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At least 451 records · Page 25
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Far-infrared line intensities of H2O and CO from warm molecular clouds

Takahashi et al. (1983) have studied the role of H2O in the overall energetics of warm molecular clouds with large optical depths. It was found that in molecular clouds associated with nearby or embedded luminosity sources, the dust is likely to be warmer than the molecular gas. Thus, the warm dust represents the primary source of heat for the gas. In some cases, H2O was found to cool the gas. Takahashi et al. (1983) have presented the formalism for treating H2O in an optically thick molecular cloud with embedded sources of luminosity. The total H2O heating and cooling rates were also calculated. In the present investigation, the emergent intensities of far-infrared lines of H2O and excited, rotational CO transitions from relatively warm molecular clouds based on the large-velocity gradient model of the previous study are calculated. It is found that the dominant submillimeter CO transitions are related to emission, while the H2O transitions can be either absorption or emission lines.

Takahashi, T.↗
NASA NTRS1985

Two dimensional, transient catalytic combustion of CO-air on platinum

The light off transient of catalytic combustion of lean CO-air mixtures in a platinum coated channel of a honeycomb monolith is studied with a model that resolves transient radial and axial gradients in both the gas and the solid. For the conditions studied it is concluded that: the initial heat release occurs near the entrance at the gas-solid interface and is controlled by heterogeneous reactions; large spatial and temporal temperature gradients occur in the solid near the entrance controlled mostly by the availability of fuel; the temperature of the solid near the entrance achieves almost its steady state value before significant heating of the back; heterogeneous reactions and the gas heated up front and flowing downstream heat the back of the solid; the overall transient time is controlled by the thermal inertia of the solid and by forced convection; radiation significantly influences both transient and steady state particularly near the entrance; the oxidation of CO occurs mostly on the catalyst and becomes diffusion controlled soon into the transient.

Sinha, N.↗
NASA NTRS1985

A wide-latitude CO survey of molecular clouds in the northern Milky Way

A wide-latitude, low angular resolution survey of CO along most of the first Galactic quadrant and part of the second was undertaken in order to investigate molecular clouds associated with the Great Rift and the diffuse component of Galactic gamma rays. The main nearby clouds have masses between a few times 10,000 and a few times 100,000 solar masses, versus a few times a million solar masses for the largest complexes elsewhere. The CO emission in the survey comes nearly equally from local clouds associated with the Great Rift and from distant clouds in the inner arms of the Galaxy 4-7 kpc from the Galactic center. The half-thickness at half-intensity of the local molecular cloud layer is greater than 50 pc and is estimated to be 75 + or - 25 pc. The results strongly support the notion that all dark nebulae are molecular clouds, and vice-versa.

Dame, T. M.↗
NASA NTRS1985

CO detections and IRAS observations of bright radio spiral galaxies at cz equal or less than 9000 kilometers per second

CO emission has been detected from 20 of 21 bright radio spirals with strong extended nuclear sources, including the most distant (NGC 7674) and the most luminous (IC 4553 = Arp 220, NGC 6240) galaxies yet detected in CO. All of these galaxies are rich in molecular gas, with M total(H2) = 3 x 10 to the 8th - 2 x 10 to the 10th solar masses. IRAS observations show that they have a strong far-infrared (FIR) excess, with L(FIR)/L(B) approximately equal to 1-35 and L(FIR) (40-400 microns) approximately equal to 10 to the 10th - 10 to the 12th L solar masses. The primary luminosity source for these radio cores appears to be star formation in molecular clouds. A strong correlation is found between the FIR and extended 21 cm continuum flux, implying that the fraction of massive stars formed is independent of the star formation rate. The ratio L(FIR)/M(H2) provides a measure of the current rate of star formation, which is found to be a factor 3-20 larger in these galaxies than for the ensemble of molecular clouds in the Milky Way. At these rates their molecular gas will be depleted in about 10 to the 8th yr.

Sanders, D. B.↗
NASA NTRS1986

The radial distribution of galactic gamma rays. III - The distribution of cosmic rays in the Galaxy and the CO-H2 calibration

The cosmic ray (CR) distribution in the Galaxy inside the solar circle is determined by using the kinematics of both H I and CO to ascertain the spatial distribution of the interstellar gas. The conversion factor between integrated CO line intensity and the molecular hydrogen column density is found, and possible large-scale variations of this relationship throughout the Galaxy are investigated. The galactocentric CR distributions are shown to be described satisfactorily by exponential distributions for radii larger than about three, with a radial scale length of 4-11 kpc for electrons and a scale length greater than 18 kpc for nuclei.

