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At least 451 records · Page 25

Distribution and significance of carbon compounds on the moon.

Exploration of available information concerning carbon on the moon, following review of what is known about carbon on the earth, and consideration of the results of studies of meteorites, which have provided the first direct clues about extraterrestrial carbon. Carbon and carbon isotope composition data taken from Apollo 11 samples are tabulated. Carbon compounds produced by pyrolysis, extracted with benzene-methanol, extracted with water, and freed by acid treatment are discussed. Carbon and carbon compounds in lunar rocks and soils appear to be distributed heterogeneously.

Chang, S.↗

Classification and soil moisture determination of agricultural fields

During the Mac-Europe campaign of 1991 several SAR (Synthetic Aperature Radar) experiments were carried out in the Flevoland test area in the Netherlands. The test site consists of a forested and an agricultural area with more than 15 different crop types. The experiments took place in June and July (mid to late growing season). The area was monitored by the spaceborne C-band VV polarized ERS-1, the Dutch airborne PHARS with similar frequency and polarization and the three-frequency PP-, L-, and C-band) polarimetric AIRSAR system of NASA/JPL. The last system passed over on June 15, 3, 12, and 28. The last two dates coincided with the overpasses of the PHARS and the ERS-1. Comparison of the results showed that backscattering coefficients from the three systems agree quite well. In this paper we present the results of a study of crop type classification (section 2) and soil moisture determination in the agricultural area (section 3). For these studies we used field averaged Stokes matrices extracted from the AIRSAR data (processor version 3.55 or 3.56).

Vandenbroek, A. C.↗

Smap: A Hydrologist Goes Crazy with a New High-Quality Dataset

By providing global measurements of near-surface soil moisture (down to about 5 cm) with unprecedented accuracy, the Soil Moisture Active/Passive (SMAP) satellite mission has opened the door to new and (in my opinion) exciting hydrological science. In this seminar, I present the results of a recent series of analyses performed with SMAP soil moisture data, covering a wide range of topics: (a) the characterization of the dynamics of near-surface soil moisture, with implications for forecasting soil moisture days into the future; (b) the multi-faceted character of the SMAP data, in the sense that different, established analysis approaches can extract information from the data that is largely (and perhaps unexpectedly) complementary; and (c) the interpretation of the data in the context of large-scale water fluxes. This final analysis is particularly exciting to me because it shows that, once the relevant algorithms are calibrated, precipitation and streamflow rates in hydrological basins can be estimated from the SMAP data alone - a reflection of the fact that the near-surface soil is a critical gateway between the atmospheric and subsurface branches of the hydrological cycle.

SMAP↗

Soil organic carbon cycling in response to simulated soil moisture variation under field conditions

The combination of extended dry periods and high intensity rainfall, common in the southeastern US, leads to greater variability in soil moisture and consequently increases uncertainty to microbial processes pertinent to soil carbon (C) mineralization. However, field-based findings on soil moisture sensitivity to soil C cycling are very limited. Therefore, a field experiment was conducted in 2018 and 2019 on a soybean (Glycine max L.) cropland in the southeastern US with three soil moisture treatments: drought (simulated using rainout-shelter from June to October in each year), rainfed (natural precipitation), and irrigated (irrigation and precipitation). Soil respiration was measured weekly from May to November in both years. Soil samples were collected multiple times each year from 0–5, 5–15, and 15–30 cm depths to determine microbial biomass C (MBC), extractable organic C (EOC), hydrolytic enzyme activities, and fungal abundance. The cumulative respiration under drought compared to other treatments was lower by 32% to 33% in 2018 and 38% to 45% in 2019. Increased MBC, EOC, and fungal abundance were observed under drought than other treatments. Specific enzyme activity indicated fewer metabolically active microbes under drought treatment compared to rainfed and irrigated treatments. Also, maintenance of enzyme pool was observed under drought condition. These results provide critical insights on microbial metabolism in response to soil moisture variation and how that influences different pools of soil C under field conditions.

