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At least 451 records · Page 25

Forced Forward Smoldering Experiments Aboard The Space Shuttle

Smoldering is a basic combustion problem that presents a fire risk because it is initiated at low temperatures and because the reaction can propagate slowly in the material interior and go undetected for long periods of time. It yields a higher conversion of fuel to toxic compounds than does flaming, and may undergo a transition to flaming. To date there have been a few minor incidents of overheated and charred cables and electrical components reported on Space Shuttle flights. With the establishment of the International Space Station, and the planning of a potential manned mission to Mars, there has been an increased interest in the study of smoldering in microgravity. The Microgravity Smoldering Combustion (MSC) experiment is part of a study of the smolder characteristics of porous combustible materials in a spacecraft environment. The aim of the experiment is to provide a better fundamental understanding of the controlling mechanisms of smoldering combustion under normal- and microgravity conditions. This in turn will aid in the prevention and control of smolder originated fires, both on earth and in spacecrafts. The microgravity smoldering experiments have to be conducted in a space-based facility because smoldering is a very slow process and consequently its study in a microgravity environment requires extended periods of time. The microgravity experiments reported here were conducted aboard the Space Shuttle. The most recent tests were conducted during the STS-105 and STS-108 missions. The results of the forward smolder experiments from these flights are reported here. In forward smolder, the reaction front propagates in the same direction as the oxidizer flow. The heat released by the heterogeneous oxidation reaction is transferred ahead of the reaction heating the unreacted fuel. The resulting increase of the virgin fuel temperature leads to the onset of the smolder reaction, and propagates through the fuel. The MSC data are compared with normal gravity data to determine the effect of gravity on smolder.

Fernandez-Pello, A. C.↗

Self-organized spiral and circular waves in premixed gas flames

A diffusive-thermal high Lewis number (Le) gas-phase oscillator has been observed in premixed flames using a lean mixture of butane and oxygen diluted with helium (Le approximately equals 3.0). This reactive-diffusive system exhibits both propagating radial pulsations and rotating spiral waves perhaps analogous to those observed in other excitable media such as the Belousov-Zhabotinsky reaction.

Pearlman, Howard G.↗

Self-similar blast waves incorporating deflagrations of variable speed

The present investigation is concerned with the development of a systematic approach to the problem of self-similar blast waves incorporating nonsteady flames. The regime covered by the presented solutions is bounded on one side by an adiabatic strong explosion and, on the other, by deflagration propagating at an infinite acceleration. Results for a representative set of accelerations are displayed, taking into account the full range of propagation speeds from zero to velocities corresponding to the Chapman-Jouguet deflagration. It is found that the distribution of stored energy in the undisturbed medium determines the acceleration of the deflagration-shock wave system. The obtained results reveal the existence of a simple relation between the location of the deflagration and its Mach number.

Guirguis, R. H.↗

Experimental Observation of Hydrocarbon Growth by Resonance‐Stabilized Radical–Radical Chain Reaction

Abstract Rapid molecular‐weight growth of hydrocarbons occurs in flames, in industrial synthesis, and potentially in cold astrochemical environments. A variety of high‐ and low‐temperature chemical mechanisms have been proposed and confirmed, but more facile pathways may be needed to explain observations. We provide laboratory confirmation in a controlled pyrolysis environment of a recently proposed mechanism, radical–radical chain reactions of resonance‐stabilized species. The recombination reaction of phenyl (c‐C 6 H 5 ) and benzyl (c‐C 6 H 5 CH 2 ) radicals produces both diphenylmethane and diphenylmethyl radicals, the concentration of the latter increasing with rising temperature. A second phenyl addition to the product radical forms both triphenylmethane and triphenylmethyl radicals, confirming the propagation of radical–radical chain reactions under the experimental conditions of high temperature (1100–1600 K) and low pressure (ca. 3 kPa). Similar chain reactions may contribute to particle growth in flames, the interstellar medium, and industrial reactors.