Bloemen, J. B. G. M.↗
NASA NTRS1986

CO(+) fluorescence in comets

Calculations of the fluorescent equilibrium of the CO(+) molecule to determine the Swings and Greenstein effects as a function of heliocentric radial velocity have been carried out. The previously ignored Baldet-Johnson (B-A) bands were included in addition to the comet tail (A-X) and first negative (B-X) bands, thus allowing a determination of the absolute intensities of all bands. As with certain other molecules such as OH and CN, the Swings effect on individual lines is large enough that integrated band fluxes in the comet tail system also exhibit the Swings effect. The flux variations for velocities in the range - 50 to + 350 km/s have been calculated and may be used to map the acceleration of CO(+) ions into the tail, even with low dispersion spectra.

Magnani, L.↗
NASA NTRS1986

The production of CO(+) (B2Sigma +) from dissociative photoionization excitation of CO2

The dissociative photoionization excitation process in CO2 is studied. In contrast to previous studies, attention is focused on the vibrational and rotational levels produced in fragment ions, partial cross-section measurements for producing such fragment ions in a specific quantum state, and the mechanisms that govern the dissociative ionization excitation processes. The partial fluorescence cross section for the production of CO(+) (B2Sigma +) from CO2 over a wide wavelength range was measured. It is concluded that the production of the CO(+) (B2Sigma +) fragment near the threshold is through a direct dissociative photoionization process.

Wu, C. Y. R.↗
NASA NTRS1987

Catalytic Oxidation of CO for Closed-Cycle CO2 Lasers

Stoichiometric mixture converted completely. High-energy pulsed CO2 lasers have potential for measuring many different features of atmosphere of Earth and particularly useful on airborne or space platforms. For this application, laser must be operated in closed cycle to conserve gas, especially if rare nonradioactive isotopes of carbon and oxygen used. However, laser discharge decomposes fraction of CO2 to CO and O2, causing rapid loss in power leading to erratic behavior. To maintain operation, CO and O2 must be recombined to form CO2.

Miller, I. M.↗
NASA NTRS1986

Spiral arms and massive star formation: Analysis of the CO face-on pictures of the galaxy

The face-on distribution of molecular gas in the first Galactic quadrant, derived from the Massachusetts-Stony Brook Galactic Plane CO Survey, was compared to the Galactic distribution of giant radio HII regions. The HII regions were found to preferentially select gas regions of higher than average density (more than twice the mean) and showed a strong correlation with the second power of the gas density. Systematic effects were tested with a Monte Carlo simulated HII region distribution and found to be negligible. The 135 HII regions were selected from the radio catalogs of Downes et at. (1980) and Wink et al. (1982). The HII regions were required to be within the CO survey 1 and b limits, within the solar circle, and not part of the 3 kpc expanding arm. The velocities of the HII regions were tabulated by the catalog authors and obvious associations with known objects and H2CO absorptions were used by them to assign distances. The distance assignments were here grouped into two categories; (1) those HII regions with definite distance assignments (85 objects); and (2) those HII regions with less secure distance assignments and those for which no near-far assignment was possible (50 objects).

Clemens, D. P.↗
NASA NTRS1987

System study of the carbon dioxide observational platform system (CO-OPS): Project overview

The resulting options from a system study for a near-space, geo-stationary, observational monitoring platform system for use in the Department of Energy's (DOE) National Carbon Dioxide Observational Platform System (CO-OPS) on the greenhouse effect are discussed. CO-OPS is being designed to operate continuously for periods of up to 3 months in quasi-fixed position over most global regional targets of interest and could make horizon observations over a land-sea area of circular diameter up to about 600 to 800 statute miles. This affords the scientific and engineering community a low-cost means of operating their payloads for monitoring the regional parameters they deem relevant to their investigations of the carbon dioxide greenhouse effect at one-tenth the cost of most currently utilized comparable remote sensing techniques.

Stephens, J. Briscoe↗
NASA NTRS1987

CO oxidation studies over supported noble metal catalysts and single crystals: A review

The catalytic oxidation of CO over noble metal catalysts is reviewed. Results obtained on supported noble metal catalysts and single crystals both at high pressures and under UHV conditions are compared. The underlying causes which result in surface instabilities and multiple steady-state oscillations are considered, in particular, the occurrence of hot spots. CO islands of reactivity, surface oxide formation and phase transformations under oscillatory conditions are discussed.

Boecker, Dirk↗
NASA NTRS1987

Nuclear star formation on 100 parsec scales: 10" resolution radio continuum, HI and CO observations

A program of radio line and continuum studies of star formation in nearby spiral galaxies is reported. The objective is a search for hot gas and peculiar dynamics in spiral nuclei with 10" to 30" angular resolution. Vigorous star formation is found to be a common phenomenon in the inner kpc of spirals. Arcsecond resolution observations of radio continuum emission at 6 and 2 cm were used to separate the thermal and nonthermal radio components. It was found that thermal and nonthermal emission are well mixed even on sizescales of 10 pc. To understand the reason for the increased level of star formation activity in spiral nuclei, HI and CO emission in these galaxies is studied. The CO transition was detected in M51, M82, NGC 253, NGC 6946 and IC 342 with T sub a approx. 0.5 to 2.0 K, at 20" angular resolution. The dynamics and spatial distribution of nuclear gas are being studied using VLA HI maps with 30" synthesized beams. Evidence for noncircular motions in HI was found in the nucleus of IC 342.