54 ENVIRONMENTAL SCIENCES↗

Coming-of-Age Characterization of Soil Viruses: A User’s Guide to Virus Isolation, Detection within Metagenomes, and Viromics

The study of soil viruses, though not new, has languished relative to the study of marine viruses. This is particularly due to challenges associated with separating virions from harboring soils. Generally, three approaches to analyzing soil viruses have been employed: (1) Isolation, to characterize virus genotypes and phenotypes, the primary method used prior to the start of the 21st century. (2) Metagenomics, which has revealed a vast diversity of viruses while also allowing insights into viral community ecology, although with limitations due to DNA from cellular organisms obscuring viral DNA. (3) Viromics (targeted metagenomics of virus-like-particles), which has provided a more focused development of ‘virus-sequence-to-ecology’ pipelines, a result of separation of presumptive virions from cellular organisms prior to DNA extraction. This separation permits greater sequencing emphasis on virus DNA and thereby more targeted molecular and ecological characterization of viruses. Employing viromics to characterize soil systems presents new challenges, however. Ones that only recently are being addressed. Here we provide a guide to implementing these three approaches to studying environmental viruses, highlighting benefits, difficulties, and potential contamination, all toward fostering greater focus on viruses in the study of soil ecology.

59 BASIC BIOLOGICAL SCIENCES↗

Photovoltaic array loss mechanisms

Loss mechanisms which come into play when solar cell modules are mounted in arrays are identified. Losses can occur either from a reduction in the array electrical performance or with nonoptimal extraction of power from the array. Electrical performance degradation is caused by electrical mismatch, transmission losses from cell surface soiling and steep angle of reflectance, and electrical losses from field wiring resistance and the voltage drop across blocking diodes. The second type of loss, concerned with the operating points of the array, can involve nonoptimal load impedance and limiting the operating envelope of the array to specific ranges of voltage and current. Each of the loss mechanisms are discussed and average energy losses expected from soiling, steep reflectance angles and circuit losses are calculated.

Gonzalez, Charles↗

Detection of microbes in the subsurface

The search for evidence of microbial life in the deep subsurface of Earth has implications for the Mars Rover Sampling Return Missions program. If suitably protected environments can be found on Mars then the instrumentation to detect biomarkers could be used to examine the molecular details. Finding a lipid in Martian soil would represent possibly the simplest test for extant or extinct life. A device that could do a rapid extraction possibly using the supercritical fluid technology under development now with a detection of the carbon content would clearly indicate a sample to be returned.

White, David C.↗

Transformation products of submicron-sized aluminum-substituted magnetite: Color and reductant solubility

Magnetite, when present as fine particles, is soluble in acid ammonium oxalate (pH equals 3). However, the commonly used extractant for free iron oxides (i.e., citrate dithionite-bicarbonate (CDB) is not very effective in dissolving magnetite in soils and geologic materials. Upon oxidation, magnetite transforms to maghemite; at elevated temperatures, maghemite inverts to hematite. This transformation causes a change in color from black to red and may affect the reductant solubility as well. The objectives here were to examine the color and reflectance spectral characteristics of products during the transformation of magnetite to maghemite to hematite and to study the effect of Al-substitution in magnetite on the above process. Reductant solubility of Al-substituted magnetite, maghemite, and hematite was also studied. In summary, the transformation of magnetite to maghemite was accompanied by a change in color from black to red because of the oxidation of Fe2(+) to Fe3(+). The phase change maghemite to hematite had a relatively minor effect on the color and the reflectance spectra.

Golden, D. C.↗

Extracting spectral albedo from NOAA-9 AVHRR multiple view data using an atmospheric correction procedure and an expert system

A 100 km by 200 km area of the Sahel was selected to demonstrate a new method of extracting hemispherical reflectance (albedo) from directional satellite data. Utilizing a stratification of the Gao region of Mali based on soil texture, satellite data for homogeneous areas were selected. These data were employed in a knowledge-based expert system called VEG, which is designed to handle a wide variety of types of input data. The calculated directional reflectance factors at ground level are very similar to ground measurements noted in the literature.