Couch, David E.↗

Experimental observation of hydrocarbon growth by resonance stabilized radical-radical chain reaction

Rapid molecular weight growth of hydrocarbons occurs in flames, in industrial synthesis, and potentially in cold astrochemical environments. A variety of high- and low-temperature chemical mechanisms have been proposed and confirmed, but more facile pathways may be needed to explain observations. Here, we provide laboratory confirmation in a controlled pyrolysis environment of a recently proposed mechanism, radical-radical chain reactions of resonance-stabilized species. The recombination reaction of phenyl (c-C 6 H 5 ) and benzyl (c-C 6 H 5 CH 2 ) radicals produces both diphenylmethane and diphenylmethyl radicals, the concentration of the latter increasing with rising temperature. A second phenyl addition to the product radical forms both triphenylmethane and triphenylmethyl radicals, confirming the propagation of radical-radical chain reactions under the experimental conditions of high temperature (1100-1600 K) and low pressure (~3 kPa). Similar chain reactions may contribute to particle growth in flames, the interstellar medium, and industrial reactors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Its a Wind, Its a Wave, Its Two Phenomena in One: Jerry Schubert, Superrotation, and the UV Markings on Venus

In the early 1970's, ground-based astronomers had already discovered that Ultraviolet (UV) cloud markings on Venus reappeared every 4 days. When radar evidence later revealed a 243-day rotation period for the solid planet, planetary scientists were faced with a quandary: Could the Venus atmosphere really move 60 times as fast as the planet below, or were the apparent movements of the UV features just an illusion caused by propagating waves? The former explanation seemed unlikely - a planet that hardly rotates should generate only a very sluggish circulation. The historical impact of Jerry Schubert's moving flame theory was twofold: It was the forerunner of current thermal tide explanations of the cloud-level superrotation, but it was also the first plausible mechanism for explaining a seemingly inconsistent set of observations. In 1974, Mariner 10 acquired UV images of the Venus clouds at unprecedented levels of detail. Although few have noted it, this began the shift of planetary atmospheric research primarily from the domain of astronomy to that of meteorology. Jerry was among the first scientists to apply terrestrial meteorology to the analysis of planetary data. At that time a young UCLA graduate student with plans to do research on mantle convection, but having flunked the solid earth geophysics section of his departmental comprehensive exam, was gently invited by Jerry to switch to atmospheric science. Jerry suggested that the Venus UV features could be revealing both superrotating winds and planetary-scale waves at the same time, and that we could distinguish the two by looking at motions on different spatial scales. This was my first science research lesson - the complexity of real geophysical systems. Over the next couple of years I was inculcated with Jerry's philosophy of a comprehensive, rigorous approach to research, which manifested itself as a scouring of the literature and the UCLA meteorology faculty to learn about every possible type of planetary-scale wave. The resulting identification of large-scale UV features on Venus as the product of Kelvin and Rossby-type wave motions was validated by extensive Pioneer Venus observations a decade later and remains one of the best examples of the use of terrestrial knowledge to understand other planets.

