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At least 451 records · Page 25

Pyrotechnic shock measurement and data analysis requirements

An investigation of laboratory measurement and analysis of pyrotechnic shock is described which was prompted when two separate facilities produced discrepant pyrotechnic-shock data while testing Mariner Jupiter/Saturn 1977 spacecraft hardware. Both testing facilities are thoroughly examined to find a possible cause for the discrepancies, and it is noted that one facility incorporated an FM tape recorder operating at 60 in./sec with a frequency response of 20 kHz while the other incorporated a tape recorder operating at 120 in./sec with a frequency response of 80 kHz. It is found that the discrepancies were a direct result of the inadequate recording frequency response of the tape recorders. Other factors involved in obtaining more accurate data are discussed.

Albers, L.↗

Coastal Atmosphere and Sea Time Series (CoASTS)

The Coastal Atmosphere and Sea Time Series (CoASTS) Project aimed at supporting ocean color research and applications, from 1995 up to the time of publication of this document, has ensured the collection of a comprehensive atmospheric and marine data set from an oceanographic tower located in the northern Adriatic Sea. The instruments and the measurement methodologies used to gather quantities relevant for bio-optical modeling and for the calibration and validation of ocean color sensors, are described. Particular emphasis is placed on four items: (1) the evaluation of perturbation effects in radiometric data (i.e., tower-shading, instrument self-shading, and bottom effects); (2) the intercomparison of seawater absorption coefficients from in situ measurements and from laboratory spectrometric analysis on discrete samples; (3) the intercomparison of two filter techniques for in vivo measurement of particulate absorption coefficients; and (4) the analysis of repeatability and reproducibility of the most relevant laboratory measurements carried out on seawater samples (i.e., particulate and yellow substance absorption coefficients, and pigment and total suspended matter concentrations). Sample data are also presented and discussed to illustrate the typical features characterizing the CoASTS measurement site in view of supporting the suitability of the CoASTS data set for bio-optical modeling and ocean color calibration and validation.

Hooker, Stanford B.↗

Hydrogen Energy Storage (HES) and Power-to-Gas Economic Analysis; NREL (National Renewable Energy Laboratory)

This presentation summarizes opportunities for hydrogen energy storage and power-to-gas and presents the results of a market analysis performed by the National Renewable Energy Laboratory to quantify the value of energy storage. Hydrogen energy storage and power-to-gas systems have the ability to integrate multiple energy sectors including electricity, transportation, and industrial. On account of the flexibility of hydrogen systems, there are a variety of potential system configurations. Each configuration will provide different value to the owner, customers and grid system operator. This presentation provides an economic comparison of hydrogen storage, power-to-gas and conventional storage systems. The total cost is compared to the revenue with participation in a variety of markets to assess the economic competitiveness. It is found that the sale of hydrogen for transportation or industrial use greatly increases competitiveness. Electrolyzers operating as demand response devices (i.e., selling hydrogen and grid services) are economically competitive, while hydrogen storage that inputs electricity and outputs only electricity have an unfavorable business case. Additionally, tighter integration with the grid provides greater revenue (e.g., energy, ancillary service and capacity markets are explored). Lastly, additional hours of storage capacity is not necessarily more competitive in current energy and ancillary service markets and electricity markets will require new mechanisms to appropriately compensate long duration storage devices.

30 DIRECT ENERGY CONVERSION↗

Human Readiness Levels in the Systems Engineering Process at Sandia National Laboratories

