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At least 433 records · Page 24

Remote Sensing Of The Cryosphere In High Mountain Asia

High Mountain Asia (HMA), often referred to as the "third pole" of the world because its high elevation glaciers, contains the largest amount of fresh water outside the polar ice sheets. The region's hydrology is strongly controlled by variations in the timing and distribution of runoff from snow and glacier melt. Recent improvements in remote sensing technologies and atmospheric / land surface models provides new approaches for assessing the HMA cryosphere. A recently-funded NASA program aims to apply these tools to advance understanding of HMA cryospheric processes. Here we present an overview of planned team activities during the three-year project.

High Mountain Asia↗

New Support for Hypotheses of an Ancient Ocean on Mars

A new analog for the giant polygons in the Chryse-Acidalia area suggests that those features may have formed in a major body of water - likely a Late Hesperian to Early Amazonian ocean. This analog -terrestrial polygons in subsea, passive margin basins derives from 3D seismic data that show similar-scale, polygonal fault systems in the subsurface of more than 50 terrestrial offshore basins. The terrestrial and martian polygons share similar sizes, basin-wide distributions, tectonic settings, and association with expected fine-grained sediments. Late Hesperian deposition from outflow floods may have triggered formation of these polygons, by providing thick, rapidly-deposited, fine-grained sediments necessary for polygonal fracturing. The restriction of densely occurring polygons to elevations below approx. -4000 m to -4100 m supports inferences that a body of water controlled their formation. Those same elevations appear to restrict occurrence of polygons in Utopia Planitia, suggesting that this analog may apply also to Utopia and that similar processes may have occurred across the martian lowlands.

Oehler, Dorothy Z.↗

Boron and Lithium in Calcium Sulfate Veins: Tracking Precipitation of Diagenetic Materials in Vera Rubin Ridge, Gale Crater

The NASA Curiosity rover's ChemCam instrument suite has detected boron in calcium-sulfate-filled fractures throughout the sedimentary strata of Gale crater including Vera Rubin ridge. The presence of elevated B concentration provides insights into Martian subsurface aqueous processes. Here, we extend the data set of B in Ca-sulfate veins across Gale crater, comparing the detection frequency and relative abundances with Li. We report 33 new detections of B within veins analyzed between Sols 1548 and 2311 where detections increase in Pettegrove Point and Jura members, which form Vera Rubin ridge. The presence of B and Li in the Ca-sulfate veins is possibly due to dissolution of preexisting B in clays of the bedrock by acids or neutral water and redistribution of the elements into the veins. Elevated frequency of B detection in veins of Gale crater correlates with presence of dehydration features such as desiccation cracks, altered clay minerals and detections of evaporites such as Mg-sulfates and chloride salts in the host rocks. The increased observations of B also coincide with decreased Li concentration in the veins (average Li concentration of veins drops by ~15 ppm). Boron and Li have varying solubilities, and Li does not form salts as readily upon dehydration as B, causing it to remain in the solution. So the weak negative correlation between B and Li may reflect the crystallization sequence during dehydration on Vera Rubin ridge.

58 GEOSCIENCES↗

Tropospheric Delay Signal in SAR Interferogram and its Correction for Precise Surface Change Detection

Synthetic Aperture Radar (SAR) interferometry has become an important tool for measuring the surface deformation and mapping topography. The largest error source of the SAR interferometry measurements is differential atmospheric delay of water vapor. It reflects detailed distribution of water vapor in troposphere at data acquisition. We found phase difference associated with atmospheric waves and severe local atmospheric phenomena in interferograms. To distinguish phase difference associated with surface deformation from tropospheric effect, we need several SAR interferograms including the time period of the deformation. Averaging the interferograms is an effective way to reduce the tropospheric delay from horizontal inhomogeneity of the water vapor distribution. Apart from the tropospheric delay of the horizontal water vapor inhomogeneity, we often find the differential phase correlated to the topography (elevation) in interferograms, which might cause error in interpretation of surface deformation. This phase is due to the differential tropospheric delay caused by the topography and vertical change of water vapor between two images in different atmospheric condition. Theoretical calculation shows that the phase difference can be approximated by linear expression of the elevation. We applied a simple and effective correction method that the error is removed by subtracting the DEM (Digital Elevation Model) multiplied a coefficient.

