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At least 433 records · Page 24

Diaspora: Resilience-Enabling Services for Real-Time Distributed Workflows

The need for real-time processing to enable automated decision making and experimental steering has driven a shift from high-performance computing workflows on a centralized system to a distributed approach that integrates remote data sources, edge devices, and diverse compute facilities. Under this paradigm, data can be processed close to the source where it is generated, thus reducing latency and bandwidth usage. System resilience is thus a key challenge, requiring distributed workflows to survive component failures and to meet stringent quality-of-service requirements, which results in the need to mitigate anomalies such as congestion and low availability of resources. To address these challenges, we propose Diaspora, a unified resilience framework that is inspired by event-driven communication patterns used in public clouds. Specifically, we propose an event fabric that extends across sites, facilities, and computations to provide timely, reliable, and accurate information about data, application, and resource status. On top of the event fabric, we build resilience-enabling services that combine QoS-aware data streaming, resilient data views, resilient compute and data resources, and anomaly detection and prediction, all of which collectively enhance workflow resilience for these scientific cases.

Rao, Nageswara↗

Initial Conditions of Planet Formation: Time Constraints from Small Bodies and the Lifetime of Reservoirs in the Solar Protoplanetary Disk

This review explores the timescales of the initial phase of planet formation, from nebular dust (CAIs and chondrules) to planetesimal accretion and differentiation, using evidence from meteorite research. Aluminium-Mg systematics of CAIs indicate either an extended period of CAI formation (∼0.3 Ma) or an initial 26 Al heterogeneity, with evidence supporting a homogeneous 26 Al abundance in the protoplanetary disk. Thermal and aqueous alteration on the parent body can disturb the U-Pb and Al-Mg chronometers in chondrules. Focusing on relatively robust isochron data from plagioclase of pristine (types ≤3.05) chondrites indicates a shift in chondrule formation locations, moving from the inner to the outer disk over time. Ages of basaltic achondrites show that silicate differentiation on small bodies was well underway within the first few million years (Ma) of our solar system. Their age record, however, reveals inconsistencies between different chronometers, partly caused by (i) secondary disturbances due to thermal metamorphism, aqueous alteration, or impacts, (ii) the presence of xenolithic minerals, and (iii) potentially variable initial 26 Al abundances due to disturbances at the mineral scale. Nucleosynthetic isotope data indicate that parent bodies of iron and stony meteorites formed in two distinct regions within the protoplanetary disk: the inner, non-carbonaceous (NC) and the outer, carbonaceous (CC) region. Based on Hf-W chronometry it has been demonstrated that NC and CC parent bodies of magmatic iron meteorites segregated their cores within ∼1–3 Ma after CAI formation, implying that parent body accretion occurred within <1 Ma in both reservoirs. Combining accretion ages with nucleosynthetic data further reveals that, at first order, NC and CC reservoirs in the solar protoplanetary disk were established within 1 Ma and existed over several Ma with limited exchange between them. In the CR chondrite accretion region of the disk, planetary bodies formed over at least 3 Ma, while in most other regions, formation spanned at least 1 Ma, with minimal changes in nucleosynthetic isotope compositions. Aerodynamical size sorting of dust likely introduced or amplified some of these variations.

26Al distribution↗

Benchmarking Demand Flexibility in Commercial Buildings and Flattening the Duck – Addressing Baseline and Commissioning Challenges