The Systems Analysis & Decision Support group (2150) at Sandia National Laboratories (SNL) led a study from 2015 to 2017 to investigate the utility of various options to achieve systematic and comprehensive incorporation of the human component of a system throughout the product lifecycle. Although technology readiness levels (TRL) are widely used in the systems engineering process to address technical maturity throughout design and development, a comparable technique to estimate the readiness of a technology for human operator use is lacking at SNL. The present study was designed to investigate the utility of a human readiness levels (HRL) scale to complement the TRL scale for the types of nuclear deterrence work conducted at SNL. The study team conducted 24 interviews with 26 individuals to (1) understand the extent to which current baseline design and development approaches at SNL incorporate the human dimension and (2) estimate the utility of various options to fully incorporate the human element in SNL work. Results confirmed that current processes do not manage the human component of a system systematically or comprehensively across programs. Although multiple options were seen to have some utility to address this shortcoming, an approach combining human readiness assessments within the existing TRL scale was perceived as relatively more useful for SNL. The study team created a proposed path forward to progress from the current ad hoc, reactive approach to a systematic, comprehensive, and rigorous approach characterized by full consideration of the human component of a system within and across programs and throughout the entire product lifecycle.

42 ENGINEERING↗

Transport Energy Impact Analysis; NREL (National Renewable Energy Laboratory)

Presented at the Sustainable Transportation Energy Pathways Spring 2015 Symposium on May 13, 2015, this presentation by Jeff Gonder of the National Renewable Energy Laboratory (NREL) provides information about NREL's transportation energy impact analysis of connected and automated vehicles.

33 ADVANCED PROPULSION SYSTEMS↗

NASA Johnson Space Center's Planetary Sample Analysis and Mission Science (PSAMS) Laboratory: A National Facility for Planetary Research

NASA Johnson Space Center's (JSC's) Astromaterials Research and Exploration Science (ARES) Division, part of the Exploration Integration and Science Directorate, houses a unique combination of laboratories and other assets for conducting cutting edge planetary research. These facilities have been accessed for decades by outside scientists, most at no cost and on an informal basis. ARES has thus provided substantial leverage to many past and ongoing science projects at the national and international level. Here we propose to formalize that support via an ARES/JSC Plane-tary Sample Analysis and Mission Science Laboratory (PSAMS Lab). We maintain three major research capa-bilities: astromaterial sample analysis, planetary process simulation, and robotic-mission analog research. ARES scientists also support planning for eventual human ex-ploration missions, including astronaut geological training. We outline our facility's capabilities and its potential service to the community at large which, taken together with longstanding ARES experience and expertise in curation and in applied mission science, enable multi-disciplinary planetary research possible at no other institution. Comprehensive campaigns incorporating sample data, experimental constraints, and mission science data can be conducted under one roof.

Draper, D. S.↗

TANK 26F SUPERNATANT AND 2F EVAPORATOR EDUCTOR PUMP SAMPLE CHARACTERIZATION RESULTS

In an effort to understand the reasons for system plugging problems in the SRS 2F evaporator, supernatant samples were retrieved from the evaporator feed tank (Tank 26F) and solids were collected from the evaporator eductor feed pump for characterization. The variable depth supernatant samples were retrieved from Tank 26F in early December of 2010 and samples were provided to SRNL and the F/H Area laboratories for analysis. Inspection and analysis of the samples at SRNL was initiated in early March of 2011. During the interim period, samples were frequently exposed to temperatures as low as 12 C with daily temperature fluctuations as high as 10 C. The temperature at the time of sample collection from the waste tank was 51 C. Upon opening the supernatant bottles at SRNL, many brown solids were observed in both of the Tank 26F supernatant samples. In contrast, no solids were observed in the supernatant samples sent to the F/H Area laboratories, where the analysis was completed within a few days after receipt. Based on these results, it is believed that the original Tank 26F supernatant samples did not contain solids, but solids formed during the interim period while samples were stored at ambient temperature in the SRNL shielded cells without direct climate control. Many insoluble solids (>11 wt. % for one sample) were observed in the Tank 26F supernatant samples after three months of storage at SRNL which would not dissolve in the supernatant solution in two days at 51 C. Characterization of these solids along with the eductor pump solids revealed the presence of sodium oxalate and clarkeite (uranyl oxyhydroxide) as major crystalline phases. Sodium nitrate was the dominant crystalline phase present in the unwashed Eductor Pump solids. Crystalline sodium nitrate may have formed during the drying of the solids after filtration or may have been formed in the Tank 26F supernatant during storage since the solution was found to be very concentrated (9-12 M Na{sup +}). Concentrated mineral acids and elevated temperature were required to dissolve all of these solids. The refractory nature of some of the solids is consistent with the presence of metal oxides such as aluminosilicates (observed as a minor phase by XRD). Characterization of the water wash solutions and the digested solids confirmed the presence of oxalate salts in both solid samples. Sulfate enrichment was also observed in the Tank 26F solids wash solution, indicating the presence of sulfate precipitates such as burkeite. OLI modeling of the Tank 26F filtered supernatant composition revealed that sodium oxalate has a very low solubility in this solution. The model predicts that the sodium oxalate solubility in the Tank 26F supernatant is only 0.0011 M at 50 C. The results indicate that the highly concentrated nature of the evaporator feed solution and the addition of oxalate anion to the waste stream each contribute to the formation of insoluble solids in the 2F evaporator system.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The use of dynamical constraints in the analysis of mesoscale rawinsonde data

