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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Recent Developments in the United Kingdom Geological Disposal Facility Programme - 17558

The United Kingdom Government remains committed to the policy of geological disposal. All major nuclear nations are actively pursuing geological disposal. It is internationally recognised that geological disposal represents the safest and most sustainable option as the end point of the management of high level waste and spent fuel considered as waste. Other countries that have also decided on a policy of geological disposal include Canada, Finland, France, Switzerland, Sweden and the United States of America. The United Kingdom Government continues to favour an approach to siting a Geological Disposal Facility that is based on the willingness of local communities to participate in the siting process. Construction and operation of a Geological Disposal Facility will be a multi-billion pound project that will provide skilled employment for hundreds of people over many decades. It will contribute greatly to the local economy and wider socio-economic framework. There are also likely to be spin-off industry benefits, infrastructure investments, benefits to local education or academic resources, and positive impacts on local service industries that support the facility and its workforce. It is also likely to involve major investments in local transport facilities and other infrastructure, which would remain after the facility had been closed. The United Kingdom Government published a renewed process for siting a Geological Disposal Facility in 2014 - the Implementing Geological Disposal White Paper. This paper discusses the status of activities in the 2014 White Paper that have been accomplished or are underway through to 2016. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

A Study Of Geological Disposal Facility (GDF) Ageing Phenomena In Bentonite - 17605

Since the 1950's, the UK's nuclear activity in energy, defence and medicine has led to the accumulation of a large amount of higher activity radioactive waste (HAW). Most of nuclear waste arises in a wide variety of physical and chemical forms with different radioisotopes and loadings. Due to complexity in HAW, it is imperative that there be a rigorous management system that ensures population and environmental safety over extended periods. The concept of Deep Geological Disposal of waste in a stable geological formation is, nowadays, an internationally accepted solution as the surest and the most viable long term method for management. Any future Geological Disposal Facility (GDF) will comprise, among other artificial and natural engineered barriers, a barrier immediately around the waste containers compounded by a sealing material. The long-term stability of a GDF will be determined by the design and construction of the engineered barriers, and the mechanical, hydraulic and geochemical interactions that may happen between the different engineered components as a result of combined processes such as the heat produced by radioactive decay and the ion water composition of the surrounding host rock. Bentonite clay has been selected as the most promising buffer and backfill material in many disposal programmes because of its swelling capacity, low permeability, plasticity and cation exchange capacity. In the nuclear scope, bentonite testing at different scale-lengths (laboratory and field scale) has been performed and implemented in order to examine the thermo-hydro-mechanical (THM) and thermo-hydro-geochemical (THG) processes that may happen in the engineered barriers and geological settings associated with a GDF. Two major European field scale tests have been performed to better understand bentonite performance and behaviour immediately after HAW emplacements. The Full-Scale Engineered Barriers Experiment (FEBEX) at the Grimsel Test Sit (Switzerland) and the Alternative Buffer Material (ABM) Project at the Aespoe Hard Rock Laboratory (Sweden). The Febex Experiment was a pilot project designed for 'field research' of HAW repository hosted in crystalline rock where surrogate HAW canisters were placed horizontally in drifts, surrounded by compacted blocks of bentonite, sealed by a concrete plug and maintaining a constant canister surface temperature of 100 deg. C. After five years of operation, a partial dismantling was carried out in 2002. Heater processes occurring in the surrounding bentonite. The dismantling of the heater no. 2 (after 18 years of operation) started in late 2014 and is planned to be finished at the end of 2016 (termed FEBEX-DP). The FEBEX Project utilised bentonite from the Cortijo de Archidona deposit (Almeria, Spain). This 'Febex' bentonite is sourced from calcium-magnesium montmorillonite with good properties in relation to swelling capacity, permeability, adsorption capacity, and thermal conductivity. The ABM Project is a large-scale programme that has been running since 2006. The programme is designed to study a suite of possible buffer materials and correlate the physical and chemical properties of eleven different types of bentonites to their fundamental mineralogical properties. The ABM test consists in three 'packages' containing a central heater tube surrounded by different pre-compacted bentonite blocks and instrumentation. Each 'package' was installed in separate boreholes. The target temperature for the surface of the heated tubes in contact with the bentonite was 130 deg. C. Both FEBEX and ABM test the bentonite was saturated with water percolating from surrounding host rock (FEBEX and ABM) and also via artificial supply systems (ABM), being the water itself acting as a long term corrosion agent. For both experiments and emerging interest is in the interaction of bentonite with metallic components, under geological disposal conditions are not considered to be thermodynamically stable and hence arising corrosion products could interact with the buffer. These interactions depend on various factors such as the redox potential, temperature, pH, solute concentration and buffer material characteristics. During the operational phases of the FEBEX and ABM and after its 'closure' a significant volume of air was found to be retained in the bentonite. Under these conditions a period of initial aerobic corrosion by the air in the bentonite barrier would have occurred followed by establishment of anaerobic corrosion would be the dominant process ongoing. The anaerobic corrosion began when the bentonite became water saturated. Under these conditions, the water acted as the major oxidant. The present project focuses on the characterization of samples arising from the FEBEX and ABM Projects as well as performing additional independent experiments designed to complement these prior studies. Characterization will focus mainly on corrosion related alteration combined with thermal effects. Through detailed sample characterization, the intention is to achieve a greater knowledge regarding the changes to the bentonite under the experimental conditions to which it was exposed, and plausible alterations in its THM and THG properties occurring during the experiment due to blended effects of temperature,water content, engineering structural components and solutes are also to be measured. The fulfilment of a large-scale 'in-situ' test is intricate, time-consuming and with an abundance of external variables that are not always well controlled. For this reason, the University of Bristol is performing a series of well constrained time-resolved laboratory tests which bentonite is being subjected to different possible scenarios that may happen whilst in a HAW repository. In virtue of this experiment, the UoB aims to understand the illitisation and cementation process and their effects on bentonite safety properties. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

