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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 451 records · Page 25

Low-cost buffer storage for solar industrial steam applications

Motivation and importance: Many industrial process heat consumers operate throughout the day, and deep decarbonization with solar energy requires thermal energy storage. Thermal energy storage provides an additional operational benefit of firm delivery of steam – essential to reducing the risk of costly production interruptions. The group of process heat consumers that use steam for biofuels production for the California transportation fuels market is incentivized through the Low Carbon Fuel Standard (LCFS) to reduce their carbon intensity through the use of solar steam. Examples include ethanol and dimethyl ether production. The production of these and other fuels involves distillation driven by steam reboilers with steam pressures in the range 100-280 psig. These pressures can be delivered from the type of thermal energy storage that has been the focus of this project – a steam accumulator Sunvapor, Inc. (SVI) calls a “Bullet Steam Accumulator” or “BSA TM ”. Our project adds to the understanding of the design and integration of steam accumulators charged by solar thermal energy in a biofuels production facility, and similar facilities that consume process steam. The fuel application requires a demanding level of Process Safety Management not found in other steam applications. The type of steam accumulator SVI engineered and built integrates steam generation and storage in one vessel to reduce cost. Achieving a first of a kind permit to operate such a first device has also added to the understanding of the industrial application of such systems. Goals: The overall goal of the project has been to demonstrate the advantages that a “Bullet Steam Accumulator” (BSA™) can provide to solar steam integration with a manufacturing process. The industrial host has already been convinced of the potential of the available solar steam to lower than carbon intensity score. They have been interviewed for a number of publications such as that tout the advantages SVI’s system brings to their operations. Accomplishments: At the end of 2023 Sunvapor placed in service the country’s first industrial solar boiler with thermal energy storage. At the same time, this placement in service represents the first pilot commercial system to decarbonize biofuels production through the use of solar thermal energy. While the full technical effectiveness will be shown as soon as the customer’s plant is able to consume the available steam, the economic feasibility was indicated early in the project when the combination of costs and steam pricing required to meet investor expectations was determined. The project represents a reference pilot from which a full-scale commercial system may be expanded. This pilot is a necessary first step in providing the full potential benefits to the public, including decarbonization of transportation fuels. The decarbonization of the separation steps in fuels production may be the most cost-effective and nearest term solar fuel. Co-benefits include a reduction of air pollutants such as NOx and particulate matter, and job creation for the construction, operation and maintenance of industrial solar facilities.

14 SOLAR ENERGY↗

Developing tools and process controls to manufacture energy-efficient powders for additive manufacturing feedstocks: Computational analysis of metal powder manufacturing via machining

Traditionally, metal powders have been produced through methods such as grinding, atomization, and electrolysis. In contrast to these techniques, Metal Powder Works, Inc. has pioneered a methodology based on metal cutting. This innovative approach utilizes a vibrating cutting tool to machine metal particles, in the form of chips, from a workpiece. This technique allows for control of powder particle size, morphology, and avoids any thermally induced material changes. This collaboration aims to elucidate metal cutting characteristics and assess performance on tough materials like Inconel alloys. Computational models, using FEA and SPH techniques, will be developed initially, focusing on aluminum alloy (Al 7075-T6) for studying mesh sensitivity, cutting forces, and chip morphology.

99 GENERAL AND MISCELLANEOUS↗

Isolation and conversion of electrolyte components into a value-added product

The overall objective of this work was to develop a process for effectively (i) recycling the electrolyte components from the end-of-life batteries and reduce the environmental hazard, (ii) understand the fundamental differences between pristine and recycled electrolyte components, (iii) electrochemically and analytically evaluate the recycled electrolyte components and (iv) establish deviations from the pristine electrolyte, and effectively separation of value-added product. We focused on determining scaling up the electrolyte recovery process by distillation of end-of-life batteries to get yield enough to use it for electrolyte formulation of reuse in the battery cell. The used cells from the ORNL battery manufacture facility (BMF)as well as received from the industry partner, Austin Elements Inc., was scaled to 10 used multilayered pouch cells in each batch of distillation and systematically separated and identified the electrolyte components of the used cells with FTIR and NMR studies. We were able to recovery 10g of solvent mass from the used pouch cells. NMR spectroscopy showed that the solvent was pure EMC,DMC and the sample was used to make a new battery cell. The end-of-life battery, it was noted that some cells were visually drier than the other cells and were more advanced in aged. In that case, even though the same distillation conditions were utilized, no usable mass of electrolyte solvent was recovered. It is expected that most of the solvent was decomposed during the battery charge-discharge cycling. The solid salt residue was separated by chemical and water treatment processes. Components of resulting solid product was analyzed by XRD and XPS measurements. The solid products are very much related to the salts used in the electrolyte solution.

