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At least 451 records · Page 25

Ion radial diffusion in an electrostatic impulse model for stormtime ring current formation

Guiding-center simulations of stormtime transport of ring-current and radiation-belt ions having first adiabatic invariants mu is approximately greater than 15 MeV/G (E is approximately greater than 165 keV at L is approximately 3) are surprisingly well described (typically within a factor of approximately less than 4) by the quasilinear theory of radial diffusion. This holds even for the case of an individual model storm characterized by substorm-associated impulses in the convection electric field, provided that the actual spectrum of the electric field is incorporated in the quasilinear theory. Correction of the quasilinear diffusion coefficient D(sub LL)(sup ql) for drift-resonance broadening (so as to define D(sub LL)(sup ql)) reduced the typical discrepancy with the diffusion coefficients D(sub LL)(sup sim) deduced from guiding-center simulations of representative-particle trajectories to a factor of approximately 3. The typical discrepancy was reduced to a factor of approximately 1.4 by averaging D(sub LL)(sup sim), D(sub LL)(sup ql), and D(sub LL)(sup rb) over an ensemble of model storms characterized by different (but statistically equivalent) sets of substorm-onset times.

Chen, Margaret W.↗

Thermodynamic data for fifty reference elements

This report is a compilation of thermodynamic functions of 50 elements in their standard reference state. The functions are C(sub p)(sup 0), (H(sup 0)(T) - H(sup 0)(0)), S(sup 0)(T), and -(G(sup 0)(T) - H(sup 0)(O)) for the elements Ag, Al, Ar, B, Ba, Be, Br2, C, Ca, Cd, Cl2, Co, Cr, Cs, Cu, F2, Fe, Ge, H2, He, Hg, I2, K, Kr, Li, Mg, Mn, Mo, N2, Na, Nb, Ne, Ni, O2, P, Pb, Rb, S, Si, Sn, Sr, Ta, Th, Ti, U, V, W, Xe, Zn, and Zr. Deuterium D2 and electron gas e(sup -) are also included. The data are tabulated as functions of temperature as well as given in the form of least-squares coefficients for two functional forms for C(sub p)(sup 0) with integration constants for enthalpy and entropy. One functional form for C(sub p)(sup 0) is a fourth-order polynomial and the other has two additional terms, one with T(exp -1) and the other with T(exp -2). The gases Ar, D2, e(sup -), H2, He, Kr, N2, Ne, O2, and Xe are tabulated for temperatures from 100 to 20,000 K. The remaining gases Cl2 and F2 are tabulated from 100 to 6000 K and 1000 to 6000 K. The second functional form for C(sub p)(sup 0) has an additional interval from 6000 to 20,000 K for the gases tabulated to 20,000 K. The fits are constrained so that the match at the common temperature endpoints. The temperature ranges for the condensed species vary with range of the data, phase changes, and shapes of the C(sub p)(sup 0) curves.

Mcbride, Bonnie J.↗

Numerical simulation of a low-emission gas turbine combustor using KIVA-II

A modified version of the KIVA-II code was used to obtain a multidimensional numerical solution for the turbulent two-phase chemically reacting flows inside a staged turbine combustor (STC). The STC under consideration is equipped with an advanced airblast fuel nozzle and encompasses a fuel nozzle (FN), a rich-burn (RB) zone, a converging connecting pipe, a quick-quench (QQ) zone, a diverging connecting pipe, and a lean-combustion (LC) zone. The STC was divided into two subsystems, namely, FN/RB zone and QQ/LC zones, and the numerical solutions were obtained separately for each subsystem. Preliminary data characterize the major features of the flow and temperature fields inside the STC. Information on velocity, temperature, and some critical species in the FN/RB zone is presented. In the QQ/LC zones, formation of the co- and counter-rotating bulk flow and the sandwiched-ring-shaped temperature field can be clearly seen. The calculations of the mass-weighted standard deviation and the pattern factor of temperature indicated that the mixing performance of the STC is very promising.