A Preliminary Analysis on the Applicability of Deep Borehole Disposal for Spent Fuels in Korea - 15496

A deep geological disposal system, the disposal depth is about 500 m below ground, is considered as the safest method to isolate the spent fuels (SF) or high-level radioactive waste from the human environment with the best available technology at present time. The disposal safety of this system has been demonstrated with underground research laboratory and some advanced countries such as Finland and Sweden are implementing their disposal project on commercial stage. However, if these high-level radioactive wastes can be disposed of in deeper and more stable rock formation than deep geological disposal depth, it has several advantages. Therefore, as an alternative disposal concept, i.e., deep borehole disposal technology is under consideration in number of countries in terms of its outstanding safety and cost effectiveness. In this paper, the general concept for deep borehole disposal of spent fuels or high level radioactive wastes was reviewed. And the key technologies and challenges in development of this disposal method with the nuclear environment were analyzed. Also, very preliminary deep borehole disposal concept including disposal canister concept was developed according to the nuclear environment. These results will be used as an input for the analyses of applicability for DBD in Korea. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2016

NWMO Canadian used nuclear fuel repository - 16314

A brief introduction to Canada's Used Fuel Repository Plan, including the status of site selection and the conceptual design. Canada's plan for the long-term care of used nuclear fuel is known as Adaptive Phased Management (APM). It emerged from dialogue with Canadians and experts and best meets the key priorities considered important by citizens. The Federal Government selected APM as Canada's plan in June 2007. The plan is consistent with the long-term management approach adopted by other countries with nuclear power programs, such as Finland, Sweden, Switzerland, the United Kingdom and France. Canada's plan is both a technical method and a management system. The project is designed to be implemented in phases over many decades. New learning and social priorities will be incorporated into Canada's plan for the long-term management of used nuclear fuel, driving refinement and adaptation of the plan throughout its implementation. The major phases for the APM project are described.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

The Evolution of Hot-Isostatic Pressing for the Treatment of Radioactive Wastes - 18276