Fujiwara, Satoshi↗

The Impact of Nonzenith Elevation Angles on Ground-Based Infrared Thermodynamic Retrievals

Observing thermodynamic profiles within the planetary boundary layer is essential to understanding and predicting atmospheric phenomena because of the significant exchange of sensible and latent heat between the land and atmosphere within that layer. The Atmospheric Emitted Radiance Interferometer (AERI) is a ground-based infrared spectrometer used to obtain the vertical profiles of temperature and water vapor mixing ratio. Most AERIs are only capable of zenith views, although the Marine AERI (M-AERI) has a design that allows it to view various elevation angles. In this study, we quantify the improvement in the information content and accuracy of the retrieved profiles when nonzenith angles are included, as is common with microwave radiometer profilers. The impacts of the additional scan angles are quantified through both a synthetic study and with M-AERI observations from the ARM Cloud Aerosol Precipitation Experiment (ACAPEX) campaign. Furthermore, the simulation study shows that low elevation angles contain more information content for temperature whereas high elevation angles have more information content for water vapor. Outside of very humid environments, the addition of low elevation angles also results in lower root-mean-square errors when compared with high angles for both temperature and water vapor mixing ratio, although this is primarily a result of averaging multiple observations together to reduce instrument noise. Real-world results from the ACAPEX dataset indicate similar results as were found for the simulation study, although not all predicted benefits are realized because of the small sample size and observational uncertainties.

54 ENVIRONMENTAL SCIENCES↗

Snow Depth Datasets for Snodgrass Catchment, Colorado, Water Year 2022-2023

This data package presents snow depths data from distributed temperature probes at 18 locations near Snodgrass catchment, Colorado. These data show that snow melt-out dates are approximately one or two weeks later under evergreen forests compared to other vegetation types even at the same elevation. These data were collected to understand how snowmelt heterogeneity impacts headwater hydrology, including streamflow and groundwater levels. They were also used to compare with process-based model simulations of snow depth to evaluate whether the model accurately represents snowmelt dynamics and their effects on headwater hydrology. Snow_DTPs_locations.csv includes all probes locations and their associated elevation and vegetation types. Snow_Depth_Snodgrass_WY2022_2023.csv includes processed snow depths datasets for Water Year (WY) 2022 and 2023. This dataset also includes a file-level metadata (flmd.csv) file that lists each file contained in the dataset with associated metadata and a data dictionary (dd.csv) file that contains column/row headers used throughout the files along with a definition, units, and data type. Several probes have recordings for WY 2021.

54 ENVIRONMENTAL SCIENCES↗

Hydroxide melt induced corrosion of Ni at elevated temperatures under steam electrolysis conditions

Molten alkali electrolyte based high temperature water electrolysis (HTWE) process offers an efficient pathway to integrate renewable energy resources for large scale and economic hydrogen production. Long term and stable operation of these systems require an in-depth understanding of materials stability under anodic and cathodic exposure conditions of the cell and cell stacks. In the present study, we report our findings on the corrosion of Ni in the presence and absence of (LieNa) hydroxide melt at 600 °C under oxidizing and reducing conditions representative of HTWE. While the Ni electrode was found to remain thermodynamically stable in metallic form under cathodic (reducing) exposure conditions, the corrosion rate in molten hydroxide under oxidizing conditions was found to be nonparabolic in nature. A cyclic voltammetry study provides the breakdown of the passive metal-oxide surface layer at the anodic overpotential region between 0.45 V and 2 V in molten hydroxide under oxidizing conditions. As a result, a thermochemical process for accelerated corrosion based on the oxide scale fluxing in hydroxide melt has been developed.

