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NASA NTRS2001

Carbon Nanotubes Growth by CVD in Various Conditions

Since the superior properties of multi-wall carbon nanotubes (MWCNT could be used in numerous devices such as electronics and sensors, many efforts have been engaged in synthesizing particular structural or dimensional MWCNT. This presentation will illustrate MWCNT synthesized on silicon substrates by thermal CVD. On the substrate, an array of catalysts is coated using sputtering deposition. A thin Ti buffer layer is also coated on some Si substrates prior to depositing catalyst particles. Nickel, cobalt or iron transition metals are used as catalysts for the MWCNT growth. Since the diameter of MWCNT depends on the size of catalyst particles, the catalyst particle size is investigated after annealed at various temperatures. MWCNT are grown on the substrate in the temperature range of 700 to 1000 C and the pressure range of 100 torr to one atmosphere. Methane and hydrogen gases with methane content of 10% to 100% are used for the MWCNT synthesis. Morphology, length and diameter of these MWCNT are determined by scanning electron microscopy and Raman spectroscopy. The detailed results of syntheses and characterizations will be discussed in the presentation.

Zhu, S.↗

NASA NTRS1985

Airborne atmospheric electricity experiments

During the 1984 U2 spring flight program, lightning spectra were measured in the wavelengths from 380 nm to 900 nm with a temporal resolution of 5 ms. With this capability, researchers simultaneously acquired both visible near-infrared lightning spectra on a pulse to pulse basis, so that the spectral variability within a flash, as well as flash to flash variations, can be studied. Preliminary results suggest that important variations do occur, particularly in the strengths of the hydrogen and singly ionized nitrogen emission lines. Also, the results have revealed significant differences in the integrated energy distributions between the lightning spectra measured above clouds and the spectral measurements of cloud-to-ground lightning made at the ground. In particular, the ratio of the energy in the near-IR to that in the visible is around 1 to 2 for cloud top spectra versus about 1/3 for surface observations. Detailed analyses of the 1984 lightning spectral data is being conducted. This data should provide improved understanding about the optical transmission properties of thunderclouds and the physics of the lightning discharge process. Efforts continue on developing and testing background signal removal algorithms using U2 spectometer and optical array sensor day-flight data sets. The goal of this research is to develop an algorithm satisfying Lightning Mapper Sensor requirements.

Blakeslee, R. J.↗

NASA NTRS1993

Use of particle beams for lunar prospecting

A key issue in choosing the appropriate site for a manned lunar base is the availability of resources, particularly oxygen and hydrogen for the production of water, and ores for the production of fuels and building materials. NASA has proposed two Lunar Scout missions that would orbit the Moon and use, among other instruments, a hard X-ray spectrometer, a neutron spectrometer, and a Ge gamma ray spectrometer to map the lunar surface. This passive instrumentation will have low resolution (tens of kilometers) due to the low signal levels produced by natural radioactivity and the interaction of cosmic rays and the solar wind with the lunar surface. This paper presents the results of a concept definition effort for a neutral particle beam lunar mapper probe. The idea of using particle beam probes to survey asteroids was first proposed by Sagdeev et al., and an ion beam device was fielded on the 1988 Soviet probe to the Mars moon Phobos. During the past five years, significant advances in the technology of neutral particle beams (NPB) have led to a suborbital flight of a neutral hydrogen beam device in the SDIO-sponsored BEAR experiment. An orbital experiment, the Neutral Particle Beam Far Field Optics Experiment (NPB-FOX) is presently in the preliminary design phase. The development of NPB accelerators that are space-operable leads one to consider the utility of these devices for probing the surface of the Moon using gamma ray, X-ray, and optical/UV spectroscopy to locate various elements and compounds. We consider the utility of the NPB-FOX satellite containing a 5-MeV particle beam accelerator as a probe in lunar orbit. Irradiation of the lunar surface by the particle beam will induce secondary and back scattered radiation from the lunar surface to be detected by a sensor that may be co-orbital with or on the particle beam satellite platform, or may be in a separate orbit. The secondary radiation is characteristic of the make-up of the lunar surface. The size of the spot irradiated by the beam is less than 1 km wide along the ground track of the satellite, resulting in the potential for high resolution. The fact that the probe could be placed in polar orbit would result in global coverage of the lunar surface. The orbital particle beam probe could provide the basis for selection of sites for more detailed prospecting by surface rovers.

