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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Comparing the Purity of Rolled versus Evaporated Lithium Metal Films Using X-ray Microtomography

Here, we present a comparison of lithium metal films produced via rolling and thermal evaporation using synchrotron hard X-ray microtomography. In past studies of rolled lithium metal foils, a large number of C, O, and N impurities were found and identified as the key cause for failure in lithium metal cells. In this comparison, the X-ray tomography data show that the evaporated lithium metal films have an average impurity concentration of 19 particles/mm3 in comparison to 1350 particles/mm3 in the rolled lithium metal. An analysis of the inner substrate/lithium interface and outer lithium surface of the thermally evaporated film shows a much greater concentration of impurities at these interfaces, further emphasizing the importance of interface engineering in producing high-quality lithium metal batteries. Furthermore, we show that, if surface contamination can be avoided, it is possible to obtain lithium films with no impurities detectable by synchrotron hard X-ray tomography.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2011

The dislocation density and twin-boundary frequency determined by X-ray peak profile analysis in cold rolled magnetron-sputter deposited nanotwinned copper

The dislocation density and the average twin boundary frequency is determined quantitatively in as-deposited and cold-rolled nanotwinned Cu thin films by high-resolution X-ray line profile analysis. After cold-rolling the dislocation density increases considerably, whereas the twin boundary frequency decreases only slightly. The physical parameters of the substructure provided by the quantitative X-ray analysis are in agreement with earlier transmission electron microscopy observations. The flow stress of the as-deposited and the cold-rolled films is directly correlated with the average thickness of twin lamellae and the dislocation density by taking into account the Hall-Petch and Taylor type strengthening mechanisms.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Kinetic Monte Carlo modeling of the efficiency roll-off in a multilayer white organic light-emitting device

Triplet-triplet annihilation (TTA) and triplet-polaron quenching (TPQ) in organic light-emitting devices (OLEDs) lead to a roll-off of the internal quantum efficiency (IQE) with increasing current density J. We employ a kinetic Monte Carlo modeling study to analyze the measured IQE and color balance as a function of J in a multilayer hybrid white OLED that combines fluorescent blue with phosphorescent green and red emission. We investigate two models for TTA and TPQ involving the phosphorescent green and red emitters: short-range nearest-neighbor quenching and long-range Förster-type quenching. Short-range quenching predicts roll-off to occur at much higher J than measured. Taking long-range quenching with Förster radii for TTA and TPQ equal to twice the Förster radii for exciton transfer leads to a fair description of the measured IQE-J curve, with the major contribution to the roll-off coming from TPQ. The measured decrease of the ratio of phosphorescent to fluorescent component of the emitted light with increasing J is correctly predicted. A proper description of the J-dependence of the ratio of red and green phosphorescent emission needs further model refinements.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

Low amplified spontaneous emission threshold and suppression of electroluminescence efficiency roll-off in layers doped with ter(9,9′-spirobifluorene)

We demonstrate that ter(9,9′-spirobifluorene) (TSBF) doped in a host matrix layer of 4,4′-bis(carbazol-9-yl)biphenyl (CBP) shows a low amplified spontaneous emission (ASE) threshold (E{sub th} = 1.0 μJ cm{sup −2}) and suppressed electroluminescence efficiency roll-off at high current densities (no roll-off up to 100 mA cm{sup −2}). One origin of the low ASE threshold is that the TSBF-doped CBP layer possesses a very large radiative decay constant (k{sub r} = 1.1 × 10{sup 9 }s{sup −1}). Singlet–triplet annihilation is almost suppressed in the TSBF-doped CBP layer, which can be ascribed to the small overlap between the emission and triplet absorption of TSBF. Also, the small energy level difference between TSBF and CBP minimizes carrier trapping in TSBF, leading to the suppression of singlet–polaron annihilation. TSBF showed one of the lowest E{sub th} and the most suppressed efficiency roll-off among organic laser dyes investigated in this study and, therefore, is believed to be a promising candidate to realize electrically pumped organic semiconductor laser diodes in the future.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2011

Extremal trajectories and the asymptotics of the Maxwell time in the problem of the optimal rolling of a sphere on a plane

The problem of a sphere rolling on a plane without twisting or slipping is considered. It is required to roll the sphere from one contact configuration to another so that the length of the curve described by the contact point is minimal. A parametrization of extremal trajectories is obtained. The asymptotics of extremal trajectories and the behaviour of the Maxwell time for the rolling of a sphere over sinusoids of small amplitude are studied; for such trajectories estimates for the so-called cut time are obtained. Bibliography: 21 titles.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2025

