The prediction of nozzle material performance for NASA's 260 SL-3 motor.
Nozzle erosion profile, char penetration and temperature response predicted for nozzle material for 260 SL-3 motor
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Nozzle erosion profile, char penetration and temperature response predicted for nozzle material for 260 SL-3 motor
Sensor device with switches for measuring surface recession of charring and noncharring ablators
Cross-linked polymers obtained by direct reaction of aryl polycarbonyls with aryl polyamines, studying char yields effect
Cross-links effect on char yields of azomethine polymers produced by aryl diamines with aryl diketones
Nozzle erosion profile, char penetration and temperature response predicted for nozzle material for 260 SL-3 motor
Fire-retardant paint, when activated by the heat of fire, reacts to form a thick, low-density, polymeric coating or char layer. Water vapor and sulphur dioxide are released during the intumescent reaction.
Surface recession of low density phenolic nylon in arc heated air using stagnation point models, noting char removal processes
Charring ablative composites pyrolysis products composition determination, comparing chemical analysis techniques
Filter radiometer utilizing photomultiplier circuit, in which a direct-coupled amplifier varies dynode voltage to maintain constant anode current, measures rapid variations of temperature of white-hot charred body at 2000 K to 3000 K.
Bibliography on emittance of high temperature materials including refractory materials, ceramics, carbon, graphites, chars, and ablative materials for use in aerospace engineering
Ablation sensor for measuring char layer recession rate using electric wires
Ablative polymers synthesis from formaldehyde, phenols and ethers reaction products, discussing char yield, thermally stable fillers incorporation and thermogravimetric analysis
Development of ablative materials based on modification of polyphenylene compounds is discussed. Chemical and physical properties are analyzed for application as heat resistant materials. Synthesis of linear polyphenylenes is described. Effects of exposure to oxyacetylene flame and composition of resultant char layer are presented.
The curing and decompositions of polyphenylenes and several nitrogen-containing condensation polymers, particularly polybenzimidazoles and pyrones, are reviewed critically. It is concluded that the condensations are usually imperfect and incomplete and that in most of the published work the late stages of the condensation are complicated by the beginnings of the charring and carbonization processes. Most discussions of mechanisms in this range are highly speculative and of little value. The most promising fields for further research are at lower temperatures, where slow oxidation processes deserve study, and at higher temperatures, where it may be possible to influence carbonization processes to obtain better products.
A study was conducted to correlate Apollo ablation and thermal response flight data using advanced state-of-the-art analytical procedures. The agreement between flight data and predictions is consistently excellent for in-depth temperature distributions, char density profiles, and surface ablation, thus validating the analytical procedures.
Analytical trade studies are presented that consider passive TPS configurations using the following material categories: (1) reuseable surface insulation - surface-coated rigidized ceramic fiber; (2) low density charring ablators; and (3) carbon-carbon and high density ablators for leading edge areas. Emphasized are effects on TPS weight by variations in entry trajectories and material thermal characteristics.
A very low density ablative material, a silicone-phenolic composite, was flight tested on a recoverable spacecraft launched by a Pacemaker vehicle system; and, in addition, it was tested in an arc heated wind tunnel at three conditions which encompassed most of the reentry heating conditions of the flight tests. The material was composed, by weight, of 71 percent phenolic spheres, 22.8 percent silicone resin, 2.2 percent catalyst, and 4 percent silica fibers. The tests were conducted to evaluate the ablator performance in both arc tunnel and flight tests and to determine the predictability of the albator performance by using computed results from an existing one-dimensional numerical analysis. The flight tested ablator experienced only moderate surface recession and retained a smooth surface except for isolated areas where the char was completely removed, probably following reentry and prior to or during recovery. Analytical results show good agreement between arc tunnel and flight test results. The thermophysical properties used in the analysis are tabulated.
Heat shielding for planetary entry probes of future Jovian and Venusian missions will encounter heating levels well beyond those previously experienced. These entries are typically dominated by radiative heating from the shock layer. This paper demonstrates the potential of reflecting this incident radiation diffusely from an ablating material. This technique contrasts with the absorption experienced by char-forming or graphitic ablators. Two dielectric materials, Teflon (polytetra-fluoroethylene) and boron nitride, are examined for their ablative performance, including reflection, in a combined convective- and radiative-heating environment. For Teflon, at the conditions obtained, superimposition of radiative heating upon a convective stream causes no additional increase in surface recession over the convective only results. For boron nitride, an excellent room-temperature reflector in the visible spectrum, a decrease in reflectivity from 90 to 55 percent is experienced when the surface undergoes sublimation at high temperatures. The process of reflection in each of these materials is described in terms of backscattering from crystals. The significance of a sizable reflection as a mode of energy accommodation is demonstrated for Venusian entries as a potential reduction in mass loss due to ablation.