Toepfer, A. J.↗

NASA NTRS1976

Thermal control systems for low temperature Shuttle payloads

Greater sensitivity and longer life for future space sensor systems place more stringent demands on cooling system technology. Results are presented for a study designed to determine and evaluate low-temperature thermal control system concepts for various cooling categories in the range 3-200 K and to generate hardware development plans for undeveloped viable system concepts. The study considered Shuttle launched payloads in the 1980-1991 time frame, with 1-5 yr of life. Cooling concepts are categorized as open-cycle (expendable), closed-cycle (mechanical), solid-state, and radiative. Particular attention is given to the concepts of multistage heat pipe radiator, diode heat pipe radiator, and radiator guarded cryostat. Results are given for parametric analyses of the Vuilleumier refrigerator, the rotary reciprocating refrigerator, the solid hydrogen refrigerator, the solid hydrogen/multistage radiator hybrid cooler, and the magneto-Peltier hybrid cooler.

Wright, J. P.↗

NASA NTRS2010

Convective Distribution of Tropospheric Ozone and Tracers in the Central American ITCZ Region: Evidence from Observations During TC4

During the Tropical Composition, Clouds and Climate Coupling (TC4) experiment that occurred in July and August of 2007, extensive sampling of active convection in the ITCZ region near Central America was performed from multiple aircraft and satellite sensors. As part of a sampling strategy designed to study cloud processes, the NASA ER-2, WB-57 and DC-8 flew in stacked "racetrack patterns" in convective cells. On July 24, 2007, the ER-2 and DC-8 probed an actively developing storm and the DC-8 was hit by lightning. Case studies of this flight, and of convective outflow on August 5, 2007 reveal a significant anti-correlation between ozone and condensed cloud water content. With little variability in the boundary layer and a vertical gradient, low ozone in the upper troposphere indicates convective transport. Because of the large spatial and temporal variability in surface CO and other pollutants in this region, low ozone is a better convective indicator. Lower tropospheric tracers methyl hydrogen peroxide, total organic bromine and calcium substantiate the ozone results. OMI measurements of mean upper tropospheric ozone near convection show lower ozone in convective outflow. A mass balance estimation of the amount of convective turnover below the tropical tropopause transition layer (TTL) is 50%, with an altitude of maximum convective outflow located between 10 and 11 km, 4 km below the cirrus anvil tops. It appears that convective lofting in this region of the ITCZ is either a two-stage or a rapid mixing process, because undiluted boundary layer air is never sampled in the convective outflow.

Avery, Melody↗

NASA NTRS1988

Dynamic cell culture system: a new cell cultivation instrument for biological experiments in space

The prototype of a miniaturized cell cultivation instrument for animal cell culture experiments aboard Spacelab is presented (Dynamic cell culture system: DCCS). The cell chamber is completely filled and has a working volume of 200 microliters. Medium exchange is achieved with a self-powered osmotic pump (flowrate 1 microliter h-1). The reservoir volume of culture medium is 230 microliters. The system is neither mechanically stirred nor equipped with sensors. Hamster kidney (Hak) cells growing on Cytodex 3 microcarriers were used to test the biological performance of the DCCS. Growth characteristics in the DCCS, as judged by maximal cell density, glucose consumption, lactic acid secretion and pH, were similar to those in cell culture tubes.

