to upper mesosphere (about -2 K/decade), at tropical latitudes of the middle mesosphere (about -1 K/decade), and at 2 hPa (or order -1 K/decade).

Remsberg, Ellis E.↗

Engineering Design Unit Primary Mirror Segment

The James Webb Space Telescope Primary Mirror Engineering Design Unit (EDU) recently demonstrated the final manufacturing process at L-3-SSG/Tinsley in Richmond, California. Shown in the picture below, the EDU is a prototype 1.4 meter diameter Beryllium mirror that is identical to the 18 flight mirror segments and is used to check out all mirror manufacturing processes prior to the actual flight mirror processing. This recent result gives confidence that all manufacturing processes are in place to figure the 18 flight mirrors. Lessons learned from the EDU have been applied to the flight mirrors improving the performance and processing time and all 18 flight mirrors are well along in their processing at L3-SSG/Tinsley. As a result of completing the final manufacturing demonstration, the EDU mirror was sent to Ball Aerospace in Boulder, Colorado where it is now undergoing integration with the hexapod mount assembly and optical testing checkout. After integration to mount assemblies, flight mirrors will be sent for cryogenic (50 degrees Kelvin) optical testing where the cryogenic distortions will be measured. After cryogenic testing, mirrors will eventually be returned to Tinsley for final cryogenic polishing. During final cryogenic polishing, the inverse of the measured cryogenic distortions will be polished into the mirror to assure the mirror works at it's cryogenic operating temperature. Once cryogenic polishing is completed to final specifications, the mirror will be coated and sent for final cryogenic testing.

Alongi, Chris↗

GHRS Observations of Cool, Low-Gravity Stars: The Outer Atmosphere and Wind of the Nearby K Supergiant Lambda Velorum - 5

UV spectra of lambda Velorum taken with the Goddard High Resolution Spectrograph (GHRS) on the Hubble Space Telescope are used to probe the structure of the outer atmospheric layers and wind and to estimate the mass-loss rate from this K5 lb-II supergiant. VLA radio observations at lambda = 3.6 cm are used to obtain an independent check on the wind velocity and mass-loss rate inferred from the UV observations, Parameters of the chromospheric structure are estimated from measurements of UV line widths, positions, and fluxes and from the UV continuum flux distribution. The ratios of optically thin C II] emission lines indicate a mean chromospheric electron density of log N(sub e) approximately equal 8.9 +/- 0.2 /cc. The profiles of these lines indicate a chromospheric turbulence (v(sub 0) approximately equal 25-36 km/s), which greatly exceeds that seen in either the photosphere or wind. The centroids of optically thin emission lines of Fe II and of the emission wings of self-reversed Fe II lines indicate that they are formed in plasma approximately at rest with respect to the photosphere of the star. This suggests that the acceleration of the wind occurs above the chromospheric regions in which these emission line photons are created. The UV continuum detected by the GHRS clearly traces the mean flux-formation temperature as it increases with height in the chromosphere from a well-defined temperature minimum of 3200 K up to about 4600 K. Emission seen in lines of C III] and Si III] provides evidence of material at higher than chromospheric temperatures in the outer atmosphere of this noncoronal star. The photon-scattering wind produces self-reversals in the strong chromospheric emission lines, which allow us to probe the velocity field of the wind. The velocities to which these self-absorptions extend increase with intrinsic line strength, and thus height in the wind, and therefore directly map the wind acceleration. The width and shape of these self-absorptions reflect a wind turbulence of approximately equal 9-21 km/s. We further characterize the wind by comparing the observations with synthetic profiles generated with the Lamers et al. Sobolev with Exact Integration (SEI) radiative transfer code, assuming simple models of the outer atmospheric structure. These comparisons indicate that the wind in 1994 can be described by a model with a wind acceleration parameter beta approximately 0.9, a terminal velocity of 29-33 km/s, and a mass-loss rate approximately 3 x 10(exp -9) solar M/yr. Modeling of the 3.6 cm radio flux observed in 1997 suggests a more slowly accelerating wind (higher beta) and/or a higher mass-loss rate than inferred from the UV line profiles. These differences may be due to temporal variations in the wind or from limitations in one or both of the models. The discrepancy is currently under investigation.