08 HYDROGEN↗

The Global Water Monitor: Wetland surface height dynamics for Ecology, Conservation, and Resource Management

The Global Water Monitor (GWM) offers surface water-related products for lakes, river reaches and wetland zones. The surface elevation change products are derived from satellite radar altimeters, such as the Jason/Sentinel series, and can span multiple decades. While the current instruments are profiling, they offer surface water height at specific locations, thus contributing to parallel observation of wetland surface water extent. GWM wetland products are “operational” with routine updates within 1-2days of satellite overpass. There is also assurance of product continuity to at least the end of 2030. Currently, the GWM holds products for a small selection (~40) of diverse wetlands for objectives that focus on conservation and water/fisheries resource monitoring. These sites have been requested by various organizations also looking to the effects of climate change and anthropogenic influences. Many of the current GWM wetland regions are in National Parks such as the Everglades (USA), the Wasur (Rep. Indonesia), and the Kakadu marshes (Australia). They also include coastal river deltas of the Danube, Mekong, Amazon, Orinoco and Ganges Rivers, and the internal Okavango Delta in Botswana. The preliminary set also ensures a diverse range of wetlands e.g., the shallow pot-hole lake region of the Sand Hills and the coastal Black Swamp of the USA, the peat fields of Malaysia and rice growing fields of Yilinzhen in China. Extensive wetlands in Brazil (the Pantanal), South Sudan (the Sudd Marshes) and Belarus (the Pinsk) are also featured, as are the mangrove regions of the Sundarbans (India) and the Laguna Terminos (Mexico). The Usangu wetland (Tanzania) is also included, a focus region where wetland ecology strongly competes with demands from irrigation, livestock, and the needs of downstream hydro-electric power. The nadir-pointing altimeter instruments record height variations regardless of vegetation or canopy cover, and height dynamics at 10-day or monthly resolution reveal seasonal and inter-annual variations as well as longer-term declining or re-charging trends. These products provide a unique, multi-decadal data set that can stand-alone or serve with cross-validation or image-fusion efforts.

Charon Birkett↗

Modeling Efforts to Gain Insight into Historical Leak Events from the Single-Shell Tank A-105 in the Hanford 241-A Tank Farm - 20113

The 241-A Tank Farm is a single-shell tank (SST) farm constructed to store process waste from Hanford nuclear operations. Millions of gallons of nuclear waste were stored in the 241-A Tank Farm SSTs and some of the SSTs leaked in the past. In addition, spills and pipeline leaks during transfers and storage and intentional discharges to cribs and trenches resulted in releasing waste to the ground. Tank liner leaks are referred to as 'leaks' and all other discharges to the soil are referred to as 'releases.' Liquid waste that could be removed by pumping has been removed from all of the SSTs to reduce the potential for future leaks. The most significant historical leak event in 241-A Tank Farm occurred in 1965 when tank A-105 experienced a pressurized steam event. This event resulted in damage to the inner steel liner flooring of A-105, which was separated from the sidewalls over part of its circumference and buckled up to 2.5 m, vertically. During this event up to 7,570 L of contaminated liquid may have leaked to the adjacent soil. This leak occurred under extreme temperature and pressure conditions. Modeling efforts to better understand the nature and extent of historical leaks from subsurface SSTs that were used to store highly radioactive, self-boiling liquid wastes at 241-A Tank Farm have recently been undertaken. These efforts have compiled the available historical information to support a preliminary non-isothermal, multiphase flow and chemical transport modeling effort to re-create the conditions under which the leaks occurred and to formulate a conceptual model as to the extent and distribution of leaked radioactive contaminants in the adjacent soil material. The focus of this work was on developing an understanding of the key features, processes and bounding conditions related to tank A-105 leak events that occurred in the 1960's. The activities include estimation of leak composition, non-isothermal multiphase flow and transport modeling, and geochemical modeling. The STOMP{sup C} Water-Air-Energy modeling code was utilized to implement the three-dimensional representation of the subsurface tank and the surrounding flow field. Once constructed, the model was used to evaluate the conceptual understanding of leaks originating from different parts of the tank under the elevated temperature boundary conditions that were imposed by surrounding tanks at the time of the historical leaks. The chemical evolution of the liquid waste was also evaluated as it leaked from the tank under transient pressure and temperature gradients. The results of the preliminary evaluation suggested the presence of a heat-pipe effect beneath tank A-105 in which water vapor at an elevated temperature is driven away from the base of the tank to a position where water vapor cools, condenses and is then drawn back toward the tank by the strong capillary attraction of the dry soil. A non-sorbing contaminant (Tc-99) was introduced into this flow field to better understand the potential distribution patterns of leaked contaminants that may have occurred during the historical leak events. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Temporal Patterns in Soil Redox Potential Vary Across a Freshwater Coastal Delta

