DOE OSTI2013
Ceramic matrix composites, in particular SiC/SiC composites, are currently being evaluated for use at high temperatures and high radiation fields in advanced concept reactors, including high-temperature gas cooled reactors (HTGR), very high temperature reactors (VHTR), gas fast reactors (GFR), sodium fast reactors (SFR) and fluoride-cooled high temperature reactors (FHR). SiC/SiC composites have many desirable properties for high temperature nuclear applications, including excellent thermal and mechanical properties and radiation resistance. However, their behavior in contact with the chemical environment in normal operation conditions and in off-normal accident conditions scenarios still needs to be evaluated. This report summarizes the information available in the literature on the chemical reactivity of SiC/SiC composites and of their components in contact with the helium coolant used in HTGR, VHTR and GFR designs. Under normal operating conditions, ultra-high purity helium will have chemically controlled impurities (water, oxygen, carbon dioxide, carbon monoxide, methane, hydrogen) that will create a slightly oxidizing gas environment. Little is known from direct experiments on the reactivity of third generation (nuclear grade) SiC/SiC composites in contact with low concentrations of water or oxygen in inert gas, at high temperature. However, there is ample information regarding the oxidation behavior of SiC/SiC composites in dry and moist air at high temperatures. This information is reviewed first in the next chapters. The emphasis is placed on the improvement in material oxidation, thermal, and mechanical properties during three stages of development of SiC fibers and at least two stages of development of the fiber/matrix interphase. The chemical stability of SiC/SiC composites in contact with oxygen or steam at temperatures that may develop in off-normal reactor conditions supports the conclusion that most advanced composites (also known as nuclear grade SiC/SiC composites) have the chemical resistance that would allow them maintain mechanical properties at temperatures up to 1200 – 1300 °C in the extreme conditions of an air or water ingress accident scenario. Further research is needed to assess the long-term stability of advanced SiC/SiC composites in inert gas (helium) in presence of very low concentrations (traces) of water and oxygen at the temperatures of normal operation of helium-cooled reactors.
ceramic matrix composites↗