Carpenter, Kenneth G.↗

Leak Mitigation in Mechanically Pumped Fluid Loops for Long Duration Space Missions

Mechanically pumped fluid loops (MPFLs) are increasingly considered for spacecraft thermal control. A concern for long duration space missions is the leak of fluid leading to performance degradation or potential loop failure. An understanding of leak rate through analysis, as well as destructive and non-destructive testing, provides a verifiable means to quantify leak rates. The system can be appropriately designed to maintain safe operating pressures and temperatures throughout the mission. Two MPFLs on the Mars Science Laboratory Spacecraft, launched November 26, 2011, maintain the temperature of sensitive electronics and science instruments within a -40 deg C to 50 deg C range during launch, cruise, and Mars surface operations. With over 100 meters of complex tubing, fittings, joints, flex lines, and pumps, the system must maintain a minimum pressure through all phases of the mission to provide appropriate performance. This paper describes the process of design, qualification, test, verification, and validation of the components and assemblies employed to minimize risks associated with excessive fluid leaks from pumped fluid loop systems.

thermal controls↗

Projections of Declining Surface-Water Availability for the Southwestern United States

16 of the CMIP5 models had all the data needed for this work for at least one simulation that was continuous from 1950 to 2040. Details of the models analyzed here are provided in Table S1. The model data analyzed here are available at http://strega.ldeo.columbia.edu:81/expert/home/.naomi/.AR5/.v2/.historical:rcp85/.mmm16/ a. Assessing the climatology of the models Despite increases in horizontal resolution of many models compared to their CMIP3 counterparts none of these models can adequately resolve the topography of the south west United States, such as the Sierra Nevada and Rocky Mountains and the associated orographic precipitation. This requires that caution be used when interpreting the results presented here. To assess the ability of the models to simulate the current hydroclimate, in Figure S1 we show the observed (from the Global Precipitation Climatology Centre gridded rain gauge data, (1)) monthly climatology of precipitation and the same for all the models and the multimodel mean for the California-Nevada, Colorado headwaters and Texas regions. The GPCC data uses rain gauges only and interpolates to regular grids of which we used the 1◦ by 1◦ one. Details of the data set can be found in (2). While the models apparently overestimate precipitation in California and Nevada the seasonal cycle with wet winters and dry summers is very well represented. It is also possible that the rain gauge observations are biased low by inadequately sampling the higher mountain regions. How ever the models might also be expected to underestimate orographic precipitation due to inadequate horizontal resolution. The 25 models are also too wet in the Colorado headwaters region but correctly represent the quite even distribution though the year. The bimodal distribution of precipitation in Texas, with peaks in May and September, and the absolute amounts, are well modeled but with the September peak too weak. The positive precipitation bias translates into a positive runoff bias for the Colorado headwaters as also shown in Figure S1. Here the observed runoff values are taken from simulations of the Variable Infiltration Capacity (VIC) land surface-hydrology model (3) forced by observed meteorology (5) that were conducted as part of the North American Land Data Assimilation System project phase 2 ( (NLDAS-2), http://www.emc.ncep.noaa.gov/mmb/nldas/. Runoff for California-Nevada is better simulated but there is a positive bias over Texas despite no strong precipitation bias. To check whether regional climate models better simulate P and runoff in these regions we analyzed the historical simulation with the Regional Climate Model version 3 driven by the National Centers for Environmental Prediction-Department of Energy Reanalysis 2 available from the North American Regional Climate Change Assessment Program (http://www.narccap.ucar.edu). This model configuration retained these biases in P and runoff although they were reduced in amplitude. Given these varying biases we plot P and P − E changes in actual values but apply the simplest bias correction possible to the runoff and soil moisture values and show the modeled changes in terms of percentages of the 20th Century model climatologies. A thorough assessment of the simulation of North American climate in CMIP5 models is conducted in Sheffield at al. (North American Climate in CMIP5 Experiments. Part I: Evaluation of 20th Century Continental and Regional Climatology, manuscript submit ted to J. Climate, available at http://www.climate.noaa.gov/index.jsp?pg=./cpo pa/ mapp/cmip5 publications.html). Sheffield et al. analyze the climatology of precipitation, surface air temperature, low level winds, moisture fluxes, runoff etc. and conclude that the main features of the hydrological cycle, including characteristics of the atmospheric moisture balance and its seasonality, are captured in the CMP5 models subject to biases in total precipitation amounts. We chose to use all available models instead of selecting some and rejecting others based on an assessment of model realism. This is in accord with the suggestions of Mote et al. for CMIP3 (4) but future work needs to revisit this matter for the case of the CMIP5 ensemble.