Widespread and persistent flooding is submerging coastal ecosystems, particularly along the Louisiana Gulf coast, where flooding results from the compounding effects of ground subsidence and rising sea level. Restoration projects aim to mitigate land loss by diverting sediment loads from rivers into degraded areas to increase ground elevation. To predict how coastal ecosystems will change over time in response to projected changes in relative sea level and restoration, it is necessary to understand how subsurface biogeochemical processes respond to dynamic hydrologic forcings. Here, this study evaluates how environmental parameters that integrate biogeochemical processes vary with water table fluctuations in the freshwater Wax Lake Delta (WLD) in Louisiana, USA, where water diversions have formed one of the only active deltas along the coast. High‐frequency observations of water level, soil redox potential, specific conductance and pH were made for 1 year along elevation transects located on the older, proximal and younger, distal ends of a deltaic island. Redox responded rapidly to changing water tables, with fluctuations occurring primarily in shallow soils (< 20 cm) and at higher elevations. Deeper soils and those at lower elevation remained inundated and reduced. Semi‐diurnal tidal fluctuations were pronounced in younger, distal soils, presumably due to rapid groundwater exchange with the river channel. Tidal signals were muted in older soils that instead exhibited seasonal variability associated with river discharge and evapotranspiration. Although much of the delta sediments are persistently reducing and anoxic, redox fluctuations in the natural levees that border the deltaic islands likely drive high rates of biogeochemical activity. Evaluating how hydrology drives the frequency and duration of redox fluctuations provides a basis for understanding how biogeochemical processes might vary with complex hydrological interactions in coastal systems.

Herndon, Elizabeth [Oak Ridge National Laboratory ↗

Centimeter and millimeter wave attenuation and brightness temperature due to atmospheric oxygen and water vapor

Calculations are presented for atmospheric absorption and radiation emission for several atmospheric conditions and elevation angles. The calculations are for frequencies in the 1 to 340 GHz frequency range. The calculations are compared to those from other models. Agreement is found to within 15% for absorption coefficient (7.5 g/m/cubed water vapor at 290 K) and approximately the same for total zenithal attenuation. The attenuation and gaseous emission noise curves defined by the International Radio Consultative Committee are found to have minor inconsistencies.

Smith, E. K.↗

Nonequilibrium plasma in water vapor

A kinetic model of a non-equilibrium water vapor plasma created by a nanosecond pulsed discharge at elevated temperatures and at low pressure is presented. The model includes equations for electron, vibrational and gas temperatures combined with equations for neutral, charged, electronically and vibrationally excited species. Simulation results are compared with the available experimental data and show good agreement in dynamics of the plasma decay and electron drift velocities. It is shown that the plasma decay in pure water vapor is controlled by the dissociative recombination. Under the conditions simulated, the concentration of electronically excited species is low, but we observe a formation of vibrationally excited species. Finally, a significant decrease in the electrical conductivity of water plasma with time, which depends on the level of initial ionization, is shown.

42 ENGINEERING↗

Data from: "Responses of alpine plant communities to climate warming"