25 ENERGY STORAGE↗

Electrifying Critical Mineral Refinement in the US (CRADA Final Report)

The technical founder of Aepnus Technology Inc. was competitively selected for support by Cyclotron Road, a U.S. Department of Energy (DOE) Lab-Embedded Entrepreneurship Program (LEEP) through an approved merit review process. Through this program, Aepnus Technology has collaborated with Lawrence Berkeley National Laboratory (LBNL) to develop and validate a novel electrolysis platform targeting the recycling of sodium sulfate waste, a pervasive byproduct in the battery supply chain. The platform aims to address inefficiencies in conventional electrolysis by leveraging Aepnus' proprietary gas diffusion electrode (GDE) technology, which replaces precious metal catalysts, such as iridium, to achieve high efficiency, reduced operational costs, and enhanced durability.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Developing tools and process controls to manufacture energy-efficient powders for additive manufacturing feedstocks

Traditionally, metal powders have been produced through methods such as grinding, atomization, and electrolysis. In contrast to these techniques, Metal Powder Works, Inc. has pioneered a methodology based on metal cutting. This innovative approach utilizes a vibrating cutting tool to machine metal particles, in the form of chips, from a workpiece. This technique allows for control of powder particle size, morphology, and avoids any thermally induced material changes. This collaboration aims to elucidate metal cutting characteristics and assess performance on tough materials like Inconel alloys. Computational models, using FEA and SPH techniques, will be developed initially, focusing on aluminum alloy (Al 7075- T6) for studying mesh sensitivity, cutting forces, and chip morphology.

36 MATERIALS SCIENCE↗

Isolation and Conversion of Electrolyte Components into a Value-Added Product

The overall objective of this work was to develop a process for effectively (i) recycling the electrolyte components from the end-of-life batteries and reduce the environmental hazard, (ii) understand the fundamental differences between pristine and recycled electrolyte components, (iii) electrochemically and analytically evaluate the recycled electrolyte components and (iv) establish deviations from the pristine electrolyte, and effectively separation of value-added product. We focused on determining scaling up the electrolyte recovery process by distillation of end-of-life batteries to get yield enough to use it for electrolyte formulation of reuse in the battery cell. The used cells from the ORNL battery manufacture facility (BMF) as well as received from the industry partner, Austin Elements Inc., was scaled to 10 used multilayered pouch cells in each batch of distillation and systematically separated and identified the electrolyte components of the used cells with FTIR and NMR studies. We were able to recovery 10g of solvent mass from the used pouch cells. NMR spectroscopy showed that the solvent was pure EMC, DMC and the sample was used to make a new battery cell. The end-of-life battery, it was noted that some cells were visually drier than the other cells and were more advanced in aged. In that case, even though the same distillation conditions were utilized, no usable mass of electrolyte solvent was recovered. It is expected that most of the solvent was decomposed during the battery charge-discharge cycling. The solid salt residue was separated by chemical and water treatment processes. Components of resulting solid product was analyzed by XRD and XPS measurements. The solid products are very much related to the salts used in the electrolyte solution.

25 ENERGY STORAGE↗

Non-catalytic pyrolysis of associated gas to zero CO 2 hydrogen and high value carbon black

The overall objective of this work is to perform a pre-Front End Engineering Design (pre-FEED) study of the conversion of associated gas produced at an active oil pad of a Bakken oil field producer, to high value carbon black and hydrogen using the Microwave Plasma Pyrolysis of Associated Gas (MPP-AG) process developed by H Quest Vanguard, Inc (HQV). The University of North Dakota’s Center for Process Engineering Research (CPER) collaborated with HQV to complete a design and techno-economic analysis for the MPP-AG deployed at an active Bakken well site flaring an average of 54,000 standard cubic feet per day of AG. The proposed design consists of: • A Microwave Pyrolysis Unit (MPU) which consists of H Quest’s proprietary MPP technology • A patent-pending Gas Conditioning Unit (GCU) designed by the University of North Dakota to condition intermittent and variable flow gas prior to pyrolysis. • An auxiliary unit running on the associated gas to power the GCU and MPU in an “island mode” configuration.

