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At least 451 records · Page 25

Stability Boundaries of Discharges Generated in the Focal Region of a CW Microwave Beam

Plasma was generated in the focal region of a multikilowatt, 4.7-GHz continuous-wave (CW) microwave beam far removed from the walls of the vacuum chamber, minimizing the nonideal effects associated with plasma-wall and beam-wall interactions. Experiments were conducted with gas mixtures of argon, nitrogen, and oxygen at gas pressures ranging from 100 to 200 mtorr. Furthermore, three types of discharges were observed during these experiments: unstable, quasi-stable, and stable discharges. It was determined that the stability of the discharges could be controlled through adjustments of the gas composition, gas pressure, and power of the microwave beam. This article reports on the operational conditions in which stable discharges were achieved and the general behavior of these discharges as the control parameters were varied.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Investigations of laser pumped gas cell atomic frequency standard

The performance characteristics of a rubidium gas cell atomic frequency standard might be improved by replacing the standard rubidium discharge lamp with a single mode laser diode. Aspects of the laser pumped gas cell atomic clock studied include effects due to laser intensity, laser detuning, and the choice of the particular atomic absorption line. Results indicate that the performance of the gas cell clock may be improved by judicious choice of the operating parameters of the laser diode. The laser diode also proved to be a valuable tool in investigating the operation of the conventional gas cell clock. Results concerning linewidths, the light shift effect and the effect of isotopic spin exchange in the conventional gas cell clock are reported.

Volk, C. H.↗

Gas ion laser construction for electrically isolating the pressure gauge thereof

The valve and the pressure gauge of a gas ion laser were electrically insulated from the laser discharge path by connecting them in series with the cathode of the laser. The laser cathode can be grounded and preferably is a cold cathode although a hot cathode may be used instead. The cold cathode was provided with a central aperture to which was connected both the pressure gauge and the gas pressure reservoir through the valve. This will effectively prevent electric discharges from passing either to the pressure gauge or the valve which would otherwise destroy the pressure gauge.

Wood, C. E.↗

Experimental clean combustor program: Turbulence characteristics of compressor discharge flows

The results of turbulence measurements at the entrance to the diffuser duct of a large gas turbine are presented. Hot film and hot wire measurements were conducted over a compressor discharge temperature range of 450K to 608K. It was found that the turbulent intensity at the I.D. and midspan locations increases gradually from 6 + or - 1 percent at idle to 7 + or - 1 percent at approach; the turbulent intensity at the O.D. location increases from 7.5 + or - 0.5 percent at idle to 15 + or - 0.5 percent at approach. The energy in the velocity waves is uniformly distributed over a 0.1 to 5 kHz bandwidth, and the cut-off frequency is not a strong function of the engine operation. The axial length of the Fourier components within this bandwidth varies from 0.021 to 1.05m. The turbulence near the diffuser O.D. is of sufficient amplitude and scale to affect the flow to the front end sections of the burner.

Follansbee, P. S.↗

High-voltage spark atomic emission detector for gas chromatography

A dc-powered, double-gap, miniature nanosecond spark source for emission spectrochemical analysis of gas chromatographic effluents is described. The spark is formed between two thoriated tungsten electrodes by the discharge of a coaxial capacitor. The spark detector is coupled to the gas chromatograph by a heated transfer line. The gas chromatographic effluent is introduced into the heated spark chamber where atomization and excitation of the effluent occurs upon breakdown of the analytical gap. A microcomputer-controlled data acquisition system allows the implementation of time-resolution techniques to distinguish between the analyte emission and the background continuum produced by the spark discharge. Multiple sparks are computer averaged to improve the signal-to-noise ratio. The application of the spark detector for element-selective detection of metals and nonmetals is reported.

Calkin, C. L.↗

Experimental and analytical sonic nozzle discharge coefficients for Reynolds numbers up to 8 x 10 to the 6th power

Sonic discharge coefficients are obtained for two different geometry flow nozzles using high-pressure nitrogen gas (100 atm) with significant real-gas flow corrections. Throat Reynolds number range extended up to 8 million. Discharge coefficients for both nozzles monotonically increase in value at the high throat Reynolds numbers. The 95-percent confidence band for each nozzle is shown. Analytical discharge coefficients for the continuous and finite radius of curvature nozzle are presented. These analytical results for the laminar and turbulent boundary-layer cases are compared to experimental values for sonic flow. Experimental values are also compared to values calculated from the best empirical curve fit equation for subsonic flow.

