Temperature dependence of the solar absorptance and thermal emittance of copper, gold, nickel, and silver.
Solar absorptance and thermal emittance of copper, gold, nickel and silver as function of temperature
THERMAL EMISSION↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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On the anisotropy and temperature dependence of ultrasonic attenuation in the mixed state of niobium.
Ultrasonic attenuation in pure Nb mixed state for magnetic field near second critical strength, noting field orientation and temperature effects
Garbuny, M.↗
Temperature-dependent daily variability of precipitable water in special sensor microwave/imager observations
We use retrievals of atmospheric precipitable water from satellite microwave observations and analyses of near-surface temperature to examine the relationship between these two fields on daily and longer time scales. The retrieval technique producing the data used here is most effective over the open ocean, so the analysis focuses on the southern hemisphere's extratropics, which have an extensive ocean surface. For both the total and the eddy precipitable water fields, there is a close correspondence between local variations in the precipitable water and near-surface temperature. The correspondence appears particularly strong for synoptic and planetary scale transient eddies. More specifically, the results support a typical modeling assumption that transient eddy moisture fields are proportional to transient eddy temperature fields under the assumption f constant relative humidity.
Gutowski, William J.↗
Temperature-Dependent Carrier Extraction and the Effects of Excitons on Emission and Photovoltaic Performance in Cs0.05FA0.79MA0.16Pb(I0.83Br0.17)3 Solar Cells
The photovoltaic parameters of triple cation perovskite [Cs0.05FA0.79MA0.16Pb(I0.83Br0.17)3] solar cells are investigated focusing on the electro-optical properties and differences in performance at low and high temperatures. The signature of a parasitic barrier to carrier extraction is observed at low temperatures, which results in a loss of performance at T < 200 K. Intensity-dependent measurements indicate extraction across this parasitic interface is limited by a combination of the exciton binding energy and thermionic emission. However, the photovoltaic performance of the device is recovered at low intensity - where the photocarrier generation rate threshold is lower than the thermionic extraction rate. Loss of solar cell performance is also observed to be strongly correlated to an increase in photoluminescence intensity, indicating inhibited carrier extraction results in strong radiative recombination and that these systems do not appear to be limited by significant thermally activated non-radiative processes. Evidence of limited carrier extraction due to excitonic effects is also observed with a strong anti-correlation in photoluminescence and carrier extraction observed at lower temperatures.
barrier↗
Understanding the Instability of the Halide Perovskite CsPbI 3 through Temperature-Dependent Structural Analysis
Despite the tremendous interest in halide perovskite solar cells, the structural reasons that cause the all-inorganic perovskite CsPbI 3 to be unstable at room temperature remain mysterious, especially since many tolerance-factor-based approaches predict CsPbI 3 should be stable as a perovskite. Here single-crystal X-ray diffraction and X-ray pair distribution function (PDF) measurements characterize bulk perovskite CsPbI3 from 100 to 295 K to elucidate its thermodynamic instability. While Cs occupies a single site from 100 to 150 K, it splits between two sites from 175 to 295 K with the second site having a lower effective coordination number, which, along with other structural parameters, suggests that Cs rattles in its coordination polyhedron. PDF measurements reveal that on the length scale of the unit cell, the Pb-I octahedra concurrently become greatly distorted, with one of the I-Pb-I angles approaching 82° compared to the ideal 90°. The rattling of Cs, low number of Cs-I contacts, and high degree of octahedral distortion cause the instability of perovskite-phase CsPbI 3 . These results reveal the limitations of tolerance factors in predicting perovskite stability and provide detailed structural information that suggests methods to engineer stable CsPbI 3 -based solar cells.
36 MATERIALS SCIENCE↗
Measuring Temperature-Dependent Propagating Disturbances in Coronal Fan Loops Using Multiple SDO-AIA Channels and Surfing Transform Technique
A set of co-aligned high resolution images from the Atmospheric Imaging Assembly (AIA) on board the Solar Dynamics Observatory (SDO) is used to investigate propagating disturbances (PDs) in warm fan loops at the periphery of a non-flaring active region NOAA AR 11082. To measure PD speeds at multiple coronal temperatures, a new data analysis methodology is proposed enabling quantitative description of sub visual coronal motions with low signal-to-noise ratios of the order of 0.1. The technique operates with a set of one-dimensional surfing signals extracted from position-timeplots of several AIA channels through a modified version of Radon transform. The signals are used to evaluate a two-dimensional power spectral density distribution in the frequency - velocity space which exhibits a resonance in the presence of quasi-periodic PDs. By applying this analysis to the same fan loop structures observed in several AIA channels, we found that the traveling velocity of PDs increases with the temperature of the coronal plasma following the square root dependence predicted for the slow mode magneto-acoustic wave which seems to be the dominating wave mode in the studied loop structures. This result extends recent observations by Kiddie et al. (2012) to a more general class of fan loop systems not associated with sunspots and demonstrating consistent slow mode activity in up to four AIA channels.