03 NATURAL GAS↗

A User-Facing Metric to Quantify the Quality of Mobility (CRADA Final Report)

The leading urban mobility data analytics firm StreetLight Data, Inc. partnered with the National Renewable Energy Laboratory to explore a commercial version of the Mobility Energy Productivity (MEP) metric. The commercialization effort was aimed to expand the adoption of the metric to key stakeholders in the urban planning space. Research comprised industry analysis, stakeholder feedback and conducting transportation practitioner focus groups. StreetLight concluded that commercialization of MEP is not feasible in the current market because users need a dynamic MEP tool that enables scenario planning. It should be able to calculate a MEP score dynamically (near instantaneous) when different inputs are changed.

33 ADVANCED PROPULSION SYSTEMS↗

Transformational Sorbent System for Post-Combustion Carbon Capture (Final Report)

As part of this DOE Contract (Transformational Sorbent System for Post-Combustion Carbon Capture, DE-FE0031734),TDA Research Inc. developed a transformational sorbent system for post combustion CO 2 capture process that captures more than 95% of CO 2 emissions from a coal fired power plant, recovering CO 2 at 95% purity with a cost of CO 2 capture significantly lower than with amine-based system (~$30 per tonne (MT) of CO 2 captured). TDA’s transformational sorbent system uses a novel, highly stable, high-capacity metal organic framework (MOF) based CO 2 sorbent in a new vacuum/concentration swing adsorption (VCSA) process that allows us to use high efficiency vacuum pumps with a low auxiliary load. A pulverized coal fired power plant equipped with TDA’s transformational sorbent system for post combustion CO 2 capture is expected to efficiently produce electricity with a low Cost of Electricity (COE) and capture greater than 95% of the CO 2 from the power plant exhaust.

01 COAL, LIGNITE, AND PEAT↗

Big Data Meets Geothermal Exploration (CRADA Final Report)

As part of the Cyclotron Road program, Zanskar Geothermal & Minerals, Inc. investigated the application of micro-earthquake and ambient noise seismology methods to imaging and characterizing the structural characteristics and hydrothermal flux of subsurface faults. Significant advances in what could be resolved were enabled by two major developments in seismology: 1) the availability of large-n arrays of low-cost seismometers, and 2) the availability of increased computational power and semi-automated data reduction algorithms. In tandem, these advances may improve the signal-to-noise ratio and spatial precision of the data collected and enable higher-resolution characterization of subsurface fracture systems and their spatio-temporal evolution. These tools supported efforts to reduce dry-hole risk and to improve wellfield productivity for geothermal resource development. In particular, two applications of these advances were evaluated: 1) fracture-seismic imaging, which was used to detect ambient emissions from fluid-filled fractures, and 2) reservoir tomography, which used information about travel paths, source locations, and source parameters of micro-earthquakes to identify areas of enhanced permeability. Integration of these methods provided guidance for siting wells and served as prior constraints for reservoir models, informing forecasts of power potential and production and injection strategies aimed at minimizing temperature decline and improving overall resource productivity.

15 GEOTHERMAL ENERGY↗

Cost Effectiveness of Laser Powder Bed Fusion for Heavy Duty Applications

ORNL (Contractor) and Cummins Inc. (Participant) collaborated to determine the cost effectiveness of laser powder bed fusion (LPBF) for heavy duty applications. The team demonstrated that coupons can be fabricated with two distinct process parameters i.e., different process parameters for the bulk and surface of the material. This is important for enabling the manufacturing of components in a production environment where the bulk of the material can be processed rapidly while high quality surface finish can minimize post-process machining as well as enable superior fatigue performance if the material were to be used in as-deposited condition.