NASA Program Flight↗

DOE OSTI2024

Demonstrating autonomous controls on hardware test beds is a necessity for successful missions to Mars and beyond

NASA and the Department of Defense are planning for a mission to Mars in the 2030s–2040s using nuclear thermal propulsion (NTP). NTP uses a nuclear reactor to heat flowing hydrogen and create thrust. A serious concern for crewed and uncrewed missions to Mars is the loss of reactor control. The reactor startup and initial rocket impulse are initiated in cislunar or near-earth orbital regions; therefore, radio communications between ground control and the NTP engine should occur in real time. However, radio communications can take more than 20 min, depending on planet positions, to reach Mars orbiters from ground control. To address this delay, local autonomous controls are implemented onboard the NTP engine to ensure acceptable operation. However, autonomous controls have not been demonstrated or implemented in research or power reactor contexts because of safety and reliability concerns. To enable autonomous controls development, demonstration, and validation, Oak Ridge National Laboratory has created a nonnuclear hardware-in-the-loop test bed. Sensors throughout the test bed relay system status and hardware response to the user control algorithm, including measurements of temperature, flow, pressure of a loop, control drum position, and drum speed. This paper discusses the development of this facility and user accessibility.

33 ADVANCED PROPULSION SYSTEMS↗

NASA NTRS2010

Extracting Oxygen from Lunar Simulant Using a Transparent Furnace Pulsed Fluidized Bed

In the event that humans return to the moon, utilizing the local materials will be beneficial for extended stays. Rather than transporting resources, such as oxygen, from Earth, NASA is investigating methods of extracting it from lunar regolith. One promising process is hydrogen reduction. In the hydrogen reduction process, lunar regolith is heated to 1000 C in the presence of hydrogen. The iron oxide (Fe-O) bonds, found in lunar material, are broken and the hydrogen attracts the oxygen to produce water vapor [Allen et al., 1996]. FeO + H2 (right arrow) Fe +H2O. The water vapor is then captured, cleaned, and electrolyzed. The hydrogen is recycled back to the reduction process and the oxygen is stored until consumed by an end user (propulsion, life support, etc.). To obtain a good oxygen yield, the majority of lunar regolith must be exposed to the hydrogen gas and have a high rate of heat transfer from heat source to particle. This is achieved with good solids mixing via fluidization or mechanical agitation. In Generation II of the ROxygen program, the ROxygen Team at Johnson Space Center (JSC) investigated the feasibility of gas only pulsed fluidization as the only means to mix synthetic lunar regolith (simulant) at high temperatures. Fluidized beds have been used in industry to effectively process powders for decades. They consist of gas flowing upward through a bed of particles. The stirring action continuously moves the grains around to achieve uniform mixing of gas, solids, and heat [Geldart, 1986]. A transparent furnace unit was developed by Thoughventions Unlimited LLC (TvU) to aid in the qualitative observation of the fluidization behavior at high temperatures. Multipoint thermocouples and pressure sensors provided quantitative information regarding the quality of mixing. The water produced was measured using humidity sensors and captured using a NASA designed and built condenser. Once the simulant was processed, pneumatically transporting the 'hot' simulant out of the furnace was investigated.

Oryshchyn, L.↗

DOE OSTI2024

Reduction of Iron (III) Oxide in Microwaves Toward Gasification Studies

The purpose of this study is to reduce hematite (Fe2O3) using hydrogen (H2), carbon monoxide (CO), and methane (CH4) gases using microwave irradiation. Conventional temperature programmed reduction of iron phase transformation under H2, CO, and CH4 agree with the literature. Furthermore, the activation energy for the iron phase transformation in a conventional reactor was in the order of H2>CO>CH4, suggesting that CH4 was the best reductant to initiate the reduction at a much lower temperature than CO, and CO was significantly better than H2 atmosphere. Due to the uneven temperature distribution, the apparent activation energy of microwave reduction under H2 was approximately 1/4th when compared to the conventional reduction in H2. X-ray diffraction (XRD) analysis showed a mixed oxide phase in microwave reduction as opposed to the clear phase transformation in conventional studies. To combat the temperature measurement issues in microwave studies, fiber optic sensors and Forward Looking InfraRed (FLIR) sensors were used to acquire the actual temperature distribution in the catalyst bed. Therefore, a reasonably accurate activation energy estimation was achieved in the catalyst bed. Combining these with the characterization and quantification of the different iron phases in microwave reduction will provide a blueprint for future microwave-assisted gasification studies.

