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At least 451 records · Page 25

Heat-Treatment of MgSiO Smokes of Astrophysical Interest: Possible Implications for Olivine-Pyroxene-Silica Assemblages in Chondritic Aggregate IDPs

Anhydrous silicates in coarse-grained ferromagnesiosilica principal components (PCs) formed during atmospheric entry flash-heating also constrain the astromineralogy of astrophysical dust. This is because of the unique closed-system behavior of these PCs in chondritic aggregate interplanetary dust particles (IDPs). Additional information is contained in the original extended abstract.

Rietmeijer, F. J. M.↗

Assembly of Colloidal Aggregates by Electrohydrodynamic Flow: Kinetic Experiments and Scaling Analysis

Electric fields generate transverse flows near electrodes that sweep colloidal particles into densely packed assemblies. We interpret this behavior in terms of electrohydrodynamic motion stemming from distortions of the field by the particles that alter the body force distribution in the electrode charge polarization layer. A scaling analysis shows how the action of the applied electric field generates fluid motion that carries particles toward one another. The resulting fluid velocity is proportional to the square of the applied field and decreases inversely with frequency. Experimental measurements of the particle aggregation rate accord with the electrohydrodynamic theory over a wide range of voltages and frequencies.

Ristenpart, W. D.↗

VIIRS Product Aggregation and Packaging

Areas where the end-users can help define the Visible/Infrared Imager Radiometer Suite (VIIRS) products distributed by NOAA include: temporal aggregation, band packaging, and gelolocation packaging. Proposals in these areas are presented along with background information, advantages and disadvantates of each proposal. The proposals are based on experience with NASA EOS missions and programs (MODIS and SeaWIFS).

Wolfe, Robert↗

Gelation in Aerosols; Non-Mean-Field Aggregation and Kinetics

Nature has many examples of systems of particles suspended in a fluid phase; colloids when in a liquid, aerosols when in a gas. These systems are inherently unstable since if the particles can come together, van der Waals forces will keep them together. In this work we studied the aggregation kinetics of particulate systems, most often aerosols. The emphasis of our work was to study dense systems and systems that gel since previous work had not considered these. Our work obtained a number of significant discoveries and results which are reported here.

Sorensen, C. M.↗

Binodal Colloidal Aggregation Test - 4: Polydispersion

Binodal Colloidal Aggregation Test - 4: Polydispersion (BCAT-4-Poly) will use model hard-spheres to explore seeded colloidal crystal nucleation and the effects of polydispersity, providing insight into how nature brings order out of disorder. Crewmembers photograph samples of polymer and colloidal particles (tiny nanoscale spheres suspended in liquid) that model liquid/gas phase changes. Results will help scientists develop fundamental physics concepts previously cloaked by the effects of gravity.

Chaikin, Paul M.↗

Infrared Spectroscopy of Naphthalene Aggregation and Cluster Formation in Argon Matrices

Fourier-transform mid-infrared absorption spectra of mixed argon/naphthalene matrices at 5 K are shown with ratios of argon-to-naphthalene that vary from 1000 to 0. These spectra show the changes as naphthalene clustering and aggregation occurs, with moderate spectral shifts affecting the C-H vibrational modes and relatively small or no shifts to the C-C and C-C-C vibrational modes. The possible contribution of homogeneous naphthalene clusters to the interstellar unidentified infrared bands is discussed. The contribution of polycyclic aromatic hydrocarbon (PAH) clusters to the 7.7 micron emission plateau and the blue shading of the 12.7 micron emission band are identified as promising candidates for future research. In addition, since PAH clusters are model components of Jupiter and Titan's atmospheres, the information presented here may also be applicable to the spectroscopy of these objects.