Szaniszlo, A. J.↗

Managing photon flux in a miniaturized photoionization detector

Miniaturized photoionization detectors (PIDs) are used in conjunction with gas chromatography systems to detect volatile compounds in gases by collecting the current from the photoionized gas analytes. PIDs should be inexpensive and compatible with a wide range of analyte species. One such PID is based on the formation of a He plasma in a dielectric barrier discharge (DBD), which generates vacuum UV (VUV) photons from excited states of He to photoionize gas analytes. There are several design parameters that can be leveraged to increase the ionizing photon flux to gas analytes to increase the sensitivity of the PID. To that end, the methods to maximize the photon flux from a pulsed He plasma in a DBD-PID were investigated using a two-dimensional plasma hydrodynamics model. The ionizing photon flux originated from the resonance states of helium, He(3P) and He(2 1 P), and from the dimer excimer He 2 *. While the photon flux from the resonant states was modulated over the voltage pulse, the photon flux from He 2 * persisted long after the voltage pulse passed. Several geometrical optimizations were investigated, such as using an array of pointed electrodes. However, increasing the capacitance of the dielectric enclosing the plasma chamber had the largest effect on increasing the VUV photon fluence to gas analytes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Preliminary investigation of high power microwave plasmas for electrothermal thruster use

Results are reported from preliminary tests to evaluate the high power microwave electrothermal thruster concept, which employs a free-floating plasma discharge maintained by applied CW microwave power to heat a propellant gas flow. Stable plasmas have been created and maintained in He, N2, and H2 as propellants in both the TM(sub 011) and TM(sub 012) modes at discharge pressures from 10 Pa to 69 kPa. Vortical inflow of the propellant gas was observed to cause the formation of on-axis 'spike' plasmas. Operation in the spike plasma condition yields maximum power absorption with minimum wall heating and maximum propellant-heating efficiency; plasmas of the three propellant gases were investigated in the spike condition in an open channel to a maximum applied power level of 11.2 kW (in N2). Microwave power coupling efficiencies of over 90 percent were routinely obtained at absorbed power levels up to 2 kW. Magnetic nozzle effects were investigated with a superconducting solenoid Al magnet applying a high magnetic field to the plasmas in, and exiting from, the discharge tube.

Power, John L.↗

Performance sensitivity analysis of Department of Energy-Chrysler upgraded automotive gas turbine engine, S/N 5-4

The performance sensitivity of a two-shaft automotive gas turbine engine to changes in component performance and cycle operating parameters was examined. Sensitivities were determined for changes in turbomachinery efficiency, compressor inlet temperature, power turbine discharge temperature, regenerator effectiveness, regenerator pressure drop, and several gas flow and heat leaks. Compressor efficiency was found to have the greatest effect on system performance.

Johnsen, R. L.↗

Disorder-induced heating as a mechanism for fast neutral gas heating in atmospheric pressure plasmas

Abstract Recent findings suggest that ions are strongly correlated in atmospheric pressure plasmas if the ionization fraction is sufficiently high ( ≳ 10 − 5 ). A consequence is that ionization causes disorder-induced heating (DIH), which triggers a significant rise in ion temperature on a picosecond timescale. This is followed by a rise in the neutral gas temperature on a longer timescale of up to nanoseconds due to ion–neutral temperature relaxation. The sequence of DIH and ion–neutral temperature relaxation suggests a new mechanism for ultrafast neutral gas heating. Previous work considered only the case of an instantaneous ionization pulse, whereas the ionization pulse extends over nanoseconds in many experiments. Here, molecular dynamics simulations are used to analyze the evolution of ion and neutral gas temperatures for a gradual ionization over several nanoseconds. The results are compared with published experimental results from a nanosecond pulsed discharge, showing good agreement with a measurement of fast neutral gas heating.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Dynamics and chemical mode analysis of plasma thermal-chemical instability

The stability of the weakly ionized plasma and the transition from a stable homogeneous discharge to unstable filaments play an important role in gas laser physics, plasma-assisted combustion, chemical reforming, and material synthesis. Here, theoretical stability analysis and thermal-chemical mode analysis were performed to understand the mechanism of plasma thermal-chemical instability by using a zero-dimensional plasma system with both simplified and detailed chemical kinetics of H 2 /O 2 /N 2 mixtures. The plasma dynamic and kinetic models accounted for multiple physical mechanisms in the chemically-reactive weakly ionized plasma, including ionization, attachment/detachment, recombination, vibrational and electronic energy relaxation, convective and diffusive species/heat removal, Joule heating, and detailed chemical kinetics. An analytical criterion and the explosive mode species/temperature pointers were formulated while the representative active species were identified for different thermal-chemical modes. The results showed that in addition to the classical thermal-ionization mechanism, various chemical modes from chemical heat imbalance and elementary kinetics significantly modified the time dynamics and the stability of the weakly ionized plasma. The present analysis provides insights and guidance to control plasma instability using chemical kinetics.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Low-Temperature Production of Cosmic Grains Analogs From Gas-Phase Molecular Precursors with the NASA Ames' COSmIC Facility

