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At least 451 records · Page 25

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NASA NTRS1989

Influence of gap states on the nonresonant second hyperpolarizabilities of conjugated organic polymers

The presence of conjugation and substitution defects introduces gap states in finite polyenes that are shown to influence the size and sign of the second molecular hyperpolarizability (SMH). Using a one-electron tight-binding model, the dependence of SMH on the defect-state occupancy and energy in finite polyenes is calculated. Defects can cause a significant decrease or enhancement of SMH by impeding charge delocalization or by creating partly filled bands (mimicking the one-band limit), respectively. Concomitant sign changes in SMH are predicted. Calculation results suggest strategies for designing molecules that can be either photochemically or electrochemically switched between states with considerably different SMHs.

Beratan, David N.↗

NASA NTRS1990

Cleaning With Supercritical CO2

Supercritical carbon dioxide effective industrial cleaning agent. Replaces conventional halocarbon solvents for degreasing parts becoming coated with oil during such manufacturing procedures as forming and machining. Presents none of environmental threats and occupational hazards associated with halocarbon solvents. Spontaneously evaporates after use and leaves no waste to be disposed of. Evaporated gas readily collected and recycled.

Herzstock, James J.↗

NASA NTRS1988

A menu of self-administered microcomputer-based neurotoxicology tests

This study examined the feasibility of repeated self-administration of a newly developed battery of mental acuity tests. Researchers developed this battery to be used to screen the fitness for duty of persons in at-risk occupations (astronauts, race car drivers), or those who may be exposed to environmental stress, toxic agents, or disease. The menu under study contained cognitive and motor tests implemented on a portable microcomputer including: a five-test core battery, lasting six minutes, which had demonstrable reliabilities and stability from several previous repeated-measures studies, and also 13 new tests, lasting 42 minutes, which had appeared in other batteries but had not yet been evaluated for repeated-measures implementation in this medium. Sixteen subjects self-administered the battery over 10 repeated sessions. The hardware performed well throughout the study and the tests appeared to be easily self-administered. Stabilities and reliabilities of the test from the core battery were comparable to those obtained previously under more controlled experimental conditions. Analyses of metric properties of the remaining 13 tests produced eight additional tests with satisfactory properties. Although the average retest reliability was high, cross-correlations between tests were low, indicating factorial richness. The menu can be used to form batteries of flexible total testing time which are likely to tap different mental processes and functions.

Kennedy, Robert S.↗

NASA NTRS1989

An investigation of a mathematical model of an optically pumped Ti(3+):Al2O3 laser system

During the last several years, solid state lasers were developed that have the potential for meeting rigorous performance requirements for space-based remote sensing of the atmosphere. In order to design a stable and efficient laser and to understand the effect on laser output of changes in the physical and design parameters, an understanding of the development of the dynamical processes of the laser is necessary. Typically, the dynamical processes in a laser system are investigated via rate equations describing the evolution of the occupancy in the electronic levels and of the photon density in the laser cavity. There are two approaches to this type of study. Most often, for the sake of simplicity, the spatial variations of the dynamic variables in the laser system are disregarded and the mathematical model consists of a system of first order nonlinear ordinary differential equations (ODE). The second approach is to take into account both spatial and temporal variations in the dynamic variables in the laser cavity. The resulting model consists of a first order semilinear system of partial differential equations (PDE). The model which was studied was studied was generic in the sense that it was a four-level laser system, but the parameters used in the numerical study were specific to Titanium-doped sapphire. For simplicity, a constant, spatially uniform pumping scheme was considered. In addition, a simplification of the model was made so that it treats a single lasing wavelength with a narrow bandwidth. The purpose was to investigate both versions of the mathematical model and to determine whether the numerical solutions are similar both qualitatively and quantitatively. The systems of ordinary differential equations were solved numerically using a Runge-Kutta-Fehlberg algorithm which was very efficient for typical values of the physical parameters. A numerical scheme, based on the Modified Euler method, for computing solutions to the system of partial differential equations was developed and implemented. The PDE model was solved numerically at the expense of greatly increased computer time.

Roberts, Lila F.↗

NASA NTRS1990

Performance of Ho:YAG as a function of temperature

The performance of two multiply doped Ho:YAG lasers has been characterized as a function of the laser rod temperature. From the experimental results, the dependence of the slope efficiency and threshold on temperature has been extracted. Threshold can be correlated with the occupation of the lower laser level. Implications on the optimum operating temperature are discussed.

Barnes, Norman P.↗

NASA NTRS1988

Fe-57 and Sn-119 Moessbauer study of La2CuO(4-y), YBa2Cu3O(7-y) and SmBa2Cu3O(7-y)

Moessbauer studies reveal antiferromagnetic order in doped La2CuO(4-7): at 77 K, H = 476 kOe at Fe-57 and H is less that 10 kOe at Sn-119. Split-source and conventional absorber experiments on RBa2Cu3O(7-y) (R = Y, Sm) are consistent with occupation of 3 sites by Fe-57, the relative population depending on sample preparation and Fe concentration.

