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At least 451 records · Page 25

GD-1: The Relic of an Old Metal-poor Globular Cluster

Combining data from Gaia DR2, SDSS DR14 and LAMOST DR6, we update the fit tomodel of the properties of the stellar stream GD-1 and find that it has an ageof $\sim 13$ Gyr, [Fe/H] of $-2.2\pm 0.12$, and a distance from the sun of $\sim 8$ kpc. We tabulate 6D phase-space fiducial points along the GD-1 streamorbit over a 90$^\circ$ arc. The fitted orbit shows that the stream has aneccentricity $e \sim 0.3$, perigalacticon of 14.2 kpc, apogalacticon of 27.0 kpc and inclination $i \sim 40^{\circ}$. There is evidence along the arc for 4candidate stellar overdensities, one candidate gap, two candidate stellarunderdensities and is cut off at $\phi_1 \sim 2^{\circ}$ (in the stream-aligned$(\phi_1,\phi_2)$ coordinate system. The spur originating at $\phi_1 \sim -40^{\circ}$ implies stars were pulled away from the stream traceby an encounter (potentially a dark matter subhalo). The narrowest place ( FWHM$\sim 44.6$ pc) of the GD-1 trace is at $(\phi_1, \phi_2^c) \sim (-14^{\circ},0.15^{\circ})$, which is $\sim (178.18^{\circ}, 52.19^{\circ})$ in (R. A.,Decl.), where the progenitor is possibly located. In conclusion, we also find six BHB and 10BS spectroscopic stars in the GD-1 stream.

79 ASTRONOMY AND ASTROPHYSICS↗

Flight Mechanics Modeling and Simulation of the Earth Entry System

Introduction: The Mars Sample Return (MSR) Campaign being planned by NASA and ESA has the ambitious goal to return Mars samples back to Earth. This international collaboration had developed a concept of operations that included a ESA-designed Earth Return Orbiter (ERO) and NASA-designed Capture, Containment, and Return System (CCRS). The Earth Entry System (EES), consisting of a protective aeroshell that houses the samples as well as sample containment vessels, would conduct entry, descent, and landing (EDL) on a direct Earth trajectory. The EES would enter on a spin-stabilized ballistic trajectory with the goal to passively achieve aerodynamic stability throughout all regions of flight. The EDL sequence would end with the EES impacting the soft playa soil of the Utah Test and Training Range (UTTR). As of the submission of this abstract, the MSR campaign is undergoing a re-architecture leading to a pause in EES development. However, the novel approaches developed in flight mechanics modeling and simulation can significantly benefit the greater IPPW community in the development of Earth return vehicles. This paper will present the latest state of EES flight mechanics modeling and simulation. The paper will highlight the simulation architecture developed and key lessons learned from understanding of EDL trajectory sensitivities. Modeling and Simulation: Figure 1 provides a high-level concept of operations for the approach, entry, descent, and landing (AEDL) phase of the CCRS-portion of MSR. The objective of EES flight mechanics is to model and simulate the EES trajectory from ERO separation to ground impact at UTTR. A variety of flight mechanics simulation models were utilized to model both exo-atmopsheric and atmospheric portions of flight. 42, a 6-DOF simulation developed at Goddard Space Flight Center, is utilized for propagating the attitude of EES during exo-atmospheric flight. 42 allows for a variety of spin eject mechanism scenarios to be simulated for analysis. 10 minutes prior to entry, the 42 states are handed off to the EDL sims. The prime EDL sim utilized by EES is the Program to Optimize Simulated Trajectories II (POST2), a 6-DOF sim developed at Langley Research Center, and the independent verification and validation EDL sim utilized is DSENDS, a 6-DOF sim developed at Jet Propulsion Laboratory. Figure 2 provides a visualization of the flight mechanics simulation model flow through various points in the AEDL phase. Due to the existence of a variety of sim models, the EES flight mechanics team developed processes for data hand-off. These processes included the development of a centralized coordinate frame document, utilization of a single, centralized simulation input document for all sims to reference, and hand-off files containing both the technical data to be ingested by other flight mechanics sims as well as annotations of modeling assumptions utilized to generate the data. Figure~\ref{fig:post2simarchitecture} provides an overview of the POST2 sim architecture wherein POST2 ingests numerous subsystem models and input files. The dispersed state file generated by MONTE provides the position/velocity state of the trajectory while the 42 Handoff file provides the attitude. The aerodynamics database, delivered by the EES aeroscience team, is utilized to simulate the aerodynamic forces and moments experienced during EDL. A custom atmosphere model, developed by EES atmosphere team, is utilized to simulate the anticipated atmosphere environment around the region of Earth through which the EES trajectory flys. These inputs and subsystem models can be varied depending on the AEDL flight mechanics scenario being simulated. Monte Carlo simulations are utilized to generate statistical AEDL performance metrics in the form of scorecards and violin plots. Furthermore, outputs from the POST2 simulation are utilized for follow-on analyses including aerothermal and landing performance. \section{Flight Mechanics Lessons Learned} Though the EES flight mechanics team uncovered a variety of lessons learned through the analysis conducted to support CCRS through preliminary design review, this paper will highlight the most important lessons. A key AEDL performance goal is to ensure the landing footprint of EES remains on the UTTR south range. A common modeling strategy used in EDL analysis is One-Variable-At-a-Time (OVAT). OVAT analysis provides insight into the key drivers that affect AEDL performance metrics. Figure 3 shows the landing ellipses for single dispersion sources as compared to the baseline aggregate of all dispersions. The figure shows that atmosphere winds alone dominate the size of the footprint ellipse (note: EES does not use a parachute unlike previous Earth-return missions and is in wind-driven free fall for ~5min). The significance of the wind led the EES flight mechanics team to pursue the development of a Custom Atmosphere Model [4], in lieu of EarthGRAM [1], built on actual radiosonde wind measurements around the UTTR-region. This decision was driven by the realism in the generated footprint ellipses and lessons-learned from Stardust [5]. These findings will be invaluable for future Earth-return missions in providing an early understanding of the key drivers affecting footprint size and modeling considerations for which to account. Another lesson learned is tied to the AEDL performance goal of achieving passive stability throughout all regions of flight. It is well understood that blunt-body aeroshells are less stable as they transition from supersonic to subsonic. Eliminating a backshell does help improvestability; however, other phenomena such as roll-induced instability during terminal descent can still arise. The EES flight mechanics team developed stability metrics as tools to better understand the causes of and better predict the onset of dynamic instability. These tools were built upon analytical models developed by Jaffe [3] and Murphy [2]. The tools were shown to both be very accurate in correlation with actual unstable cases and useful in developing stability margin policies based on the vehicle design and simulation considerations (e.g. sphere-cone angle change, mass change, wind turbulence). These tools allowed for the current EES design to demonstrate the ability to achieve passive stability and can be an invaluable tool for consideration in the design of parachute-less Earth-return vehicles.