Seager, Richard↗

Exploring Alternate Parameterizations for Snowfall with Validation from Satellite and Terrestrial Radars

Increases in computational resources have allowed operational forecast centers to pursue experimental, high resolution simulations that resolve the microphysical characteristics of clouds and precipitation. These experiments are motivated by a desire to improve the representation of weather and climate, but will also benefit current and future satellite campaigns, which often use forecast model output to guide the retrieval process. Aircraft, surface and radar data from the Canadian CloudSat/CALIPSO Validation Project are used to check the validity of size distribution and density characteristics for snowfall simulated by the NASA Goddard six-class, single-moment bulk water microphysics scheme, currently available within the Weather Research and Forecast (WRF) Model. Widespread snowfall developed across the region on January 22, 2007, forced by the passing of a midlatitude cyclone, and was observed by the dual-polarimetric, C-band radar King City, Ontario, as well as the NASA 94 GHz CloudSat Cloud Profiling Radar. Combined, these data sets provide key metrics for validating model output: estimates of size distribution parameters fit to the inverse-exponential equations prescribed within the model, bulk density and crystal habit characteristics sampled by the aircraft, and representation of size characteristics as inferred by the radar reflectivity at C- and W-band. Specified constants for distribution intercept and density differ significantly from observations throughout much of the cloud depth. Alternate parameterizations are explored, using column-integrated values of vapor excess to avoid problems encountered with temperature-based parameterizations in an environment where inversions and isothermal layers are present. Simulation of CloudSat reflectivity is performed by adopting the discrete-dipole parameterizations and databases provided in literature, and demonstrate an improved capability in simulating radar reflectivity at W-band versus Mie scattering assumptions.

Molthan, Andrew L.↗

Exploring Alternative Parameterizations for Snowfall with Validation from Satellite and Terrestrial Radars

Increases in computational resources have allowed operational forecast centers to pursue experimental, high resolution simulations that resolve the microphysical characteristics of clouds and precipitation. These experiments are motivated by a desire to improve the representation of weather and climate, but will also benefit current and future satellite campaigns, which often use forecast model output to guide the retrieval process. The combination of reliable cloud microphysics and radar reflectivity may constrain radiative transfer models used in satellite simulators during future missions, including EarthCARE and the NASA Global Precipitation Measurement. Aircraft, surface and radar data from the Canadian CloudSat/CALIPSO Validation Project are used to check the validity of size distribution and density characteristics for snowfall simulated by the NASA Goddard six-class, single moment bulk water microphysics scheme, currently available within the Weather Research and Forecast (WRF) Model. Widespread snowfall developed across the region on January 22, 2007, forced by the passing of a mid latitude cyclone, and was observed by the dual-polarimetric, C-band radar King City, Ontario, as well as the NASA 94 GHz CloudSat Cloud Profiling Radar. Combined, these data sets provide key metrics for validating model output: estimates of size distribution parameters fit to the inverse-exponential equations prescribed within the model, bulk density and crystal habit characteristics sampled by the aircraft, and representation of size characteristics as inferred by the radar reflectivity at C- and W-band. Specified constants for distribution intercept and density differ significantly from observations throughout much of the cloud depth. Alternate parameterizations are explored, using column-integrated values of vapor excess to avoid problems encountered with temperature-based parameterizations in an environment where inversions and isothermal layers are present. Simulation of CloudSat reflectivity is performed by adopting the discrete-dipole parameterizations and databases provided in literature, and demonstrate an improved capability in simulating radar reflectivity at W-band versus Mie scattering assumptions.