Identifying rolling resistance and air resistance simultaneously for an electric truck

Accurately estimating rolling and air resistance is essential for predicting the energy consumption of vehicles. This study presents a field-based approach using a rolldown test to simultaneously determine rolling and air resistance coefficients. Unlike prior methods that frequently used simulations or models, we employ a goal programming methodology to improve precision and evaluate the actual vehicle and environmental conditions. Our methodology was tested using a Class 8 Freightliner eCascadia on a surveyed road section, ensuring controlled conditions for data collection. By analyzing the time–velocity relationship across multiple test runs, we derived resistance coefficients for both loaded and unloaded conditions. The study confirms that rolling resistance is largely independent of velocity at low speeds but exhibits a nonlinear dependency at higher speeds. Additionally, road surface conditions, tire condition, axle configuration, aerodynamic properties, and weather conditions significantly impact resistance values, emphasizing the need for real-world testing rather than relying solely on standardized projections. Our results align with existing literature while demonstrating the efficacy of the goal programming approach in refining resistance estimates. This work contributes to improved vehicle energy modeling, offering practical insights for fleet operators and policymakers seeking accurate energy consumption predictions for electric trucks operating under varying environmental conditions.

47 OTHER INSTRUMENTATION↗
DOE OSTI2016

Correlation of filament distortion and RRR degradation in drawn and rolled PIT and RRP Nb 3 Sn wires

PIT and RRP® Nb3Sn strands are being developed for high field accelerator magnet upgrades for the high luminosity LHC. Here we report a quantitative study of the shape and position of PIT filaments and RRP® sub-elements after rolling lengths of unreacted PIT and RRP® round wires to simulate cabling deformation. In the as-drawn condition, filament shape distortion occurs preferentially in the outer ring filaments. By contrast, rolling induces non-uniform shear bands that generate greater distortion of inner ring filaments. By making a full digitization of the shapes of all filaments, we find that a critical distortion occurs for thickness reductions between 10% and 20% when filament shapes in inner filament rings heavily degrade, especially in the vicinity of the strong 45° shear bands imposed by the rolling. It is well known that maintaining diffusion barrier integrity is vital to retaining adequate RRR in the stabilizing copper needed for magnet stability. Diffusion barrier breaks occur preferentially in these distorted inner filaments and drive local Sn leakage during reaction, increasing RRR degradation.

36 MATERIALS SCIENCE↗
DOE OSTI2011

Can slow roll inflation induce relevant helical magnetic fields?

We study the generation of helical magnetic fields during single field inflation induced by an axial coupling of the electromagnetic field to the inflaton. During slow roll inflation, we find that such a coupling always leads to a blue spectrum with B{sup 2}(k)∝k, as long as the theory is treated perturbatively. The magnetic energy density at the end of inflation is found to be typically too small to backreact on the background dynamics of the inflaton. We also show that a short deviation from slow roll does not result in strong modifications to the shape of the spectrum. We calculate the evolution of the correlation length and the field amplitude during the inverse cascade and viscous damping of the helical magnetic field in the radiation era after inflation. We conclude that except for low scale inflation with very strong coupling, the magnetic fields generated by such an axial coupling in single field slow roll inflation with perturbative coupling to the inflaton are too weak to provide the seeds for the observed fields in galaxies and clusters.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

Inflationary signatures of single-field models beyond slow-roll

If the expansion of the early Universe was not close to de Sitter, the statistical imprints of the primordial density perturbation on the cosmic microwave background can be quite different from those derived in slow-roll inflation. In this paper we study the inflationary signatures of all single-field models which are free of ghost-like instabilities. We allow for a rapid change of the Hubble parameter and the speed of sound of scalar fluctuations, in a way that is compatible with a nearly scale-invariant spectrum of perturbations, as supported by current cosmological observations. Our results rely on the scale-invariant approximation, which is different from the standard slow-roll approximation. We obtain the propagator of scalar fluctuations and compute the bispectrum, keeping next-order corrections proportional to the deviation of the spectral index from unity. These theories offer an explicit example where the shape and scale-dependences of the bispectrum are highly non-trivial whenever slow-roll is not a good approximation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