Solar Corona↗
Temperature-dependent creep buckling of plates
Time-dependent lateral deflection of flat rectangular plates is predicted by the Norton-Bailey (Norton 1929, Bailey 1935) power law for material creep. The plates have a through-thickness steady-state temperature distribution, and the effects are considered by using Maxwell's law to modify the power creep law. Equations are derived for creep exponents of 3 and 5, using the sandwich plate element to predict creep buckling of plates. Predictions of creep buckling with a temperature variation between the inner and outer plate surfaces are found to be somewhat dependent on the creep buckling relationship assumed. When significant scatter justifies a variation in the creep constants up to an order of magnitude, discrepancies in predictions using the two exponents are reasonable, and for one engineering material, the predictions have the same degree of agreement with experimental data as have the respective creep laws.
Ross, D. A.↗
Temperature-Dependent Speciation of Ni(II) in Molten Chloride, Bromide, and Iodide Salts
Understanding the fundamental speciation and local structure of metal cations─such as nickel, which is present as a corrosion product─in molten salt media is essential for assessing their impact on the thermal and physical properties of salts used for advanced nuclear energy applications. In this study, we employed an integrated approach of combining X-ray absorption spectroscopy (XAS), UV–vis spectroscopy, and ab initio molecular dynamics (AIMD) to investigate the halide-dependent speciation of divalent nickel ions, Ni(II), in LiCl–KCl, LiBr–KBr, and LiI–KI eutectic salt mixtures from room temperature to 600 °C. Our findings show that both halide type and temperature significantly influence the local coordination of nickel in these molten salt systems. A notable aspect of Ni(II) speciation in LiI–KI salts is the formation of a polyiodide species. In conclusion, our findings provide critical insights into metal ion speciation in molten salt systems, enhancing our understanding of the factors that govern the physicochemical properties of these complex fluids.
36 MATERIALS SCIENCE↗
Temperature-Dependence of Corrosion of Ni-Based Superalloys in Hot CO 2 -Rich Gases Containing SO 2 Impurities
Future power plants will require Ni-based superalloys resistant to high-temperature corrosion in CO 2 -rich environments containing impurities. In this work, several commercially available Ni-based alloys (617, 230, 625, 263, 740H) were exposed at 600°C, 650°C, 750°C and 1 atm to 95% CO 2 , 4% H 2 O, 1% O 2 without/with 0.1% SO 2 to simulate compositions expected in a direct-fired supercritical CO 2 power cycle. The results indicate no effect of SO 2 at 750°C, a small negative effect at 650°C, and a large negative effect at 600°C. Alloys exposed at the higher temperatures (650–750°C) formed thin Cr-rich oxide scales, whereas the lowest temperature (600°C) resulted in thicker scales consisting of non-protective oxides and sulfates. Thermodynamic analysis indicates this increased corrosion is associated with a transition in the stable compounds in contact with the gas. Understanding the factors that affect this transition will aid in the selection or design of alloys for future CO 2 -based power systems.
36 MATERIALS SCIENCE↗
Temperature-dependent phonon lifetimes and thermal conductivity of silicon by inelastic neutron scattering and ab initio calculations
In this paper, inelastic neutron scattering on a single crystal of silicon was performed at temperatures from 100 to 1500 K. These experimental data were reduced to obtain phonon spectral intensity at all wave vectors $\overset{→}{Q}$ and frequencies ω in the first Brillouin zone. Thermal broadenings of the phonon peaks were obtained by fitting and by calculating with an iterative ab initio method that uses thermal atom displacements on an ensemble of superlattices. Agreement between the calculated and experimental broadenings was good, with possible discrepancies at the highest temperatures. Distributions of phonon widths versus phonon energy had similar shapes for computation and experiment. These distributions grew with temperature but maintained similar shapes. Parameters from the ab initio calculations were used to obtain the thermal conductivity from the Boltzmann transport equation, which was in good agreement with experimental data. Despite the high group velocities of longitudinal acoustic phonons, their shorter lifetimes reduced their contribution to the thermal conductivity, which was dominated by transverse acoustic modes.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Temperature dependence of elastic and plastic deformation behavior of a refractory high-entropy alloy
The present work discovers the unique deformation behavior of a refractory high-entropy alloy at elevated temperatures.