The Alpine Treeline Warming Experiment (ATWE) was a common garden-climate manipulation experiment set up across an elevation gradient in Niwot Ridge, in the Front Range of the Colorado Rocky Mountains, USA. The project sought to learn more about the effects of climate change on alpine and subalpine ecosystems, namely tree species ranges and alpine plant communities. Plots were experimentally manipulated using infrared heaters set up to warm plots to temperatures comparable to those projected for the year 2100. Other treatments include watering, and a combination of watering and heating. Three sites were set up at different elevations to study three tree species, with the highest-elevation “Alpine” site ( ~3540 m) containing twenty additional plots to study alpine plant communities. Data in this package originate from these unseeded alpine plots. To evaluate soil nitrogen availability given site treatments, resin bags were deployed, removed, and extracted annually to produce ammonium and nitrate/nitrite readings.--------------------------------------------------Data files within this archive are in comma-separated-values (.csv) and Microsoft Excel (.xlsx) formats. .csvs can be read and opened by Microsoft Excel, R, or any other simple text-editing software, and .xlsx files can be opened using Microsoft Excel. Geospatial data associated with this package are in .kml and ESRI shapefile (.shp) formats. .kml files can be read using Google Earth or Google Maps, and shapefiles can be read with any software compatible with the file type, such as QGIS or ESRI’s ArcMap suite.Data files in this package - excluding “Winkler_2019_ALPO_inorganic_N_allyears.csv” - are provided in both Microsoft Excel and .csv formats, for added accessibility and flexibility in workflows. File contents are identical.

54 ENVIRONMENTAL SCIENCES↗

Present and Future Changes in Land‐Atmosphere Coupling of Water and Energy Over Extratropical Forest Regions

Abstract Couplings between land and the near surface atmosphere are modulated by interactions between soil conditions, vegetation dynamics, turbulent fluxes, and atmospheric properties. How the land‐atmosphere coupling responds to warming and elevated CO 2 are important for understanding the land surface carbon, energy, and water cycles. In this work, we documented this coupled land‐atmosphere network based on observations and the Energy Exascale Earth System Model (E3SM) simulations over extratropical forest ecosystems. We employed a transfer entropy approach and novel network metrics to reveal patterns and strength of the land‐atmosphere coupling under historical conditions and a future high emission scenario (SSP585). We found that, in observations, the present‐day extratropical forest coupling network has high network connectivity (72%–88% of the targeted processes are coupled). E3SM reasonably captured the extratropical forest coupling network (modeled network connectivity was 81%–96%) and predicted that the coupling strength would significantly increase by 28% (±3%) under warming and elevated CO 2 conditions. Furthermore, E3SM factorial coupled experiments suggested that warming enhanced soil nitrogen mineralization favoring plant nitrogen uptake and vegetation growth were responsible for the strengthening future land‐atmosphere coupling. This work provides new metrics to analyze and document complex couplings for coupled earth system processes and highlights the important roles soil nutrient availability and biogeochemistry have on land‐atmosphere coupling.

54 ENVIRONMENTAL SCIENCES↗

Characterization of Contaminants and Mobility in WMA A-AX Boreholes D0006 and D0008