Kimes, D. S.↗

Cryo-EM visualization of viruses from partially irrigated soils

Viruses are numerically the most abundant forms on Earth, and most are present in soil. Even though viruses are highly abundant in soil and critical to rhizosphere function, visualizing the diverse morphotypes within soil has been challenging. The difficulty is primarily due to the heterogenous nature of isolated suspensions that typically contain nanometer to micron scale debris which renders protein crystallography for structural studies unfeasible and hinders cryo-electron microscopy due to ice thickness and contrast issues. Here we employed and compared a simple spin filtration method to cleanup solutions of extracted viruses for direct observation with cryo-electron microscopy. The method employs common physical biochemical separation steps to remove large and small debris which dramatically improves image quality and preservation of structural features to permit visualizing morphotypes not typically seen with conventional negative stain approaches. In addition to tailed and non-tailed polyhedral phages, several under reported or novel morphotypes of soil viruses are directly visualized as a particle library with both 2D and 3D information.

cryo-EM↗

Analysis of Organic Molecules Extracted from Mars Analogues and Influence of Their Mineralogy Using N-Methyl-N-(tert-butyldimethylsilyl)Trifluoroacetamide Derivatization Coupled with Gas Chromatography Mass Spectrometry in Preparation for the Sample Analysis at Mars Derivatization Experiment on the Mars Science Laboratory Mission

The search for complex organic molecules on Mars, including important biomolecules such as amino acids and carboxylic acids will require a chemical extraction and derivatization step to transform these organic compounds into species that are sufficiently volatile to be detected by gas chromatography mass spectrometry (GCMS). We have developed, a one-pot extraction and chemical derivatization protocol using N-methyl-N-(tert-butyldimethylsilyl)trifluoroacetamide (MTBSTFA) and dimethylformamide (DMF) for the Sample Analysis at Mars (SAM) experiment on the Mars Science Laboratory (MSL). The temperature and duration the derivatization reaction, pre-concentration of chemical derivatives, and gas chromatographic separation parameters have been optimized under SAM instrument design constraints. MTBSTFA/DMF extraction and derivatization at 300 C for several minutes of a variety of terrestrial Mars analogue materials facilitated the detection of amino acids and carboxylic acids in a surface soil sample collected from the Atacama Desert and a carbonate-rich stromatolite sample from Svalbard. However, the rapid reaction of MTBSTFA with water in several analogue materials that contained high abundances of hydrated minerals and the possible deactivation of derivatized compounds by iron oxides, as detected by XRD/XRF using the CheMin field unit Terra, proved to be highly problematic for the direct extraction of organics using MTBSTFA, The combination of pyrolysis and two different chemical derivatization methods employed by SAM should enable a wide range of organic compounds to be detected by GCMS if present on Mars,

Stalport, F.↗

The Influence of Mineralogy on Recovering Organic Acids from Mars Analogue Materials Using the One-Pot Derivatization Experiment on the Sample Analysis at Mars(SAM) Instrument Suite

The search for complex organic molecules on Mars, including important biomolecules such as amino acids and carboxylic acids, will require a chemical extraction and a derivatization step to transform these organic compounds into species that are sufficiently volatile to be detected by gas chromatography mass spectrometry (GCMS). We have developed a ''one-pot'' extraction and chemical derivatization protocol using N-methyl-N-(tert-butyldimethylsilyl) trifluoroacetamide (MTBSTFA) and dimethylformamide (DMF) for the Sample Analysis at Mars (SAM) experiment instrument suite on NASA's the Mars Science Laboratory (MSL) mission. The temperature and duration of the derivatization reaction, pre-concentration of chemical derivatives, and gas chromatographic separation parameters have been optimized under SAM instrument design constraints. MTBSTFA/DMF extraction and derivatization at 300 1C for several minutes of a variety of terrestrial Mars analog materials facilitated the detection of amino acids and carboxylic acids in a surface soil sample collected from the Atacama Desert and a carbonate-rich stromatolite sample from Svalbard. However, the rapid reaction of MTBSTFA with water in several analog materials that contained high abundances of hydrated minerals, and the possible deactivation of derivatized compounds by iron oxides, as detected by XRD/XRF using the CheMin field unit Terra, proved to be highly problematic for the direct extraction of organics using MTBSTFA. The combination of pyrolysis and two different wet-chemical derivatization methods employed by SAM should enable a wide range of organic compounds to be detected by GCMS if present on Mars.