DelGenio, Anthony↗

A Warm Garage for a Lunar Rover

Approach: One approach to heating a rover during the lunar night is the so-called thermal wadis concept [1]. This involves heating the regolith with solar concentrators and placing the rover on the heated surface for the night. Since the regolith is heated by a relatively weak heat flux, a high thermal conductivity is required for heating a sufficiently large mass of regolith. However, lunar regolith has a low thermal conductivity. Therefore, the concept involves increasing the conductivity by sintering the regolith, which requires a significant energy input and complex procedures. Here we propose an alternative approach where the low thermal conductivity of regolith is an advantage. Specifically, we propose to use a highly exothermic combustible mixture for heat generation. The mixture pellets are placed in the surface layer of regolith and ignited. The combustion forms condensed products and releases heat, which then slowly spreads to the surrounding regolith. Heat can also be transferred, for example, by heat pipes, into radiant heating surfaces installed on the ground. A greenhouse that transmits sunlight during the day and decreases the radiative heat losses during the night can also be installed. Selection of the Heat-generating Mixture: The reactive mixture should have a high specific energy and generate only condensed products since gases could disturb the regolith layer, carry enthalpy out of the system, and lead to an explosion. There are mixtures, (sometimes called pyrolants) that possess very high specific energies. One example is magnesium-Teflon-Viton mixtures used in flares. However, they produce gases and may cause explosions. Other mixtures that include magnesium cannot be used either because of the high vapor pressure of Mg at temperatures well below the combustion temperature. Recently, mixtures that involve lithium peroxide (Li2O2) have been proposedfor using in space power systems [2]. However, they produce lithium oxide (Li2O), which boils at 2800 K at 1 atm and hence at a lower temperature in vacuum. Fortunately, there exist many mixtures that release a lot of heat and form only condensed products during the combustion. Many such mixtures have been used for self-propagating high-temperature synthesis (SHS) of various materials [3, 4]. For the application discussed here, t itanium/boron (1:2 mole ratio) mixture appears to be particularly promising. The specific energy is 4.0 MJ/kg (1.1 kWh/kg), the adiabatic flame temperature is about 3200 K, and the reaction forms solid titanium diboride (TiB2, melting point: 3500 K). The mixture can be ignited easily with a heated tungsten wire, and it has been used widely as a booster to ignite the main mixture in the SHS process.Estimates: Assuming that specific heat of regolith is 500 J/(kg∙K) [5] and all generated heat is transferred to regolith, 12.5 kg of the Ti/B mixture would increase the temperature of 1000 kg of regolith by 100 K. To evaluate the rate of heat transfer in the regolith, a spherical model was analyzed where the heat released by a 12.5 kg Ti/B core propagates by thermal conduction through a 1000 kg regolith shell with no heat loss from its outer surface. At a bulk density of 1500 kg/m3 [5], the radius of the shell was 54 cm, while the radius of the core was about 11 cm. The calculations were conducted using Thermal Desktop SINDA/FLUINT (Cullimore and Ring Technologies) software at two constant values of bulk thermal conductivityk of the regolith: 0.001 and 0.01 W/(m∙K). The results show that after 14.5 days the core lost 31% of the released heat at the lower k and 77% at the higher k. At a distance of 20 cm from the core surface, the temperature of the regolith increased by only 1 K at the lower k and by 132 K at the higher k. In reality, the regolith near the heat source will be melted, so its thermal conductivity will increase significantly. Nevertheless, the conducted estimates indicate that combustion-based heat generators, placed directly in the regolith, could provide heat during a rather long period such as the lunar night.Conclusion: Heat generators based on gasless combustion of highly energetic reactive mixtures could be installed directly in the surface layer of lunar regolith. Because of the low thermal conductivity of the regolith, such generators would keep thermal energy for days and gradually supply heat to a rover/lander.Acknowledgment: The material presented in this work is based upon the work supported by National Aeronautics and Space Administration (NASA) under Grant #80NSSC20K0293.References: [1] Balasubramaniam R. et al. (2011) J. Thermophys. Heat Trans., 25,130−139. [2] Blair R.G. and Vasu S.S. (2022) Conf. Advanced Power Systems for Deep Space Exploration. [3] Varma A. et al. (1998) Adv. Chem. Eng., 24,79−226. [4] Levashov E.A. et al. (2017) Int. Mater. Rev., 62,203−239. [5] Wood-Robinson R. et al. (2019) J. Geophys. Res. Planets, 124, 1989−2011.

lunar↗

Examination of entrainment, combustibility, and heat transfer due to cell venting inside simplified battery energy storage enclosures