Rohan Deshmukh↗

Peak selection matters in Principal Component Analysis: A case study of syntrophic microbes

In situ liquid time-of-flight secondary ion mass spectrometry (ToF-SIMS) is a powerful technique to address surface characterization of living biofilms in hydrated conditions. Principal component analysis (PCA) is an important tool to process a large amount of data and interpret the information from ToF-SIMS spectra. However, ToF-SIMS data analysis is still a great challenge in complicated bacterial biofilms, because many interference peaks from the medium may result in inaccurate interpretation of ToF-SIMS spectral analysis. In this study, two syntrophic Geobacter populations were investigated using in situ liquid ToF-SIMS to reveal the biofilm surface changes between them as due to direct interspecies electron transfer (DIET). Peak overlay is an effective strategy to eliminate the matrix effects in handling complex ToF-SIMS data and was used to accomplish peak selection in this work. Both all peak and selected peak spectral PCA showed a distinctive separation among different samples. However, medium samples occupied high scores values in all peak PCA compared with the selected peak PCA, suggesting a strong interference from the medium as the matrix effect. Amino acids and lipids contributed significantly in separating all samples in selected peak PCA, which indicated that surface membrane components such as pili and proteins are important in the co-cultured Geobacter community compared to controls such as the single population planktonic cells and biofilms, respectively. Additionally, the spectral PCA results of high intensity and high resolution data obtained from liquid ToF-SIMS were compared. Selected peak PCA obtained nice separation among samples in both data sets; however, the high resolution data showed better separation between co-culture planktonics and co-culture aggregates, confirming that the higher mass accuracy is useful in analysis of microbial samples. Furthermore, amino acid and water cluster as an important media for microbial metabolite were selected for a more focused selected peak PCA comparison. Consistent scores and loadings plots were achieved. In conclusion, we show that peak selection is critical for acquiring effective microbial information and interpretation of syntrophic Geobacter using spectral data from in situ liquid ToF-SIMS.

spectral overlay, peak selection, matrix effect, P↗

Human adipose-derived stem cells and simvastatin-functionalized biomimetic calcium phosphate to construct a novel tissue-engineered bone