With the transition from our traditional electric grid to a cleaner grid with renewable power generation, there is a need to enable building loads to be flexible. Load shedding and shifting will be essential for flattening the “Duck” for decarbonization. This paper explored the trend in the timing of DR events as a reflection of the grid’s needs using recent four years of event data from 203 retail stores in 11 states. The events are becoming significantly shorter with 2-hour duration being the most popular; shifting to late afternoon and early evening is another trend beyond California. Benchmarking will be essential for accounting DF as a reliable grid resource. This paper addresses a challenging aspect of benchmarking – inaccuracies in counterfactual baseline methods can introduce significant DF metrics variations in addition to weather and building characteristics related factors. The conventional “10/10” with adjustment baseline method has inherent limitation by design for load shifting applications. Therefore, it is imperative to identify alternative methods. This study compared three hourly regression baseline methods with “10/10” methods using two groups of commercial buildings that participated in DR programs: (1) 121 big-box retail stores, and (2) 11 office buildings in CA. The 14-day hourly outdoor temperature regression method was found to produce least error in the tested datasets and is promising for load shifting. The paper also pointed out that commissioning issues can also be a significant barrier for achieving consistent DF performance, which building managers and utilities should be aware of.

Liu, Jingjing↗

Time Refraction of Spin Waves

Here, we present an experimental study of time refraction of spin waves (SWs) propagating in microscopic waveguides under the influence of time-varying magnetic fields. Using space- and time-resolved Brillouin light scattering microscopy, we demonstrate that the broken translational symmetry along the time coordinate results in a loss of energy conservation for SWs and thus allows for a broadband and controllable shift of the SW frequency. With an integrated design of SW waveguide and microscopic current line for the generation of strong, nanosecond-long, magnetic field pulses, a conversion efficiency up to 39% of the carrier SW frequency is achieved, significantly larger compared to photonic systems. Given the strength of the magnetic field pulses and its strong impact on the SW dispersion relation, the effect of time refraction can be quantified on a length scale comparable to the SW wavelength. Furthermore, we utilize time refraction to excite SW bursts with pulse durations in the nanosecond range and a frequency shift depending on the pulse polarity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Lifetime and Degradation Study of Poly(Methyl Methacrylate) via a Data-Driven Study Protocol Approach

We report to optimize and extend the service life of polymeric materials in outdoor environments, a domain knowledge-based and data-driven approach was utilized to quantitatively investigate the temporal evolution of degradation modes, mechanisms, and rates under various stepwise accelerated exposure conditions. Six formulations of poly(methyl methacrylate) (PMMA) with different combinations of stabilizing additives, including one unstabilized formulation, were exposed in three accelerated weathering conditions. Degradation was dependent on wavelength as samples in UV light at 340 nm (UVA) exposure showed the most yellowing. The unstabilized PMMA formulation showed much higher yellowness index values (59.5) than stabilized PMMA formulations (2–12). Urbach edge analysis shows a shift toward longer wavelength from 285 to 500 nm with increasing exposure time and an increased absorbance around 400 nm of visible region as the unstabilized samples increase in yellowing. The degradation mechanisms of PMMA were tracked using induced absorbance to dose at specific wavelengths that correspond to known degradation mechanisms. The degradation pathway of PMMA was modeled in a framework using network structural equation modeling (netSEM). netSEM showed changes in degradation pathway as PMMA transition stages of degradation.

36 MATERIALS SCIENCE↗

Scalar field in Reissner–Nordström spacetime: Bound state and scattering state (with appendix on eliminating oscillation in partial sum approximation of periodic function)

Highlights: • Bound-state and scattering-state solutions of massive scalar fields in R-N spacetime. • Bound-state wave functions and eigenvalues of massive scalar fields in R-N spacetime. • Solving explicit expressions of scattering phase shifts by integral equation methods. • Introducing tortoise coordinates for R-N spacetime. • Eliminating oscillations in the partial sum approximation of periodic functions. In this paper, we solve the massive scalar field in the Reissner–Nordström spacetime. The scalar field in the Reissner–Nordström spacetime has both bound states and scattering states. For bound states, we solve the bound-state wave function and the eigenvalue spectrum. For scattering states, we solve the scattering wave function and give an explicit expression for scattering phase shift by the integral equation method. Especially, we introduce the tortoise coordinate for the Reissner–Nordström spacetime. Moreover, in the calculation of scattering cross sections, we encounter a difficulty in partial sum approximation. If the sum of partial waves cannot be performed exactly, one has to turn to the partial sum approximation which approximates a function by the first several terms of the series. However, in the partial sum approximation there exists an incorrect oscillation which cannot be eliminated by keeping more terms. In the appendix we suggest an approach for eliminating such oscillations in the partial sum.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Circadian clock control of ribosome composition promotes rhythmic translation and termination fidelity