Battery energy storage systems (ESS) assembled of modules containing lithium-ion batteries can pose fire and explosion hazards during thermal runaway because vented gases may accumulate, combust, or escape enclosures. Here, we propose a prototypical configuration composed of the main components of an ESS rack, where modules are represented as rectangles within an enclosure and vent gas is injected steadily through the top of a module. This idealized geometry allows for exploration of how rack-level characteristics can influence smaller single-cell or module-level scales. Through this geometry, we conduct numerical simulations to understand how variations in the vent velocity, temperature, and vertical location affect entrainment rates, fraction of uncombusted fuel, rich-gas coverage, and heat flux to other modules. At lower vent velocities and vertical positions, buoyancy drives enough entrainment and mixing to react with most of the vent gases on the converging plenum. As jet momentum increases and/or buoyancy decreases via higher vent position in the rack, vent gases can propagate into and burn in the divergence plenum. Heat flux to the impinged module scales strongly with vent momentum and temperature, while heat transfer to upper modules peaks when flames in the diverging plenum reach the surface and declines when combustion is suppressed.

Computational fluid dynamics↗

Introduction: Thermal Radiation in Industrial Flames

The following topics are addressed: (1) emissive characteristics of a blackbody; (2) definition of properties for nonblack surfaces; (3) fundamentals of radiation in absorbing, emitting, and scattering media; (4) radiation in the presence of other modes of energy transfer; and (5) propagation in isotropic medium (the complex refractive index).

Siegel, R.↗

Initiation and Carbene Induced Radical Chain Reactions in CH 2 F 2 Pyrolysis

High temperature dissociations of organic molecules typically involve a competition between radical and molecular processes. In this work, we use a modeling, experiment, theory (MET) framework to characterize the high temperature thermal dissociation of CH 2 F 2 , a flammable hydrofluorocarbon (HFC) that finds widespread use as a refrigerant. Initiation in CH 2 F 2 proceeds via a molecular elimination channel; CH 2 F 2 →CHF+HF. Here we show that the subsequent self-reactions of the singlet carbene, CHF, are fast multichannel processes and a facile source of radicals that initiate rapid chain propagation reactions. These have a marked influence on the decomposition kinetics of CH 2 F 2 . The inclusion of these reactions brings the simulations into better agreement with the present and literature experiments. Additionally, flame simulations indicate that inclusion of the CHF+CHF multichannel reaction leads to a noticeable enhancement in predictions of laminar flame speeds, a key parameter that is used to determine the flammability of a refrigerant.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Investigation on the explosion dynamics of large-format lithium-ion pouch cells

Explosion is the most extreme case of thermal runaway of lithium-ion (Li-ion) batteries. In this study, explosion dynamics of large-format Li-ion cells are investigated experimentally and numerically. Overcharge-to-explosion tests are conducted on 40 Ah Li-ion cells with Li[Ni 0.8 Co 0.1 Mn 0.1 ]O 2 cathode. Based on the explosion physics, shockwave and detonation models are used to characterize the shock effect of the cell explosion and evaluate the explosion equivalent. Von Neumann peak is observed on the pressure curves, and the shockwave velocity is supersonic at this time; the unwrinkled spherical flame phenomenon observed in the experiment indicates that it is detonation. Additionally, a geometric model is established based on the real testing scenario, and the explosion behavior is numerically studied. The characteristics of the explosion dynamics process are interpreted and the propagation mechanism of the shockwave are revealed; the deflagration to detonation transition (DDT) phenomenon in this process is caused by the formation of “hot spots”, and the explosion of the cells eventually turns into stable combustion. Here this study fills the gap in the research on thermal runaway of Li-ion cells, especially in the extreme cases of fire and explosion, and provide useful guidance for battery safety.

