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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25

Verification and Validation of START: A Spent Nuclear Fuel Routing and Decision Support Tool

This is a technical presentation that does not take into account contractual limitations or obligations under the Standard Contract for Disposal of Spent Nuclear Fuel and/or High-Level Radioactive Waste (Standard Contract) (10 CFR Part 961). For example, under the provisions of the Standard Contract, spent nuclear fuel in multi-assembly canisters is not an acceptable waste form, absent a mutually agreed to contract amendment.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A successful start for mLife

mLife made its debut with the publication of the inaugurating issue on March 30, 2022. We are pleased to have published 42 high-quality articles, including reviews, research articles, and application notes, which cover microbial genetics, biochemistry and physiology, ecology and evolution, pathogenic and public health microbiology, and so forth. Nine of the articles concern technical innovations and applications in areas including genome editing, single-cell analysis, and database. To pay tribute to the great microbiologist Carl Woese on the 10th anniversary of his death, the Journal published a special section containing three thought-provoking articles in the last issue of the year. mLife and its collaborating publisher Wiley have made great efforts to increase the Journal's national and continental representation. As a result, the Journal received submissions from over 20 countries in five continents last year. The authors of the published articles are from China, United States, Great Britain, France, Canada, Ger many, Japan, Switzerland, and Austria.

59 BASIC BIOLOGICAL SCIENCES↗

Possibilities for Optimizing the Self-Starting Process of Auxiliary Electric Motors at a Nuclear Power Plant

The existing technique of switching on the auxiliary reserve network of an NPP formulates the switch-on commands directly after a shutdown. Due to delay in activating the automatic switch, the command is completed with a certain time delay. The nature of the subsequent processes is not very predictable. It is proposed to determine, based on developed computer models of the actual equipment, the moments of formation of the reserve activation commands, thus ensuring smaller perturbations at the subsequent switch-on.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Synthesis and Comparison of Two cBN Composites with Starting Ternary Carbide Binders

Ti{sub 3}SiC{sub 2} and Ti{sub 3}AlC{sub 2} are two promising binders for the ultrahard composite polycrystalline cubic boron nitride (PcBN). In this study, the cBN composites with Ti{sub 3}SiC{sub 2} and Ti{sub 3}AlC{sub 2} binders with different binder contents were synthesized under the same high pressure (~5.5 GPa) and high temperature (1350 °C) conditions. Their mechanical properties were measured separately, including Vickers hardness, bending hardening, and compression hardening. Together with XRD results, the phase compounds were also investigated. The decomposition and reaction processes were affected by binder content. Some new compounds formed during sintering, these compounds were TiC, TiSi{sub 2,} SiC, TiB{sub 2}, SiB{sub 4}, TiB{sub 2}, and TiC{sub 0.7}N{sub 0.3} in Ti{sub 3}SiC{sub 2}-cBN composites, as well as TiC{sub 0.7}N{sub 0.3}, TiB{sub 2}, and AlN in Ti{sub 3}AlC{sub 2}-cBN composites. The microstructure of the cracks surface was obtained after the bending tests, and was used to further investigate and compare their crack mode by SEM. The crack surface profile and elementary analysis on the oxidative surface were also discussed.

36 MATERIALS SCIENCE↗

Fuel Cells Catalyst for Start-up and Shutdown Conditions: Electrochemical, XPS, and TEM Evaluation of Sputter-Deposited Ru, Ir, and Ti on Pt-Nano-Structured Thin Film (NSTF) Support

Minute amounts of Ru, Ir and Ti (2 and 10 g/cm2) sputter-deposited over 3M Pt-coated nano-structured thin film (NSTF) substrate were evaluated as oxygen evolution reaction (OER) catalysts in a polymer electrolyte membrane (PEM) environment. The purpose of the study was to explore the suitability of these elements for modifying both the anode and the cathode catalysts in order to lower the overpotential for the oxidation of water during transient conditions. By keeping the electrode potential as close as possible to the thermodynamic potential for OER, other components in the fuel cell, such as platinum, the gas diffusion layer and the bipolar plates, will be less prone to degradation. While Ru and Ir were chosen due to their high OER activity in aqueous environment, Ti was also included due to its ability to stabilize the OER catalysts. The 3M Pt-NSTF was selected as a stable, carbon-free substrate. The surface chemistry and the morphology of OER catalysts on Pt-NSTF were examined by x-ray photoelectron spectroscopy (XPS) and scanning transmission electron microscopy (STEM). The OER catalytic activity of Ru and Ir in PEMs compares well with their behavior in aqueous environment. It was found that Ru is more active than Ir, that Ir is considerably more stable, while the mass activity of both is higher in comparison with similar OER catalyst.