Molthan, Andrew L.↗

Resolution of the buoyancy in the 8-foot high temperature tunnel combustor

Currently, the 8-Foot High Temperature Tunnel (8-Ft. HTT) combustor produces a good profile at only one point (2000 psia and 3650 R with oxygen enrichment). Air is enriched with oxygen (liquid) so that the combustor product gas will contain the volumetric amount of oxygen normally found in air. The oxygen enriched air has a large fraction that is not reacted and flows through the outer periphery of the fuel injector. This ring of cold air in addition to the relatively cold walls of the combustor set up buoyancy forces that produce a segregation of relatively cool gases at the bottom of the combustor exit. The basic problem is to produce a test gas that has uniform properties at all combustor conditions. The combustor temperature may be as high as 3700 R or as low as 2000 R. Combustor pressures can be as high as 3500 psia (no oxygen enrichment) and as low as 600 psia. The segregation is most severe with oxygen enriched air, since its temperature is lower and its density is high. The combustor is lined with nickel 201 and can be operated at about 1600 R maximum. A global mixing process is desired that produces an acceptable profile of temperature, species, and velocity at the exit of the combustor. The ultimate goal is a temperature profile with about 100 R variance and about 2 percent variance in oxygen. The exit total temperature must not be lowered significantly by the mixing apparatus or mechanisms employed. If immersed bodies are used, they must also be kept very hot. All combustor wall modifications must be able to survive the heat and structural conditions of the varied operating conditions. Our approach to resolving this issue is being conducted in three stages: (1) Consider mixing exclusively, (2) Resolve the heat transfer concerns resulting from the chosen mixing strategy, and (3) Solve the material and structural problems resulting from stages (1) and (2). Since the 8-Ft. HTT is unavailable for experimentation, the study is conducted exclusively with computational fluid dynamic (CPD) codes (Fluent/Uns and Rampant 3.1) using unstructured grid through body fitted coordinates. Both CFD codes are general purpose Navier-Stokes solution packages that can solve integral conservation equations for conservation of mass, momentum and energy. The governing equations are discretized using a control-volume finite-element method on unstructured triangular 2-D grids. In the interest of time, a 3-D tetrahedral grid was used to check the 2-D results on one mixing strategy and the 2-D results were confirmed. Preliminary results indicate that excellent mixing can be achieved with a body placed in the center of the flowing hot fluid with a minor modification to the combustor wall similar to a model positioned in the test section of a wind tunnel. The concept here, is to create longitudinal vortices strong enough to bring both fluids into intimate contact with each other near the wall where the cold fluid resides. However, there may be a trade-off in the choice of mixing strategy, heat transfer and structural requirements. Currently, we are examining the more promising geometries for heat transfer concerns and developing strategies for the material of construction of the center body.

Loney, Norman W.↗

Effect of Power Plant Capacity on the CAPEX, OPEX, and LCOC of the CO2 Capture Process in Pre-Combustion Applications - Abstract

Aspen Plus v8.8 was used to simulate the pre-combustion CO2 capture process from a typical fuel gas stream at different power plant capacities ranging from 54.3 to 543 MW. Polyethylene glycol polydimethyl siloxane (PEGPDMS-1) was used as a physical solvent to capture CO2 in a countercurrent packed-bed absorber containing a structured packing (Mellapak 250Y). The process pressure was 51.4 bar and the solvent temperature was varied from 10 to 40 <sup>o</sup>C. The internal diameter of the absorber ranged from 1.9 to 7 m and the packing height from 13.9 to 45.5 m. The physico-chemical properties were obtained and modeled using the Perturbed Chain-Statistical Associating Fluid Theory (PC-SAFT) Equation-of-State (EOS).<p> Four process constraints were imposed in Aspen Plus: (1) no flooding in the absorber, (2) the absorber height to diameter ratio (H/D) is greater than or equal 6, (3) at least 90 mol% of the CO2 capture from the fuel gas stream, and (4) the CO2 stream destined to sequestration sites should contain less than 600 ppm water concentration and less than or equal 0.5 mol% of fuel gases (H2, CO, CH4). The plant lifetime was assumed to be 30 years with an annual discount rate of 10% and an annual maintenance cost of 4% of the total capital expenses.</p><p> Seven power plants with different capacities were used and for each plant, the corresponding CO2 capture process was simulated. The absorber flooding was checked using the generalized pressure drop correlation (GPDC) by Leva [1] and the capital expenditure (CAPEX), operating expenditure (OPEX), and levelized costs per ton of CO2 captured (LCOC) were calculated [2-5]. Normalized by the largest power plant capacity (543 MW) used in the simulation, the results indicated that the capital and operating expenditures increased, however, the LCOC decreased with increasing plant capacity. This behavior was due to the increased annual tonnage of the CO2 captured with plant capacity as shown in Figure 1. The calculated CAPEX, OPEX, LCOC and the tonnage of CO2 captured for the 543 MW power plant were about 52 MM$, 22 MM$/year, 7.46 $/ton and 4 MM ton/year.</p>