Aireddy, Divakar Reddy↗

NASA NTRS2023

Cryogenic Fluid In-Situ Liquefaction for Landers: Prototype Demonstration

As the advancement of In-Situ Resource Utilization concepts and systems continue to develop, applicable technology development and maturation continues in parallel. While there are many different ways to use the resources found on other bodies, one of the most prevalent suggested applications is the manufacturing of propellants. One of the key technologies for the eventual use of these propellant production based ISRU systems is the liquefaction and storage of the produced propellants. The most mentioned propellant combinations include oxygen-hydrogen and oxygen-methane. The liquefaction of oxygen in these systems will be different than oxygen liquefaction systems on Earth, which mainly revolves around the distillation of air. These systems have been developed conceptually and many of the components have been previously tested or are in development. However, the need to demonstrate the system level operations still exists. The demonstration of a prototypical oxygen liquefaction system using tube-on-tank broad area cooling was completed to better understanding system level operations during liquefaction activities. Demonstration testing included system performance determination, constant liquefaction demonstrations, and transient liquefaction demonstrations. The demonstrations showed the operational capabilities of the tube-on-tank system with an integrated cryocooler. Additional testing explored subsurface vs ullage introduction of the gaseous oxygen flow stream as well as demonstrating a novel fiber optic sensor that measured the temperature gradients along the fluid center line within the tank.

ISRU↗

NASA NTRSDate not supplied

Cryogenic Fluid In-Situ Liquefaction for Landers: Prototype Demonstration

ISRU↗

DOE OSTI2024

Quantitative measurements of reactive oxygen species partitioning in electron transfer flavoenzyme magnetic field sensing

Biological magnetic field sensing that gives rise to physiological responses is of considerable importance in quantum biology. The radical pair mechanism (RPM) is a fundamental quantum process that can explain some of the observed biological magnetic effects. In magnetically sensitive radical pair (RP) reactions, coherent spin dynamics between singlet and triplet pairs are modulated by weak magnetic fields. The resulting singlet and triplet reaction products lead to distinct biological signaling channels and cellular outcomes. A prevalent RP in biology is between flavin semiquinone and superoxide (O 2 •–) in the biological activation of molecular oxygen. This RP can result in a partitioning of reactive oxygen species (ROS) products to form either O 2 •– or hydrogen peroxide (H 2 O 2 ). Here, we examine magnetic sensing of recombinant human electron transfer flavoenzyme (ETF) reoxidation by selectively measuring O 2 •– and H 2 O 2 product distributions. ROS partitioning was observed between two static magnetic fields at 20 nT and 50 μT, with a 13% decrease in H 2 O 2 singlet products and a 10% increase in O 2 •– triplet products relative to 50 µT. RPM product yields were calculated for a realistic flavin/superoxide RP across the range of static magnetic fields, in agreement with experimental results. For a triplet born RP, the RPM also predicts about three times more O 2 •– than H 2 O 2 , with experimental results exhibiting about four time more O 2 •– produced by ETF. The method presented here illustrates the potential of a novel magnetic flavoprotein biological sensor that is directly linked to mitochondria bioenergetics and can be used as a target to study cell physiology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