Complex carbon molecules and ions are ubiquitous in space and form the building blocks of carbonaceous cosmic dust grains, ultimately contributing to the formation of planets. Here, we report the first experimental investigations of the low temperature chemical pathways leading to the production of cosmic grain analogs from gas phase molecular precursors in order to better understand the evolution of cosmic carbon. The experiments were performed using the COsmic SImulation Chamber (COSmIC) to generate and characterize grains formed from gas phase precursors under controlled conditions representative of astrophysical environments [1]. Using COSmIC, it is possible to investigate the evolution of cosmic carbon from the formation of neutral and ionized gas phase hydrocarbons and PAHs [2], to carbon grains [3, 4]. This is achieved by using a discharge nozzle to (1) produce an adiabatic jet expansion and cool down Ar-hydrocarbon/PAH gas mixtures to astrophysically relevant temperature (150 K) before inducing chemistry by generating a plasma discharge in the stream of the expansion. This plasma-induced chemistry results in the formation of complex molecules and solid particles, analogs of cosmic grains. Solid grains are produced in-situ in the plasma expansion, carried by the accelerated gas in the expansion, and collected on substrates placed a few centimeters downstream of the electrodes. The results of a preliminary solid phase ex-situ analysis of cosmic grain analogs produced at low temperature in COSmIC from gas mixtures including molecular precursors of cosmic carbon grains, i.e., such as CH4 and C2H2 found in circumstellar ejecta of late C stars [3] as well as PAHs ubiquitously detected in IR emission bands seen in galactic and extragalactic environments [4] will be discussed. Scanning Electron Microscopy imaging was used to provide insight on the morphology and growth structure of the grains produced in COSmIC, and to investigate how the precursors used to produce the grains affect these parameters [3]. Laser desorption mass spectrometry was used to identify the molecules making up the main structures within the condensed grains [4]. NIR to FIR optical properties are characterized to provide critical information (functional groups, optical constants) to the scientific community, for use in radiative transfer models in particular, and to help decipher and enhance the return data from space observations.

F. Salama↗

An experimental investigation of cusped magnetic field discharge chambers

Several features of a proposed model of ion thruster performance are tested experimentally. The experiment conducted demonstrates the effects of variation in thruster operating parameters on the average plasma ion energy costs and extracted ion fractions of various ring and line cusp discharge chambers. The results indicate that the model correctly predicts the variation in the plasma ion energy cost resulting from changes in: propellant gas, grid transparency to neutral atoms, beam extraction area, and discharge voltage. In addition, the model is shown to be applicable to both ring and line cusp designs. Measurements of the extracted ion fraction indicate that this parameter tends to increase with decreasing discharge voltage and is generally higher for operation with argon as opposed to krypton propellant. Results suggest that to use the proposed thruster performance model as an aid in thruster design the performance may be described in terms of four thruster configuration dependent constants and two operating parameters.

Brophy, J. R.↗

Low Temperature Formation of Carbonaceous Grains from Hydrocarbons and PAHs with the COSmIC Facility