Highlights: • Performance of a strategy of constructing a novel tissue-engineered bone (TEB). • Simvastatin could release in a sustained manner after incorporated in the TEB. • This novel TEB could promote the bone formation capability of hASCs more effectively. To repair bone defects, we evaluate the in-vitro and in-vivo osteogenic activities of a novel tissue-engineered bone (TEB) by elaborately combining biomimetic calcium phosphate (BioCaP) granules with internally-incorporated simvastatin (SIM) and human adipose-derived stem cells (hASCs). First, we constructed BioCaP with SIM internally incorporated (SIM-BioCaP). Then we characterized the morphology and chemical composition of SIM-BioCaP. The release kinetics of SIM was monitored in vitro spectroscopically. Thereafter, we explored the in-vitro cellular responses of hASCs to SIM-BioCaP by performing scanning electron microscopy observation, proliferation assay, alkaline phosphatase (ALP) activity assay, alizarin red staining and real-time PCR. Finally, we investigated the in-vivo osteogenic activities of the novel TEB in a subcutaneous bone induction model in nude mice. We found that SIM was successfully incorporated internally in BioCaP and showed a slow release manner without significantly affecting the attachment and proliferation of hASCs. The released SIM from BioCaP could significantly enhance the proliferation, ALP activities, mineralized nodules formation and osteogenic genes of hASCs. The in-vivo tests showed this TEB could induce new bone formation while the other groups could not. Taken together, the present data show that this novel TEB represented a very promising construct to treat critical-volume bone defects.

60 APPLIED LIFE SCIENCES↗

Inorganic “Conductive Glass” Approach to Rendering Mesoporous Metal–Organic Frameworks Electronically Conductive and Chemically Responsive

A representative mesoporous metal–organic-framework (MOF) material, NU-1000, has been rendered electronically conductive via a robust inorganic approach that permits retention of MOF crystallinity and porosity. The approach is based on condensed-phase grafting of molecular tin species onto the MOF nodes via irreversible reaction with hydroxyl and aqua ligands presented at the node surface, a self-limiting process termed solvothermal installation (of metal ions) in MOFs (SIM, a solution-phase analog of atomic layer deposition in MOFs). Treatment of the modified MOF with aerated steam at 120 °C converts the grafted tin molecules to tetratin(IV)oxy clusters, with the clusters being sited between insulating pairs of zirconia-like nodes (the zirconium component being key to endowing the parent material with requisite chemical and thermal stability). By introducing new O–H presenting ligands on the modified-MOF node, the high-temperature steam step additionally serves to reset the material to reactive form, thus enabling a second self-limiting tin-grafting step to be run (and after further steam treatment, enabling a third). Difference-envelop-density (DED) analyses of synchrotron-derived X-ray scattering data, with and without installed tin species, show that the clusters formed after one cycle are spatially isolated, but that repetitive SIM cycling adds metal and oxygen ions in a way that enshrouds nodes, links clusters, and yields continuous one-dimensional strands of oxy-tin(IV), oriented exclusively along the c axis of the MOF. Two-probe conductivity measurements show that the parent MOF and the version containing isolated oxy-tin(IV) clusters are electrically insulating, but that the versions featuring continuous strands show an electrical conductivity of 1.8 × 10–7 S/cm after three Sn-SIM cycles. When combined with interdigitated microelectrodes, the solvent-free and conductive-glass-modified material (three Sn-SIM cycles) displays a substantial and persistent increase in electrical conductivity during exposure to 5% H2, indicating a role for dissociated H2 as an electronic dopant. The increase can be repetitively reversed by alternating H2 with air, illustrating the ability of the conductive MOF to function as a resistive sensor for H2 and suggesting further potential applications that may capitalize on the combination of high volumetric surface area, high mesoporosity, high chemical and thermal stability, and significant electrical conductivity.

bio-inspired↗

The Space Interferometry Mission

The Space Interferometry Mission (SIM) is the next major space mission in NASA's Origins program after SIRTF. The SIM architecture uses three Michelson interferometers in low-earth orbit to provide 4 microarcsecond precision absolute astrometric measurements on approx. 40,000 stars. SIM will also provide synthesis imaging in the visible waveband to a resolution of 10 milliarcsecond, and interferometric nulling to a depth of 10(exp -4). A near-IR (1-2 micron) capability is being considered. Many key technologies will be demonstrated by SIM that will be carried over directly or can be readily scaled to future Origins missions such as TPF. The SIM spacecraft will carry a triple Michelson interferometer with baselines in the 10 meter range. Two interferometers act as high precision trackers, providing attitude information at all time, while the third one conducts the science observations. Ultra-accurate laser metrology and active systems monitor the systematic errors and to control the instrument vibrations in order to reach the 4 microarcsecond level on wide-angle measurements. SIM will produce a wealth of new astronomical data. With an absolute positional precision of 4 microarcsecond, SIM will improve on the best currently available measures (the Hipparcos catalog) by 2 or 3 orders of magnitude, providing parallaxes accurate to 10% and transverse velocities to 0.2 km/s anywhere in the Galaxy, to stars as faint as 20th magnitude. With the addition of radial velocities, knowledge of the 6-dimension phase space for objects of interest will allow us to attack a wide array of previously inaccessible problems such as: search for planets down to few earth masses; calibration of stellar luminosities and by means of standard candles, calibration of the cosmic distance scale; detecting perturbations due to spiral arms, disk warps and central bar in our galaxy; probe of the gravitational potential of the Galaxy, several kiloparsecs out of the galactic plane; synthesis imaging of circumstellar disks around young stellar objects; imaging the narrow-line regions of AGNs in the optical; direct distance determination of a half dozen nearby spiral galaxies using rotational kinematics, thereby sidestepping reddening and metallicity issues in the calibration of distance estimators like Tully-Fisher; imaging exozodiacal dust disks (when operating in its nulling mode, SIM will be sensitive, at a distance of (beta) Pic (20 pc), to scales ranging from 0.2 to 5 AU).