Ribosome composition is dynamic, shifting with cell state and stress, but whether it varies with circadian time is unknown. Here, we uncover circadian clock-driven changes in ribosome composition in Neurospora crassa . Mass spectrometry of ribosomes across circadian time identified six ribosomal proteins and one associated factor under clock control. Rhythms in eL31 abundance were validated in purified ribosomes, and deletion of el31 disrupted translation rhythms in nearly half of rhythmically translated mRNAs. N. crassa eL31 promotes circadian control of translation termination and impacts elongation fidelity while maintaining Mg homeostasis, a key determinant of translational accuracy. These findings reveal that the circadian clock reprograms ribosome composition to orchestrate rhythmic translation and fidelity, temporally expanding the proteome beyond the static genome to align cellular function with time of day.

circadian clock↗

Breaking Down the Computational Barriers to Real-Time Urban Flood Forecasting

Flooding impacts are on the rise globally, and concentrated in urban areas. Currently, there are no operational systems to forecast flooding at spatial resolutions that can facilitate emergency preparedness and response actions mitigating flood impacts. We present a framework for real-time flood modeling and uncertainty quantification that combines the physics of fluid motion with advances in probabilistic methods. The framework overcomes the prohibitive computational demands of high-fidelity modeling in real-time by using a probabilistic learning method relying on surrogate models that are trained prior to a flood event. This shifts the overwhelming burden of computation to the trivial problem of data storage, and enables forecasting of both flood hazard and its uncertainty at scales that are vital for time-critical decision-making before and during extreme events. The framework has the potential to improve flood prediction and analysis and can be extended to other hazard assessments requiring intense high-fidelity computations in real-time.

54 ENVIRONMENTAL SCIENCES↗

An energetics assessment of benzo[ a ]tetracene and benzo[ a ]pyrene as triplet–triplet annihilation emitters

Optical upconversion (UC) of low energy photons into high energy photons enables solar cells to harvest photons with energies below the band gap of the absorber, reducing the transmission loss. UC based on triplet–triplet annihilation (TTA) in organic chromophores can upconvert photons from sunlight, albeit with low conversion efficiency. We utilize three energy-based criteria to assess the UC potential of TTA emitters in terms of the quantum yield (QY) and the anti-Stokes shift. The energy loss in the singlet pathway of an emitter encounter complex, where a high energy photon is emitted, determines whether a chromophore may undergo TTA. The energy loss in the triplet pathway, which is the main competing process, impacts the TTA QY. The energy difference between the lowest singlet and triplet excitation states in TTA emitters sets an upper bound for the anti-Stokes shift of TTA-UC. Using the energetic criteria evaluated by time-dependent density functional theory (TDDFT) calculations, we find that benzo[a]tetracene, benzo[a]pyrene, and their derivatives are promising TTA emitters. The energetics assessment and computer simulations could be used to efficiently discover and design more candidate high-performance TTA emitters.

