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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24

Heat sink effects on weld bead: VPPA process

An investigation into the heat sink effects due to weldment irregularities and fixtures used in the variable polarity plasma arc (VPPA) process was conducted. A basic two-dimensional model was created to represent the net heat sink effect of surplus material using Duhamel's theorem to superpose the effects of an infinite number of line heat sinks of variable strength. Parameters were identified that influence the importance of heat sink effects. A characteristic length, proportional to the thermal diffusivity of the weldment material divided by the weld torch travel rate, correlated with heat sinking observations. Four tests were performed on 2219-T87 aluminum plates to which blocks of excess material were mounted in order to demonstrate heat sink effects. Although the basic model overpredicted these effects, it correctly indicated the trends shown in the experimental study and is judged worth further refinement.

Steranka, Paul O., Jr.↗

Heat sink effects on weld bead: VPPA process

An investigation into the heat sink effects due to weldment irregularities and fixtures used in the variable polarity plasma arc (VPPA) process was conducted. A basic two-dimensional model was created to represent the net heat sink effect of surplus material using Duhamel's theorem to superpose the effects of an infinite number of line heat sinks of variable strength. Parameters were identified that influence the importance of heat sink effects. A characteristic length, proportional to the thermal diffusivity of the weldment material divided by the weld torch travel rate, correlated with heat sinking observations. Four tests were performed on 2219-T87 aluminum plates to which blocks of excess material were mounted in order to demonstrate heat sink effects. Although the basic model overpredicted these effects, it correctly indicated the trends shown in the experimental study and is judged worth further refinement.

Steranka, Paul O., Jr.↗

Cold-air performance of a 15.41-cm-tip-diameter axial-flow power turbine with variable-area stator designed for a 75-kW automotive gas turbine engine

An experimental evaluation of the aerodynamic performance of the axial flow, variable area stator power turbine stage for the Department of Energy upgraded automotive gas turbine engine was conducted in cold air. The interstage transition duct, the variable area stator, the rotor, and the exit diffuser were included in the evaluation of the turbine stage. The measured total blading efficiency was 0.096 less than the design value of 0.85. Large radial gradients in flow conditions were found at the exit of the interstage duct that adversely affected power turbine performance. Although power turbine efficiency was less than design, the turbine operating line corresponding to the steady state road load power curve was within 0.02 of the maximum available stage efficiency at any given speed.

Mclallin, K. L.↗

Global circuit variability from multiple stratospheric electrical measurements

The vertical component of the electric field, conductivity, and the derived current density from eight superpressure balloons are examined. Special emphasis was placed on the fair-weather, simultaneous measurements from widely spaced constant-altitude (26 km) balloons. The conductivity measurements were well organized by a simple ionization rate parameterization depending on the geomagnetic latitude. The variability of all the electrical parameters was found to be independent of the balloon separation. Much of the time the current density measurements were within 20 percent, for simultaneous flights, even though the balloons were up to 6000 km apart. Also, these simultaneous current density data show that the global current source was significantly variable on hourly and daily time scales. Finally, the use of the simultaneous current density data is discussed as a possible 'geoelectric index'. Advantages and limitations of such an index are discussed.

Norville, Kent↗

Degradation behavior of CIGS solar Cells: A parametric analysis

A parametric study of the effect of bulk and interface properties on device characteristics as a function of heat and light stress under open-circuit and short-circuit conditions is developed for Cu(In,Ga)(S,Se) 2 solar cells using SCAPS-1D simulator. The variables and interdependencies modeled include: (1) conduction band offset (CBO) between buffer and absorber; (2) buffer ionized donor density; (3) CIGS shallow acceptor density; (4) CIGS deep acceptor density; (5) CIGS shallow donor density; (6) ionized acceptor concentration in the ordered vacancy compound (OVC) CIGS/buffer interface; and (7) back contact work-function. An increase in absorber shallow acceptor or a decrease in shallow donor density results in an increase in net carrier density and open-circuit voltage (V OC ). Further, a decrease in V OC is observed with an increase in the deep acceptors or neutral midgap defects in the CIGS due to higher charge carrier recombination. A change of CBO from spike to cliff condition is a dominant mechanism of decreasing VOC with an interface defect density of 10 12 cm -2 . The minimum depletion width is found to be specifically sensitive to CBO and interface defect density. An inflection in the capacitance–voltage curves (in reverse bias) is observed with simultaneous increase in bulk deep acceptor density and shallow donor density near the back contact.