Unwin, Stephen C.↗

The Combined Detection of Morphological and Molecular Biomarkers: Implications for Astrobiology

Experience gathered by previous researchers during their hunt for evidence of early Earth life has shown the complexity in interpreting observations of possible microfossils and to establish the evidence to be positive. Similarly, the stillsimmering controversy on the nature of the nano-structures in Martian meteorite ALH84001 described by McKay et al. (1996) emphasizes the difficulties of conclusively identifying those structures as (a) fossilized bacterial cells and (b) establish their indigeneity. A better understanding of biological signatures in rocks is needed in order to identify traces of microbial life, which include morphological, mineralogical and chemical traces. It is thus considered crucial to tackle the problems emerging in the search for evidence of early life on Earth and in exopaleontological research with a multidisciplinary approach. With this is mind we applied surface sensitive Time of Flight-Secondary Ion Mass Spectroscopy (ToF-SIMS) to a previously described 25 m.y. old fossil bacterial biofilm. This technique allows in situ analysis with high mass resolution as well as molecular imaging of micron sized structures. As no extraction or derivatisation of the sample is required for ToF-SIMS analysis, electron microscopical investigation of the same samples subsequent to analysis is possible, thus allowing the combination of molecular and morphological biomarkers. The analysed fossil bacterial biofilms were associated with macrofossils from volcanoclastic lacustrine sediments from the Upper Oligocene Enspel formation (Germany). Preliminary scanning electron microscopy (SEM) studies have shown that a fossil structure interpreted as a coprolite purely consisted of fossilized bacterial biofilm. For ToF-SIMS investigation small particles were taken from the fossil biofilm and mounted onto Au-coated In-foil and analysed in a Phi Evans T-2000 TRIFT system. The ToF-SIMS analysed samples were Au/Pd-sputter coated and imaged using a Philips XL40 Field Emission Gun SEM (FEG-SEM). ToF-SIMS analysis of the organic rich fossil biofilm (TOC 29%) in the 0-100 Dalton (Da) range showed significant amounts of inorganic species, confirming the results obtained previously by EDX analysis, clearly showing the bacterial fossils to be mineralised. ToF-SIMS furthermore revealed the presence of a variety of low- and high-mass organic molecules and fragments thereof. These include peaks indicative of alkenes and alkanes, aromatic organic species and the polycyclic aromatic hydrocarbon naphthalene. More tentatively, peaks indicative of alkyl pyrroles and pyridyl-CH2 were identified. Other peaks of interest include peaks indicative of C(n)H(2n)O2 and C(n)H(2n-2)O2, which according to their general formula would suggest the presence of both saturated and unsaturated fatty acids although further in situ derivatisation experiments and GC-MS (Gas Chromatography MS) need to be applied to verify this beyond doubt. Furthermore, peaks at m/z 370, 384, 398, 412, 426, 440, 454 and 468 were identified, which indicate the potential presence of bacterial hopanes, a class of biomarkers indicative of bacteria. The main diagnostic peak for this group of chemicals is the fragment at m/z 191.18. Our studies conducted on purified hopane standards have shown that in the high-mass resolution mode differentiation of this diagnostic hopane peak and polyethylene at m/z 191.05 is possible. However, the spectra discussed here were collected in the lower resolution mapping mode, therefore this differentiation was not possible. The centroids of the possible hopane peaks obtained on the fossil biofilms are well within the range associated with bacterial hopanes. There is a strong possibility therefore that hopanoids may be associated with the fossil bacterial cells. Due to the non-destructive nature of ToF-SIMS, analysed samples can be studied using SEM, thus allowing the combination of morphological and molecular biomarkers. Subsequent SEM analysis of the ToF-SIMS analysed samples confirmed that the analysed material purely consists of fossil bacterial cells. This is thus the first successful effort to demonstrate the combination of spectral and morphological biomarkers. The advantages of highly sensitive non-destructive in situ analysis techniques for biomarker detection are invaluable, particularly with respect to envisaged Mars sample return missions, as it may allow us to identify remains and traces of former microbial life in both ancient terrestrial and extraterrestrial materials. This technique may prove particularly useful in the quest for extraterrestrial life with respect to precious extraterrestrial materials, as minute quantities are sufficient to conduct analysis.