MSL↗

A Global Evaluation of IMERG Precipitation Occurrence Using SMAP Detected Soil Moisture Change

A globally consistent ground validation method for remotely sensed precipitation products is crucial for building confidence in these products. This study develops a new methodology to validate the IMERG precipitation products through the use of SMAP soil moisture changes as a proxy for precipitation occurrence. Using a standard 2x2 contingency table method, preliminary results provide confidence in SMAP’s ability to be utilized as a validation tool for IMERG as results are comparable to previous validation studies. However, the method allows for an overestimate of false alarm frequency due to light precipitation events that can evaporate before the subsequent SMAP overpass and changes in overpass-to-overpass SMAP soil moisture that are within the range of SMAP uncertainty. To counter these issues, a 3x3 contingency table is used to reduce noise and extract more signal from the detection method. Through the use of this novel approach, the validation method produces a global mean POD of 0.64 and global mean FAR of 0.40, the first global-scale ground validation skill scores for the IMERG products. Advancing the method to validate precipitation quantity and the development of a real-time validation for the IMERG Early product are the crucial next developments.

Precipitation↗

Combining organic amendments with enhanced rock weathering shifts soil carbon storage in croplands

Enhanced rock weathering (ERW) involves applying crushed silicate minerals to cropland soils to remove carbon dioxide and stabilize the global climate. If practiced widely, ERW has the potential to mitigate climate change and improve soil health and crop productivity. However, most ERW studies emphasize inorganic carbon (IC) chemistry, using model-based estimates and short-term mesocosms. Limited field data exist on how ERW interacts with organic amendments to affect organic carbon (C) cycling in soils. In a three-year field study in conventionally managed, irrigated maize fields, we monitored how key soil variables responded to crushed rock-alone, and in combination with compost and/or biochar. We measured weathering indicators (pH, major cations, and IC contents) and organic fractions, including particulate organic matter (POM), mineral-associated organic matter (MAOM), microbial biomass C, and water-extractable organic C. Rock-alone treatments increased weathering proxies (pH and IC) and showed an increasing trend in POM and MAOM, relative to control. In contrast, combining crushed rock with organic amendments resulted in lower soil organic C and nitrogen (N) concentrations (in both POM and MAOM) compared to organic amendments alone, though IC increased in the rock+compost treatment. Combining rock with both compost and biochar (compost/biochar) significantly lowered MAOM-N compared to compost/biochar alone. Overall, co-applying rock with organic inputs may promote weathering and C accrual but slow the accrual rate of organic C and N relative to organic amendments alone. Quantifying these trade-offs over multiple years and scales is critical to integrating ERW with existing soil health practices and climate mitigation strategies.

Biological and medical sciences↗

Spectral reflectance of surface soils - A statistical analysis

The relationship of the physical and chemical properties of soils to their spectral reflectance as measured at six wavebands of Thematic Mapper (TM) aboard NASA's Landsat-4 satellite was examined. The results of performing regressions of over 20 soil properties on the six TM bands indicated that organic matter, water, clay, cation exchange capacity, and calcium were the properties most readily predicted from TM data. The middle infrared bands, bands 5 and 7, were the best bands for predicting soil properties, and the near infrared band, band 4, was nearly as good. Clustering 234 soil samples on the TM bands and characterizing the clusters on the basis of soil properties revealed several clear relationships between properties and reflectance. Discriminant analysis found organic matter, fine sand, base saturation, sand, extractable acidity, and water to be significant in discriminating among clusters.

Crouse, K. R.↗

Robust Exploration and Commercial Missions to the Moon Using LANTR Propulsion and Lunar Liquid Oxygen Derived from FeO-Rich Pyroclastic Deposits

