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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Ice clathrate as a possible source of the atmospheres of the terrestrial planets

The presence and compositions of atmospheres on the terrestrial planets do not follow directly from condensation models which would have earth accreting near 500 K. No single mechanism yet proposed adequately accounts for the abundances of noble gases and carbon and nitrogen in the atmospheres. We show that the composition of clathrates forming at low temperatures in cold regions of the nebula can be predicted. Addition of about 1 ppm clathrate material to the earth can explain observed abundances of Ar, Kr, and Xe. Condensation and adsorption processes occurring at 400-500 K are necessary to explain the observed abundances of Ne, H2O, C, and N. Possible sources of clathrates could be cometary bodies formed in the outer solar system.

Sill, G. T.↗
NASA NTRS1978

Mars - Regolith adsorption and the relative concentrations of atmospheric rare gases

Laboratory measurements of Kr and Xe adsorption on samples of ground montmorillonite, limonite and basalt at -77 C have been performed. Results suggest that (1) most degassed martian Xe could be adsorbed on a regolith with a large effective surface area, and (2) if this is the case the elemental composition of martian nonradiogenic rare gas (counting that in the regolith) may be virtually identical to that of ordinary chondrites.

Fanale, F. P.↗
NASA NTRS1978

Electron impact excitation of highly charged sodium-like ions

Optical transition probabilities and electron collision strengths for Ca X, Fe XVI, Zn XX, Kr XXVI and Mo XXXII are calculated for transitions between n equal to 3 and n equal to 4 levels. The calculations neglect relativistic effects on the radial functions. A semi-empirical approach provides wave functions of the excited states; a distorted wave function without exchange is employed to obtain the excitation cross sections. The density dependence of the relative intensities of certain emission lines in the sodium isoelectronic sequence is also discussed.

Blaha, M.↗
NASA NTRS1978

Planetary-type rare gases in an upper mantle-derived amphibole

All 23 stable rare gas isotopes in a mantle-derived aluminous Ti-rich amphibole, kaersutite, were measured, and the abundance pattern indicated by the results is similar to the 'planetary' rare gas pattern of carbonaceous chondrites. The He-3/He-4 ratio of (4.9 + or - 0.6) times 10 to the -5th power is anomalously high. Ne-21 is enriched relative to the abundance of the other two neon isotopes in the atmosphere, while the heavy isotopes of Kr and the Xe isotopes are within error of the atmospheric values. The analytical procedure is described. It is concluded that part of the primordial rare gases of the earth are still present in some parts of the upper mantle and that these gases retain a faithful record of the 'planetary' primordial rare gas elemental signature.

Saito, K.↗
NASA NTRS1978

The ionosphere and airglow of Venus - Prospects for Pioneer Venus

The paper presents model calculations for the Cytherean nighttime and daytime ionosphere. It is shown how some of the proposed mechanisms can be tested with the aid of the Pioneer Venus observations scheduled for December 1978. Theoretical calculations of the energetics of the Cytherean ionosphere are performed, and it is concluded that the Project Venus measurements will find elevated ion and electron temperatures, resulting primarily from energy fluxes associated in some manner with the solar wind. According to this model, the energy flux will act directly on the ion gas. Ultraviolet dayglow intensities were calculated, and it is anticipated that hundreds of kR's of CO2-related emission features such as the CO Cameron bands will be observed. Nightside ionosphere calculations were made assuming the precipitation of energetic electrons as an ionization source, and the intensities of some of the resulting emission features are calculated.

Cravens, T. E.↗
NASA NTRS1975

Trapped xenon in lunar anorthositic breccia 60015

The isotropic composition of trapped xenon released at temperatures in excess of 1000 C from the Apollo 16 cataclastic anorthosite 60015 is found to be indistinguishable from that of the terrestrial atmosphere, in confirmation of the recent reports of terrestrial-like trapped xenon in similar lunar samples. The order-of-magnitude difference between the abundances of this trapped component in two very similar rocks (60015 and 60025) is interpreted as possible evidence for a lunar origin for the trapped xenon. Although the alternative explanation as terrestrial contamination cannot be ruled out, the relative abundances of trapped Ar, Kr, and Xe in rocks with terrestrial-like xenon provide additional evidence against a terrestrial origin.

Leich, D. A.↗
NASA NTRS1975

Rare gases and Ca, Sr, and Ba in Apollo 17 drill-core fines

Trapped gas isotopic compositions and spallation gas concentrations as functions of depth in the Apollo 17 drill core were determined from mass spectrometer studies by means of correlation techniques. The distribution of He, Ne, Ar, Kr, and Xe as well as Ca, Sr, and Ba was investigated, and rare-gas spallation and neutron capture profiles are compared with attention to proposed depositional models for the Taurus-Littrow regolith. The data exclude a sedimentation pattern similar to that found at the Apollo 15 site but are possibly compatible with long-term continuous accretion models or models of very recent rapid accumulation of regolith.