Toporski, J.↗

Cosmic Pairs: A DESI Census of Dual and Offset AGN as Precursors to Massive Black Hole Binaries

We present a systematic census of dual and offset active galactic nuclei (AGN) using spectroscopic data from the first data release (DR1) of the Dark Energy Spectroscopic Instrument (DESI). After correcting for observational systematics, our final sample contains $>7,000$ dual AGN and 27,000 galaxy pairs containing one AGN over the redshift range $0 \lesssim z \lesssim 3.6$. This sample expands the known dual AGN sample by $\sim 1-2$ orders of magnitude at $0.2 \lesssim z \lesssim 0.4$, includes $\sim 50$ dwarf dual AGN candidates in a regime where only a handful were previously known, and triples the census at $z>2$. Dual AGN are preferentially found at small separations, consistent with merger-driven triggering of AGN activity. The two members of a pair differ in their star formation response: the more massive (primary) host changes little with separation, while the less massive (secondary) lies $\sim 0.3$ dex above matched inactive and one-AGN companions at the same projected separation in main-sequence offset. Using ASTRID simulations, we predict that the fraction of DESI dual AGN whose central black holes will merge by $z \sim 0$ increases with redshift, reaching $\sim 76\%$ by $z \sim 2$, while the fraction producing LISA-detectable mergers peaks at $\sim 37\%$ near $z \sim 0.9$. These results provide the largest uniformly selected spectroscopic sample of kpc-scale dual and offset AGN candidates from a single survey, connecting their host-galaxy and AGN demographics to the progenitor population of massive black hole mergers detectable by LISA.

Dadiani, Ekaterine [Carnegie Mellon U.] (ORCID:000↗

Development and Validation of High Precision Thermal, Mechanical, and Optical Models for the Space Interferometry Mission

SIM Planetquest (SIM) is a large optical interferometer for making microarcsecond measurements of the positions of stars, and to detect Earth-sized planets around nearby stars. To achieve this precision, SIM requires stability of optical components to tens of picometers per hour. The combination of SIM s large size (9 meter baseline) and the high stability requirement makes it difficult and costly to measure all aspects of system performance on the ground. To reduce risks, costs and to allow for a design with fewer intermediate testing stages, the SIM project is developing an integrated thermal, mechanical and optical modeling process that will allow predictions of the system performance to be made at the required high precision. This modeling process uses commercial, off-the-shelf tools and has been validated against experimental results at the precision of the SIM performance requirements. This paper presents the description of the model development, some of the models, and their validation in the Thermo-Opto-Mechanical (TOM3) testbed which includes full scale brassboard optical components and the metrology to test them at the SIM performance requirement levels.

astronomy↗

Search for top squarks in the four-body decay mode with single lepton final states in proton-proton collisions at $ \sqrt{s} $ = 13 TeV

A search for the pair production of the lightest supersymmetric partner of the top quark, the top squark ($ {\overset{\sim }{\textrm{t}}}_1 $), is presented. The search targets the four-body decay of the $ {\overset{\sim }{\textrm{t}}}_1 $, which is preferred when the mass difference between the top squark and the lightest supersymmetric particle is smaller than the mass of the W boson. This decay mode consists of a bottom quark, two other fermions, and the lightest neutralino ($ {\overset{\sim }{\chi}}_1^0 $), which is assumed to be the lightest supersymmetric particle. The data correspond to an integrated luminosity of 138 fb$^{−1}$ of proton-proton collisions at a center-of-mass energy of 13 TeV collected by the CMS experiment at the CERN LHC. Events are selected using the presence of a high-momentum jet, an electron or muon with low transverse momentum, and a significant missing transverse momentum. The signal is selected based on a multivariate approach that is optimized for the difference between m($ {\overset{\sim }{\textrm{t}}}_1 $) and m($ {\overset{\sim }{\chi}}_1^0 $). The contribution from leading background processes is estimated from data. No significant excess is observed above the expectation from standard model processes. The results of this search exclude top squarks at 95% confidence level for masses up to 480 and 700 GeV for m($ {\overset{\sim }{\textrm{t}}}_1 $) − m($ {\overset{\sim }{\chi}}_1^0 $) = 10 and 80 GeV, respectively.[graphic not available: see fulltext]

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Metal–Organic-Framework-Supported and -Isolated Ceria Clusters with Mixed Oxidation States