Turner, Jean L.↗
NASA NTRS1986

High temperature tensile and creep behaviour of low pressure plasma-sprayed Ni-Co-Cr-Al-Y coating alloy

The high temperature tensile and creep behavior of low pressure plasma-sprayed plates of a typical Ni-Co-Cr-Al-Y alloy has been studied. From room temperature to 800 K, the Ni-Co-Cr-Al-Y alloy studied has nearly a constant low ductility and a high strength. At higher temperatures, it becomes weak and highly ductile. At and above 1123 K, the behavior is highly dependent on strain rate and exhibits classic superplastic characteristics with a high ductility at intermediate strain rates and a strain rate sensitivity of about 0.5. At either higher or lower strain rates, the ductility decreases and the strain rate sensitivities are about 0.2. In the superplastic deformation range, the activation energy for creep is 120 + or - 20 kJ/mol, suggesting a diffusion-aided grain boundary sliding mechanism. Outside the superplastic range, the activation energy for creep is calculated to be 290 + or - 20 kJ/mol.

Hebsur, M. G.↗
NASA NTRS1986

The effect of CO chemisorption on the metal surface CO/Ni(100)

The chemisorption of CO on Ni(100) is studied with a cluster model. The calculations suggest that chemisorption changes the nature of the Ni 3d orbitals. The open shell Ni 3d accepts charge from the Ni valence 4s4p orbitals, reducing the open shell 3d character on the Ni. The closed shell Ni 3d orbitals also mix with the Ni valence 4s4p orbitals and donate charge to the CO; thus helping to maintain the Ni 3d population near 9. These changes should affect the density of 3d states near the Fermi level and the surface magnetic moment. The variation in the bonding with the size of cluster is also discussed.

Bauschlicher, Charles, W., jr.↗
NASA NTRS1987

Detection of CO(1-0) emission and optical imaging of the Seyfert galaxy/QSO Markarian 231

The detection of CO(J = 1-0) emission and optical imaging of the luminous infrared galaxy Markarian 231 are reported. The galaxy is extremely rich in molecular gas with MT(H2) approximately equal to 1.4 x 10 to the 10th solar masses, approximately 5 times the molecular gas content of the Galaxy. Markarian 231 is the most luminous object in the local universe (z approximately equal to or less than 0.1), with a far-infrared luminosity (lambda = 40-400 microns) of 2.1 x 10 to the 12th solar luminosities. THe CO detection yields a L(FIR)/M(H2) ratio of 150. A deep optical CCD image shows two striking tidal tails with total extent of about 75 kpc. The CCD image strongly suggests that Markarian 231 is an advanced merger system. If the molecular gas is highly concentrated in the nuclear region it may fuel an intense starburst and possibly feed the accretion onto an embedded QSO. The trigger for the intense activity observed in Markarian 231 appears to be the collision of two gas-rich spiral galaxies.

Sanders, D. B.↗
NASA NTRS1987

Warm dense gas in luminous protostellar regions - A submillimeter and far-infrared CO line study

Spectroscopic measurements of the CO J = 7-6 and J = 16-15 sub-mm/far-IR rotational lines are combined for a study of the molecular gas in four massive star formation regions: W51 IRS 2, W51 Main, G34.3+0.1, and W49. CO emission over a wide velocity range is found in three of the four regions. Mass outflows from newly formed stars in the two W51 sources carry an order-of-magnitude-greater mass and momentum than in the Orion/KL flow; it is concluded that mass outflow rates scale with source luminosity up to the most luminous galactic star formation regions.

Jaffe, D. T.↗
NASA NTRS1987

Opposed jet burner studies of effects of CO, CO2, and N2 air-contaminants on hydrogen-air diffusion flames

The blowoff/restore characteristics for jets of various H2/N2 mixtures opposed to jets of air contaminated by N2, CO, and CO2 have been determined using a counterflow diffusion flame formed by a tubular opposed jet burner. Both blowoff and restore limits are found to be sensitive to fuel and air composition. Empirically derived variations in the limits of the average mass flux of incoming H2 with percent contaminant, at fixed incoming fuel and H2/O2 inputs, are used to quantify the effects of oxygen dilution, flame augmentation, and flame retardation by N2, CO, and CO2 contaminants. The implications of the results are discussed.

Guerra, Rosemary↗