Roser, J. E.↗

Mineralogy of Stardust Track 112 Particle: Relation to Amoeboid Olivine Aggregates

The successful analysis of comet 81P/Wild 2 particles returned by the Stardust mission has revealed that the Wild 2 dust contains abundant silicate grains that are much larger than interstellar grains and appear to have formed in the inner regions of the solar nebula [1]. Wild 2 particles include minerals which are isotopically and mineralogically similar to CAIs [e.g., 2, 3] and chondrules [e.g., 4] in chondrites. In addition, particles similar to amoeboid olivine aggregates (AOAs) also have been discovered [5, 6,7]. C2067,2,112,1 is a terminal particle recovered from track #112 (T112). Nakamura-Messenger et al. [7] showed that the forsterite grain in T112 has O-16 enrichment of approximately 40 0/00 (vs. SMOW) and possibly formed together with AOAs. In this study, we have examined the mineralogy of the T112 particle and compared the possible relationships between T112 and AOAs in primitive meteorites.

Komatsu, M.↗

Protein Colloidal Aggregation Project

To investigate the pathways and kinetics of protein aggregation to allow accurate predictive modeling of the process and evaluation of potential inhibitors to prevalent diseases including cataract formation, chronic traumatic encephalopathy, Alzheimer's Disease, Parkinson's Disease and others.

Technology Portfolio System↗

Empirical Relationships Between Optical Properties and Equivalent Diameters of Fractal Soot Aggregates at 550 Nm Wavelength.

Soot aggregates (SAs)-fractal clusters of small, spherical carbonaceous monomers-modulate the incoming visible solar radiation and contribute significantly to climate forcing. Experimentalists and climate modelers typically assume a spherical morphology for SAs when computing their optical properties, causing significant errors. Here, we calculate the optical properties of freshly-generated (fractal dimension Df = 1.8) and aged (Df = 2.6) SAs at 550 nm wavelength using the numericallyexact superposition T-Matrix method. These properties were expressed as functions of equivalent aerosol diameters as measured by contemporary aerosol instruments. This work improves upon previous efforts wherein SA optical properties were computed as a function of monomer number, rendering them unusable in practical applications. Future research will address the sensitivity of variation in refractive index, fractal prefactor, and monomer overlap of SAs on the reported empirical relationships.

deuterium fluorides↗

Petrology of Amoeboid Olivine Aggregates in Antarctic CR Chondrites: Comparison With Other Carbonaceous Chondrites

Amoeboid olivine aggregates (AOAs) are important refractory components of carbonaceous chondrites and have been interpreted to represent solar nebular condensates that experienced high-temperature annealing, but largely escaped melting. In addition, because AOAs in primitive chondrites are composed of fine-grained minerals (forsterite, anorthite, spinel) that are easily modified during post crystallization alteration, the mineralogy of AOAs can be used as a sensitive indicator of metamorphic or alteration processes. AOAs in CR chondrites are particularly important because they show little evidence for secondary alteration. In addition, some CR AOAs contain Mn-enriched forsterite (aka low-iron, Mn-enriched or LIME olivine), which is an indicator of nebular formation conditions. Here we report preliminary results of the mineralogy and petrology of AOAs in Antarctic CR chondrites, and compare them to those in other carbonaceous chondrites.

Komatsu, M.↗

Amoeboid Olivine Aggregates in Antarctic CR Chondrites: Petrologic Variations Among CR Chondrites

Amoeboid olivine aggregates (AOAs) are important components of carbonaceous chondrites that are interpreted as solar nebula condensates, and can be used as sensitive indicators of metamorphic or alteration processes. We have been investigating a set of Antarctic CR chondrites from the Japanese-NIPR collection in order to study variations within the CRs in general and their AOAs in particular. Main goals are to identify variations in conditions of nebular condensation, parent body effects and terrestrial weathering.

Komatsu, M.↗

Petrology of Amoeboid Olivine Aggregates in Antarctic CR Chondrites: Evidence for Aqueous Alteration and Shock Metamorphism

CR chondrites are the group of carbonaceous chondrites that preserve records of formation of their components in the solar nebula. Although they are affected by aqueous alteration, many chondrules and CAIs are well-preserved, suggesting they have experienced little thermal metamorphism. We have been investigating the petrologic variations among the CR chondrites in Japanese-NIPR Antarctic meteorite collection. Especially we focused on the petrology of amoeboid olivine aggregates (AOAs) in order to understand secondary alteration on CR chondrite parent body. AOAs are composed of fine-grained forsteritic olivine and refractory minerals formed by condensation from solar nebula, and can be used as sensitive indicators of secondary alteration processes.