Hot-isostatic Pressing (HIPing) was first developed by Battelle in the 1950's for applications in the nuclear program. The use of HIPing as a means of treating radioactive wastes was first proposed and patented in Sweden in the 1970's and subsequently gained traction in the US, where throughout the 1980's and 90's work was undertaken at Rockwell, Lawrence Livermore National Laboratory (LLNL), and Idaho National Laboratory (INL) on waste-forms for US Defense wastes. This development was coupled with front-end processing options leading to conceptual plant designs which included hot-cell layouts and costings. Industrial maturation of hot-isostatic press (HIP) technology over the last 20+ years has seen it increasingly become a candidate for treating a variety of waste streams. In this paper, we discuss HIP concepts for treating radioactive wastes, present some recent work undertaken by the authors to demonstrate the feasibility of HIPing for sludge wastes and ion exchangers, and discuss the options and technology challenges for implementation. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2016

Implications of Zero-Carbon Nuclear Renewable Economy: Equity, Economics, and Social Costs

Different energy systems have different impacts on equity, economics, and social costs of energy. This leads to alternative strategies for a zero-carbon economy from considering all options to a renewables-only strategy. We examine implications of different choices from a long-term perspective. This is coupled to but separate from the discussion of how to transition to a low-carbon energy system. If we are to stop greenhouse gas emissions with current goals, the transition must be fast. That requires a large nuclear contribution. Experiences in France and Sweden indicate that one can transition the electric grid from fossil fuels to nuclear in 20 to 25 years if it is a priority. Neither renewables with associated storage and transmission nor carbon capture and sequestration for fossil fuel use in electricity generation are available today at competitive costs to do that. The cost of energy has historically been a major factor in determining where industry and cities are built because it is a large fraction of the global economy. The development of low-cost methods to transport coal, oil, and natural gas partly broke that connection by enabling relatively uniform global energy costs. Nuclear energy because of the low-cost of fuel transport has the same characteristic. Renewables are location dependent. In a renewables-only future, the renewable resources distribution determines local energy costs that directly impacts where there is future economic growth and where there will be lower costs of living. In the U.S. today solar is generally uneconomic. Some Great Plains wind is competitive. Offshore wind is uneconomic. Based on projections of renewables costs, an all-renewable U.S. would see (1) movement of industry and people to between the Mississippi River (water and transportation) and the high plains (high wind velocities and low construction costs) and the southwest and (2) growing regional differences in standards of living. The costs of moving energy from renewables long distances is partly because of the high cost of transport systems (high-voltage lines with low capacity factors, hydrogen inter-conversion losses, etc.) and partly because of the non-dispatchability of renewables. A nuclear renewable world will have large variations in the relative amounts of nuclear, wind and solar with location-reflecting local cost of renewable resources. The deployment of wind and solar would be similar to hydro and geothermal-deployed where there is a concentrated resource. In the U.S. and globally this will likely be the norm because countries with limited access to low-cost renewables will not accept lower standards of living. The relative quantities of nuclear, wind and solar will change with relative advances in energy technologies. Energy is a large fraction of the economy; thus, energy choices have major economic, equity, and social implications. That, in turn, impacts standards of living and economic competitiveness. (authors)

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2020

Progress in demonstrating the performance of Engineered Barriers for the disposal of HLW and SNF: lab studies and demonstration experiments - 20293

Disposal of high-level radioactive waste (HLW) and spent nuclear fuels (SNF) in a geological disposal facility requires a fundamental understanding of the degradation processes of materials used in its engineered barrier system (EBS) over very long timescales. Beyond the wasteform itself (i.e. the borosilicate glass for HLW or the fuel matrix and cladding for SNF), materials often employed in a disposal concept include metallic containers (typically copper and/or carbon steel) and clay-based buffer materials (typically bentonite). In this paper we explore key developments on the long-term evolution of materials employed for the immobilisation, isolation and containment of HLW and SNF in a geological disposal facility, including nuclear glasses, candidate container materials and clay buffers. Our discussion is based on the latest findings from both experimental studies and in-situ demonstration experiments. We present relevant findings from the long-term evolution of HLW glasses (UK composition), metallic materials for the containment system (envisaged in Switzerland, Sweden, Canada and other countries), and bentonite clays (envisaged in many national disposal programmes). (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2016