Yang, S. L.↗

Post-eruptive alteration of silicic ignimbrites and lavas, Gran Canaria, Canary Islands - Strontium, neodymium, lead, and oxygen isotopic evidence

The isotopic composition of lavas from oceanic islands provides important information about the composition and evolution of the earth's mantle. Isotopic analyses of Miocene comenditic, pantelleritic, and trachyphonolitic ignimbrites and lavas from the Canary islands were performed. Results provide evidence for posteruptive mobility of Rb and Sr during low temperature postemplacement interaction with circulating ground water. Calculated Sr isotope ratios define a magmatic trend in the stratigraph section. 87Sr/86Sr ratios in hydrated vitrophyte and devitrified matrix separates indicate significant posteruptive interaction with meteoric water starting soon after deposition. This process extends patchily through the entire pyroclastic flow and may be ongoing. 87Sr/86Sr ratios determined by whole rock analysis of silicic rocks from oceanic islands are suspect and should not be incorporated into mantle tracer studies. Anorthoclase phenocrysts are resistant to these processes and may produce useful data.

Cousens, Brian L.↗

Ages of pristine noritic clasts from lunar breccias 15445 and 15455

The Rb-Sr and Sm-Nd isotopic ages were determined for two Apollo 15 pristine lunar breccias, 15445 and 15455, collected near Spur Crater on the Apennine Front. The analyses of mineral separates from two norite samples in breccia 15445 showed that the Sm-Nd isotopic system for both norites from the large Clast B of 15445 was well defined, yielding precise ages of 4.28 +/- 0.03 Ga and 4.46 +/- 0.07 Ga, suggesting that the Cast B is a mixture of two or more lithologies. The overall age results indicate that some Mg-suite rocks are as old as ferroan-anorthosite-suite rocks. Moreover, age data of three major crustal rocks (a Mg suite, a ferroan-anorthosite suite, and an evolved suite) show that they all have variable ages.

Shih, C.-Y.↗

Antarctic polymict eucrite Yamato 792769 and the cratering record on the HED parent body

Compared to most other Yamato polymict eucrites, Yamato Y792769 eucrite includes fewer and smaller eucritic clasts with homogenized pyroxenes, and its fine-grained matrix is shock-compacted and sintered. In this work, the relationships between the Antarctic eucrite Y792769, monomict eucrites, polymict eucrites, and isotopic ages are investigated, using results of Ar-39/Ar-40 method to date the time of the major thermal event on the Y792769 body and the Rb-Sr and Sm-Nd methods to determine whether relict older ages might have been preserved in some of the breccia materials. The Ar-39/Ar-40 time of the last thermal event which produced the Y792769 texture is 3.99 +/- 0.04 Ga. The complete resetting of the Ar-39/Ar-40 age is consistent with the texture of Y792769 observed in TEM, suggesting that shock compaction converted part of the matrix plagioclase to maskelynite. The Sm-Nd data give an age of 4.23 +/- 0.12 Ga, reflecting partial resetting of the Sm-Nd system during breccia formation. The 3.9 Ga Ar-39/Ar-40 age probably reflects a period of intense meteoroid bompardment which affected the entire inner solar system.

Bogard, D.↗

Geochemistry and petrogenesis of proterozoic mafic dykes in north Kerala, southwestern Indian Shield - Preliminary results

Mafic dyke intrusions occur in three distinct orientations ( NNW-SSE and NW-SE and NE-SW) in north Kerala regions, the southwestern part of the Indian Shield. Dating of two NNW-SSE trending dykes by K-Ar method has yielded Middle Proterozoic ages (ca. 1660 Ma and ca. 1420 Ma respectively). Our initial geochemical results on these dyke rocks (0.65-0.15 wt pct K2O, 0.37-0.38 wt pct P2O5, 3.30-1.00 wt pct TiO2, 11-1 p.p.m. Rb, 250-90 p.p.m. Sr, 230-40 p.p.m. Ba, 160-40 p.p.m. Zr, and 30-10 x chondrite rare earth elemental abundances) indicate a transitional character between abyssal and plateau tholeiites. Petrogenetic modelling suggests that the dyke compositions have been derived by different degrees of partial melting of a heterogenous source mantle. The mantle sources with accessory amphibole and/or garnet, variably enriched in LREE and LIL elements, are compatible with the observed geochemical data.

Radhakrishna, T.↗

Rubidium and cesium in the earth and the moon

The purpose of the study is to provide an alternative perspective on both the mass balance issue and on the issue of secular change in the Rb-Cs ratio in the earth mantle. In particular, it is argued that the apparent secular change in the Rb/Cs ratio may be simply an artifact of alteration of older rocks through weathering and/or metamorphism subsequent to formation. It is also shown that there is not necessarily a need for a hidden, undepleted reservoir, and the consistency of this result with other mass calculations is explored. New methods for estimating the Rb/Cs ratio of the bulk silicate earth are suggested.