This study was initiated to determine if subsurface contaminants in the A-AX vadose zone at the Hanford site (boreholes D0006 and D0008) caused corrosion of nearby stainless steel well casings (299-E-24-19, 299-E25-46, and 299-E25-236) and, based on the type and distribution of contaminants, determine if contaminants are from one or more sources including a) the A-104 and/or A-105 tanks, b) the 242A evaporator, and c) the 200-E-286 ditch. A tiered approach was used for characterizing contaminants in vadose zone sediments starting with mobile and total contaminant concentrations (Tier 1), characterizing contaminant speciation (Tier 2), and measuring contaminant leaching (Tier 3). Total and mobile contaminant measurements at seven depths showed elevated sulfate and nitrate in all samples (130 to 280 ft depth), elevated chloride in five depths, and no elevated radionuclides except I-129 in D0006 at 206 to 208 ft depth. If these contaminants were initially acidic, stainless-steel corrosion would occur. However, because sediments likely have a high acid neutralization capacity, an acidic spill would have been neutralized within tens of feet, so casing corrosion would likely occur in shallow sediments. GEL labs data also shows low (but above natural) chromate from shallow to 170 ft depth, then higher chromate to 280 ft, suggesting a surface Cr spill or casing corrosion. GEL labs data also showed evidence of more than one plume, with deep nitrate, sulfate, and chloride migration, but only shallow tritium migration. Tritium should migrate nearly unretarded in the subsurface like nitrate and chloride. Elevated aqueous cations and anions in the D0006 206 to 208' depth pore water (SO 4 2- , NO 3 - , Na + , K + , Ca 2+ , Mg 2+ , Si) could be the result of acid disposal and calcite dissolution at shallow depth, with deeper migration of SO 4 2- , NO 3 - from acids and Ca 2+ and Mg 2+ from calcite. Elevated Si (160 mg/L) indicates dissolution of clays or other silicates, which can also occur in acids. Acid extractable metals did show elevated Cr (but not Fe, Ni, Mo, and Mn) above natural levels, which may indicate stainless-steel well corrosion or transport of metals from a shallow spill. The elevated I-129 in D0006 at 206 to 208' depth was low with 0.34 μg/g in pore water and 1.5 μg/g total extractable I-129 in the sediment, which indicates significant fraction of I-129 was bound in one or more precipitates. Although total I-129 was below detection limits in most extractions due to high molybdate interference, I-127 analysis provided some insight into potential precipitate phases. Total I-127 was mainly extracted by acetate or acetic acid (67%), which may be iodine in calcite. Inorganic carbon measurement identified 1.65% calcite, and total organic carbon (TOC) was below detection limits, so iodine was not associated with organic matter. Nearly all the I-127 was present as iodide. In 1-D leach experiments, I-127 as iodide leached from the sediment within 2 pore volumes. Due to high and dynamic molybdate leaching from the sediment and interference with I-129 analysis, there were few quantifiable I-129 measurements. The calculated molybdate release rates from the sediment suggested Mo was being released from the same precipitate phase, such as molybdate incorporated into calcite. Overall, because there was little radioactive contamination measured in D0006 and D0008 boreholes, potential releases from A-104 and A-105 did not reach this location south of the A tank farm. Elevated cations and anions found in D0006 and D0008 at depth as the result of acidic disposal could cause shallow stainless steel casing corrosion. The nearby 242A evaporator generally contained alkaline waste and tritium, but the nearby 200-E-286 ditch generally contained high Cl - liquid effluent, so these are unlikely to be acidic sources.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A GCM Study of Responses of the Atmospheric Water Cycle of West Africa and the Atlantic to Saharan Dust Radiative Forcing

The responses of the atmospheric water cycle and climate of West Africa and the Atlantic to radiative forcing of Saharan dust are studied using the NASA finite volume general circulation model (fvGCM), coupled to a mixed layer ocean. We find evidence of an "elevated heat pump" (EHP) mechanism that underlines the responses of the atmospheric water cycle to dust forcing as follow. During the boreal summerr, as a result of large-scale atmospheric feedback triggered by absorbing dust aerosols, rainfall and cloudiness are ehanIed over the West Africa/Eastern Atlantic ITCZ, and suppressed over the West Atlantic and Caribbean region. Shortwave radiation absorption by dust warms the atmosphere and cools the surface, while longwave has the opposite response. The elevated dust layer warms the air over West Africa and the eastern Atlantic. As the warm air rises, it spawns a large-scale onshore flow carrying the moist air from the eastern Atlantic and the Gulf of Guinea. The onshore flow in turn enhances the deep convection over West Africa land, and the eastern Atlantic. The condensation heating associated with the ensuing deep convection drives and maintains an anomalous large-scale east-west overturning circulation with rising motion over West Africa/eastern Atlantic, and sinking motion over the Caribbean region. The response also includes a strengthening of the West African monsoon, manifested in a northward shift of the West Africa precipitation over land, increased low-level westerlies flow over West Africa at the southern edge of the dust layer, and a near surface westerly jet underneath the dust layer overr the Sahara. The dust radiative forcing also leads to significant changes in surface energy fluxes, resulting in cooling of the West African land and the eastern Atlantic, and warming in the West Atlantic and Caribbean. The EHP effect is most effective for moderate to highly absorbing dusts, and becomes minimized for reflecting dust with single scattering albedo at0.95 or higher.