The formation of oxygen vacancies via reversible transitions between Ce(IV) and Ce(III) plays a crucial role in the propensity of cerium oxide to act as a supporting promoter in oxidative heterogeneous catalysis. An open challenge is, however, preparation of high-porosity, supported arrays of isolated ceria(IV, III) clusters with high porosity. In this article, we report two examples of oxy-Ce(IV, III) clusters supported and spatially isolated on an oxy-zirconium MOF, NU-1000. The clusters are introduced using either of two Ce complexes (precursors): Ce IV (tmhd) 4 (tmhd = 2,2,6,6-tetramethyl-3,5-heptanedionate) or Ce III (iPrCp) 3 (iPrCp = tris(isopropyl-cyclopenta-dienyl), via SIM (solvothermal installation in MOFs). The prepared materials are named Ce-l-SIM-NU-1000 and Ce-n-SIM-NU-1000, respectively. X-ray photoelectron spectroscopy characterization shows that the ratio of Ce(III) to Ce(IV) oxidation states can be modulated. Difference envelope density analyses of X-ray scattering show that Ce x O y H z clusters in Ce-n-SIM-NU-1000 are located between pairs of Zr6 nodes, whereas in Ce-l-SIM-NU-1000, they are sited on MOF linkers throughout the micropores of NU-1000. Cluster size differences were further evaluated by pair function distribution (PDF) analyses of total X-ray scattering reveal that the node sited clusters contain of only a few cerium ions, whereas the linker-sited clusters each contain ~90 cerium ions. The observed size appears to be defined by the size of NU-1000s triangular pores, that is, cluster formation appears to be pore templated. The Ce-SIM functionalized materials are catalytically active for hydrolysis of DMNP (dimethyl 4-nitrophenyl phosphate), a nerve-agent simulant. Conversion of a small fraction of the Ce(IV) ions in which the presence of small fractions of the cerium(IV) ions in Ce-l-SIM-NU-1000 to cerium(III) significantly enhances catalytic activity-perhaps by labilizing aqua ligands and facilitating simulant binding to the clusters Lewis-basic metal ions. While not explored here, the larger clusters, when partially reduced, are, we believe, candidate catalysts for O 2 activation and subsequent selective oxidation of organic substrates.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Properties of a fading AGN from SDSS-IV MaNGA

ABSTRACT We identify a fading AGN SDSS J220141.64+115124.3 from the internal Product Launch-11 (MPL-11) in Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey. The central region with a projected radius of $\sim$2.4 kpc is characterized as LINER-like line ratios while the outskirts extended to $\sim$15 kpc show Seyfert-like line ratios. The ${\rm{[O {\small III}]}}$$\lambda$5007 luminosity of the Seyfert regions is a factor of 37 (2) higher than the LINER regions without (with) dust attenuation correction, suggesting that the AGN activity decreases at least $\sim$8 $\times$ 10$^3$ yr ($\sim$2.4 kpc/light-speed) ago. We model the emission line spectra in the central region with double Gaussian components (a narrow core and a broad wing) and analyse the properties of each component. The narrow core component mostly co-rotates with the stellar disc, whereas the broad wing component with a median of the velocity dispersion $\sim$300 km s$^{-1}$ is related to a wind outflow. The kinematic position angle (PA) of the ionized gas shows an $\sim 20^{\circ }$ twist from the galaxy centre to 1.5 effective radius. The median of the PA difference between the gas and stellar components is as large as $\sim 50^{\circ }$ within 0.4 effective radius. The tidal feature in DESI image and star–gas misalignment suggest this galaxy is a merger remnant. Combining all these observational results as well as public available X-ray and MIR luminosities, we confirm this is a fading AGN, the merger process kick-started the central engine to quasar phase which ionized gas composed of tidal debris, and now the activity of the central black hole decreases. The discontinuity in ${\rm{[O {\small III}]}}$$\lambda$5007 flux and EQW maps is due to multiple AGN outbursts triggered by merger remnant gas inflows.

Mo, Hao (ORCID:0000000234430768)↗

Inspection of next-generation EUV resists with nano-projectile secondary ion mass spectrometry