36 MATERIALS SCIENCE↗
The temperature dependence of the rate constant for the reaction of hydroxyl radicals with nitric acid
The rate constant for the reaction of hydroxyl radicals with nitric acid in the 225-443 K temperature range has been measured by means of the flash photolysis resonance fluorescence technique. Above 300 K, the rate constant levels off in a way that can only be explained by the occurrence of two reaction channels, of which one, operative at low temperatures, proceeds through the formation of an adduct intermediate. The implications of these rate constant values for stratospheric reaction constants is discussed.
Kurylo, M. J.↗
Temperature dependence of the abundances of elements in solar He-3 rich events
The element abundances in solar He-3-rich events are observed to vary with the soft X-ray temperature of the parent flare. The observations are consistent with thermal collisional ionization of the elements to the equilibrium-charge states expected within the flare-heated plasma at (10-15) x 10 to the 6th K. Proposed photoionization mechanisms appear to be excluded. Rapid ionization of the ions requires that the heating occur sufficiently low in the corona that the electron density exceed about (1-5) x 10 to the 8th/cu cm. Heavy-element enhancements might be a signature of material processed in the flash phase of events in contrast to unheated ambient material accelerated by a coronal shock.
Reames, D. V.↗
A temperature dependent kinetic study of the reaction of the hydroxyl radical with CH2Br
Rate constants have been measured for the gas phase reaction of the hydroxyl radical (OH) with CH3Br over the temperature range 250 to 400 K. The Arrhenius expression k = (5.79 x 10 exp -12) exp(-1560/T) cu cm/molecule per sec was derived from the kinetic data. From the rate constant at 277 K, the tropospheric lifetime of CH3Br with respect to reaction with OH is estimated to be 2.2 years and the overall atmospheric lifetime to be 2.1 years.
Zhang, Zhengyu↗
Temperature Dependence of Diffusivities in Liquid Elements (LMD)
This research was to advance the understanding of diffusion mechanisms in liquid metals and alloys through accurate diffusivity measurements over a wide range of temperatures, including the proximity of the materials melting points. Specifically, it was driven towards developing a methodology (and subsequent flight hardware) to enable several diffusion coefficient measurements (i.e., at several different temperatures) to be performed using a single sample. The Liquid Metal Diffusion (LMD) was funded as a Flight Definition Project in February 1993 in response to NRA 91-OSSA-20 (Microgravity Science and Applications Division). The Science Concept Review for LAID was held during April 1994. In January 1995 we were informed that we had failed this review and the project was change to ground-based activities only. A new proposal was submitted for the next NRA addressing the panels concerns. As part of NASA's Risk Mitigation program, a scaled-down version of the hardware was funded in July of 1995 for a flight opportunity utilizing experiment on the Microgravity Isolation Mount. This experiment was to determine the self-diffusivity of indium at 185 C. The LMD was transferred to the Mir Space Station in STS-81 and returned on STS-84 (January - May 1997). Three, out of five, self-diffusion data sets were returned. A description of this experiment/hardware is included below. This summary is only intended to give the reader an overview of the results obtained for the tasks outlined in the original proposal. Research that was not published is explained in more detail. At the end of this report is a list of refereed publications and invited talks that were given as a result of this work. The reader is directed to these for further details. Attachment: Real-time diffusivity measurements in liquids at several temperatures with one sample, On the insensitivity of liquid diffusivity measurements to deviations from 1D transport, and Numerical simulations of the convective contamination of diffusivity measurements in liquids.