36 MATERIALS SCIENCE↗

Real-time breath analysis towards a healthy human breath profile

Abstract The direct analysis of molecules contained within human breath has had significant implications for clinical and diagnostic applications in recent decades. However, attempts to compare one study to another or to reproduce previous work are hampered by: variability between sampling methodologies, human phenotypic variability, complex interactions between compounds within breath, and confounding signals from comorbidities. Towards this end, we have endeavored to create an averaged healthy human ‘profile’ against which follow-on studies might be compared. Through the use of direct secondary electrospray ionization combined with a high-resolution mass spectrometry and in-house bioinformatics pipeline, we seek to curate an average healthy human profile for breath and use this model to distinguish differences inter- and intra-day for human volunteers. Breath samples were significantly different in PERMANOVA analysis and ANOSIM analysis based on Time of Day, Participant ID, Date of Sample, Sex of Participant, and Age of Participant ( p < 0.001). Optimal binning analysis identify strong associations between specific features and variables. These include 227 breath features identified as unique identifiers for 28 of the 31 participants. Four signals were identified to be strongly associated with female participants and one with male participants. A total of 37 signals were identified to be strongly associated with the time-of-day samples were taken. Threshold indicator taxa analysis indicated a shift in significant breath features across the age gradient of participants with peak disruption of breath metabolites occurring at around age 32. Forty-eight features were identified after filtering from which a healthy human breath profile for all participants was created.

60 APPLIED LIFE SCIENCES↗

High harmonic generation in mixed XUV and NIR fields at a free-electron laser

Abstract We present the results of an experiment investigating the generation of high-order harmonics by a femtosecond near-infrared (NIR) laser pulse in the presence of an extreme ultraviolet (XUV) field provided by a free-electron laser (FEL), a process referred to as XUV-assisted high-order harmonic generation (HHG). Our experimental findings show that the XUV field can lead to a small enhancement in the harmonic yield when the XUV and NIR pulses overlap in time, while a strong decrease of the HHG yield and a red shift of the HHG spectrum is observed when the XUV precedes the NIR pulse. The latter observations are in qualitative agreement with model calculations that consider the effect of a decreased number of neutral emitters but are at odds with the predicted effect of the correspondingly increased ionization fraction on the phase matching. Our study demonstrates the technical feasibility of XUV-assisted HHG experiments at FELs, which may provide new avenues to investigate correlation-driven electron dynamics as well as novel ways to study and control propagation effects and phase matching in HHG.

47 OTHER INSTRUMENTATION↗

Quantum optimal control of ten-level nuclear spin qudits in Sr 87

We study the ability to implement unitary maps on states of the I = 9 / 2 nuclear spin in Sr 87 , a d = 10 dimensional (qudecimal) Hilbert space, using quantum optimal control. Through a combination of nuclear spin resonance and a tensor ac Stark shift, by solely modulating the phase of a radio-frequency magnetic field, the system is quantum controllable. Alkaline-earth-metal atoms, such as Sr 87 , have a very favorable figure of merit for such control due to narrow intercombination lines and the large hyperfine splitting in the excited states. We numerically study the quantum speed limit, optimal parameters, and the fidelity of arbitrary state preparation and full SU(10) maps, including the presence of decoherence due to optical pumping induced by the light-shifting laser. We also study the use of robust control to mitigate some dephasing due to inhomogeneities in the light shift. We find that with an rf Rabi frequency of Ω rf and 0.5% inhomogeneity in the the light shift we can prepare an arbitrary Haar-random state in a time T = 4.5 π / Ω rf with average fidelity ( F ψ ) = 0.9992 , and an arbitrary Haar-random SU(10) map in a time T = 24 π / Ω rf with average fidelity ( F U ) = 0.9923 .

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

eCounter: Inline Per-IP Network Monitoring at Millisecond Resolution via eBPF

Scientific data acquisition (SciDAQ) systems are shifting from archive-based workflows to streaming paradigms, where real-time, fine-grained network monitoring becomes essential. While P4-enabled devices offer per-packet in-band observability, they require specialized switches and routers. Host-side tools like Prometheus exporters lack sufficient temporal granularity. To bridge this gap, we present eCounter, a lightweight, hardware-agnostic, inline telemetry agent built on extended Berkeley Packet Filter (eBPF). eCounter captures per-interface ingress and egress traffic, categorized by IP address and protocol, at millisecond to sub-millisecond resolution. In a 100 Gbps environment, it continuously exports up to 3,257 time-series bins per second with only 4% CPU utilization at a 35¿KiB/s data rate. We evaluate eCounter across diverse NIC MTU settings, hook types, CPU architectures and operating systems, and observed negligible impact on concurrent high-throughput streaming applications. Complexity analysis confirms that it can be readily scaled to distributed SciDAQ deployments.