Ashkanani, Husain↗

Thermal Hydraulic Experimental Test Article - Report of THETA Commissioning for METL Testing

The Thermal Hydraulic Experimental Test Article (THETA) is a facility that will be used to develop sodium components and instrumentation as well as acquire experimental data for validation of reactor thermal hydraulic and safety analysis codes. The facility will simulate nominal conditions as well as protected/unprotected loss of flow accidents in a sodium-cooled fast reactor (SFR). High fidelity distributed temperature profiles of the developed flow field will be acquired with Rayleigh backscatter based optical fiber temperature sensors. The facility is being designed in partnership with systems code experts to tailor the experiment to ensure the most relevant and highest quality data for code validation. THETA is comprised of a traditional primary and secondary system. The primary system is submerged in the pool of sodium and consists of a pump, electrically heated core, intermediate heat exchanger, and connected piping and thermal barriers (redan). The secondary system, located outside of the sodium pool, consists of a pump, sodium to air heat exchanger, and connected piping and valves. Figure 1 illustrates the main components of the primary system. THETA has been installed in the Mechanisms Engineering Test Loop (METL) with the primary system in the 28 inch Test Vessel #4, Figure 2 and Figure 3. Since the FY20 THETA status report, [1], further water shakedown testing was performed, some final welding modifications were performed, all system components were sanitized, dry assembled, and commissioned before installing into METL test vessel #4. The THETA submersible electromagnetic flowmeter was welded closed to hermetically seal internal components from sodium followed by a helium leak check for the final time

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Search for Organic Nanoglobules in Carbonaceous Chondrites Using Microtomography

Primitive solar materials have various organic matters. In recent years, novel organic materials called organic nanoglobules of a few hundred micrometers in typical size were discovered in carbonaceous chondrites, IDPs, and comet 81P/Wild 2. The organic globules are spherical shape and in many cases with hollow structures. Composition of the globules are mainly aromatic carbon. The isotopic anomalies of SD and 6N 15 observed in the globules indicate that they were formed from photochemical reaction to ice particles at very low temperature environment, such as molecular clouds or outer protosolar disk. Aqueous alteration of organic matters and the gamma-ray irradiation to PAH are also suggested as alternative possible formation processes. If the globules are made from organic ice particles, the hollow regions of the globules are suggested to be once filled with volatile H20-rich organic ices, while if they were formed by aqueous alteration, the hollow regions should be filled with a fluid which caused the aqueous alteration. However, fluids in the globules have not been detected so far in the previous studies. If fluids were originally preserved in the hollows, they might be lost during destructive processes of sample separation or preparation for TEM observation. X-ray computed tomography (CT) is a nondestructive method which can determine 3-D internal structures of objects. SR (synchrotron radiation)-based imaging microtomography can give submicron spatial resolution [8] and was applied to micro textures in extraterrestrial materials, such as cometary grains captured by the Stardust mission [9]. If organic globules are observed non-destructively in carbonaceous chondrites by tomography, we can check the presence of fluids in the hollows. If fluids are preserved, we may analyze chemical and isotopic compositions of the fluids. The purpose of this study is to observe organic nanoglobules using imaging tomography for future analysis.