Banish, R. Michael↗
Study of the rotational-level and temperature dependence of the quenching rate of OH fluorescence due to collisions with water molecules
The importance of the OH radical as an intermediate in many combustion reactions and in atmospheric photochemistry has led many researchers to use it as a diagnostic tool in these processes. The amount of data that has been acquired over the years for this radical is quite considerable. However, the quenching rate of OH with water molecules as a function of temperature and the rotational level of the excited state is not very well understood. The motivation of the studies undertaken is to bridge the gap between the low temperature measurements and the high temperature ones reported in the literature. The technique generally employed in these diagnostics is laser-induced fluorescence (LIF), through which rotational state selective excitation of the radical is possible. Furthermore, in a combustion medium, water is produced in abundance so that knowledge of the quenching rate of OH due to water molecules plays a crucial role in interpreting the data. In general, the precursor to an understanding of the collisional quenching rates of OH involves a characterization of the mode in which the radical is produced; the resulting rotational and translational distribution, followed by a measurement of the OH temperature; and ultimately obtaining the rate constants from the pressure dependence of the fluorescence signal. The experimental implementation of these measurements therefore involved, as a first step, the production of the OH radicals in a microwave discharge cell using water vapor as the source, wherein a hydrogen atom is abstracted from H2O. The second step involved the absorption of photons from the frequency-doubled output of a pulsed amplified, single-frequency cw ring dye laser. By tuning the laser to the peak of the transition and observing the fluorescence decay after the laser pulse, the lifetime of the OH in a particular rotational electronic state was determined (tau = 1.4 microseconds for Q(sub 1)(3)). Knowledge of this parameter led to a determination of the quenching rate. By varying the water vapor pressure in the cell and measuring the lifetime as a function of pressure a linear plot of the quenching rate as a function of pressure was obtained. Using this plot, the quenching cross section was deduced. It has therefore been possible to measure the local translational temperature and the quenching cross section with one laser system.
Koker, Edmond B.↗
Understanding the Origin of Negative Temperature Dependence and Activity of N-Coordinated Cobalt Sites During Ethylene Dimerization
The on-demand production of short-chain linear alpha olefins (LAOs; C4-C8) via C2H4 dimerization and oligomerization is industrially attractive, prompting extensive research on designing active, selective, and stable catalysts for industrial use. Cobalt supported on ammoniated carbon (Co(NH3)x/C) catalysts have shown remarkable activity and selectivity in this process. However, critical aspects such as the active phase, active site structure, the role of the catalyst support, cobalt loading effects, and the inverse correlation of the reaction rate with temperature remain inadequately understood. This study systematically explores these factors using a combination of steady-state differential catalytic tests, in situ molecular characterization including diffuse reflectance UV-Vis (DR-UV-Vis), Infrared, and Raman spectroscopies, and ex situ X-ray diffraction (XRD) and high annular aberration-corrected dark field transmission electron microscopy (HAADF-STEM). Various supports (SiO2, Al2O3, NH4-ZSM-5, g-C3N4, and C) and cobalt loadings (1.0-3.0 Co nm-2) were studied to determine the optimal catalyst composition and identify the active phase and sites. Carbon-supported catalysts uniquely produce C4-8 LAOs during C2H4 dimerization, with site-time-yield remaining constant (~10-3 s-1) for 1.0-4.0 Co nm-2 at prolonged reaction times (24-48?h time-on-stream). At higher loadings of 6.0 Co nm-2, the formation of crystalline CoO and Co3O4 phases reduces catalytic activity and LAO selectivity. Our findings show that active catalysts lack crystalline cobalt oxides and instead feature dispersed Co2+ sites, tetra-coordinated to a mix of N/NH3 and O/H2O ligands, which catalyze C2H4 dimerization via the Cossee-Arlman mechanism, exhibiting 1st order dependence on C2H4 concentration. The observed inverse rate-temperature correlation is attributed to compensation effects (i.e., presence of Cremer-Constable relationship) linked to changes in adsorption enthalpic and entropic factors.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Pressure and temperature dependence kinetics study of the NO + BrO yielding NO2 + Br reaction - Implications for stratospheric bromine photochemistry
The reactivity of NO with BrO radicals over a wide range of pressure (100-700 torr) and temperature (224-398 K) is investigated using the flash photolysis-ultraviolet absorption technique. The flash photolysis system consists of a high-pressure xenon arc light source, a reaction cell/gas filter/flash lamp combination, and a 216.5 half-meter monochromator/polychromator/spectrography for wavelength selectivity. The details of the reaction and its corresponding Arrhenius expression are identified. The results are compared with previous measurements, and atmospheric implications of the reaction are discussed. The NO + BrO yielding NO2 + Br reaction is shown to be important in controlling the concentration ratios of BrO/Br and BrO/HBr in the stratosphere, but this reaction does not affect the catalytic efficiency of BrOx in ozone destruction.
Watson, R. T.↗