A process for data interpolation which seeks to maintain dynamical consistency is applied to the analysis of mesoscale rawinsonde data obtained from the National Severe Storms Laboratory. The analysis procedure is in two steps: a successive-corrections interpolation to gridpoints, followed by a variational adjustment which uses a set of forecast equations of horizontal momentum as dynamical constraints. The objective analysis is applied in case studies of conditions on May 22, 1966 and June 8, 1966, and it is shown that the adjusted winds and geopotentials have greatly reduced residuals compared to the initial fields. Adjustments to the wind and geopotential fields have root mean square values of 1-2 m/sec and 30-50 sq m/sec per sec, respectively. In addition, the vertical velocity fields computed from the adjusted winds are found to be in closer agreement with actual weather data.

Bloom, S. C.↗

Strategy for Long-Term Stewardship and Monitoring of Amchitka Island - 12190

The Long-Term Surveillance and Maintenance Plan (LTSMP) for Amchitka details how the U.S. Department of Energy (DOE) intends to fulfill its mission to maintain protection of human health and the environment at and around the sites on Amchitka Island. The LTSMP calls for monitoring to be performed every 5 years, at least in the initial phase of the project. The purpose of the monitoring is to develop a baseline of activity concentrations for selected radionuclides in biota, water, and soil, both on Amchitka and at the reference location on Adak Island, approximately 322 km (200 miles) northeast of Amchitka. Data compiled by the Consortium for Risk Evaluation with Stakeholder Participation (CRESP, 2006) are being included as part of the baseline data set. The specific biological, water, and sediment samples collected during the 2011 sampling event were developed through close coordination with the primary stakeholders, including the Alaska Department of Environmental Conservation, the Aleutian Pribilof Island Association, and the U.S. Fish and Wildlife Service (USFWS). Amchitka is managed by the USFWS as part of the Alaska Maritime National Wildlife Refuge. Two plans were developed to address specific needs of the biological- and the terrestrial-monitoring programs. Results from these monitoring programs will help determine whether the environment is being impacted by radionuclide migration and uptake, and if subsistence and commercial-catch seafood is safe for human consumption. The RESRAD-BIOTA code is being used to evaluate ecological health relative to the radionuclide levels determined from this sampling event. The samples were sent to three laboratories for analysis. With the exception of the seawater samples, most of the samples were sent to the Center for Accelerator Mass Spectrometry at the Lawrence Livermore National Laboratory. A smaller subset of rock-weed samples, Star reindeer lichen samples, and soil samples collected from beneath the lichen were sent to UAF for cesium-137 analysis. Marine sediment samples were also collected and sent to UAF for testing. The seawater samples were sent to the University of Miami Tritium Laboratory for enriched tritium analysis. Results from the seawater samples for tritium were received in September 2011. Results from the 2011 sampling are expected to be available on the LM web site in 2012. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Comments on the analysis of returned comet samples

It is argued that returned comet samples should be distributed to individual laboratories for analysis much in the same way that lunar samples are. In the context of emerging technologies, certain developments in other fields which may prove beneficial to the study of comets are reviewed, including cryogenic and tomographic techniques. It is noted that the lack of expertise in the area of cryogenic examination of comet samples is a current weakness in the ability of the extraterrestrial material community to handle comet samples and thus requires further training and preparations. Computer tomography scan images of a 'dirty snowball' are presented to illustrate the importance of developing new methods for comet sample analysis. It is suggested that microanalytic measurements of extraterrestrial samples at the atom-counting limit appear promising for the future.