36 MATERIALS SCIENCE↗

Making an s1G Self-Preserving Environmental DNA (eDNA) Filter from Sustainable Materials

Environmental DNA (eDNA) sampling of aquatic environments is a powerful new tool for resource managers to use in detecting the presence of rare and endangered species. The use of eDNA for species detection is quickly becoming an industry-standard methodology in environmental science, and the technology sector is moving quickly to create purpose-built tools for eDNA sampling. Smith-Root, Inc. pioneered the new technology of self-preserving eDNA filters that automatically preserve the DNA captured on filters by desiccating the internal filter membrane. This capability saves the sampling technician significant time in the field and drastically reduces the potential for sample contamination. One main constraint of this new technology, however, is the necessity of single-use plastics for eDNA sampling. Single-use designs are employed because sampling equipment must be devoid of potential contaminating DNA, and the time required to sterilize equipment is often not cost-effective for practitioners. Thus, this technology is creating a significant new source of plastic waste—something that eDNA practitioners, and society, would like to avoid. This project explores the use of alternative bio based polymers and composites as replacements for incumbent industrial standards for eDNA filtration systems, with an emphasis on ease of processing and biodegradable options. 8 candidate materials, 3 for the top filter housing and 5 for the bottom filter housing, were investigated to replace incumbent housing materials. Of the 8 candidates, 2 materials were identified for future investigation which met performance requirements, were bio-based and could potentially offer better disposal options like soil degradation or composting, features sought by the customers of these products. The top housing candidate, material 1, has comparable performance to the incumbent material and equally manufacturable. The bottom housing candidate, material 6, improved desiccation performance by 81% after 1 hour in comparison to the incumbent material, is 100% bio-based, compostable and can be sourced domestically throughout the U.S.A.

36 MATERIALS SCIENCE↗

Community-Controlled Transportation: The Western New York E-Bike Library Network: Preprint

Shared Mobility Inc. (SMI) has used their mission of community-controlled transportation to partner with community based organizations on the launch and operations of E-Bike Libraries (EBLs) in Western New York (WNY) and beyond since 2021. For almost four years, the WNY EBLs have provided e-bikes at no cost to underserved communities in Buffalo and Niagara Falls. Participants used the e-bikes for commuting, recreational rides, community bike rides, running errands, and accessing essential services. This program significantly increased e-bike accessibility, with 71% of participants being first-time riders and 78% identifying as Black/African American. Challenges such as bike maintenance, battery charging logistics, and the need for suitable storage were addressed through partnerships with community-based organizations and adjustments to program logistics. Those lessons have been applied to additional EBLs in Pacoima, California and Carlisle, Pennsylvania, which have also been launched by SMI with a continued emphasis on the importance of community based approaches to sustainable transportation. All of these programs demonstrate the potential of e-bikes to provide an affordable, efficient, and fun transportation option, particularly for underserved communities. By leveraging community partnerships and focusing on accessibility and inclusivity, E-Bike Libraries can significantly contribute to sustainable transportation solutions and promote broader participation in the transportation electrification revolution.

33 ADVANCED PROPULSION SYSTEMS↗

Enhancing cold spray coatings: Microstructural dynamics and performance attributes of Inconel 625 with chromium carbide incorporation for hydropower applications

The incorporation of chromium carbide (CrC) particles into the cold spray (CS) process is known to mitigate nozzle clogging, although at the expense of deposition efficiency. This study explores the intricate microstructural changes induced by varying amounts of CrC powder (12.5 % and 6 %) in conjunction with Inconel-625 (Inc-625) powder. The deposition was carried out onto A27 cast steel under different CS parameters. Microstructural characterization, including detailed electron microscopy studies, reveals a complex yet structurally stable coating. Noteworthy features include grain fragmentation and a cellular structure enriched with Nb and Mo, with minimal plastic deformation of CrC in the matrix. The cold-sprayed coatings exhibit a significant (~4 times) increase in microhardness compared to the A27 substrate. Mechanical and cavitation erosion properties were systematically investigated. Coatings subjected to higher particle energy conditions with a gas pressure of 600 psi and gas temperature of 650 °C, demonstrated superior resistance to cavitation erosion. This resistance is attributed to a combination of factors, including microstructural characteristics and porosity. Altogether, the study provides valuable insights into the structural dynamics and performance of CS coatings enriched with CrC particles.