Towards a Neutronic and Thermal-Hydraulic Safety Analysis of PWR Fuel Bow with SIMULATE5 and COBRA-TF

In the 1990's, collective fuel assembly bow was observed in the Ringhals PWRs in Sweden. Back then fuel vendors reinforced the fuel assemblies' dashpot, decreased hold-down spring forces, increased guide tube wall thickness, and introduced guide tube materials with higher creep resistance in order to improve dimensional stability. Nevertheless, twenty years later in 2010, the same kind of collective bow with S and C shape patterns started to appear in most of Germany's PWRs. At this time the SIMULATE5 (S5) core simulator with its delta-gap bow model (DGA) which was originally developed for safety analysis at Ringhals, could be used as an off-the-shelf solution to assess the impact of bow on Fq and FH. However, these two quantities are of secondary importance in German PWRs in normal operation because the most restricting licensing criteria set limits on DNBRmin values. For this purpose, a method was developed to extract S5 pin powers from DGA calculations and automatically generate COBRA-TF input files (CTF) to analyze DNBR values in the cores. In the following two sections, it is shown how the S5 model for DGA calculations has been verified with independent MCNP6 calculations in order to check its predictions on pin power changes for delta gaps up to 1 cm in size and how the existing licensed DNBR calculation methodology has been updated to bowed fuel assembly situations with the help of CTF. Finally, the applicability of the Doroschuk CHF correlation, which is the licensing standard in most German PWRs, is discussed. For the fuel bow patterns considered, it is assumed that only the gap between fuel assemblies change and that the pitch between fuel rods inside the assemblies remains largely unchanged. This approximation can be justified by the visual inspections conducted at the plants during the outages. Every calculation of the pin-power impact of delta-gaps in the core under operating conditions is only as good as the knowledge of the bow pattern. Measurements of fuel assembly bow at cold conditions have been made for some German PWRs for all the fuel assemblies in the core during plant outages. Together with methods developed by the fuel assembly vendors, a best-estimate bow pattern during operation could be reconstructed. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2024

Cold Climate Degradation: An Analysis of Double-Axis Tracked, E-W Vertical, and Fixed-Tilt Photovoltaic Deployments in Alaska

As countries around the world transition towards renewable energy, there is increasing interest in using photovoltaic (PV) technologies to help decarbonize remote northern communities due to their scalability and affordability. However, a major barrier towards large-scale adoption of PV in cold climates is performance uncertainty under extreme environmental conditions including snowfall, freeze-thaw cycles, and high wind loads. Existing literature on PV degradation rates in the North is relatively limited, with published degradation rates varying between -0.2%/year (Sweden) to -1.3%/year (Scotland). At this workshop, we will present preliminary results on the long-term performance of two diverse photovoltaic sites located in Fairbanks, Alaska at 64.8 degrees N: a monofacial Al-BSF double-axis tracking site maintained by the Cold Climate Housing Research Center (CCHRC), and a bifacial PERC/SHJ E-W vertical and south-facing fixed-tilt site maintained by the Alaska Center Energy and Power (ACEP). CCHRC data has been collected over a period of 15 years, while ACEP site data has been collected over 4 years. Using the degradation analysis tool, RdTools, we will present annual system degradation rates, seasonal performance ratio, and identify potential cold climate failure mechanisms for commercially available PV technologies. This analysis will add to existing literature by directly comparing the performance of multiple PV configurations in Alaska.

bifacial↗
DOE OSTI2025

Emergence of pseudoresonance in high-intensity resonant inelastic x-ray scattering