Complex carbon molecules and ions are ubiquitous in space and form the building blocks of the carbonaceous components of cosmic dust grains, ultimately contributing to the formation of planets. We report experimental investigations of the low temperature chemical pathways leading to the formation of cosmic grain analogs from gas phase molecular precursors to better understand the evolution of cosmic carbon. The study of the formation of dust is essential to understand and to quantify the budget of extraterrestrial organic molecules. Although dust plays an important role in the evolution of interstellar chemistry and in the formation of organic molecules, little is known on the formation and destruction processes of carbonaceous dust. The experiments were performed using the Cosmic Simulation Chamber (COSmIC) to generate and characterize solid grains formed from gas phase precursors under controlled conditions representative of astrophysical environments [1]. Using COSmIC, it is possible to investigate the evolution of cosmic carbon from the formation of neutral and ionized hydrocarbons and PAHs in the gas phase [2], to solid carbon grains [3, 4, 5]. This is achieved by using a pulsed slit discharge nozzle to produce an adiabatic jet expansion and cool down Ar-hydrocarbon and PAH gas mixtures to astrophysically relevant temperature before inducing chemistry by generating a plasma discharge in the stream of the expansion. This plasma induced chemistry results in the formation of complex molecules and solid particles, analogs of cosmic grains in situ in the plasma expansion (i.e., without wall effects) that are carried by the accelerated gas in the expansion, and collected on substrates placed a few centimeters downstream of the electrodes. The results of a preliminary solid phase ex-situ analysis of cosmic grain analogs produced from a series of gas mixtures including hydrocarbons such as CH4 and C2H2 [3] and PAHs [4, 5] found in circumstellar ejecta of late C stars will be discussed. SEM imaging was used to provide insight on the impact of the precursors on the morphology and growth structure of the grains produced [3]. Laser desorption mass spectrometry was used to identify the molecules making up the main structures within the condensed grains [4] while X-ray irradiation and X-ray photoemission spectroscopy were used to investigate the impact the impact of stellar X-rays on cosmic dust.

Carbonaceous Grains↗

Investigations into Plasma-Mediated Decomposition of Organoiodide Species as a Pretreatment for Mitigation of Radioiodine Emissions

A plasma-mediated pretreatment step is proposed to decompose methyl iodide (CH 3 I) for facilitating the capture of the iodine radioisotopes present in off-gas streams from used nuclear fuel reprocessing operations. Simulated CH 3 I gas streams were exposed to dielectric barrier discharge (DBD) plasma in a quartz glass continuous-flow reactor using copper electrodes. The kinetics of decomposition of CH 3 I in nitrogen was investigated by varying the applied voltage, inlet concentration, and residence time. The rate of decomposition was proportional to CH 3 I concentration and increased as the applied potential was increased. This effect was incorporated in the kinetics through the dependence of the rate constant on the applied electric field. Decomposition of CH 3 I was not affected by moisture, and the DBD pretreatment is likely to be similarly effective in an air environment as well; however, the results were confounded by a plasma-mediated reaction between nitrogen and oxygen.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Inertial and anisotropic pressure effects on cross-field electron transport in low-temperature magnetized plasmas

In this paper, a one-dimensional (1D) particle-in-cell Monte Carlo collision (PIC-MCC) model is developed to investigate the effects of anisotropic pressure and inertial terms due to non-Maxwellian velocity distribution functions on cross-field electron transport. The conservation of momentum is evaluated by taking the moments of the first-principles gas-kinetic equation. A steady-state discharge is obtained without any low-frequency ionization oscillations by considering an anomalous electron scattering profile. Further, the results obtained from the 1D PIC-MCC model are compared with fluid models, including the quasi-neutral drift-diffusion (DD), non-neutral DD, and full fluid moment models. The discharge current obtained from the PIC-MCC model is in good agreement with the fluid models. The cross-field electron transport due to the inertial terms, i.e. the gradient of axial and azimuthal drift, is evaluated. Moreover, PIC-MCC simulation results show non-zero, anisotropic, off-diagonal pressure tensor terms due to asymmetric non-Maxwellian electron velocity distribution function, potentially contributing to cross-field electron transport.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Carbon-free high-performance cathode for solid-state Li-O 2 battery

The development of a cathode for solid-state lithium-oxygen batteries has been hindered in practice by a low capacity and limited cycle life despite their potential for high energy density. Here, a previously unexplored strategy is proposed wherein the cathode delivers a specific capacity of 200 milliampere hour per gram over 665 discharge/charge cycles, while existing cathodes achieve only ~50 milliampere hour per gram and ~100 cycles. A highly conductive ruthenium-based composite is designed as a carbon-free cathode by first-principles calculations to avoid the degradation associated with carbonaceous materials, implying an improvement in stability during the electrochemical cycling. In addition, water vapor is added into the main oxygen gas as an additive to change the discharge product from growth-restricted lithium peroxide to easily grown lithium hydroxide, resulting in a notable increase in capacity. Thus, the proposed strategy is effective for developing reversible solid-state lithium-oxygen batteries with high energy density.

36 MATERIALS SCIENCE↗

Negative feedback system reduces pump oscillations

External negative feedback system counteracts low frequency oscillations in rocket engine propellant pumps. The system uses a control piston to sense pump discharge fluid on one side and a gas pocket on the other.

Rosenmann, W.↗