Matsumoto, T.↗

DECOVALEX-2023: Task D Final Report

Task D of DECOVALEX-2023 is focused on the simulation of the coupled thermal hydraulic-mechanical (THM) behaviour in the full-scale engineered barrier system (EBS). The Horonobe EBS experiment is the demonstration of the full-scale EBS in the underground research laboratory (URL) (performed by JAEA in the Horonobe URL in Japan). Task D consisted of the three steps, a preliminary step (Step 0), simulation of the laboratory tests (Step 1) and simulation of the in-situ full-scale EBS experiment (Step 2). Since the Horonobe EBS experiment demonstrates the vertical emplacement option of the EBS, the experiment gallery is also backfilled with the backfill material. Therefore, interaction between the EBS and the backfill material can also be demonstrated, such as deformation (change of density) of the buffer material. The underground water in the Horonobe URL is saline. This fact adds chemical processes to THM behaviour. For example, mechanical properties (such as swelling pressure of the buffer material and backfill material) and hydraulic properties (such as permeability of the buffer material and backfill material) change depending on the water chemistry. Task D was therefore a challenging Task focused on not only the relatively simple THM behaviour but also complex THM behaviour including chemical processes. Six research teams (BGR, CAS, JAEA, KAERI, SNL and Taipower) participated the Task D. BGR, CAS, JAEA, KAERI and Taipower research teams selected a THM approach, while the SNL research team selected a TH approach. Step 1 involved the simulation of laboratory test results and was important to check the numerical codes developed by the research teams. Step 1 was divided into four sub steps. The simulation results through the Step 1 identified the parameters for simulation of the Step 2. Basic parameters of the materials (buffer material, backfill material, rock mass, concrete, sand) were provided by JAEA. Special parameters which research team needed were identified by back analysis of Step 1. Most notably the mechanical behaviour of swelling and displacement depended on the applied model (elastic model or elastoplastic model). Parameters such as Young’s modulus were found to need smaller values than characterised in the fundamental laboratory test results (Step 1-1, 1-2) for the elastic model. Although laboratory experiments are usually simple, test results contained some error. For example, if the saturation level is 100 % or higher, it should be considered an error. This situation was presented in the Step 1-3. A possible reason is that the buffer material is a mixture of bentonite and silica sand. When a specimen is cut to measure volume or weight, sand grains will affect the measurement data. In Step 2, boundary conditions such as temperature on the surface of the simulated overpack, heater power of the electrical heaters installed in the simulated overpack, injection pressure and inflow rate of the test water, were applied. The outer boundary conditions can be selected using measured data (injection pressure and inflow rate of the test water that is controlled by the injection systems installed in the sand layer around the buffer material and in the boundary between backfill material and concrete support). Since such measured data has some noise, research teams developed their own simplified boundary conditions. Inner boundary conditions can be selected using measured data as heater power and temperature on the surface of the simulated overpack. These data also contain some noise, so research teams developed their own simplified developed boundary conditions. Task D validated various approaches thorough the simulation of the in-situ full scale EBS system including backfill of the gallery: variations in the coupling processes (THM or THC), analysis codes, and boundary conditions. Temperature distribution in the buffer material was simulated well by all research teams. This means thermal behaviour is not sensitive to the simulation approaches. Although the water content distribution on the outside of the buffer material was well simulated by all research teams, the simulation results differ from the measured values inside the buffer material (at the centre and inside, near the simulated overpack). The buffer material is made from tap water, but in the in-situ experiment, saline groundwater infiltrates the buffer material. Therefore, the selection of the hydraulic parameters of the buffer material greatly affects the simulation results of the re saturation behaviour of the buffer material. In the Horonobe EBS experiment, measured values suitable for validating the simulation results were not obtained near the simulated overpack. When simulating the pressure and deformation of the buffer material, the measurement data is easily affected by the installation conditions of the measurement sensors, so verifying the measurement data itself remains an issue. Mechanical simulation results differ depending on whether they are considered as elastic or elastoplastic phenomena. The accuracy of measured in-situ data can be assessed by detailed analysis comparing sampling specimen analysis and measured data. The Horonobe EBS experiment is scheduled to be dismantled in the future (FY2026 and 2027). This detailed dismantling investigation will finally confirm the measured data.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