A27 cast steel↗

Pitka's Point/St. Mary's Wind Energy Construction Project. Final report

This is the final report for the St. Mary’s/Pitka’s Point Wind Construction Project. Under the project Alaska Village Electric Cooperative, Inc. (AVEC) constructed and commissioned one new 900 kW-capacity wind turbine at a site in Pitka’s Point about 4 miles from the diesel-fired prime power plant in St. Mary’s. The main objective of this project is to generate electric power from a renewable resource in an effort to reduce the local dependency on fuel oil as the sole source of electric power generation. The wind generator’s output augments the prime source generation provided by the diesel-powered generators.

17 WIND ENERGY↗

Bethel Wind Energy Construction Project. Final report

Final report for the Bethel (Alaska) Wind Construction project. Under this project, Alaska Village Electric Cooperative, Inc. (AVEC) constructed and commissioned one new 900 kW-capacity wind turbine at a site in Bethel about 3.3 miles NE of the diesel-fired prime power plant. The wind generator’s output will augment the prime source generation provided by the diesel-powered generators.

17 WIND ENERGY↗

A System Approach to Deep Heating Savings Through Measurement, Management, and Motivation

Across multi-tenant commercial office and multifamily buildings, centrally metered fuel use represents a substantial fraction of whole-building energy use. Energy audit practitioners understand that improving heating distribution efficiency is typically more of an opportunity than combustion efficiency and that differing thermal comfort preferences between tenants are the bane of operators across these building typologies. There is an unmet market need for retrofit technologies that allow for the delivery of the right amount of heat to the right spaces, at the right time. The Energy Management and Information System (EMIS) package fills this gap through enhanced controls and metering, incorporating low-cost sensors and wireless communication infrastructure to provide a platform for ongoing commissioning and tenant feedback, including heat cost allocation. With support from the US DOE Building Technologies Office, Steven Winter Associates, Inc. (SWA) partnered with Sentient Buildings, E Source, building owners, and utility and policy stakeholders, to demonstrate a market viable EMIS that achieves a reduction in space heating energy use by reducing heating load, improving control, and positively impacting behavior while providing an acceptable financial return. In this study, EMIS packages were implemented in two New York City multifamily rental buildings. Both buildings conducted basic mechanical work (e.g., repairing steam traps) to ensure the heating system was operating well before any tenant feedback was layered in. Heating Energy Use Reports (HEUR) were created to provide tenants with social comparisons and energy savings tips to influence their behavior; these were provided monthly to all tenants in both buildings. Additionally, one building allocated heating costs to a portion of the tenants. Heat cost allocation (HCA) has a long history in the European Union (EU), although it is not common in the US or in steam-heated buildings. SWA leveraged existing EU best practices and stakeholder feedback to develop a Heat Cost Allocation algorithm that was considered equitable and intuitive. Energy use and tenant behavior impacts were tracked throughout the study. The basic mechanical repair work saved between 11-20% of heating energy. Those savings rose to 17-24% with the addition of tenant feedback. While it may not be possible to precisely determine the impact of COVID-19 on research studies like this, there may have been additional savings realized had the study taken place in a period of normal occupancy patterns. These types of central heating systems have been a blind spot for utilities, who have traditionally had little visibility into detailed behind-the-meter gas usage. Heating energy savings stayed consistent during the coldest months, indicating the potential for utilities to utilize EMIS packages for peak gas demand reductions or demand response programs. Tenant comfort was also improved. Post installation, room temperatures more closely matched thermostat set points. Perhaps due to this greater level of control, the vast majority of tenants being billed for heating were accepting of the allocation costs. And tenants receiving heat cost allocations were more likely to reduce their thermostat setpoints than tenants receiving behavioral feedback without financial impacts were. Variation in building specifics makes it difficult to provide precise energy and financial savings estimates. But within the range of expected conditions, the study identified a few key variables that can have the greatest impact on financial returns: the cost of fuel, the ability and willingness to allocate heating costs to tenants, and a well-functioning heating system as a starting point. This study focused on two multifamily buildings, but additional use cases, such as commercial buildings and affordable housing, should be explored to better understand the full market potential. While this type of upgrade has the potential for deep energy reductions and cost savings, future projects should take into account the balance of costs and benefits between owners and tenants, especially in the affordable, regulated, or other low-to-moderate income (LMI) segments of the market. Rent credits, utility allowances, or a shared savings program are possible options to accelerate adoption of this strategy in these market segments.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