There is a rapidly growing need for new materials for extreme ultraviolet (EUV) lithography, which incorporate high EUV absorbing elements. Hybrid resists, which are a combination of inorganic and organic moieties, are promising as they offer both high EUV sensitivity and high etch resistance. However, there is a glaring lack of methods to examine the uniformity of these important materials at the nanoscale. We examine the capabilities of nano-projectile secondary ion mass spectrometry (NP-SIMS) to investigate hybrid resists. NP-SIMS is a mass spectrometry-based technique with high lateral resolution. Using NP-SIMS, a surface is probed stochastically with a suite of individual projectiles, 10 6 to 10 7 in total, separated in time and space. Examining these individual mass spectra allows for nanoscale investigation of the uniformity of the surface. We evaluated the performance of NP-SIMS using samples of poly(methyl methacrylate) (PMMA) infiltrated with varying amounts of InO x via vapor-phase infiltration (VPI), an organic–inorganic hybridization method derived from atomic layer deposition. Here, we found that NP-SIMS measurements contained abundant characteristic ions related to both the PMMA and infiltrated In. The intensity of In atomic ions increased linearly with the number of infiltration cycles; however, the uniformity of In and PMMA varied with the number of infiltration cycles. After one cycle, we found that both the PMMA and In were relatively inhomogeneous. The homogeneity improved with subsequent infiltration cycles. In addition, NP-SIMS measurements contained characteristic ions related to the infiltration reaction and provided insights into the VPI mechanism. Overall, the results show that NP-SIMS is capable of examining both the inorganic and organic moieties in a hybrid resist and will be an important method for understanding the performance of these materials for use in EUV lithography.

36 MATERIALS SCIENCE↗

Multi-Satellite Measurements and Model Predictions of Mesospheric and Upper Stratospheric Influences from the Very Large July 14-16, 2000, Solar Proton Event

A large solar flare with an associated coronal mass ejection occurred in mid-July and caused a very large solar proton event at the earth in the time period July 14-16, 2000. So far this is the largest solar storm of solar cycle 23. The solar proton fluxes were measured by instruments aboard the GOES-10 satellite and used in our proton energy deposition model to help quantify the energy input to the middle atmosphere during this large solar event. Using this computed energy deposition in the GSFC 2D atmospheric model resulted in a prediction of $>$ 20\% increases in HO$-(x)$ (H, OH, HO$-(2)$) and $>$ 100\% increases in NO$-(x)$ (N, NO, NO$-(2)$) constituents in the mesosphere and upper stratosphere at polar latitudes ($>$ 60 degrees geomagnetic). Both the HO$-(x)$ and NO$_fx)$ increases impacted ozone. Large atmospheric impacts have been measured with the NOAA 14 SBUV/2 instrument (0$_(3)$), the UARS HALOE instrument (NO, NO$-(2)$, 0$-(3)$), and the POAM III instrument (0$_{3}$, NO$-(2)$). Preliminary analysis indicates that measured (SBUV/2) and modelled 0$_{3}$ decreases from this solar event are generally in agreement in the Northern Hemisphere. Short-term ozone changes (during the event) indicate $\sim$ 15% reduction at 2 hPa ($\sim$ 45 km) up to $\sim$ 40% reduction at 0.5 hPa ($\sim$ 55 km). A longer-term ozone depletion of $\sim$ 5% is indicated between 4 and 2 hPa ($\sim$ 40-45 km). The middle atmospheric changes caused by this solar event were very large and occurred fairly quickly ($\sim$ 1-2 days). Such a significant natural perturbation provides a good test of our understanding of the middle atmosphere. The measured and modelled impacts of this solar event will be compared and discussed in this paper.

Jackman, Charles H.↗

Evaluation of micromilling/conventional isotope ratio mass spectrometry and secondary ion mass spectrometry of δ 18 O values in fish otoliths for sclerochronology

Stable oxygen isotope ratios (δ 18 O values) measured in fish otoliths can provide valuable detailed information on fish life history, fish age determination, and ocean thermography. Traditionally, otoliths are sampled by micromilling followed by isotope ratio mass spectrometry (IRMS), but direct analysis by secondary ion mass spectrometry (SIMS) is becoming more common. However, these two methods have not been compared to determine which, if either, is better for fish age validation studies. Hence, the goals were to: (1) determine if the δ 18 O signatures from the two different methods are similar, (2) determine which method is better for fish age validation studies, and (3) examine biogeographic and migration history. Both analytical techniques, micromilling/IRMS and SIMS, were used to measure δ 18 O values in six Pacific cod (Gadus macrocephalus) otoliths. A series of measurements was made from the center of each otolith to its edge to develop a life-history δ 18 O signature for each fish. The sampling resolution of SIMS analyses was 2–3 times greater than that obtained by micromilling/IRMS. We found an offset between SIMS and micromilling/IRMS δ 18 O values, about 0.5‰ on average, with SIMS yielding lower values. However, the δ 18 O patterns from both methods (i.e., the number of δ 18 O maxima) correspond to the estimated age determined by otolith growth-zone counts, validating fish age determination methods. Both techniques resolved δ 18 O life-history signatures and showed patterns consistent with seasonal variation in temperatures and changes due to fish migration. When otoliths are large, micromilling/IRMS can provide adequate resolution for fish age validation. Finally, SIMS is the better option if greater sampling resolution is required, such as when otoliths are small or specimens are longer lived and have compact growth zones.