Jones, John H.↗

Minor and trace element composition and age of Yukon probable-microtektites

Major, minor, and trace element composition of the candidate micro tektites from Yukon Territory suggest a possible impact site of hydrothermally altered limestone and sand or chert, or possibly a carbonatite. Their REE/chondrite curve is similar in character to, but higher than, shale composites of North America, Australia, and Europe. Relative to these same composites, the Yukon droplets are enriched in Y, F, S, Sr, P, Mn, Mg, and Ca. They are depleted in Rb, Li, Th, Nb, Ti, K, Na, Fe, Si, and Al. Biostratigraphic constraints on the droplets indicate they are Middle to Late Devonian, more likely Middle Devonian, in age.

Boundy-Sanders, S. Q.↗

Rhenium-osmium isotope systematics of Group 2A and Group 4A iron meteorites

We are investigating the Re-Os isotope systematics of two groups of magmatic iron meteorites (2A, 4A) in an attempt to establish precise 'total rock' isochrons by the Re-Os system. The Re-187/Os-187 isotope system is recognized as a method by which the ages of iron meteorites can be directly determined and that can provide information on the timing of FeNi segregation and core formation in planetesimals. The Re-Os isotope system permits the direct absolute dating of the metal phase in iron meteorites. Indirect dating of iron meteorites has been achieved in the past through the Rb-Sr, K-Ar, and most recently, Sm-Nd for silicate inclusions, where present. Relative dating has been obtained directly by extensive studies of the short-lived system Pd-107/Ag-107 for the metal and sulfide phases and indirectly using I-129/Xe-129 in silicate and sulfide inclusions.

Creaser, R. A.↗

Petrologic models of 15388, a unique Apollo 15 mare basalt

Mare basalt 15388, a feldspathic microgabbro from the Apennine Front, is chemically and petrographically distinct from Apollo 15 picritic, olivine-normative (ON), and quartz-normative basalts. The evolved chemistry, coarse texture, lack of olivine, and occurrence of cristobalite in 15388 argue for derivation by a late-stage magmatic process that is significantly removed from parental magma. It either crystallized from a magma evolved from the more mafic Apollo 15 basalts, or it crystallized from a currently unrepresented magma. Rb-Sr and Sm-Nd isotopic systematics yield isochron ages of 3.391 plus or minus 0.036 and 3.42 plus or minus 0.07 Ga, respectively, and epsilon(sub Nd) = 8.6 plus or minus 2.4, which is relatively high for Apollo 15 mare basalts. In contrast to chemical patterns of average Apollo 15 ON basalts and Apollo 15 picritic basalt, 15388 has a strongly positive LREE slope, high Ti, shallower HREE slope and a slightly positive Eu anomaly. These features argue against 15388 evolution by simple olivine fractionation of a parental ON or picritic basalt magma, although olivine is a dominant liquidus phase in both potential parents.

Hughes, S. S.↗

On the composition of neuKREEP: QMD contamination at Apollo 11?

The Group A basalts of Apollo 11 differ in many respects from other high-Ti basalts of the region. Chemically, they are the only high-K (greater than 2000 ppm K) variety of high-Ti basalt and are enriched in incompatible trace elements relative to other basalts from both the Apollo 11 and Apollo 17 sites. In addition, Group A basalts are the youngest of all high-Ti basalts, with an age of 3.56 +/- 0.02 Ga. The cluster of compositions is consistent with the Apollo 11 Group A basalts representing a single flow. Papanastassiou et al. have also indicated the uniqueness of these basalts, based particularly on relatively young Rb-Sr model ages (3.8 - 3.9 Ga). A model for the formation of the Group A basalts was presented by Jerde et al., wherein the Apollo 17 orange volcanic glass is the parent liquid. Fractionation of this composition, coupled with the assimilation of incompatible-element-rich material, results in compositions akin to those of the Apollo 11 Group A basalt population. Orange glass of similar major-element composition is present at the Apollo 11 site as well, although complete trace element analyses are not available. New modelling results using the Apollo 11 orange glass major elements are grossly similar to those obtained using the Apollo 17 orange glass, indicating approximately 30 percent fractionation.