We report resonant inelastic x-ray scattering (RIXS) spectra of neon atoms interacting with intense x-ray pulses generated using an x-ray free-electron laser (XFEL). We find that an unexpected peak emerges near the 𝐾⁢𝛼 line of Ne, which does not coincide with any physical resonances of neon ions. We perform theoretical calculations based on a quantum-state-resolved rate-equation approach with x-ray-induced processes including possible resonant excitations. Our dynamics simulations demonstrate that a sequence of multiple resonant photoabsorption events are involved and the interplay of those multiple resonances in combination with the relatively large spectral bandwidth of XFEL radiation leads to the emergent resonance-like structure at a position where no resonances exist. Our finding offers critical guidance for future applications of high-intensity RIXS at XFEL facilities.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2025

Biofluid-based staging of Alzheimer’s disease

Recently, conceptual systems for the in vivo staging of Alzheimer’s disease (AD) using fluid biomarkers have been suggested. Thus, it is important to assess whether available fluid biomarkers can successfully stage AD into clinically and biologically relevant categories. In the TRIAD cohort, we explored whether p-tau217, p-tau205 and NTA-tau (biomarkers of early, intermediate and late AD pathology, respectively) have potential for biofluid-based staging in cerebrospinal fluid (CSF; n = 219) and plasma (n = 150), and compared them in a paired CSF and plasma subset (n = 76). Our findings suggest a good concordance between biofluid staging and underlying pathology when classifying amyloid-positivity into three categories based on neurofibrillary pathology: minimal/non-existent (p-tau217 positive), early-to-intermediate (p-tau217 and p-tau205 positivity), and advanced tau tangle deposition (p-tau217, p-tau205 and NTA-tau positive), as indexed by tau-PET. Discordant cases accounted for 4.6% and 13.3% of all CSF and plasma measurements respectively (9.2% and 11.8% in paired samples). Notably, CSF- and plasma-based staging matched one another in 61.7% of the cases, while approximately 32% of the remaining participants were one to three biofluid stages higher in CSF as compared to plasma. Overall, these exploratory results suggest that biofluid staging of AD holds potential for offering valuable insights into underlying AD hallmarks and disease severity. However, its applicability beyond molecular characterization at research settings has yet to be demonstrated.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2025

Deuteron Evaporation from N = Z Compound Nuclei

Deuteron evaporation was observed from the N = Z compound nuclei 52 Fe ⋆ , 56 Ni ⋆ , and 64 Ge ⋆ in an experiment conducted at Argonne National Laboratory, USA. The experiment included a novel combination of two highly pixelated double-sided Si-strip detectors inside the Microball chargedparticle detection array, allowing for unequivocal discrimination of evaporated deuterons from protons and α particles. In conjunction with the Gammasphere array, Neutron Shell, and additional ancillary detectors, decay paths into various residual nuclei were investigated. The study provides insights into the competition of deuteron vs. proton-neutron evaporation as a function of available excitation energy and populated angular momentum. Results are interpreted using a statistical evaporation formalism for multiple subsequent particle emissions. The decisive factor in the comparison appears to be the available excitation energy in the residual system, with single nucleon evaporation preferred over deuteron evaporation for higher excitation energies.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

In-situ probing of the Fischer-Tropsch reaction on Co single crystal surfaces up to 1 bar

The surface chemistry of the Fischer-Tropsch catalytic reaction over Co has still several unknows. Here, we report an in-situ X-ray photoelectron spectroscopy study of Co$(0001)$ and Co$(10\bar{1}4)$, and in-situ high energy surface X-ray diffraction of Co$(0001)$ during the Fischer-Tropsch reaction at 0.15 bar - 1 bar and 406 K - 548 K in a H 2 /CO gas mixture. We find that these Co surfaces remain metallic under all conditions and that the coverage of chemisorbed species ranges from 0.4–1.7 monolayers depending on pressure and temperature. The adsorbates include CO on-top, C/-C x H y and various longer hydrocarbon molecules, indicating a rate-limiting direct CO dissociation pathway and that only hydrocarbon species participate in the chain growth. The accumulation of hydrocarbon species points to the termination step being rate-limiting also. Furthermore, we demonstrate that the intermediate surface species are highly dynamic, appearing and disappearing with time delays after rapid changes in the reactants’ composition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

The impact of kidney function on Alzheimer’s disease blood biomarkers: implications for predicting amyloid-β positivity