Jha, S.↗

NASA NTRS1990

Infrared spectra and crystal chemistry of scapolites - Implications for Martian mineralogy

Near-IR and mid-IR spectra of 27 scapolites with a wide range of compositions were compared to the features of the 2.35-micron band absorption system that was recently discovered in reflectance spectra of Mars. Results suggest that the 2.36-micron features are due to the presence of small amounts (about 0.5 wt pct each) of HCO3(-) and HSO4(-) in the anion sites of a scapolite. Five of the scapolites (including two meionite and three mizzonite samples) showed absorption features unique to HCO3(-) and HSO4(-). It was determined that the features of the 2.36-micron-centered system are produced by a disordered anion site occupancy and that the band intensity also depends on the HCO3(-)/HSO4(-) ratio. It was found (Clark et al., 1990) that HCO3(-) and HSO4(-) bearing minerals other than scapolites do not exhibit spectral features of the scapolite.

Swayze, Gregg A.↗

NASA NTRS1990

Transition density of one-dimensional diffusion with discontinuous drift

The transition density of a one-dimensional diffusion process with a discontinuous drift coefficient is studied. A probabilistic representation of the transition density is given, illustrating the close connections between discontinuities of the drift and Brownian local times. In addition, some explicit results are obtained based on the trivariate density of Brownian motion, its occupation, and local times.

Zhang, Weijian↗

NASA NTRS1990

Surface electrons in inverted layers of p-HgCdTe

Anodic oxide passivation of p-type HgCdTe generates an inversion layer. Extremely high Hall mobility data for electrons in this layer indicated the presence of a two-dimensional electron gas. This is verified by use of the Shubnikov-de Haas effect from 1.45 to 4.15 K. Data are extracted utilizing a numerical second derivative of dc measurement. Three sub-bands are detected. Their relative occupancies are in excellent agreement with theory and with experimental results obtained on anodic oxide as accumulation layers of n-type HgCdTe. The effective mass derived is comparable to what was expected.

Schacham, Samuel E.↗

NASA NTRS1989

A successful intervention program for high ability minority students

Among professional occupations in the United States, non-Asian minorities are least represented in science and engineering fields. The Bureau of Labor Statistics predicts that over the next decade, civilian employment of scientists and engineers has the potential to grow by 40 percent. Furthermore, projections for the year 2000 indicate that 100,000 fewer B.S. and B.A. degrees will be awarded than were awarded in 1984. The latter projection takes into consideration the overall declining proportion of all 18 year old college students. Within this shrinking pool of 18 year old potential college students will be an increasing proportion of Blacks and Hispanics. In order to change the educational patterns for minority youth, an intense look at the factors that affect the science and mathematics performance of minorities. Furthermore, the work of programs that are successful at producing minority scientists and engineers must be examined and documented with the intent of replicating these programs. The fundamental concern at this time appears to be the quality of precollege experience because research has shown that lack of precollege preparation is the single most important cause of underrepresentation of minorities in science and engineering careers. For many years, intervention programs have attempted to improve the quality of the minority precollege experience by latter year intervention in grades eleven and twelve. Later efforts, such as this one, have concentrated on earlier years. The effectiveness of intervention programs is widely accepted but not rigorously documented. The mechanisms these programs have developed need to be identified and their potential for broader use evaluated. The ultimate goal of such studies would be to provide the different educational communities with a set of proven cost-effective state of the art mechanisms designed to increase participation and success of minority students in science and mathematics-related courses. One such intervention program is the Saturday Academy program for high ability minority students in the Washington, D.C. area. A description of the Saturday Academy is provided with the intent of making it available to personnel who are considering the development of similar projects. The effect of participation in the program on high school graduate rates, college enrollment, and choice of quantitative major is examined.

Coleman, Winson R.↗

NASA NTRS1990

The Physical/Chemical Closed-Loop Life Support Research Project

The various elements of the Physical/Chemical Closed-Loop Life Support Research Project (P/C CLLS) are described including both those currently funded and those planned for implementation at ARC and other participating NASA field centers. The plan addresses the entire range of regenerative life support for Space Exploration Initiative mission needs, and focuses initially on achieving technology readiness for the Initial Lunar Outpost by 1995-97. Project elements include water reclamation, air revitalization, solid waste management, thermal and systems control, and systems integration. Current analysis estimates that each occupant of a space habitat will require a total of 32 kg/day of supplies to live and operate comfortably, while an ideal P/C CLLS system capable of 100 percent reclamation of air and water, but excluding recycling of solid wastes or foods, will reduce this requirement to 3.4 kg/day.

Bilardo, Vincent J., Jr.↗

NASA NTRS1989

Some unsolved problems in evolutionary dynamics in the solar system

Several unsolved problems in the evolutionary histories leading to current dynamical configurations of the planets and their systems of satellites are discussed. These include the possibilities of rather tight constraints on the primordial rotation states of Mercury and Venus and the stabilizing mechanism for the latter's retrograde spin, a brief mention of the problem of origin of the moons of earth and Mars, the excessive heat flow from Jupiter's satellite Io which is not compatible with an otherwise self-consistent model of origin of the Laplace three-body libration, the mechanism for the long history of resurfacing of Saturn's satellite Enceladus and the possibly short lifetime of the A ring and the mechanisms for resurfacing the satellites of Uranus, especially Ariel, if the high stability of the mean motion orbital resonances at the 2/1 commensurability involving Ariel and Umbriel precludes a long term occupancy of the resonance. Finally, excessive times of accumulation of the outer planets in current models may possibly be reducible from the effects of nebular gas drag.