Lau, K. M.↗

Response of the Water Cycle of West Africa and Atlantic to Radiative Forcing by Saharan Dust

The responses of the atmospheric water cycle and climate of West Africa and the Atlantic to radiative forcing of Saharan dust are studied using the NASA finite volume general circulation model (fvGCM), coupled to a mixed layer ocean. We find evidence in support of the "elevated heat pump" (EHP) mechanism that underlines the responses of the atmospheric water cycle to dust forcing as follow. During the boreal summer, as a result of large-scale atmospheric feed back triggered by absorbing dust aerosols, rainfall and cloudiness are enhanced over the West Africa/Easter Atlantic ITCZ, and suppressed over the West Atlantic and Caribbean. region. Shortwave radiation absorption by dust warms the atmosphere and cools the surface, while long wave has the opposite response. The elevated dust layer warms the air over Nest Africa and the eastern Atlantic. The condensation heating associated with the induced deep convection drives and maintains an anomalous large-scale east-west overturning circulation with rising motion over West Africa/eastern Atlantic, and sinking motion over the Caribbean region. The response also includes a strengthening of the West African monsoon, manifested in northward shift of the West Africa precipitation over land, increased low-level westerlies flow over West Africa at the southern edge of the dust layer, and a near surface energy fluxes, resulting in cooling of the Nest African land and the eastern Atlantic, and a warming in the West Atlantic and Caribbean. The EHP effect is most effective for moderate to highly absorbing dusts, and becomes minimized for reflecting dust with single scattering albedo at 0.95 or higher.

Lau, K. M.↗

Airborne and Ground-Based Measurements Using a High-Performance Raman Lidar

A high-performance Raman lidar operating in the UV portion of the spectrum has been used to acquire, for the first time using a single lidar, simultaneous airborne profiles of the water vapor mixing ratio, aerosol backscatter, aerosol extinction, aerosol depolarization and research mode measurements of cloud liquid water, cloud droplet radius, and number density. The Raman Airborne Spectroscopic Lidar (RASL) system was installed in a Beechcraft King Air B200 aircraft and was flown over the mid-Atlantic United States during July August 2007 at altitudes ranging between 5 and 8 km. During these flights, despite suboptimal laser performance and subaperture use of the telescope, all RASL measurement expectations were met, except that of aerosol extinction. Following the Water Vapor Validation Experiment Satellite/Sondes (WAVES_2007) field campaign in the summer of 2007, RASL was installed in a mobile trailer for groundbased use during the Measurements of Humidity and Validation Experiment (MOHAVE-II) field campaign held during October 2007 at the Jet Propulsion Laboratory s Table Mountain Facility in southern California. This ground-based configuration of the lidar hardware is called Atmospheric Lidar for Validation, Interagency Collaboration and Education (ALVICE). During theMOHAVE-II field campaign, during which only nighttime measurements were made, ALVICE demonstrated significant sensitivity to lower-stratospheric water vapor. Numerical simulation and comparisons with a cryogenic frost-point hygrometer are used to demonstrate that a system with the performance characteristics of RASL ALVICE should indeed be able to quantify water vapor well into the lower stratosphere with extended averaging from an elevated location like Table Mountain. The same design considerations that optimize Raman lidar for airborne use on a small research aircraft are, therefore, shown to yield significant dividends in the quantification of lower-stratospheric water vapor. The MOHAVE-II measurements, along with numerical simulation, were used to determine that the likely reason for the suboptimal airborne aerosol extinction performance during theWAVES_2007 campaign was amisaligned interference filter. With full laser power and a properly tuned interference filter,RASL is shown to be capable ofmeasuring themain water vapor and aerosol parameters with temporal resolutions of between 2 and 45 s and spatial resolutions ranging from 30 to 330 m from a flight altitude of 8 km with precision of generally less than 10%, providing performance that is competitive with some airborne Differential Absorption Lidar (DIAL) water vapor and High Spectral Resolution Lidar (HSRL) aerosol instruments. The use of diode-pumped laser technology would improve the performance of an airborne Raman lidar and permit additional instrumentation to be carried on board a small research aircraft. The combined airborne and ground-based measurements presented here demonstrate a level of versatility in Raman lidar that may be impossible to duplicate with any other single lidar technique.

Whiteman, David N.↗