Mei, Xinxin [Computational Sciences and Technology↗

Modeling Assessment of Residential Air-to-Water Heat Pumps Coupled with Cooling Thermal Storage

This study explored the performance and operating cost viability of air-to-water heat pumps (AWHPs) coupled with thermal energy storage (TES) in efficient new residential construction. AWHPs are an emerging technology in this country, but offer promise in terms of high efficiency, fully contained and factory charged outdoor refrigeration system, and hydronic delivery capabilities, which facilitates zoning, ducts in conditioned space, and TES integration for summer load-shifting. Although this AWHP+TES strategy is not yet mainstream, the authors feel that in ten years as decarbonization efforts proceed and TOU rates become more common, strategies such as this will be more accessible. Validated EnergyPlus simulation models were developed based on detailed monitoring data collected over several years at Pacific Gas and Electric's CVRH laboratory test homes located in Stockton, California. One of the CVRH test homes (1,962 ft 2 two-story) had been testing various AWHP systems and configurations over the past six years. The validated model was then updated with high efficiency IECC ZERH envelope and component requirements for climate zones 1-5, including ducts in conditioned space thermal distribution. Simulations were completed for the 1,962 ft 2 home in each climate zone for a minimum efficiency ASHP, an AWHP coupled with a fan coil, and an AWHP coupled with TES sized to eliminate summer on-peak compressor operation. To maintain consistency in reporting energy use estimates, all cases were run with a similar indoor thermostat control strategy to pre-cool the house below the nominal 76 degrees Fahrenheit set point prior to the on-peak period and float slightly above the set point during the peak period. The AWHP+TES configuration was controlled to alternately condition the indoor space or to charge the TES tanks prior to the beginning of the on-peak. Three composite TOU rates were developed based on existing TOU rates across the U.S. to provide differing economic scenarios to evaluate customer bill impacts throughout the summer. Two of the TOU rates had short three-hour peak periods, while the third rate had a longer seven-hour duration peak period. AWHP modeling projections were based on the observed field performance of the Chiltrix CX34 variable speed unit. Other products on the market or entering the market in the near term would likely perform differently.

25 ENERGY STORAGE↗

Quantifying resolution in cosmological N- body simulations using self-similarity

ABSTRACT We demonstrate that testing for self-similarity in scale-free simulations provides an excellent tool to quantify the resolution at small scales of cosmological N-body simulations. Analysing two-point correlation functions measured in simulations using abacus , we show how observed deviations from self-similarity reveal the range of time and distance scales in which convergence is obtained. While the well-converged scales show accuracy below 1 per cent, our results show that, with a small force softening length, the spatial resolution is essentially determined by the mass resolution. At later times, the lower cut-off scale on convergence evolves in comoving units as a−1/2 (a being the scale factor), consistent with a hypothesis that it is set by two-body collisionality. A corollary of our results is that N-body simulations, particularly at high red-shift, contain a significant spatial range in which clustering appears converged with respect to the time-stepping and force softening but has not actually converged to the physical continuum result. The method developed can be applied to determine the resolution of any clustering statistic and extended to infer resolution limits for non-scale-free simulations.