Pepin, R. O.↗
NASA NTRS1975

Agglutinates as indicators of lunar soil maturity - The rare gas evidence at Apollo 16

The weight percent of lunar agglutinic glass (glass-welded aggregates resulting from micrometeorite impacts) in Apollo 16 bulk soils is considered with respect to quantities of trapped rare gases, e.g., He-4, Ne-20, Ar-36, Kr-84, and Xe-132, in an effort to determine the cumulative time a given soil sample has spent exposed on the lunar surface. The agglutinic glass, which reacts strongly in a magnetic field, is obtained by the standard fluid (methanol)-magnetic technique. It is noted that the absolute concentrations of trapped rare gases all show a linear relationship with increasing agglutinic glass content.

Charette, M. P.↗
NASA NTRS1975

Long-term differential energy spectrum for solar-flare iron-group particles

A long-term solar-flare differential energy spectrum for iron-group nuclei from approximately 0.1 to approximately 600 MeV/amu is derived from track density profile measurements in sample 64455 and sample 68815. Measurements from uneroded surfaces were obtained from quench crystals of plagioclase in 64455, and a Kr-81/Kr method indicates that the exposure age of this sample is 2,010,000 yrs. The power laws which best fit the normalized track density data are reported; the energy spectrum consists of two power law curves smoothly joined together which in turn are smoothly connected to a modulated galactic cosmic-ray spectrum. Standard track production versus depth profiles can be used to determine solar-flare track exposure ages and erosion rates for lunar samples.

Blanford, G. E.↗
NASA NTRS1978

Uniform magnesium oxide adsorbents

Kr adsorption on MgO is used to characterize the surface uniformity of MgO smoke and thermally decomposed Mg(OH)2. It is found that initially heterogeneous samples develop progressively sharper stepwise isotherms with increasingly-high-temperature heat treatment, apparently due to the removal of imperfections and high-energy facets, leaving surfaces of highly uniform (100) planes.

Dash, J. G.↗
NASA NTRS1979

Time-dependent local density measurements in unsteady flows

A laser-induced fluorescence technique for measuring the relative time-dependent density fluctuations in unsteady or turbulent flows is demonstrated. Using a 1.5-W continuous-wave Kr(+) laser, measurements have been obtained in 0.1-mm-diameter by 1-mm-long sampling volumes in a Mach 3 flow of N2 seeded with biacetyl vapor. A signal amplitude resolution of 2% was achieved for a detection frequency bandwidth of 10 kHz. The measurement uncertainty was found to be dominated by noise behaving as photon statistical noise. The practical limits of signal-to-noise ratios have been characterized for a wide range of detection frequency bandwidths that encompasses those of interest in supersonic turbulence measurements.

Mckenzie, R. L.↗
NASA NTRS1978

Industrial ion source technology

An analytical model was developed to describe the development of a coned surface texture with ion bombardment and simultaneous deposition of an impurity. A mathematical model of sputter deposition rate from a beveled target was developed in conjuction with the texturing models to provide an important input to that model. The establishment of a general procedure that will allow the treatment of manay different sputtering configurations is outlined. Calculation of cross sections for energetic binary collisions was extened to Ar, Kr.. and Xe with total cross sections for viscosity and diffusion calculated for the interaction energy range from leV to 1000eV. Physical sputtering and reactive ion etching experiments provided experimental data on the operating limits of a broad beam ion source using CF4 as a working gas to produce reactive species in a sputtering beam. Magnetic clustering effects are observed when Al is seeded with Fe and sputtered with Ar(?) ions. Silicon was textured at a micron scale by using a substrate temperature of 600 C.

Kaufman, H. R.↗
NASA NTRS1979

Physical processes in directed ion beam sputtering

The general operation of a discharge chamber for the production of ions is described. A model is presented for the magnetic containment of both primary and secondary or Maxwellian electrons in the discharge plasma. Cross sections were calculated for energy and momentum transfer in binary collisions between like pairs of Ar, Kr, and Xe atoms in the energy range from about 1 eV to 1000 eV. These calculations were made from available pair interaction potentials using a classical model. Experimental data from the literature were fit to a theoretical expression for the Ar resonance charge exchange cross section over the same energy range. A model was developed that describes the processes of conical texturing of a surface due to simultaneous directed ion beam etching and sputter deposition of an impurity material. This model accurately predicts both a minimum temperature for texturing to take place and the variation of cone density with temperature. It also provides the correct order of magnitude of cone separation. It was predicted from the model, and subsequently verified experimentally, that a high sputter yield material could serve as a seed for coning of a lower sputter yield substrate. Seeding geometries and seed deposition rates were studied to obtain an important input to the theoretical texturing model.