NASA Tech Briefs, June 2014

Topics include: Real-Time Minimization of Tracking Error for Aircraft Systems; Detecting an Extreme Minority Class in Hyperspectral Data Using Machine Learning; KSC Spaceport Weather Data Archive; Visualizing Acquisition, Processing, and Network Statistics Through Database Queries; Simulating Data Flow via Multiple Secure Connections; Systems and Services for Near-Real-Time Web Access to NPP Data; CCSDS Telemetry Decoder VHDL Core; Thermal Response of a High-Power Switch to Short Pulses; Solar Panel and System Design to Reduce Heating and Optimize Corridors for Lower-Risk Planetary Aerobraking; Low-Cost, Very Large Diamond-Turned Metal Mirror; Very-High-Load-Capacity Air Bearing Spindle for Large Diamond Turning Machines; Elevated-Temperature, Highly Emissive Coating for Energy Dissipation of Large Surfaces; Catalyst for Treatment and Control of Post-Combustion Emissions; Thermally Activated Crack Healing Mechanism for Metallic Materials; Subsurface Imaging of Nanocomposites; Self-Healing Glass Sealants for Solid Oxide Fuel Cells and Electrolyzer Cells; Micromachined Thermopile Arrays with Novel Thermo - electric Materials; Low-Cost, High-Performance MMOD Shielding; Head-Mounted Display Latency Measurement Rig; Workspace-Safe Operation of a Force- or Impedance-Controlled Robot; Cryogenic Mixing Pump with No Moving Parts; Seal Design Feature for Redundancy Verification; Dexterous Humanoid Robot; Tethered Vehicle Control and Tracking System; Lunar Organic Waste Reformer; Digital Laser Frequency Stabilization via Cavity Locking Employing Low-Frequency Direct Modulation; Deep UV Discharge Lamps in Capillary Quartz Tubes with Light Output Coupled to an Optical Fiber; Speech Acquisition and Automatic Speech Recognition for Integrated Spacesuit Audio Systems, Version II; Advanced Sensor Technology for Algal Biotechnology; High-Speed Spectral Mapper; "Ascent - Commemorating Shuttle" - A NASA Film and Multimedia Project DVD; High-Pressure, Reduced-Kinetics Mechanism for N-Hexadecane Oxidation; Method of Error Floor Mitigation in Low-Density Parity-Check Codes; X-Ray Flaw Size Parameter for POD Studies; Large Eddy Simulation Composition Equations for Two-Phase Fully Multicomponent Turbulent Flows; Scheduling Targeted and Mapping Observations with State, Resource, and Timing Constraints;

Source record↗

Checking Contamination during Storage of Carbonaceous Chondrites for Micro FTIR Measurements

We examined organic contamination by Fourier transform infrared micro spectroscopic (micro FTIR) measurements of carbonaceous chondrite samples. Carbonaceous chondrites, Tagish Lake (C2), Murchison (CM2) and Moss (CO3), and some mineral powder samples pressed on aluminum plates were measured by micro FTIR before and after storage in several containers with silicone rubber mat. During storage, samples did not touch directly anything except the holding aluminum plates. The carbonaceous chondrites containing hydrous minerals (Tagish Lake and Murchison) pressed on aluminum plates and measured by transmission-reflection micro FTIR measurements were found to be contaminated during storage after only one day, as revealed by an increase of approximately 2965 /cm and approximately 1260 /cm peaks. The Moss meteorite which contains no hydrous minerals, did not show an increase of these peaks, indicating no organic contamination. This difference is probably related to the differing mineralogy and physical properties (including porosity and permeability) of these chondrites. Hydrous minerals such as antigorite, muscovite, montmorillonite and silica gel showed organic contamination by the same infrared measurements, while anhydrous materials such as SiO2 and KBr showed no contamination. These results indicate importance of surface OH groups for the organic contamination. Organic contamination was found on silica gel samples pressed on aluminum plates when they were stored within containers including silicone rubber, silicone grease or adhesive tape. Long path gas cell FTIR measurements for silicone rubber indicated methylsiloxane oligomers were released from the silicone rubber. In-situ heating infrared measurements on the contaminated antigorite and Tagish Lake showed decrease of the 1262 /cm (Si-CH3) and 2963 /cm (CH3) peaks from room temperature to 200-300 C indicating desorption of volatile contaminants. These results indicate that careful preparation and storage are essential for FTIR measurements on precious astromaterial samples such as meteorites, IDPs and samples returned from comets, asteroids and Mars. Every possible contamination source should be evaluated before anything is done to these samples.

Zolensky, Michael E.↗