79 ASTRONOMY AND ASTROPHYSICS↗

The persistence and conversion of coastal foredune and swale vegetation community distributions 63 years later

Vegetation shifts can directly alter habitat dynamics and indirectly impact habitat stability relative to disturbance response. Barrier island dune habitats exhibit spatiotemporally dynamic topography that is affected by vegetation. However, vegetation distribution data can be rare and vegetation persistence is largely unknown such that species turnover over in communities can occur unnoticed. This is true despite concerns and documented cases of woody encroachment related to climate change in these ecogeomorphic habitats where physical stability to resist storm erosion varies with vegetation distribution and density. In 1956 and 1957, the vegetation of Island Beach State Park, NJ, was mapped as a permanent record for subsequent ecological study. In June 2020, we remapped the vegetation of 5.4 of 17 km north to south, seaward of the thicket community boundary. We maintained the same classification system as the historic record, physically mapping vegetation patches via GPS. We quantified changes in thicket, heather, and grass community distribution between the two time periods. Habitat persistence and conversion varied in the 63 years. Heath communities saw 80%–97% habitat loss in conversion to woody thicket. Conversely, thicket community distribution drastically increased, replacing heath where it was previously prevalent. This represents the first known documented instances of woody encroachment for Morella pensylvanica. When they did not expand, thicket communities receded landward or underwent turnover to an invasive species. Woody species of interest for dune stabilization occupied areas of similar habitat characteristics. Dune vegetation distribution persistence from 1957 to 2020 was relatively consistent and stable with the exception of heath habitat conversion. Barrier island stability is directly related to vegetation stability such that understanding where community shifts might occur over time can aid in managing and modeling efforts surrounding these dynamic ecogeomorphic habitats.

54 ENVIRONMENTAL SCIENCES↗

Sizing Considerations for EV Dynamic Wireless Charging Systems with Integrated Energy Storage

Roadways with dynamic wireless charging systems (DWCS) enable charge-sustaining in-motion EV charging, which can reduce charging idle time while increasing range capabilities. Spatially distributed transmitter coils are controlled in response to traffic load that varies significantly minute to minute with high power levels, very short charging time, and low system utilization like wind turbine power. Traffic load estimation and localized analysis may guide effective sizing and topology adoption for feasible and scalable DWCS deployment. DWCS traffic load approximation is reviewed with measured Automated Traffic Recorder (ATR) data and statistical distributions being used to create a synthetic load analyzed using proposed metrics quantifying system utilization over time. Lumped coil section segmentation is compared between second-based distance and spatial density analysis methods, offering 17-27% greater system utilization. A peak load shifting method is proposed for traffic redirection across two tracks with optional BESS integration increasing system utilization by 50-60% depending on time-based and power reserve-based sizing and control.

Lewis, Donovin D.↗

Electron thermalization and relaxation in laser-heated nickel by few-femtosecond core-level transient absorption spectroscopy

Direct measurements of photoexcited carrier dynamics in nickel are made using few-femtosecond extreme ultraviolet (XUV) transient absorption spectroscopy at the nickel M 2,3 edge. It is observed that the core-level absorption line shape of photoexcited nickel can be described by a Gaussian broadening (σ) and a red shift (ω s ) of the ground-state absorption spectrum. Theory predicts and the experimental results verify that after initial rapid carrier thermalization, the electron temperature increase (ΔT ) is linearly proportional to the Gaussian broadening factor σ, providing quantitative real-time tracking of the relaxation of the electron temperature. Measurements reveal an electron cooling time for 50 nm thick polycrystalline nickel films of 640 ± 80 fs. With hot thermalized carriers, the spectral red shift exhibits a power-law relationship with the change in electron temperature of ω s ∝ ΔT 1.5 . Rapid electron thermalization via carrier-carrier scattering accompanies and follows the nominal 4-fs photoexcitation pulse until the carriers reach a quasithermal equilibrium. Entwined with a <6 fs instrument response function, carrier thermalization times ranging from 34 fs to 13 fs are estimated from experimental data acquired at different pump fluences and it is observed that the electron thermalization time decreases with increasing pump fluence. Here, the study provides an initial example of measuring electron temperature and thermalization in metals in real time with XUV light, and it lays a foundation for further investigation of photoinduced phase transitions and carrier transport in metals with core-level absorption spectroscopy.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