Impaired kidney function has a potential confounding effect on blood biomarker levels, including biomarkers for Alzheimer’s disease (AD). Given the imminent use of certain blood biomarkers in the routine diagnostic work-up of patients with suspected AD, knowledge on the potential impact of comorbidities on the utility of blood biomarkers is important. We aimed to evaluate the association between kidney function, assessed through estimated glomerular filtration rate (eGFR) calculated from plasma creatinine and AD blood biomarkers, as well as their influence over predicting Aβ-positivity. We included 242 participants from the Translational Biomarkers in Aging and Dementia (TRIAD) cohort, comprising cognitively unimpaired individuals (CU; n = 124), mild cognitive impairment (MCI; n = 58), AD dementia (n = 34), and non-AD dementia (n = 26) patients all characterized by [ 18 F] AZD-4694. Plasma samples were analyzed for Aβ42, Aβ40, glial fibrillary acidic protein (GFAP), neurofilament light chain (NfL), tau phosphorylated at threonine 181 (p-tau181), 217 (p-tau217), 231 (p-tau231) and N-terminal containing tau fragments (NTA-tau) using Simoa technology. Kidney function was assessed by eGFR in mL/min/1.73 m 2 , based on plasma creatinine levels, age, and sex. Participants were also stratified according to their eGFR-indexed stages of chronic kidney disease (CKD). We evaluated the association between eGFR and blood biomarker levels with linear models and assessed whether eGFR provided added predictive value to determine Aβ-positivity with logistic regression models. Biomarker concentrations were highest in individuals with CKD stage 3, followed by stages 2 and 1, but differences were only significant for NfL, Aβ42, and Aβ40 (not Aβ42/Aβ40). All investigated biomarkers showed significant associations with eGFR except plasma NTA-tau, with stronger relationships observed for Aβ40 and NfL. However, after adjusting for either age, sex or Aβ-PET SUVr, the association with eGFR was no longer significant for all biomarkers except Aβ40, Aβ42, NfL, and GFAP. When evaluating whether accounting for kidney function could lead to improved prediction of Aβ-positivity, we observed no improvements in model fit (Akaike Information Criterion, AIC) or in discriminative performance (AUC) by adding eGFR to a base model including each plasma biomarker, age, and sex. While covariates like age and sex improved model fit, eGFR contributed minimally, and there were no significant differences in clinical discrimination based on AUC values. We found that kidney function seems to be associated with AD blood biomarker concentrations. However, these associations did not remain significant after adjusting for age and sex, except for Aβ40, Aβ42, NfL, and GFAP. While covariates such as age and sex improved prediction of Aβ-positivity, including eGFR in the models did not lead to improved prediction for any biomarker. Our findings indicate that renal function, within the normal to mild impairment range, does not seem to have a clinically relevant impact when using highly accurate blood biomarkers, such as p-tau217, in a biomarker-supported diagnosis.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2025

Operando Characterization of Fe in Doped Ni x (Fe 1– x )O y H z Catalysts for Electrochemical Oxygen Evolution

Iron-doped nickel oxyhydroxides, Ni x (Fe 1– x )O y H z , are among the most promising oxygen evolution reaction (OER) electrocatalysts in alkaline environments. Although iron (Fe) significantly enhances the catalytic activity, there is still no clear consensus on whether Fe directly participates in the reaction or merely acts as a promoter. To elucidate the Fe’s role, we performed operando X-ray spectroscopy studies supported by DFT on Ni x (Fe 1– x )O y H z electrocatalysts. We probed the reversible changes in the structure and electronic character of Ni x (Fe 1– x )O y H z as the electrode potential is cycled between the resting (here at 1.10 V RHE ) and operational states (1.66 V RHE ). DFT calculations and XAS simulations on a library of Fe structures in various NiO y H z environments are in favor of a distorted local octahedral Fe(III)O 3 (OH) 3 configuration at the resting state with the NiO y H z scaffold going from α-Ni(OH) 2 to γ-NiOOH as the potential is increased. Under catalytic conditions, EXAFS and HERFD spectra reveal changes in p-d mixing (covalency) relative to the resting state between O/OH ligands and Fe leading to a shift from octahedral to square pyramidal coordination at the Fe site. XES measurements and theoretical simulations further support that the Fe equilibrium structure remains in a formal Fe(III) state under both resting and operational conditions. These spectral changes are attributed to potential dependent structural rearrangements around Fe. The results suggest that ligand dissociation leads to the C 4v symmetry as the most stable intermediate of the Fe during OER. This implies that Fe has a weakly coordinated or easily dissociable ligand that could serve to coordinate the O–O bond formation and, tentatively, play an active role in the Ni x (Fe 1– x )O y H z electrocatalyst.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Multimodal Ambient Pressure Sample Environment for the HIPPIE Solid-Gas Endstation at MAX IV Laboratory