14 SOLAR ENERGY↗

Dynamics of Cation-Induced Conformational Changes in Nanometer-Sized Uranyl Peroxide Clusters

Conformational changes of the pyrophosphate (Pp)-functionalized uranyl peroxide nanocluster [(UO 2 ) 24 (O 2 ) 24 (P 2 O 7 ) 12 ] 48– ({U 24 Pp 12 }), dissolved as a Li/Na salt, can be induced by the titration of alkali cations into solution. The most symmetric conformer of the molecule has idealized octahedral ( O h ) molecular symmetry. One-dimensional 31 P NMR experiments provide direct evidence that both K + and Rb + ions trigger an O h -to- D 4 h conformational change within {U 24 Pp 12 }. Variable-temperature 31 P NMR experiments conducted on partially titrated {U 24 Pp 12 } systems show an effect on the rates; increased activation enthalpy and entropy for the D 4 h -to- O h transition is observed in the presence of Rb + compared to K + . Two-dimensional, exchange spectroscopy 31 P NMR revealed that magnetization transfer links chemically unique Pp bridges that are present in the D 4 h conformation and that this magnetization transfer occurs via a conformational rearrangement mechanism as the bridges interconvert between two symmetries. The interconversion is triggered by the departure and reentry of K (or Rb) cations out of and into the cavity of the cluster. This rearrangement allows Pp bridges to interconvert without the need to break bonds. Cs ions exhibit unique interactions with {U 24 Pp 12 } clusters and cause only minor changes in the solution 31 P NMR signatures, suggesting that O h symmetry is conserved. Single-crystal X-ray diffraction measurements reveal that the mixed Li/Na/Cs salt adopts D 2 h molecular symmetry, implying that while solvated, this cluster is in equilibrium with a more symmetric form. Thus, these results highlight the unusually flexible nature of the actinide-based {U 24 Pp 12 } and its sensitivity to countercations in solution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Influence of nuclear quantum effects on the electronic properties of amorphous carbon

We carry out quantum simulations to study the physical properties of diamond-like amorphous carbon by coupling first-principles molecular dynamics with a quantum thermostat, and we analyze multiple samples representative of different defective sites present in the disordered network. We show that quantum vibronic coupling is critical in determining the electronic properties of the system, in particular its electronic and mobility gaps, while it has a moderate influence on the structural properties. We find that despite localized electronic states near the Fermi level, the quantum nature of the nuclear motion leads to a renormalization of the electronic gap surprisingly similar to that found in crystalline diamond. We also discuss the notable influence of nuclear quantum effects on band-like and variable-hopping mechanisms contributing to electrical conduction. Our calculations indicate that methods often used to evaluate electron–phonon coupling in ordered solids are inaccurate to study the electronic and transport properties of amorphous semiconductors composed of light atoms.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Laboratory time series moisture manipulative experiment from sediment across San Antonio, Texas: time series aerobic respiration and geochemistry

This dataset supports a broader study examining the effects of wetting and drying on hyporheic zone respiration. The dataset provides data generated from a laboratory moisture manipulation experiment. The contents include time series aerobic respiration and moisture; dissolved oxygen; sediment geochemistry data; and field metadata (including qualitative information on instream and river corridor characteristics). Samples were collected as part of the WHONDRS Allison Veach collaboration (AV1). The data package associated with the AV1 study is available at https://data.ess-dive.lbl.gov/datasets/doi:10.15485/2529428. AV1 sampling occurred across 7 perennial and 7 intermittent streams in San Antonio, Texas. Each stream/site was visited both in summer during base flow (July-September 2023) and winter during peak flow (January-February 2024). This study uses subsamples from a subset of AV1 samples. The original field samples were labeled as AV1_###. Subsequent subsamples for this study were labeled as EV_###. The labels from the field samples and the EV subsamples can be mapped directly based on the digits following the prefix and underscore (i.e., EV_001 is a subsample from AV1_001). See the critical details section below for more details on sample naming. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. This dataset is comprised of one main data folder containing (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) readme; (5) field protocol; and a (6) a subfolder with sediment sample data from the incubation experiment. The sample data subfolder contains (1) effect size; (2) iron (II); (3) gravimetric moisture; (4) respiration rates; (5) raw dissolved oxygen values and plots; (6) specific conductance; (7) pH; (8) temperature; (9) a summary containing mean, median, and standard deviation values of each data type for each treatment (wet and dry); and (10) methods codes. All files are .csv or.pdf.