Peale, S. J.↗

NASA NTRS1990

Multiple manipulator control from orbiter for Space Station assembly

This paper discusses the assembly process of the Space Station Freedom. It is shown that the assembly of the Space Station will require 29 flights of the Space Shuttle Orbiter: six shuttle flights during the initial assembly stage when the Space Station will not have sufficient life-support capability; seven more flights before the Station will support human occupation independent of the presence of the Space Shuttle; and 16 more flights for achieving full operational capability. The shuttle systems to be used in the Space Station assembly are described together with the results of simulation and analyses. Special attention is given to the Space Shuttle Remote Manipulator System which will be available on all Shuttle flights to support the Space Station assembly.

Price, Charles R.↗

NASA NTRS1991

Formation of cosmic structure by Doppler instability

A new mechanism is described which can create an instability in homogeneous gaseous matter at very low density. When an isotropic background radiation field has, near an electronic resonance, a spectral feature for which photon occupation number increases with frequency, moving atoms increase their speed by taking energy from the photon distribution. In a cosmological setting, a sufficiently intense spectral feature can interact with neutral atomic gas, after recombination, to generate protogalactic perturbations of the scale and magnitude needed to explain large-scale cosmic structure.

Hogan, Craig J.↗

NASA NTRS1992

Tailoring Laminates For Protection Against Projectiles

Fiber/matrix composite laminates developed to protect military land vehicles against projectiles and spacecraft against impacts by micrometeroids. Although types, sizes, and velocities of expected incident objects differ between terrestrial and outer-space cases, general protection problems and solutions exhibit some common features. Configurations of fibers and matrices optimized with respect to protection, bulk, and weight, to obtain shield that breaks rapidly moving incident object into harmless smaller, more-slowly-moving pieces, containing debris, vaporizes debris, and/or otherwise absorbs kinetic energy of object to prevent harm to vehicle and occupants.

Gassner, John J.↗

NASA NTRS1991

Programmable digital modem

The design of the Programmable Digital Modem (PDM) is outlined. The PDM will be capable of operating with numerous modulation techniques including: 2-, 4-, 8- and 16-ary phase shift keying (PSK), minimum shift keying (MSK), and 16-ary quadrature amplitude modulation (QAM), with spectral occupancy from 1.2x to 2x the data symbol rate. It will also be programmable for transmission rates ranging from 2.34 to 300 Mbit/s, where the maximum symbol rate is 75 Msymbol/s. Furthermore, these parameters will be executable in independent burst, dependent burst, or continuous mode. In dependent burst mode the carrier and clock oscillator sources are common from burst to burst. To achieve as broad a set of requirements as these, it is clear that the essential signal processing must be digital. In addition, to avoid hardware changes when the operational parameters are changed, a fixed interface to an analog intermediate frequency (IF) is necessary for transmission; and, common system level architectures are necessary for the modulator and demodulator. Lastly, to minimize size and power, as much of the design as possible will be implemented with application specific integrated circuit (ASIC) chips.

Poklemba, John J.↗

NASA NTRS1992

Runway exit designs for capacity improvement demonstrations. Phase 2: Computer model development

The development is described of a computer simulation/optimization model to: (1) estimate the optimal locations of existing and proposed runway turnoffs; and (2) estimate the geometric design requirements associated with newly developed high speed turnoffs. The model described, named REDIM 2.0, represents a stand alone application to be used by airport planners, designers, and researchers alike to estimate optimal turnoff locations. The main procedures are described in detail which are implemented in the software package and possible applications are illustrated when using 6 major runway scenarios. The main output of the computer program is the estimation of the weighted average runway occupancy time for a user defined aircraft population. Also, the location and geometric characteristics of each turnoff are provided to the user.

Trani, A. A.↗

NASA NTRS1991

The electronic Hamiltonian for cuprates

A realistic many-body Hamiltonian for the cuprate superconductors should include both copper d and oxygen p states, hopping matrix elements between them, and Coulomb energies, both on-site and inter-site. We have developed a novel computational scheme for deriving the relevant parameters ab initio from a constrained occupation local density functional. The scheme includes numerical calculation of appropriate Wannier functions for the copper and oxygen states. Explicit parameter values are given for La2CuO4. These parameters are generally consistent with other estimates and with the observed superexchange energy. Secondly, we address whether this complicated multi-band Hamiltonian can be reduced to a simpler one with fewer basis states per unit cell. We propose a mapping onto a new two-band effective Hamiltonian with one copper d and one oxygen p derived state per unit cell. This mapping takes into account the large oxygen-oxygen hopping given by the ab initio calculations.

Annett, James F.↗