BICEP2 implications for single-field slow-roll inflation revisited

It is generally believed that in single-field slow-roll inflation, a large tensor-to-scalar ratio r > 0.1 requires inflaton field values close to or above the Planck scale. Recently, it has been claimed that r > 0.15 can be achieved with much smaller inflaton field values Δφ < M{sub Pl}/10. We show that in single-field slow-roll inflation, it is impossible to reconcile r > 0.1 with such small field values, independently of the form of the potential, and that the recent claim to the contrary is based on an invalid approximation. We conclude that the result of the BICEP2 measurement of r > 0.1, if confirmed, truly has the potential to rule out small-field models of single-field slow-roll inflation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Non-Gaussianity in two-field inflation beyond the slow-roll approximation

We use the long-wavelength formalism to investigate the level of bispectral non-Gaussianity produced in two-field inflation models with standard kinetic terms. Even though the Planck satellite has so far not detected any primordial non-Gaussianity, it has tightened the constraints significantly, and it is important to better understand what regions of inflation model space have been ruled out, as well as prepare for the next generation of experiments that might reach the important milestone of Δ f {sub NL}{sup local}=1. We derive an alternative formulation of the previously derived integral expression for f {sub NL}, which makes it easier to physically interpret the result and see which types of potentials can produce large non-Gaussianity. We apply this to the case of a sum potential and show that it is very difficult to satisfy simultaneously the conditions for a large f {sub NL} and the observational constraints on the spectral index n {sub s} . In the case of the sum of two monomial potentials and a constant we explicitly show in which small region of parameter space this is possible, and we show how to construct such a model. Finally, the new general expression for f {sub NL} also allows us to prove that for the sum potential the explicit expressions derived within the slow-roll approximation remain valid even when the slow-roll approximation is broken during the turn of the field trajectory (as long as only the ε slow-roll parameter remains small).

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Modeling the formation of double rolls from heterogeneously patterned gels

Both stimuli-responsive gels and growing biological tissue can undergo pronounced morphological transitions from two-dimensional (2D) layers into 3D geometries. We derive an analytical model that allows us to quantitatively predict the features of 2D-to-3D shape changes in polymer gels that encompasses different degrees of swelling within the sample. We analyze a particular configuration that emerges from a flat rectangular gel that is divided into two strips (bistrips), where each strip is swollen to a different extent in solution. The final configuration yields double rolls that display a narrow transition layer between two cylinders of constant radii. To characterize the rolls' shapes, we modify the theory of thin incompatible elastic sheets to account for the Flory-Huggins interaction between the gel and the solvent. This modification allows us to derive analytical expressions for the radii, the amplitudes, and the length of the transition layer within a given roll. Furthermore, our predictions agree quantitatively with available experimental data. In addition, we carry out numerical simulations that account for the complete nonlinear behavior of the gel and show good agreement between the analytical predictions and the numerical results. Our solution sheds light on a stress focusing pattern that forms at the border between two dissimilar soft materials. Moreover, models that provide quantitative predictions on the final morphology in such heterogeneously swelling hydrogels are useful for understanding growth patterns in biology as well as accurately tailoring the structure of gels for various technological applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Shear Thickening and Jamming of Dense Suspensions: The "Roll" of Friction.

Particle-based simulations of discontinuous shear thickening (DST) and shear jamming (SJ) suspensions are used to study the role of stress-activated constraints, with an emphasis on resistance to gearlike rolling. Rolling friction decreases the volume fraction required for DST and SJ, in quantitative agreement with real-life suspensions with adhesive surface chemistries and "rough" particle shapes. It sets a distinct structure of the frictional force network compared to only sliding friction, and from a dynamical perspective leads to an increase in the velocity correlation length, in part responsible for the increased viscosity. The physics of rolling friction is thus a key element in achieving a comprehensive understanding of strongly shear-thickening materials.

Singh, Abhinendra↗
DOE OSTI2023

Residual strain orientation in rolled titanium determined with synchrotron X-ray Laue microdiffraction

Previously, synchrotron X-ray Laue microdiffraction has been used to measure the magnitudes of residual strain in materials. Recently the method was advanced to determine the orientation of the strain ellipsoid and applied to naturally deformed quartzites; however, the deformation history of these quartzites is ambiguous due to their natural origin. Here, in this study, synchrotron X-ray Laue microdiffraction (µXRD) is used to measure the residual strain for the first time in a sample with known stress history, rolled titanium. A deviatoric strain tensor is calculated from each Laue diffraction image collected with two µXRD scans of a rolled titanium sheet in different sample orientations. The principal strain axes are calculated using an eigen decomposition of the deviatoric strain tensors. The results show that the principal axis of compression is aligned with the normal direction of the titanium sheet, and the principal axis of extension is aligned with the rolling direction. Pole figures are used to represent the 3D distribution of residual strain axes.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Rolling Root Mean Square Based Multimodal Anomaly Detection for Real Time Monitoring of Smart Grid