Komatsu, M.↗

Satellite Constellation Cost Modeling: An Aggregate Model

Satellite constellations and Distributed Spacecraft Mission (DSM) architectures offer unique benefits to Earth observation scientists and unique challenges to cost estimators. The Cost and Risk (CR) module of the Tradespace Analysis Tool for Constellations (TAT-C) being developed by NASA Goddard seeks to address some of these challenges by providing a new approach to cost modeling, which aggregates existing Cost Estimating Relationships (CER) from respected sources, cost estimating best practices, and data from existing and proposed satellite designs. Cost estimation through this tool is approached from two perspectives: parametric cost estimating relationships and analogous cost estimation techniques. The dual approach utilized within the TAT-C CR module is intended to address prevailing concerns regarding early design stage cost estimates, and offer increased transparency and fidelity by offering two preliminary perspectives on mission cost. This work outlines the existing cost model, details assumptions built into the model, and explains what measures have been taken to address the particular challenges of constellation cost estimating. The risk estimation portion of the TAT-C CR module is still in development and will be presented in future work. The cost estimate produced by the CR module is not intended to be an exact mission valuation, but rather a comparative tool to assist in the exploration of the constellation design tradespace. Previous work has noted that estimating the cost of satellite constellations is difficult given that no comprehensive model for constellation cost estimation has yet been developed, and as such, quantitative assessment of multiple spacecraft missions has many remaining areas of uncertainty. By incorporating well-established CERs with preliminary approaches to approaching these uncertainties, the CR module offers more complete approach to constellation costing than has previously been available to mission architects or Earth scientists seeking to leverage the capabilities of multiple spacecraft working in support of a common goal.

Science Data Processing↗

An Algorithm for Characterization of Fiber Aggregation in Composite Microstructures

Composite structures are susceptible to localized flaws, or variability, that drive global failure. To capture this variance, a multiscale model needs to be introduced that not only accurately represents the statistical nature of the composite microstructure but is also efficient. At the microscale, fiber aggregation creates local stress concentrations, where failure is likely to occur sooner than expected. A method of rapid microstructure generation, in conjunction with cluster characterization, is examined to develop accurate reproductions of 2D composite cross-sections. Parameterization of shape and size of fiber clusters is used to characterize representative volume elements. The discrete element method is used to generate pseudo-microstructures. The clustering parameters from the pseudo- and actual microstructure arrangements (obtained from micrographs) can be compared to determine the validity of the representative volume element generated with the discrete element method. Results show a promising approach to evaluating randomness of fiber distributions and how to accurately recreate microstructures for strength analysis.

Carbon fiber↗

The Potassium Isotope Composition of Aggregate Material From Asteroid Bennu

NASA’s OSIRIS-REx mission re-turned material from asteroid Bennu on September 24, 2023, marking the first time a U.S. mission has delivered asteroid samples to Earth, and the largest asteroid sample return to date. Due to the pristine nature of these primitive carbonaceous-rich samples, they allow us a rare opportunity to study our solar system’s formation to a degree not previously possible. Isotopes of moderately volatile elements (MVEs) have been recently developed as robust tracers for tracking different volatilization events within our Solar System. Of the MVEs, K has gained significant interest in recent years due to its ideal chemical and physical properties combined with technique improvements. Due to this, several recent studies have investigated the K isotope systematics within bulk chondrites and found an isotopic dichotomy be-tween the carbonaceous and non-carbonaceous chondrites (Figure 1), likely reflecting their different reservoirs which formed in the inner and outer protoplanetary disk respectively. Furthermore, systematic K isotope variations across the different carbonaceous chondrite groups and correlations with mass independent isotope systems such as Cr, Ti, and Ni, have also been observed. As a result, establishing the K isotope composition of bulk Bennu can be used to test the mission hypothesis that “Bennu’s parent asteroid accreted in the outer protoplanetary disk, beyond Jupiter, as recorded by distinct isotopic anomalies in a variety of elements” . In addition to early solar system processes, K isotopes can also be fractionated by space weathering as shown by comparisons between mature and immature lunar regolith. The degree of K isotope fractionation caused by space weathering correlates with the regolith maturity index and is an order of magnitude larger than what is observed in bulk meteorite samples which have not undergone strong space weathering processes. As such, the K isotope systematics of Bennu samples could provide an independent assessment of regolith maturity of the asteroid surface, helping to directly test the mission hypothesis that “Space weathering changed the chemistry and mineralogy of optically active surfaces” . In order to test both this hypothesis, and the hypothesis relating to Bennu’s accretion location, we aim to conduct high-precision K isotope analysis on bulk Bennu aggregates.