2023 Real-time Optimization Workflow Status Update

Nuclear integrated energy systems are composed of a diverse set of energy generation sources and exist in dynamic and competitive electricity markets. With the inclusion of thermal energy storage, nuclear power systems can store heat for future use through various processes, such as water desalination or hydrogen generation. This heat storage can be managed in such a way as to economically optimize its usage. By combining real-time price data from the day-ahead and real-time markets with predictive and intelligent models, the charging and discharging of the thermal energy storage may be determined and optimized. This research details an approach through models and systems for the real-time optimization (RTO) of capacity allocation. Virtual models of the energy system and its physics phenomenon and component interactions provide intelligence to verification and prediction of operations. An optimization framework can use data generated from both a set of physical assets as well as the virtual models to predict future performance and create optimization and control workflows. Data warehouse technologies can be used to combine data across models, optimization workflows, market price data, and sensor data to intuitively store various types of data and provide integrations to physical control systems as well as user visualizations. Put together, these components can create a system for the RTO of nuclear integrated energy systems. Various virtual models and bench-scale physical demonstrations have been successfully performed and verified using this system. Larger scale testbeds that include thermal energy storage systems have been identified as future opportunities. A gap analysis that details the steps necessary to reach a physical demonstration at this scale is provided, along with conclusions on the current effort and future work.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

DOE OSTI2026

Hydrogen Detection via a Low-Cost Prototype Fiber-Optic Sensing System

The developed low-cost prototype sensing system successfully detects hydrogen concentrations across a wide range, demonstrating immediate feasibility for commercial deployment. Utilizing fiber-optic technology, the system delivers stable, reproducible performance from parts-per-million levels up to 100% pure H2 environments. Environmental and chemical cross-sensitivity evaluations confirm robust selectivity against methane and temperature changes, establishing its readiness for near-term commercialization.

fiber-optic H2 sensor↗

NASA NTRS2008

Calibrating the Helium Pressurization System for the Space Shuttle Liquid-Hydrogen Tank

Analysis of the results from the STS-114 tanking tests and subsequent launch called into question existing thermal and mass models of helium pressurization of the liquid hydrogen tank. This hydrogen tank, which makes up the bottom two-thirds of the External Tank, is pressurized prior to launch to avoid cavitation in the Shuttle Main Engine pumps. At about 2 minutes prior to launch, the main vent valve is closed, and pressurized helium flows into the tank ullage space to achieve set point pressure. As the helium gas cools, its pressure drops, calling for additional helium. Subsequent helium flows are provided in short, timed pulses. The number of pulses is taken as a rough leak indicator. An analysis of thermal models by Marshall Space Flight Center showed considerable uncertainty in the pressure-versus-time behavior of the helium ullage space and the ability to predict the number of pulses normally expected. Kennedy Space Center proposed to calibrate the dime-sized orifice, which together with valves, controls the helium flow quantity (Figure 1). Pressure and temperature sensors were installed to provide upstream and downstream measurements necessary to compute flow rate based on the orifice discharge coefficient. An assessment of flow testing with helium indicated an extremely costly use of this critical resource. In order to reduce costs, we proposed removing the orifices from each Mobile Launcher Platform (MLP) and asking Colorado Engineering Experiment Station Inc. (CEESI) to calibrate the flow. CEESI has a high-pressure air flow system with traceable flow meters capable of handling the large flow rates. However, literature research indicated that square-edged orifices of small diameters often exhibit significant hysteresis and nonrepeatability in the vicinity of choked or sonic flow. Fortunately, the MLP orifices behaved relatively well in testing (Figure 2). Using curve fitting of the air-flow data, in conjunction with ASME orifice modeling equations, a method of relating the helium mass flow to measured air flow data was obtained. This analysis showed that the highest uncertainty in flow occurred in the vicinity of the choking pressure ratio, as would be expected. In addition, analysis of typical flow pulses showed that most of the helium flow occurred either well below or well above this uncertain area. The final result is the ability to provide postlaunch estimates of helium mass flows that are within 1.5 percent of the actual value.

