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At least 451 records · Page 25

A comprehensive analysis of transient pressure and rate data from CO 2 storage projects in a depleted pinnacle reef oil field complex, Michigan, USA

Pressure and rate data are commonly recorded as part of a basic monitoring program in CCS projects. This paper discusses the application of multiple analytical techniques to interpret pressure and rate transient data from CO 2 injection and storage operations. The techniques of interest, i.e., injection-falloff analysis, injectivity/productivity index analysis and pressure pulse arrival time analysis, are commonly used in the oil and gas industry to assess reservoir properties, but not well known in the CCS literature (especially the last two). Injection-falloff analysis involves log-log pressure derivative plotting for the falloff data and history-matching of the entire injection-falloff sequence to determine permeability. In the injectivity/productivity index analysis, rate-normalized pressure buildup is plotted against material balance time or ratio of cumulative injection to injection rate to determine the injectivity index (ratio of injection rate to stabilized pressure buildup) which can be related to the permeability-thickness product. The arrival time analysis identifies the arrival of a pressure disturbance (~0.1 psi change from ambient) to determine the hydraulic diffusivity from which permeability can be estimated. The applicability of these techniques is demonstrated via illustrative examples from multiple wells in different pinnacle carbonate reefs undergoing CO 2 -EOR in Northern Michigan. The paper ends with a discussion of the relative merits of each interpretive technique, as well as recommendations that could be useful for other field projects.

42 ENGINEERING↗

A comprehensive techno-eco-assessment of CO 2 enhanced oil recovery projects using a machine-learning assisted workflow

Carbon dioxide enhanced oil recovery (CO 2 -EOR) projects not only extract residual oil but also sequestrate CO 2 in the depleted reservoirs. Here, this study develops a machine-learning-based workflow to co-optimize the hydrocarbon recovery, CO 2 sequestration volume and project net present value (NPV) simultaneously. Considering the trade-off relationships among the objective functions, support vector regression with Gaussian kernel (Gaussian- SVR) proxies are coupled with multi-objective particle swarm optimization (PSO) protocol and generate Pareto optimal solutions. Taking advantage of the high computational efficacy of the proxy model, economic uncertainties introduced by tax credits, capital costs and oil price are investigated by this study. The results indicate that the tax incentive policy (Section 45Q) plays a vital role in enhancing the economic returns of CO 2 -EOR projects, especially under the depression of crude oil market. The proposed workflow has been successfully implemented to optimize a water alternative CO 2 (CO 2 -WAG) injection project in a depleted oil sand in the US. The optimization results yield an incremental oil production of 15.8 MM STB and 1.37 MM metric tons of CO 2 storage in a 20-year development strategy, with the highest project NPV to be 205.6 MM US dollars.

03 NATURAL GAS↗

Comprehensive framework for data-driven model form discovery of the closure laws in thermal-hydraulics codes

The two-phase two-fluid model is a basis of many thermal-hydraulics codes used in design, licensing, and safety considerations of nuclear power plants. Thermal-hydraulics codes rely on the closure laws to close the system of conservation equations and describe the interactions between phases. These laws, derived from years of experimental investigations, are semi-empirical correlations that lack generality and have a limited range of applicability. Increase of computational power, availability of new experiments, and development of high-fidelity simulations has increased the number of validation data. The discrepancies between the code predictions and the validation data are a great source of knowledge. Missing physics that are not included in the model but are important for the considered phenomena can be discovered by propagating the information from the experimental results through the model. Furthermore, physics-discovered data-driven model form (P3DM) methodology integrates available integral effect tests and separate effects tests to determine the necessary corrections to the model form of the closure laws. In contrast to existing calibration techniques, the methodology modifies the functional form of the closure laws. Based on the functional form of the correction, the missing physics that were not included in the original model can be discovered. The methodology provides the alternative to the machine learning approach, in which the model is discovered in the form of the intractable black-box relation. In this work, the methodology was applied to the CTF subchannel code to improve the prediction of the two-phase flow phenomena.

42 ENGINEERING↗

Atomic Layer Thermopiles: Comprehensive static calibration, comparison and application in subsonic and supersonic flows

Here, this paper compares the calibration of different heat flux sensors in radiation- and convection-based sub- and supersonic operation. First, four heat flux sensors based on different principles: ALTP (Transverse Seebeck Effect), HFM-8E (differential-layer device), coaxial Thermocouple and a TG-2000 (circular-foil gage) are calibrated in a laser-based radiation setup. In a second step, all heat flux sensors are compared with a slug-calorimeter within a subsonic convection-dominated facility based on stagnation-point measurements of an impinging hot air jet. The obtained results indicate that a sensitivity transfer between a radiative calibrated sensor used in a mainly convective environment is not always possible and can lead to significant, systematic errors. Calibration in a subsonic shear flow with thermocouple readings demonstrate small divergence from the manufacturer provided sensitivity. Finally, supersonic testing with high frequency shock-boundary layer interactions highlight the need for ALTP rather than the conventional use of thermocouple arrays to resolve the high frequency phenomena associated with shock boundary layer interactions.

42 ENGINEERING↗

A comprehensive review on regeneration strategies for direct air capture

Direct air capture (DAC), which removes CO 2 directly from ambient air, is a critical negative emission technology for mitigating global climate change. Efficiency and the source of energy are crucial considerations for DAC to enable negative emissions. Substantial technological progress has been made in DAC technologies, and promising opportunities exist for commercial-scale deployments. However, DAC technologies require high regeneration energy to release CO 2 from sorbents. Various approaches have been tested and optimized for different DAC systems. This review demonstrates that the work equivalent regeneration energy demand (supported by either the electric grid or fossil fuel combustion) ranges from 0.5–18.75 GJ/t-CO 2 for solid sorbent DAC systems and 0.62–17.28 GJ/t-CO 2 for liquid solvent DAC systems. The regeneration process is the energy-demanding process in DAC that is a key step for efficient operation. Potential methods to lower the regeneration energy demand include microwave, ultrasound, magnetic particle heating, and electric swing. Although the potential methods to date are still at the lab scale, significant work is being done to optimize DAC system processes.

54 ENVIRONMENTAL SCIENCES↗

UV/chlorine advanced oxidation processes for degradation of contaminants in water and wastewater: A comprehensive review

Advanced oxidation processes (AOPs) have recently gained increasing attention as promising alternatives to conventional water and wastewater treatment technologies. As an AOP, there has been a growing interest in UV/chlorine due to its multiple disinfection modes and ability to maintain chlorine residuals in drinking water distribution systems. Compared to the popular UV/H 2 O 2 AOP treatment process, UV/chlorine AOP possesses several advantages including a higher radical production efficiency and a lower power demand. The process has recently been applied for the degradation of a wide range of natural and synthetic organic as well as inorganic compounds including pharmaceutical and personal care products, natural organic matter, herbicides and insecticides, taste and odor, and different types of water and wastewaters. The focus of the present work is to review and evaluate the efficiency of the UV/chlorine process on the oxidation of these pollutants. Here a critical overview is provided of the fundamentals of UV/chlorine, controlling factors of the process performance, and a comparison with other UV-based AOPs. The formation of disinfection by-products (DBPs), one of the concerns associated with UV/chlorine treatment, is discussed and strategies to tackle this obstacle are provided for future studies and applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