54 ENVIRONMENTAL SCIENCES↗

Effect of wind pressure and modulation schemes on rain interrupted optical wireless links under tropical climates

Tropical and subtropical regions experience heavy rain intensities often accompanied with medium to strong winds. In this work, the effect of perpendicular wind flow and various modulation formats on a rain interrupted optical wireless link is investigated experimentally under controlled laboratory conditions. Attenuation as a function of rain rate is observed at different wind pressure. It is found that rain induced scattering dominates the rain specific attenuation however significant attenuation is expected at much higher wind pressure which normally increases with altitudes. A comparative performance of modulation formats like direct intensity modulation (D-IM), pulse width modulation (PWM) and various subcarrier intensity modulated (SIM) signals under heavy rain conditions is reported. It is found that SIM-FSK and SIM-AM offer better signal to noise performance (approximately two times) followed by subcarrier phase (SIM-PM) and frequency (SIM-FM) respectively. Also, SIM-FSK and PWM are least attenuated in heavy precipitation.

42 ENGINEERING↗

Transfer learning-based soybean LAI estimations by integrating PROSAIL, UAV, and PlanetScope imagery

Accurate Leaf Area Index (LAI) estimations at the soybean plot scale is achievable using high-resolution Unmanned Aerial Vehicle (UAV) imagery and field measurement samples. However, the limited coverage of UAV flights restricts large-scale remote sensing monitoring in expansive soybean fields. This study leverages the broad coverage and 3-m resolution of PlanetScope satellite imagery to extend LAI prediction from UAV to satellite scales through transfer learning, using UAV-scale LAI estimates as a benchmark to validate cross-scale consistency. To address this challenge, this study proposed the LAI-TransNet, a two-stage transfer learning framework designed for precise and scalable soybean LAI prediction across large areas, demonstrating its effectiveness in cross-scale monitoring. In Stage 1, a UAV-scale benchmark is established using PROSAIL-simulated UAV reflectance data (UAV-Sim) and field-measured soybean LAI. Traditional machine learning, deep learning, and transfer learning models are trained on a hybrid UAV-Sim and field-measured dataset (UAV-Sim_Measured), with the transfer learning model CNN-TL, fine-tuned using pre-trained weights derived from UAV-Sim, achieving the highest accuracy (R 2 = 0.81, RMSE = 0.64 m 2 /m 2 , rRMSE = 11.5 %). In Stage 2, LAI-TransNet is developed by fine-tuning the CNN-TL model on PlanetScope simulated data (PS-Sim), preprocessed via cross-domain mapping to align UAV and satellite spectral features. Real PlanetScope imagery is corrected for reflectance consistency with reference to UAV imagery spectral profiles. LAI-TransNet outperforms other deep learning models trained directly on PS-Sim (R 2 = 0.69 vs. 0.60–0.63), ensuring robust cross-scale consistency. In conclusion, by bridging UAV and satellite scales, LAI-TransNet enables large-scale soybean LAI monitoring, enhancing precision agriculture management through improved monitoring with the PlanetScope imagery.

Leaf area index (LAI)↗

In Situ Liquid Secondary Ion Mass Spectrometry: A Surprisingly Soft Ionization Process for Investigation of Halide Ion Hydration

The understanding of ion solvation phenomenon is of significance due to their influences on many important chemical, biological and environmental processes. Mass spectrometry (MS) based methods have been used to investigate this topic with molecular insights. As ion-solvent interactions are weak, ionization processes should be as soft as possible in order to retain solvation structures. An in situ liquid secondary ion MS (SIMS) approach developed in our group has been recently utilized in investigations of Li ion solvation in non-aqueous solution and detected a series of solvated Li ions. As traditionally SIMS has long been recognized as a hard ionization process with strong damage occurring at the sputtering interface, it is very interesting to study further how soft in situ liquid SIMS can be. In this work, we used halide ion hydration as an example to compare the ionization performance of in situ liquid SIMS approach with regular electrospray ionization MS (ESI-MS). Results show that although ESI has been recognized as a soft ionization method, nearly no solvated halide ions were detected by ESI-MS analysis, which acquired only strong signals of salt ion clusters. In contrast, in liquid SIMS spectra, a series of obvious hydrated halide ion compositions could be observed. We further evaluated the hydration numbers of halide ions and revealed the effects of the ion size, charge density and polarizability on the hydration phenomenon. Our findings demonstrated that the in situ liquid SIMS approach is surprisingly soft, and expected to have very broad applications on investigation of various ion-solvent interactions and many other interesting chemical processes (e.g., the initial nucleation of nanoparticle formation) in liquid environment.

Zhang, Yanyan↗