K Wang↗

Transmission Electron Microscopy of Carbonaceous Matter in Bennu Aggregate Samples

Preliminary analyses of regolith samples from asteroid Bennu show high bulk carbon abundances (~4.7 wt.%). The organic matter is readily apparent in scanning electron microscopy (SEM), transmission electron microscopy (TEM), and NanoSIMS observations. A major objective of the OSIRIS-REx mission is to understand the nature and origin of the pre-biotic organic matter inventory in Bennu samples. Here we report on TEM studies of indigenous organic matter in Bennu aggregate samples.

L P Keller↗

Molecular Inventory and Comparative Organic Profiling of A Homogenized Aggregate Sample From Asteroid (101955) Bennu

Evaluating the distribution and diversity of solvent-soluble organic molecules in extraterrestrial materials provide information about the physicochemical environments where prebiotic chemistry occurred and is essential for assessing the inventory of prebiotic compounds available to the early Earth. In this work, we conducted a comprehensive molecular characterization of solvent-soluble organic compounds in a homogenized aggregate sample (ID: OREX-800107-128) of unsorted regolith from asteroid (101955) Bennu returned by NASA’s OSIRIS-REx mission. Using two-dimensional gas chromatography coupled with high-resolution time-of-flight mass spectrometry (GC×GC-HRMS), we identified 87 organic compounds across several molecular classes, including alkanes, polycyclic aromatic hydrocarbons, and nitrogen-, oxygen-, and sulfur-bearing species. Comparison with the organic inventory of CI (Orgueil), C2-ungrouped (Tagish Lake and Tarda), and CM2 (Murchison) carbonaceous chondrites revealed that Bennu sample OREX-800107-128 is most similar to Tagish Lake and Tarda yet compositionally distinct from all of these meteorites. This Bennu sample exhibits a relatively high abundance of low-molecular-weight aromatics (e.g., toluene), pyridine derivatives, and sulfur species such as dimethyl sulfite, consistent with episodic low-temperature aqueous alteration. The presence of these organic compounds suggests that this material experienced chemically diverse processes in the parent body conducive to complex organic synthesis, including aldol condensation reactions responsible for N- and O-bearing compounds. We also compared the molecular distributions of this Bennu sample and previously analyzed samples from (162173) Ryugu to assess potential common origins between these two carbonaceous asteroids. Bennu shows more chemically diverse and nitrogen-rich organic materials than Ryugu. While both asteroids share broadly similar primitive compositions, the observed chemical differences indicate distinct evolutionary histories within a likely common formation environment though whether Bennu and Ryugu derive from a single compositionally heterogeneous parent body or from multiple closely related progenitors remains unresolved. Further detailed comparative analyses of material from Bennu, Ryugu, and specific carbonaceous meteorites (e.g., Tagish Lake and Tarda) will provide new insights into how the N-rich molecular profile observed in Bennu samples was formed and evolved in the outer Solar System.

sample return↗

SolSmart Webinar - Community Choice Aggregation & Solar Development

This webinar focuses on community choice aggregation (CCA) as a potential strategy for local governments to achieve their clean energy goals. The webinar provides an overview of what CCA is, how it works, and considerations for local governments interested in establishing or participating in a CCA program. The webinar will highlight case studies from CCAs across the U.S. that support local renewable energy development. This webinar provides one AICP CM continuing education credit. Who: Ben Butterwoth, Senior Associate, The Cadmus Group; Megan Lynch, Analyst, The Cadmus Group; Jenna Famular, Communications Manager, MCE Clean Energy; Meghan Shaw, Outreach Director for Cambridge Energy Alliance, City of Cambridge; Daniel Falk, Project Manager, The Solar Foundation

14 SOLAR ENERGY↗