The HIPPIE APXPS instruments have undergone several major upgrades, such as developing a dedicated solid gas endstation to specialize in multimodal ambient pressure sample environments centered around X-ray photoelectron spectroscopy. Herein, the technical specifications of the HIPPIE solid gas endstation are detailed; upgrades to the laser heating and gas systems, as well as the addition of an offline 1 bar reactor, are introduced. To demonstrate how the endstation is currently being utilized, scientific examples of all upgrades are presented, as well as science cases using infrared reflection-adsorption spectroscopy. The HIPPIE solid gas endstation is maturing into an instrument offering bespoke sample environments aimed at pushing experimental capabilities, especially in the time-resolved domain.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

The ambiguous AT2022rze: changing-look AGN mimicking a supernova in a merging galaxy system

AT2022rze is a luminous, ambiguous transient located south-east of the geometric centre of its host galaxy at redshift $z = 0.08$. The host appears to be formed by a merging galaxy system. The observed characteristics of AT2022rze are reminiscent of active galactic nuclei (AGNs), tidal disruption events, and superluminous supernovae. The transient reached a peak absolute magnitude of $-$20.2 $\pm$ 0.2 mag, showing a sharp rise (t$_{\mathrm{rise,1/e}} = 27.5 \pm 0.6$ d) followed by a slow decline (t$_{\mathrm{dec,1/e}} = 382.9 \pm 0.6$). Its bumpy light curve and narrow Balmer lines indicate the presence of gas (and dust). Its light curve shows rather red colours, indicating that the transient could be affected by significant host extinction. The spectra reveal coronal lines, indicative of high-energy (X-ray/UV) emission. Archival data reveal no prior activity at this location, disfavouring a steady-state AGN, although an optical spectrum obtained prior to the transient is consistent with an AGN classification of the host. Based on this, we conclude that the transient most likely represents a changing-look AGN at the centre of the smallest component of the merging system.

galaxies: active↗
DOE OSTI2025

Identification of Prompt Proton Emission in $N = Z - 1$ 61 Ga: Isospin Symmetry at the Limit of Nuclear Binding

Excited states in the proton drip line nucleus 61 Ga were populated via the fusion-evaporation reaction 24 Mg ⁢( 40 Ca, 𝑝⁢2⁢𝑛)⁢ 61 Ga. The experimental setup at Argonne National Laboratory comprised a novel combination of the Gammasphere array with two CD-shaped double-sided Si-strip detectors inside the Microball CsI(Tl) charged-particle detection array, as well as the Neutron-Shell liquid scintillators and the Fragment Mass Analyzer. Owing to the setup’s unprecedented in-beam proton spectroscopy and tracking capabilities, a coincidence between a 957.6(5)-keV 𝛾 ray and a 1.876(24)-MeV proton line was observed, which identifies the quasibound proton 𝜋⁢𝑔 9/2 single-particle state in 61 Ga at 𝐸 𝑥 = 2150⁢(34) keV. This probes isospin symmetry at the limit of nuclear binding by providing a unique challenge for the shell-model interpretation of mirror nuclei beyond doubly magic 56 Ni .

Hrabar, Yuliia [Lund Univ. (Sweden)] (ORCID:000000↗