Walker, Robert M.↗

Techno-Economic Analysis of Chemical Precipitation Followed by Low Hydraulic Residence Time Biological Treatment, Including Ultrafiltration

This National Energy Technology Laboratory (NETL) analysis is a techno-economic evaluation of chemical precipitation followed by low hydraulic residence time biological treatment, which was identified as Best Available Technology for treatment and control of selenium emissions from wet flue gas desulfurization wastewater streams.

54 ENVIRONMENTAL SCIENCES↗

Astromaterials Research Office (KR) Overview

The fundamental goal of our research is to understand the origin and evolution of the solar system, particularly the terrestrial, "rocky" bodies. Our research involves analysis of, and experiments on, astromaterials in order to understand their nature, sources, and processes of formation. Our state-of-the-art analytical laboratories include four electron microbeam laboratories for mineral analysis, four spectroscopy laboratories for chemical and mineralogical analysis, and four mass spectrometry laboratories for isotopic analysis. Other facilities include the experimental impact laboratory and both 1-atm gas mixing and high-pressure experimental petrology laboratories. Recent research has emphasized a diverse range of topics, including: Study of the solar system's primitive materials, such as carbonaceous chondrites and interplanetary dust; Study of early solar system chronology using short-lived radioisotopes and early nebular processes through detailed geochemical and isotopic characterizations; Study of large-scale planetary differentiation and evolution via siderophile and incompatible trace element partitioning, magma ocean crystallization simulations, and isotopic systematics; Study of the petrogenesis of Martian meteorites through petrographic, isotopic, chemical, and experimental melting and crystallization studies; Interpretation of remote sensing data, especially from current robotic lunar and Mars missions, and study of terrestrial analog materials; Study of the role of organic geochemical processes in the evolution of astromaterials and the extent to which they constrain the potential for habitability and the origin of life.

Draper, David S.↗

Calibration and Sequence Development Status for the Sample Analysis at Mars Investigation on the Mars Science Laboratory

The measurement goals of the Sample Analysis at Mars (SAM) instrument suite on the "Curiosity" Rover of the Mars Science Laboratory (MSL) include chemical and isotopic analysis of organic and inorganic volatiles for both atmospheric and solid samples [1,2]. SAM directly supports the ambitious goals of the MSL mission to provide a quantitative assessment of habitability and preservation in Gale crater by means of a range of chemical and geological measurements [3]. The SAM FM combined calibration and environmental testing took place primarily in 2010 with a limited set of tests implemented after integration into the rover in January 2011. The scope of SAM FM testing was limited both to preserve SAM consumables such as life time of its electromechanical elements and to minimize the level of terrestrial contamination in the SAM instrument. A more comprehensive calibration of a SAM-like suite of instruments will be implemented in 2012 with calibration runs planned for the SAM testbed. The SAM Testbed is nearly identical to the SAM FM and operates in a ambient pressure chamber. The SAM Instrument Suite: SAM's instruments are a Quadrupole Mass Spectrometer (QMS), a 6-column Gas Chromatograph (GC), and a 2-channel Tunable Laser Spectrometer (TLS). Gas Chromatography Mass Spectrometry is designed for identification of even trace organic compounds. The TLS [5] secures the C, H, and O isotopic composition in carbon dioxide, water, and methane. Sieved materials are delivered from the MSL sample acquisition and processing system to one of68 cups of the Sample Manipulation System (SMS). 59 of these cups are fabricated from inert quartz. After sample delivery, a cup is inserted into one of 2 ovens for evolved gas analysis (EGA ambient to >9500C) by the QMS and TLS. A portion of the gas released can be trapped and subsequently analyzed by GCMS. Nine sealed cups contain liquid solvents and chemical derivatization or thermochemolysis agents to extract and transform polar molecules such as amino acids, nucleobases, and carboxylic acids into compounds that are sufficiently volatile to transmit through the GC columns. The remaining 6 cups contain calibrants. SAM FM Calibration Overview: The SAM FM calibration in the Mars chamber employed a variety of pure gases, gas mixtures, and solid materials. Isotope calibration runs for the TLS utilized 13C enriched C02 standards and 0 enriched CH4. A variety of fluorocarbon compounds that spanned the entire mass range of the QMS as well as C3-C6 hydrocarbons were utilized for calibration of the GCMS. Solid samples consisting of a mixture of calcite, melanterite, and inert silica glass either doped or not with fluorocarbons were introduced into the SAM FM cups through the SAM inlet funnel/tube system.