Source record↗

NASA NTRS2009

Silicon Nanowire Growth at Chosen Positions and Orientations

It is now possible to grow silicon nanowires at chosen positions and orientations by a method that involves a combination of standard microfabrication processes. Because their positions and orientations can be chosen with unprecedented precision, the nanowires can be utilized as integral parts of individually electronically addressable devices in dense arrays. Nanowires made from silicon and perhaps other semiconductors hold substantial promise for integration into highly miniaturized sensors, field-effect transistors, optoelectronic devices, and other electronic devices. Like bulk semiconductors, inorganic semiconducting nanowires are characterized by electronic energy bandgaps that render them suitable as means of modulating or controlling electronic signals through electrostatic gating, in response to incident light, or in response to molecules of interest close to their surfaces. There is now potential for fabricating arrays of uniform, individually electronically addressable nanowires tailored to specific applications. The method involves formation of metal catalytic particles at the desired positions on a substrate, followed by heating the substrate in the presence of silane gas. The figure illustrates an example in which a substrate includes a silicon dioxide surface layer that has been etched into an array of pillars and the catalytic (in this case, gold) particles have been placed on the right-facing sides of the pillars. The catalytic thermal decomposition of the silane to silicon and hydrogen causes silicon columns (the desired nanowires) to grow outward from the originally catalyzed spots on the substrate, carrying the catalytic particles at their tips. Thus, the position and orientation of each silicon nanowire is determined by the position of its originally catalyzed spot on the substrate surface, and the orientation of the nanowire is perpendicular to the substrate surface at the originally catalyzed spot.

Getty, Stephanie A.↗

NASA NTRS2001

Synthesis of Carbon Nanotubes Array by CVD

Since the properties of multi-wall carbon nanotubes (MWCNT) are superior in many devices such as electronics and sensors, many efforts have been involved in synthesizing particular structural or dimensional MWCNT. Uniform aligned MWCNT array is one of the prototype structures for devices such as filed emission device and microelectromechanical systems in which a large length to diameter ratio may also be required. Most aligned MWCNT recently synthesized by plasma enhanced chemical vapor deposition (CVD) have cone shaped structures. This presentation will illustrate aligned MWCNT array synthesized on silicon substrates using thermal CVD that could produce MWCNT with uniform diameter. An array of nickel particles was used as catalyst for MWCNT growth. A thin Ti or Au buffer layer was coated on the substrate prior to depositing nickel particles. Because the MWCNT size depends on the catalyst particle size, the nickel particle size annealed at various temperatures was investigated. MWCNT were grown on the substrate in the temperature range of 700 C - 1000 C and the pressure range of 1 to 300 torr. Methane and hydrogen gases with methane content of 1 - 10 % were used for the MWCNT synthesis. Morphology, length and diameter of MWCNT were determined by scanning electron microscopy and Raman spectroscopy. The detailed results of synthesis and characterizations will be discussed in the presentation.

Zhu, S.↗

NASA NTRS2012

Testing Lunar Permanently Shadowed Regions for Water Ice: LEND Results from LRO

We use measurements from the Lunar Exploration Neutron Detector (LEND) collimated sensors during more than one year of the mapping phase of NASA's Lunar Reconnaissance Orbiter (LRO) mission to make estimates of the epithermal neutron flux within known large Permanently Shadowed Regions (PSRs). These are compared with the local neutron background measured outside PSRs in sunlit regions. Individual and collective analyses of PSR properties have been performed. Only three large PSRs, Shoemaker and Cabeus in the south and Rozhdestvensky U in the north, have been found to manifest significant neutron suppression. All other PSRs have much smaller suppression, only a few percent, if at all. Some even display an excess of neutron emission in comparison to the sunlit vicinity around them. Testing PSRs collectively, we have not found any average suppression for them. Only the group of 18 large PSRs, with area >200 square kilometers, show a marginal effect of small average suppression, approx. 2%, with low statistical confidence. An approx. 2% suppression corresponds to approx. 125 ppm of hydrogen taking into account the global neutron suppression near the lunar poles and assuming a homogeneous H distribution in depth in the regolith. This means that all PSRs, except those in Shoemaker, Cabeus and Rozhdestvensky U craters, do not contain any significant amount of hydrogen in comparison with sunlit areas around them at the same latitude.

LEND↗