54 ENVIRONMENTAL SCIENCES↗

Thermodynamic controls on the synthesis, structure and reactivity of materials for energy (Final Report)

The major objectives have been: a) to advance and use unique calorimetric capabilities to determine the energetics of oxide and other materials having possible energy applications, with an emphasis on new materials for batteries, fuel cells and solar energy conversion, b) to understand, in terms of both macroscopic energetics and microscopic structure and bonding, the interplay of defect chemistry, oxidation-reduction, and size effects at the bulk and nanoscale in determining materials properties. This project emphasizes mixed ionic-electronic conduction materials containing transition metals of variable valence, especially perovskites and lithium containing phases, with M = Mn, Fe, Co, Ni. The thermochemistry of new families of complex halide, chalcogenide, nitride and hybrid (organic-inorganic) perovskite materials were explored. The major and unique technique employed is high temperature oxide melt solution calorimetry, with careful attention given to materials synthesis and characterization. The thermochemical studies will be coupled with structural studies, especially to characterize order-disorder phenomena by in situ high temperature diffraction techniques.

14 SOLAR ENERGY↗

Implications of Aerosol Physicochemical Properties Including Ice Nucleation at ARM Mega Sites for Improved Understanding of Microphysical Atmospheric Cloud Processes (Final Technical Report)

Continuous, long-term measurements of atmospheric ice-nucleating particles (INPs) that influence clouds and precipitation were conducted to investigate the abundance and variability of ground-level INPs across the world. Three field campaigns were organized by the DOE Atmospheric Radiation Measurement (ARM) program, including Examining INP from Southern Great Plains (ExINP-SGP, 2019), Examining INP from Eastern North Atlantic (ExINP-ENA, 2020 – 2021), and Examining INP from North Slope of Alaska (ExINP-NSA, 2021 – 2024). Additional small-scale supporting field experiments were performed in 2019 and 2021 to collect airborne particulate matter at SGP for complementary laboratory characterization of the particles’ physical and chemical properties [Aerosol-Ice Formation Closure Pilot Study (AEROICESTUDY), 2019; ExINP-SGP II, 2021]. In these studies, the PI’s team measured INP concentration with both real-time and laboratory measurements in a wide range of freezing temperatures ($T$ from 0 °C to about –30 °C). This project elucidated spatial variability and seasonality in the abundance of immersion mode active INPs across three ARM sites using a single instrument, a Portable Ice Nucleation Experiment (PINE) chamber version 03 (PINE-03 hereafter). Collocated aerosol and meteorological data were analyzed to assess the correlation between ambient INP abundance, air mass origin region, and meteorological variability. Our findings suggest very high freezing efficiency of INPs at the NSA site across the measured temperatures (ice nucleation active surface site density, $n_s(T)$, $\approx 2 \times 10^{8} - 10^{10}$ m -2 for from –16 to –31 °C), which is a factor of 10 – 1000 times greater efficiency as compared to that found in the previous mid-latitude INP measurements in autumn using the same instrument; surprisingly high INP abundance ($\ge 1 \text{ L}^{-1}$ at –25 °C) for the examined temperatures throughout the year that PINE-03 did not measure at other sites; and high INP concentration in spring, possibly related to arctic haze episodes.

58 GEOSCIENCES↗

Seasonal/Spatial Vertical New Particle Formation Variation Study (SSVNV) Field Campaign Report

The Seasonal/Spatial Vertical NPF Variation Study (SSVNV) campaign was conducted to investigate vertically resolved aerosol variability, boundary-layer structure, and new particle formation (NPF) processes across contrasting atmospheric environments through coordinated tethered balloon system (TBS) observations during U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) User Facility fixed-site measurements (Dexheimer et al. 2026). The campaign leveraged the overlapping deployments of the third ARM Mobile Facility (AMF3) at Bankhead National Forest (BNF; Kuang et al. 2023, 2026), Alabama, and the first ARM Mobile Facility 1 (AMF1) Coast-Urban-Rural Gradient Atmospheric Experiment (CoURAGE) in the Baltimore region. The campaign was operated by the TBS team led by Darielle Dexheimer from Sandia National Laboratories, in collaboration with the BNF site science team lead by Chongai Kuang from Brookhaven National Laboratory and the ARM team.

54 ENVIRONMENTAL SCIENCES↗

Detection of Galactic and Extragalactic Millimeter-wavelength Transient Sources with SPT-3G

High angular resolution cosmic microwave background experiments provide a unique opportunity to conduct a survey of time-variable sources at millimeter wavelengths, a population that has primarily been understood through follow-up measurements of detections in other bands. Here we report the first results of an astronomical transient survey with the South Pole Telescope (SPT) using the SPT-3G camera to observe 1500 deg 2 of the southern sky. The observations took place from 2020 March to November in three bands centered at 95, 150, and 220 GHz. This survey yielded the detection of 15 transient events from sources not previously detected by the SPT. The majority are associated with variable stars of different types, expanding the number of such detected flares by more than a factor of two. Additionally, the stellar flares are unpolarized and bright, in some cases exceeding 1 Jy, and have durations from a few minutes to several hours. Another population of detected events last for 2–3 weeks and appear to be extragalactic in origin. Though data availability at other wavelengths is limited, we find evidence for concurrent optical activity for two of the stellar flares. Future data from SPT-3G and forthcoming instruments will provide real-time detection of millimeter-wave transients on timescales of minutes to months.