Jerde, Eric A.↗

REE and other trace lithophiles in MAC88177, LEW88280 and LEW88763

In order to investigate the petrogenesis of primitive achondrites, we have carried out precise isotope dilution analyses of REE, Sr, Ba, Rb, K, Li, Ca, Mg, and Fe for three new meteorites: (Lodranites) MAC88177, LEW88280, (Brachinite) LEW88763, together with analyses for Acapulco. Present results are compared with those of other primitive achondrites previously reported by us and others.

Nakamura, N.↗

Fragments of ancient lunar crust: Ferroan noritic anorthosites from the descartes region of the Moon

Noritic anorthosite clasts from breccia 67016 have bulk compositions similar to that of the upper crust of the Moon and petrogenetic affinities with pristine ferroan anorthosites. Rb-Sr and Sm-Nd isotopic compositions of mineral separates from one of these clasts suggest very old (greater than or = 4.4 Ga) ages, but interpretation of these data is complicated by the multi-stage history of the clasts which involved magmatic crystallization, brecciation, subsolidus recrystallization, and sulfide metasomatism. These clasts record some of the earliest events on the Moon, including early crust formation, accretionary bombardment, and degassing of the lunar interior. Modal analyses of these clasts show they are now composed of about 70 percent plagioclase, 28 percent pyroxene, 2 percent troilite, and minor amounts of ilmenite and chromite. No metallic iron, phosphates, or other trace phases were observed. Olivine is very rare, occurring only as relicts within secondary troilite+pyroxene intergrowths which may reflect reaction of olivine with sulfurous vapors. PIXE proton microprobe analyses of the sulfides show that the metasomatism was accompanied by enrichments of Cu, Zn, Ni, Se, and Sb. The clasts have been only mildly shocked since the observed texture was established. Major and minor element mineral compositions are very homogeneous and strikingly similar to those of pristine ferroan anorthosites. Pyroxene compositions indicate equilibration temperatures of 850-900 C. Except for the sulfide and chalcophile element metasomatism, these clasts appear to be essentially monomict and probably represent a noritic member of the ferroan anorthosite suite. Their low Ni contents and Ni/Co ratios are consistent with the interpretation of these clasts as igneous rocks which have escaped mixing with meteoritic material.

Norman, M. D.↗

Fine resolution chronology based on initial Sr-87/Sr-86

It has been recognized that small variations in initial Sr-87/Sr-86 (Sr(sub I)), can provide a fine scale relative chronology for the chemical fractionation of materials with low Rb/Sr from parent reservoirs with high Rb/Sr. Similarly, Sr(sub I), as determined for low Rb/Sr phases in meteorites, may permit a fine resolution chronology of the recrystallization or metamorphism of planetary materials. For the establishment of a primitive Sr-87/Sr-86 chronology, it is important to search for samples with extremely low Rb/Sr for which the measured Sr-87/Sr-86 is below BABI, in which case the primitive nature of the Sr can be directly established. Using the measured Rb/Sr to calculate an initial Sr-87/Sr-86 can introduce substantial uncertainty if the Rb-Sr are disturbed. We report Sr-87/Sr-86 in plagioclase from silicate pebbles from the Vaca Muerta mesosiderite on which we have reported Sm-147-Nd-143 and Ne-142 correlations. For the purpose of cross-calibration with our previous work we have performed extensive new measurements on Angra dos Reis and on anorthite from Moore County, which have very low Rb/Sr and primitive Sr-87/Sr-86.

Stewart, B. W.↗

The Sm-Nd systematics of silicate inclusions in iron meteorites: Results from Caddo (IAB)