Reliable real-time monitoring is valuable for maintaining the operational integrity of modern electrical smart grids. Deployment of heterogeneous sensing technologies in substations has enabled high-resolution, multichannel waveform monitoring, but also introduces challenges for anomaly detection due to noise, baseline drift, and modality-dependent signal characteristics. In this work, we present a computationally efficient unsupervised method for multimodal event detection based on Rolling Root Mean Square based Event Detection (RRMSED). The method is developed using in-house, field deployed sensors collecting data at a utility substation. The sensing system comprises voltage and current sensors, triaxial accelerometers, and magnetometers, collectively capturing electrical, vibrational, and magnetic waveform measurements at high temporal resolution. RRMSED operates by extracting rolling RMS energy features and their first-order temporal differences from consecutive waveform segments for each channel and then applying channel-specific statistical thresholds learned from historical data. A persistence-based exceedance logic is employed to robustly identify transient events while suppressing impulsive noise, and to provide precise temporal localization with high resolution. The framework is designed for continuous server-side operation and can be deployed in real time without requiring complex models. Experiments on simulated waveform data with known ground truth demonstrate low false positive (FP) and false negative (FN) rates. Application to real substation data shows RRMSED to identify events that are not captured by conventional monitoring indicators including fast transient detection algorithm currently deployed in the system. These results indicate that rolling RMS based features provide an effective and practical basis for real-time multimodal event detection in smart-grid substations.

Mukherjee, Subrata [ORNL] (ORCID:0000000309930338)↗
DOE OSTI2020

PHOTO‐SENSITIVE LEAF ROLLING 1 encodes a polygalacturonase that modifies cell wall structure and drought tolerance in rice

Summary The biosynthesis and modification of cell wall composition and structure are controlled by hundreds of enzymes and have a direct consequence on plant growth and development. However, the majority of these enzymes has not been functionally characterised. Rice mutants with leaf‐rolling phenotypes were screened in a field. Phenotypic analysis under controlled conditions was performed for the selected mutant and the relevant gene was identified by map‐based cloning. Cell wall composition was analysed by glycome profiling assay. We identified a photo‐sensitive leaf rolling 1 ( psl1 ) mutant with ‘napping’ (midday depression of photosynthesis) phenotype and reduced growth. The PSL1 gene encodes a cell wall‐localised polygalacturonase (PG), a pectin‐degrading enzyme. psl1 with a 260‐bp deletion in its gene displayed leaf rolling in response to high light intensity and/or low humidity. Biochemical assays revealed PG activity of recombinant PSL1 protein. Significant modifications to cell wall composition in the psl1 mutant compared with the wild‐type plants were identified. Such modifications enhanced drought tolerance of the mutant plants by reducing water loss under osmotic stress and drought conditions. Taken together, PSL1 functions as a PG that modifies cell wall biosynthesis, plant development and drought tolerance in rice.

Zhang, Guangheng↗
DOE OSTI2022

Effects of Water Contamination on Micropitting and Rolling Contact Fatigue of Bearing Steels

Abstract In this research, the effects of water contamination in oil were investigated on two kinds of failures that occur in bearing steel: micropitting and rolling contact fatigue. Whereas the presence of water in the oil had little effect on the generation of surface wear in these experiments, increases in the occurrences of micropitting and rolling contact fatigue were observed due to the presence of either dissolved or free water in lubricants. Additionally, the presence of white etching matter at crack interfaces was observed and evaluated. The experimental results showed that water content can be considered as a significant factor that accelerates the formation of micropitting and fatigue cracks in rolling bearings.

Engineering↗
DOE OSTI2013

Roll-up of validation results to a target application.

Suites of experiments are preformed over a validation hierarchy to test computational simulation models for complex applications. Experiments within the hierarchy can be performed at different conditions and configurations than those for an intended application, with each experiment testing only part of the physics relevant for the application. The purpose of the present work is to develop methodology to roll-up validation results to an application, and to assess the impact the validation hierarchy design has on the roll-up results. The roll-up is accomplished through the development of a meta-model that relates validation measurements throughout a hierarchy to the desired response quantities for the target application. The meta-model is developed using the computation simulation models for the experiments and the application. The meta-model approach is applied to a series of example transport problems that represent complete and incomplete coverage of the physics of the target application by the validation experiments.

Hills, Richard Guy↗