42 ENGINEERING↗

Experiments to ensure Space Station fire safety - A challenge

Three experiments have been formulated in order to address prominent fire safety requirements aboard the NASA Space Shuttle; these experiments are to be conducted as part of a Space Station-based Technology Development Mission for the growth phase of Space Station construction and operation. The experiments are: (1) an investigation of the flame-spread rate and combustion-product evolution in the burning of typical spacecraft materials in low gravity; (2) an evaluation of the interaction of fires and candidate fire extinguishers in low gravity; and (3) an investigation of the persistence and propagation of smoldering and deep-seated combustion in low gravity.

Youngblood, W. W.↗

Investigation of the feasibility of temperature profiling optical diagnostics in the SSME fuel pre-burner

Results of an analytical investigation to determine the feasibility of temperature profiling in the space shuttle main engine (SSME) fuel preburner are presented. In this application it is desirable to measure temperature in the preburner combustor with a remote, nonintrusive optical technique. Several techniques using laser excitation were examined with a consideration of the constraints imposed by optical access in the fuel preburner and the problems associated with operation near the functioning space shuttle engine. The potential performance of practical diagnostic systems based on spontaneous Raman backscattering, laser induced fluorescence, and coherent anti-Stokes Raman spectroscopy were compared analytically. A system using collection of spontaneous Raman backscattering excited by a remotely located 5 to 10 watt laser propagated to the SSME through a small diameter optical fiber was selected as the best approach. Difficulties normally associated with Raman scattering: weak signal strength and interference due to background radiation are not expected to be problematic due to the very high density in this application, and the low flame luminosity expected in the fuel rich hydrogen oxygen flame.

Shirley, J. A.↗

Separating Direct and Indirect Turbofan Engine Combustion Noise While Estimating Post-Combustion (Post-Flame) Residence Time Using the Correlation Function

A previous investigation on the presence of direct and indirect combustion noise for a full-scale turbofan engine using a far-field microphone at 130 is extended by also examining signals obtained at two additional downstream directions using far-field microphones at 110 deg and 160 deg. A generalized cross-correlation function technique is used to study the change in propagation time to the far field of the combined direct and indirect combustion noise signal as a sequence of low-pass filters are applied. The filtering procedure used produces no phase distortion. As the low-pass filter frequency is decreased, the travel time increases because the relative amount of direct combustion noise is reduced. The indirect combustion noise signal travels more slowly because in the combustor entropy fluctuations move with the flow velocity, which is slow compared to the local speed of sound. The indirect combustion noise signal travels at acoustic velocities after reaching the turbine and being converted into an acoustic signal. The direct combustion noise is always propagating at acoustic velocities. The results show that the estimated indirect combustion noise time delay values (post-combustion residence times) measured at each angle are fairly consistent with one another for a relevant range of operating conditions and demonstrate source separation of a mixture of direct and indirect combustion noise. The results may lead to a better idea about the acoustics in the combustor and may help develop and validate improved reduced-order physics-based methods for predicting turbofan engine core noise.

Miles, Jeffrey Hilton↗

Recovery of burner acoustic source structure from far-field sound spectra

A method is presented that permits the thermal-acoustic efficiency spectrum in a long turbulent burner to be recovered from the corresponding far-field sound spectrum. An acoustic source/propagation model is used based on the perturbation solution of the equations describing the unsteady one-dimensional flow of an inviscid ideal gas with a distributed heat source. The technique is applied to a long cylindrical hydrogen-flame burner operating over power levels of 4.5-22.3 kW. The results show that the thermal-acoustic efficiency at a given frequency, defined as the fraction of the total burner power converted to acoustic energy at that frequency, is rather insensitive to burner power, having a maximum value on the order of 10 to the -4th at 150 Hz and rolling off steeply with increasing frequency. Evidence is presented that acoustic agitation of the flame at low frequencies enhances the mixing of the unburned fuel and air with the hot products of combustion. The paper establishes the potential of the technique as a useful tool for characterizing the acoustic source structure in any burner, such as a gas turbine combustor, for which a reasonable acoustic propagation model can be postulated.