79 ASTRONOMY AND ASTROPHYSICS↗

Reduction and error analysis of the AVE 2 pilot experiment data

The reduction techniques used to process data from the pilot experiment of the second NASA atmospheric variability experiment (AVE IIP), which was conducted during a 24 hour period beginning at 1200 GMT on May 11, 1974, and ending at 1200 GMT on May 12, 1974 are described. Each step of the data handling process is described through the presentation of computer flow charts, programs, equations, and narrative. An error analysis of the final output is presented, and results of the AVE IIP reduction process are compared with results from the National Weather Service. The AVE IIP sounding data contain more detail than National Weather Service data, but the two data sets may be used together without difficulty.

Fuelberg, H. E.↗

Aerodynamic characteristics of a hypersonic research airplane concept having a 70 degree swept double delta wing at Mach numbers from 1.50 to 2.86

An experimental investigation of the static longitudinal, lateral, and directional stability characteristics of a hypersonic research airplane concept having a 70 deg swept double-delta wing was conducted in the Langley unitary plan wind tunnel. The configuration variables included wing planform, tip fins, center fin, and scramjet engine modules. The investigation was conducted at Mach numbers from 1.50 to 2.86 and at a constant Reynolds number, based on fuselage length, of 3,330,000. Tests were conducted through an angle-of-attack range from about -4 deg to 24 deg with angles of sideslip of 0 deg and 3 deg and at elevon deflections of 0, -10, and -20 deg. The complete configuration was trimmable up to angles of attack of about 22 deg with the exception of regions at low angles of attack where positive elevon deflections should provide trim capability. The angle-of-attack range for which static longitudinal stability also exists was reduced at the higher Mach numbers due to the tendency of the complete configuration to pitch up at the higher angles of attack. The complete configuration was statically stable directionally up to trimmed angles of attack of at least 20 deg for all Mach numbers M with the exception of a region near 4 deg at M = 2.86 and exhibited positive effective dihedral at all positive trimmed angles of attack.

Penland, J. A.↗

A search for slowly varying radio continuum emission from UV Ceti stars

The paper presents results of a search conducted at the Arecibo Observatory for variable 430-MHz emission from the active flare stars EQ Peg, YZ CMi, and AD Leo. No statistically significant evidence for slowly varying emission is found to a level of 0.05 Jy for AD Leo, 0.018-0.021 Jy for YZ CMi, and 0.009-0.018 Jy for EQ Peg. Upper limits of about 10 trillion K are determined for the brightness temperature of active radio regions on these stars at the time of the observations.

Spangler, S. R.↗

OSU participation in the CTS communications link characterization experiment

A four element self phased array was developed for propagation measurements utilizing the Communication Technology Satellite 11.7 GHz downlink. The parameters of interest in measurements were attenuation, amplitude scintillation, and angle of arrival variability. Simultaneous scintillation measurements were also conducted at 360 MHz, 2.075 GHz, and 30 GHz utilizing ATS-6. The unique movement of ATS-6 during 1976 permitted extensive measurement of scintillation characteristics as a function of path elevation angle.

Hodge, D. B.↗

User requirements for a patient scheduling system

A rehabilitation institute's needs and wants from a scheduling system were established by (1) studying the existing scheduling system and the variables that affect patient scheduling, (2) conducting a human-factors study to establish the human interfaces that affect patients' meeting prescribed therapy schedules, and (3) developing and administering a questionnaire to the staff which pertains to the various interface problems in order to identify staff requirements to minimize scheduling problems and other factors that may limit the effectiveness of any new scheduling system.

Zimmerman, W.↗

LANDSAT-4 band 6 data evaluation

The radiometric integrity of the LANDSAT-D thematic mapper (TM) thermal infrared channel (band 6) data was evaluated to develop improved radiometric preprocessing calibration techniques for removal of atmospheric effects. Primary data analysis was spent in evaluating the line to line and detector to detector variation in the thermal infrared data. The data studied was in the core area of Lake Ontario where very stable temperatures were expected. The detectors and the scan direction were taken as separate parameters and an analysis of variance was conducted. The data indicate that significant variability exists both between detectors and between scan directions.

Source record↗