Mahaffy, Paul R.↗

Statistical analysis of an inter-laboratory comparison of small-scale safety and thermal testing of RDX

In this study, the Integrated Data Collection Analysis (IDCA) program has conducted a proficiency test for small-scale safety and thermal (SSST) testing of homemade explosives (HMEs). Described here are statistical analyses of the results from this test for impact, friction, electrostatic discharge, and differential scanning calorimetry analysis of the RDX Class 5 Type II standard. The material was tested as a well-characterized standard several times during the proficiency test to assess differences among participants and the range of results that may arise for well-behaved explosive materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Probing local structure in the yellow phosphor LaSr[subscript 2]AlO[subscript 5]:Ce[superscript 3+], by the maximum entropy method and pair distribution function analysis

The compound LaSr{sub 2}AlO{sub 5} was recently introduced as a competitive Ce{sup 3+} host material for blue-pumped yellow phosphors for use in white light emitting diodes. A crucial feature of the crystal structure of LaSr{sub 2}AlO{sub 5} is that La, which is the host site for Ce{sup 3+}, is located in the 8h positions of the I4/mcm crystal structure, a site equally shared with Sr. While the average crystal structure of LaSr{sub 2}AlO{sub 5} as revealed by Rietveld analysis of laboratory and synchrotron X-ray diffraction data suggests nothing untoward, maximum entropy method analysis of the synchrotron X-ray data reveals the existence of conspicuous non-sphericity of the electron density. Pair distribution function analysis of the data suggests that despite their occupying the same crystallographic site, La and Sr possess distinct coordination environments, and the environment around La is more compact and regular than the environment suggested by the Rietveld refinement of the average structure. The absorption and emission from Ce{sup 3+} centers is controlled by the local coordination and symmetry, and the use of powerful new tools in unraveling details of these strengthens the rational search for new phosphors for solid state white lighting.

36 MATERIALS SCIENCE↗

Backpack Laser Induced Breakdown Spectroscopy: Atomic Emission Analysis System User's Manual

The backpack LIBS (Laser Induced Breakdown Spectroscopy) system is designed to provide rapid, in-field, elemental analysis of environmental samples important to the safeguarding of special nuclear materials. Currently, environmental elemental analysis is performed by collection, packaging, and shipping of samples to an approved analytical laboratory for analysis. This practice can take days to months, if not longer, to complete and is also costly, especially if some of the samples are contaminated with actinide elements. The backpack LIBS system is designed to be user friendly, with several integrated safety features making the system safe to operate under normal conditions. Operators should be aware that this system contains a Class IV embedded laser. Since safety interlock features, both software and hardware, have been integrated into the system, no laser safety eyewear is required. Depending upon the intended use and analysis scenario, most analyses can be completed in a matter of minutes. The complete system is operated from battery power in a standalone mode and weighs approximately 25 pounds. The nominal operational lifetime of the backpack LIBS system is approximately 3.5 hours.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