Mahan, J. R.↗

Flammability: A Review and Analysis

With its founding in 1975, Committee G-4 of the American Society for Testing and Materials (ASTM) embarked on the process of defining the flammability of metallic materials in oxygen-enriched atmospheres. In this process, they are joined by the National Aeronautics and Space Administration (NASA), the National Fire Protection Association (NFPA), and the Compressed Gas Association (CGA). Although none of these organizations has explicitly defined flammability, the following definitions and statements provide a composite understanding of the concept: 1. "This Standard Guide (ASTM G94-92) is concerned primarily with the properties of a material associated with its relative susceptibility to ignition and propagation of combustion." 2. "A material is considered flammable at the maximum use pressure if at least one sample burns more than 6 in. (15.2 cm). At least, five samples must be tested." NASA 3. "Flammable: Capable, when ignited of maintaining combustion under the specified environmental conditions." NFPA 53. 4. "Combustion: A complex sequence of chemical reactions between a fuel and an oxidant accompanied by the evolution of heat, and usually, the emission of light." NFPA 53. and 5. "A safe oxygen-piping transmission or distribution system is one that is designed and installed in accordance with all applicable codes and regulations for the service conditions and locations involved and further meets the special requirements for oxygen services." CGA-G4 Flammability thus equates, after ignition, to propagation of combustion, synonymous with steady state burning, under specified environmental conditions. Properties for which quantitative values are given in ASTM G94-92 and which are used to describe metals flammability consistent with the concept of steady state burning are either system independent properties, such as, enthalpies of reaction, burn ratios, flame temperatures, thermal conductivity, and heat release; or system dependent properties, such as, oxygen index, promoted combustion, threshold pressure and burn rates. Each property is reviewed and analyzed as to whether it provides an absolute or relative measure for flammability. It is shown that burn ratio, as applied to the actual steady state combustion condition, approaches the desired absolute measure of flammability.

Wilson, D. Bruce↗

NASA Alternative Orion Small Cell Battery Design Support

The NASA Orion Crew Module Reference Design was produced to address large scale thermal runaway (TR) hazard with specific safety controls for the Orion Spacecraft. The design presented provides the description of a full scale battery design reference for implementation as a drop in replacement to meet all spacecraft energy requirements with compatible 120 Vdc electrical and mechanical interface using small cell technology (18650) packaging. The 32V SuperBrick incorporates unique support features and an electrical bus bar arrangement that allows cells negative can insertion into heat sink that is compressively coupled to the battery enclosure to promote good thermal management. The housing design also provides an internal flame suppression "filter tray" and positive venting path internal to the enclosure to allow hot effluent ejecta to escape in the event of single cell TR. Virtual cells (14P Banks) that are supported to provide cell spacing with interstitial materials to prevent side can failures that can produce cell to cell TR propagation. These features were successfully test in four separate TR run with the full scale DTA1 test article in February 2016. Successfully Completed Test Objectives - Four separate TR test runs with Full-Scale DTA1 housing with Two SuperBricks, Two SuperBrick Emulators All Tests resulted in "clean" gas with less than 6 C rise at Battery vent All Tests resulted in less than 2 C temperature rise on cold-plate outlet All Tests resulted in less than 6 psi pressure rise in the battery housing Test Run 1 -One neighbor cell TR, highest remaining neighbor 139 C. Ejecta shorted to bus caused prolonged additional heating, One shorted cell did experience TR after 12 minutes, remaining cells had adequate thermal margin Test Run 2 - No cell to cell propagation, highest neighbor cell 112 C; Test Run 3 - No cell to cell propagation, highest neighbor cell 96 C; Test Run 4 - No cell to cell propagation, highest neighbor cell 101 C; Primary TR testing and analysis were completed and reviewed for endorsement by NASA Engineering and Safety Center team members. All Key Test Objectives were met and the small cell design alternative was demonstrated and selected to be a feasible drop in replacement for the MPCV Orion CM Battery for EM2 mission.

Haynes, Chuck↗