Studies conducted by NASA and its contractors (early 1980s early 1990s) indicated a substantial benefit from using lunar-derived propellants specifically lunar-derived LO2 (LLO2) or LUNOX in a lunar space transportation system (LTS). With a LTS using LO2/LH2 chemical rockets, approx. 6 kilograms (kg) of mass in low Earth orbit (LEO) is required to place 1 kg of payload on the lunar surface (LS). Of this 6 kg, approx. 70% (4.2 kg) is propellant and 6/7th of this mass (3.6 kg) is oxygen assuming an O/H MR 6:1. Since the cost of placing a kilogram of mass on the LS is approx. 6X the cost of delivering it to LEO, the ability to produce and utilize LUNOX or lunar-derived LO2 and hydrogen (LLH2) from lunar polar ice (LPI) deposits can provide significant mission leverage. Providing LUNOX for use in fuel cells, life support systems and LO2/LH2 chemical rockets used on lunar landing vehicles (LLVs), can allow high value cargo (people, manufacturing and scientific equipment, etc.) to be transported to LEO, then to the Moon instead of bulk LO2 propellant. Oxygen is abundant in the lunar regolith (approx. 43% by mass) and can be extracted using a variety of techniques, such as hydrogen reduction of ilmenite (FeOTiO2) or FeO-rich volcanic glass (orange soil) discovered during the Apollo 17 mission to Taurus-Littrow. While considerable interest has been expressed about mining and processing LPI for rocket propellant, ground truth must first be established to quantify the physical state of the ice (e.g., its vertical thickness and areal extent, levels of soil contamination, etc.) and the deep, extremely cold (approx. 26-100 K) permanently shadowed craters where the ice resides.

Nuclear Thermal Propulsion↗

In-Situ Resource Utilization (ISRU) Living off the Land on the Moon and Mars

In-Situ Resource Utilization (ISRU) is the concept of using local resources at various destinations to provide products and services for robotic and human explorers. This idea of 'living off the land' has the potential of reducing reliance on earth to supply mission consumables such as propellants and life support consumables. Local resources include: water, oxygen, and metals within the surface soil material (regolith), atmospheric gases (eg CO2 on Mars), and the regolith material itself. ISRU systems involve physically and chemically extracting these resources and converting them into desired products.

In-situ resource utilization↗

Aqua Factorem: Ultra Low Energy Lunar Water Extraction

We propose a new method we call Aqua Factorem to extract lunar water. It will drastically reduce energy and complexity of lunar mining operations helping to establish this industry. Other methods to extract water from the regolith are based on phase change, pumping energy into the regolith to sublimate the ice into vapor, then capturing the vapor, re-freezing it, and hauling the solid ice to a chemical processor where it is converted again into vapor for purification then electrolysis. This requires transporting high power into the permanently shadowed regions (PSRs) not only to vaporize the ice in situ in the soil but to heat the surrounding soil itself, which is wasted energy. Still other methods are based on strip mining and hauling the resource along with slag (the unwanted silicates, which constitutes about 95% of the mass), to a processing unit that is located outside the PSRs. That may be a simpler architecture but is generally not favored because hauling 49,000 t of regolith over many kilometers yearly to produce the projected demand of 2,450 t of propellant would be terribly difficult and expensive with high risk that the vehicles will get stuck driving with such loads across the unprepared regolith. We propose an alternative to both of these approaches, taking advantage of the processing that the unique lunar geology has already performed. Micrometeoroid bombardment has already broken most solid material in the upper part of the regolith into fine grains. This includes solid material of all compositions, including the ice, which is as hard as granite at PSR temperatures and is therefore essentially another type of rock. These ice grains are intermixed with all the other minerals, so a simple, ultra-low-energy grain-sorting process can extract the ice without phase change. As another benefit it can extract the 1 wt% free metal known to be in lunar soil, again with very little energy. The ice can then be hauled to the chemical processing unit in solid phase and converted into rocket propellant. We estimate the 800 kW power needed for thermal extraction can be reduced to less than 100 watts using the new method. This affects the entire architecture of the mining operation producing extensive economic benefit, which we will quantify in this study. We will study it in the context of a mission to mine propellants commercially for space tugs that boost commercial communication satellites from Geosynchronous Transfer Orbit (GTO) to Geostationary Orbit (GEO) then return to the lunar surface for refueling. This simple architecture requires the minimum number of in-space elements, and notably does not require an in-space propellant depot, so it provides the lowest cost and lowest risk startup for a commercial operation. The study will also test the innovative Aqua Factorem process through laboratory experiments, and this will produce basic insights into the handling of lunar resources.

lunar↗