OER↗

Effect of starting microstructure on helium plasma-materials interaction in tungsten

Here, in a magnetic fusion energy (MFE) device, the plasma-facing materials (PFMs) will be subjected to tremendous fluxes of ions, heat, and neutrons. The response of PFMs to the fusion environment is still not well defined. Tungsten metal is the present candidate of choice for PFM applications such as the divertor in ITER. However, tungsten's microstructure will evolve in service, possibly to include recrystallization. How tungsten's response to plasma exposure evolves with changes in microstructure is presently unknown. In this work, we have exposed hot-worked and recrystallized tungsten to an 80 eV helium ion beam at a temperature of 900 °C to fluences of 2 × 10 23 or 20 × 10 23 He/m 2 . This resulted in a faceted surface structure at the lower fluence or short but well-developed nanofuzz structure at the higher fluence. There was little difference in the hot-rolled or recrystallized material's near-surface (≤50 nm) bubbles at either fluence. At higher fluence and deeper depth, the bubble populations of the hot-rolled and recrystallized were different, the recrystallized being larger and deeper. This may explain previous high-fluence results showing pronounced differences in recrystallized material. The deeper penetration in recrystallized material also implies that grain boundaries are traps, rather than high-diffusivity paths.

36 MATERIALS SCIENCE↗

Alternative translation initiation from two in-frame start codons in DHX33 gene

Highlights: • DHX33 can be translated via leaky scanning. • The isoforms of DHX33 via leaky scanning have similar localization and functions. • Leaky scanning of DHX33 is conserved in human and in mouse. DHX33 has been shown to play key roles in promoting cell proliferation. We have previously found that DHX33 protein is a doublet. In this report, we discovered that DHX33 doublet is due to alternative translation initiation by two in-frame initiation codons. This is supported by studies from both cell lines and mouse models. DHX33 translation initiation from either AUG codon happens at equal efficiency. Short DHX33 protein has similar cellular location and functions with full-length DHX33. Our results suggest that leaky scanning normally occur in DHX33 mRNA translation, which may serve as a safeguard mechanism to ensure optimal DHX33 translation efficiency. This is the first report of DEAD/DEAH box proteins that can be regulated by alternative translation initiation.

60 APPLIED LIFE SCIENCES↗

A comparative study of silver- and palladium-exchanged zeolites in propylene and nitrogen oxide adsorption and desorption for cold-start applications

Here, silver and palladium ion-exchanged BEA zeolites (Si/Al = 12.5) and silver ion-exchanged ZSM-5 zeolites (Si/Al = 15) were studied for their ability to adsorb and desorb propylene and NO under simulated diesel exhaust conditions. The adsorption experiment results demonstrated the excellent ability of bare BEA zeolites to adsorb propylene, but only a small amount of NO. The presence of H 2 O inhibited the adsorption of both C 3 H 6 and NO. Ion-exchanging BEA zeolites with Ag (1.2 and 5.1 wt.% Ag/BEA) attenuated the inhibiting effect of H 2 O on C 3 H 6 adsorption, while NO storage remained inhibited. Adsorption experiments indicated that C 3 H 6 and NO competed with each other for Pd sites with C 3 H 6 showing stronger adsorption compared to NO, whereas Ag sites preferentially adsorbed C 3 H 6 . DRIFTS data indicated the formation of nitrate, formate and acetate species on Ag and Pd, while C 3 H 6 and NO adsorption was also observed on the zeolite hydroxyl groups in the absence of H 2 O. However, the C 3 H 6 and NO adsorption on the zeolite hydroxyl groups was significantly inhibited in the presence of H 2 O. Additionally, nitrosyl, acrolein and carbonate species were formed over 1.0 wt.% Pd/BEA. The effluent analysis during the temperature-programmed desorption in the DRIFTS reactor revealed that adsorbed C 3 H 6 and NO reacted during the release to form oxidation reaction byproducts. The 1.0 wt.% Pd/BEA zeolite showed the greatest oxidation ability during desorption with the majority of stored C 3 H 6 converted to CO 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

An improved numerical method to compute neutron/gamma deexcitation cascades starting from a high spin state

Numerous nuclear processes involve the deexcitation of a compound nucleus through the emission of several neutrons, gamma-rays and/or conversion electrons. The characteristics of such a deexcitation are commonly derived from a total statistical framework often called “Hauser–Feshbach” method. In this work, we highlight a numerical limitation of this kind of method in the case of the deexcitation of a high spin initial state. To circumvent this issue, an improved technique called the Fluctuating Structure Properties (FSP) method is presented. Two FSP algorithms are derived and benchmarked on the calculation of the total radiative width for a thermal neutron capture on 238 U. We compare the standard method with these FSP algorithms for the prediction of particle multiplicities in the deexcitation of a high spin level of 143 Ba. The gamma multiplicity turns out to be very sensitive to the numerical method. The bias between the two techniques can reach 1.5 γγ/cascade. Lastly, the uncertainty of these calculations coming from the lack of knowledge on nuclear structure is estimated via the FSP method.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