The timing of events leading to the formation of silicate-rich and metal-rich regions in planetesimals remains an important problem in the study of planetary formation and differentiation in the early solar system. The IAB irons are especially important as they are considered to represent a magmatic differentiation series. Iron meteorites present a particular challenge for chronological studies, due to the relative paucity of phases serving as hosts for radioactive parent-daughter nuclides. Recent work using the Re-Os system, following on the pioneering work by Herr et al. and Luck and Allegre, appears promising, but investigators up to now have concentrated on whole rock isochrons. Silicate clasts enclosed within iron meteorites can provide information about the chronology and thermal history of irons. Extensive work on Rb-Sr, K-Ar, and I-Xe has been reported on silicate inclusions in iron meteorites. We report the initial results from our Sm-Nd study of an inclusion with the Caddo IAB iron, the first Sm-Nd isotopic study of a silicate clast embedded within an iron meteorite. Our results include measurements of the standard long-lived Sm-147/Nd-143 (tau = 152 AE) system, as well as the shorter-lived SM-146/Nd-142 (tau = 0.149 AE) system, which has been shown to be very useful in deciphering the history of the early solar system. The Caddo silicate clast was described by Palme et al., who kindly provided us with a major part of the inclusion. The inclusion is coarse-grained consisting predominantly of olivine, clinopyroxene, and plagioclase, with lesser amounts of orthopyroxene, Fe-Ni metal, sulfide, and phosphate. The relatively large grain size (up to 3 mm) and 120 degree grain boundaries suggest extensive metamorphism at high temperatures. Based on study of a thin section, there is evidence for metal invading along grain boundaries in some regions of the inclusion, suggesting that the Fe-Ni metal was molten when the silicate clast was incorporated. Metamorphic recrystallization may have occurred during this event.

Stewart, Brian W.↗

Monte Carlo simulations of precise timekeeping in the Milstar communication satellite system

The Milstar communications satellite system will provide secure antijam communication capabilities for DOD operations into the next century. In order to accomplish this task, the Milstar system will employ precise timekeeping on its satellites and at its ground control stations. The constellation will consist of four satellites in geosynchronous orbit, each carrying a set of four rubidium (Rb) atomic clocks. Several times a day, during normal operation, the Mission Control Element (MCE) will collect timing information from the constellation, and after several days use this information to update the time and frequency of the satellite clocks. The MCE will maintain precise time with a cesium (Cs) atomic clock, synchronized to UTC(USNO) via a GPS receiver. We have developed a Monte Carlo simulation of Milstar's space segment timekeeping. The simulation includes the effects of: uplink/downlink time transfer noise; satellite crosslink time transfer noise; satellite diurnal temperature variations; satellite and ground station atomic clock noise; and also quantization limits regarding satellite time and frequency corrections. The Monte Carlo simulation capability has proven to be an invaluable tool in assessing the performance characteristics of various timekeeping algorithms proposed for Milstar, and also in highlighting the timekeeping capabilities of the system. Here, we provide a brief overview of the basic Milstar timekeeping architecture as it is presently envisioned. We then describe the Monte Carlo simulation of space segment timekeeping, and provide examples of the simulation's efficacy in resolving timekeeping issues.

Camparo, James C.↗

Mineralogy and Ar-39 - Ar-40 of an old pristine basalt: Thermal history of the HED parent body

Previous investigations of mineral chemistry and Rb-Sr and Sm-Nd ages indicated that clast,84 from eucrite Yamato 75011 had preserved the pristine nature of its initial crystallization during an early stage of the HED parent body. Microscale mineralogy and Ar-39-Ar-40 ages of this clast, however, revealed local disturbance of microtextures and partially reset ages. This evidence suggests that, in addition to initial crystallization and rapid cooling, the Y75011,84 clast experienced shock deformation, reheating of short duration at higher temperature, and brecciation. These characteristics suggest two or more impact events. Fe-rich olivine filling fractures in pyroxene may have been introduced during the accompanying shock fracturing. The inferred Ar-39-Ar-40 degassing ages for Y75011 matrix and clast, 84 are 3.94 +/- 0.04 Ga and 3.98 +/- 0.03 Ga, respectively. The suggested degassing age for a clast from Y790020, believed to be paired with Y75011, is approximately 4.03 Ga, but could be younger. We consider it likely that all three samples experienced a common degassing event 3.95 +/- 0.05 Ga ago, but we cannot rule out two or more events spaced over a approximately 0.1 Ga interval. Higher temperature extractions of the two clast samples show significantly older apparent ages up to approximately 4.5 Ga and suggest that the time/temperature regime of this event was not sufficient to degas Ar totally. Most likely, the K-Ar ages were reset by thermal metamorphism associated with one or more impact events associated with shock fracturing, formation of Fe-rich olivine veins, and/or meteorite brecciation. The pyroxene annealing that commonly occurs in many eucrites is likely to be a much earlier process than the impact-produced textural changes and reset K-Ar ages observed in these meteorites. The existence of mineralogical and chronological evidence for metamorphism in an otherwise pristine eucrite suggests that the HED parent body experienced an extensive degree of early cratering.

Takeda, Hiroshi↗