Robinson, R. S.↗
NASA NTRS1978

Rare-gas-rich separates from carbonaceous chondrites

This paper describes an analysis of carbon-rich separates prepared by demineralization of colloidal fractions after disaggregation of bulk samples of the type C2 meteorites Murray, Murchison, and Cold Bokkeveld, as well as a methanol colloid extracted from acid-resistant residues of the Allende meteorite (type C3V) obtained by dissolution of most of the minerals in HCl and HF acids. The carbonaceous separates, or lAlates (a coined word designating colloids prepared sometimes before and sometimes after acid treatment), are characterized incompletely and with difficulty. A stepwise heating experiment on a Murray lAlate is discussed which revealed bimodal release of all noble gases, with similar patterns for Ar, Kr, and Xe. Chemical reactions are suggested as the likely mechanism for gas release. The results are shown to support the concept of a carbonaceous gas carrier uniformly present in meteorites of various types.

Reynolds, J. H.↗
NASA NTRS1979

Thermal metamorphism of primitive meteorites. VIII - Noble gases, carbon and sulfur in Allende /C3/ meteorite heated at 400-1000 C

Noble gases, C and S, are lost from Allende samples heated for 1 week at temperatures of 400-1000 C in a low pressure environment. In the extreme, losses of He-3 and He-4 are about 100 x while for C, S and Ne, Ar and Kr isotopes and Xe-132 these are less than or equal to 10 x. Except for He, these losses are less severe than those of Bi or Tl from samples heated in the same runs. Significant He, Ne and Ar isotopic fractionation during heating indicates preferential outgassing of specific reservoirs. Next to He, Ar-40 is the most labile of those species considered here but still less so than Bi or Tl. L-group (but not H- or LL-group) chondrites may have lost mobile elements like Tl while being outgassed after late impact-associated heating. A less likely alternative involving a collateral relation between condensation conditions and depth in a parent object may also explain the L-group trend.

Herzog, G. F.↗
NASA NTRS1979

Identification of the UV nightglow from Venus

Observations of atmospheric ultraviolet emission between 1350 and 2200 A from the night side of Venus, made by the International Ultraviolet Explorer (IUE), are reported. Low dispersion spectra taken by the short and long wavelength IUE spectrographs clearly show the (0,0) band of the NO delta system at 1909 A; the delta (0,1) band at 1980 A and the delta (0,2) band are indicated, while the (2,0) Cameron band of CO at 1928 A does not seem to be present. The relative band intensities appear to be the same as in earth airglow, where the excitation mechanism has been identified as radiative association of O and N atoms. The column emission rate of 0.5 kR implies a larger N to O ratio in the atmosphere of Venus than in that of the earth.

Feldman, P. D.↗
NASA NTRS1979

Energetic binary collisions in rare gas plasmas

Calculations have been made of cross sections for energy and momentum transfer in binary collisions between like pairs of Ar, Kr, and Xe atoms in the energy range from about 1 to 1000 eV. These calculations were made using a classical model with pair interaction potentials for the rare gases developed from experimental sources, e.g., investigations of specific heats, viscosities, solid-state parameters, and scattering data. Cross sections in this energy range have not been available. The cross sections exhibit a rapid decrease from accepted values at thermal energies as the interaction energy increases. This behavior can be used to understand directed beam propagation limits as well as particle propagation within a plasma. Experimental data have also been fit to a theoretical expression for the Ar resonance charge exchange cross section over the same energy range.

Robinson, R. S.↗
NASA NTRS1979

A cosmological redshift-distance square law

This paper directly examines the claims of Segal (1976) that the (m,z) Hubble diagram is fitted best by a square law z = Kr-squared rather than by the traditional Hubble law z = Hr in the low-redshift range, z no more than about 0.01, corresponding to galaxies brighter than 14th mag. Segal attempts to fit a distance relation to the (m,z) scatter diagram in which each individual galaxy is plotted. The exact relation between the mean redshift for all galaxies in a small magnitude interval and the apparent magnitude is calculated. This relation is independent of luminosity function and peculiar velocity distribution about the general expansion, and is not affected by sample incompleteness as a function of apparent magnitude or the clustering of galaxies in the sample. Segal's method is affected by all of these and requires a highly sophisticated statistical analysis to deal with the non-Gaussian pointwise scatter. The present analysis favors the Hubble law and conclusively rules out the square law for the small redshift region.

Soneira, R. M.↗