Dual Effect of Structure and Hydration on Magnesium-Ion Insertion into Electrodeposited V 2 O 5 Thin Films
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The research has advanced understanding of the interrelation between the crystal structure and magnetism in several materials which are or can be of interest for the development of improved, specialized or more cost-effective permanent magnets, as well as in selected materials for biomedical and catalytic applications. Fundamental aspects of ferromagnetism were investigated for Mn-Ge, Co-V and Co-Ge nanoclusters and for melt-spun Co-Sn alloys. New solution-chemistry synthesis methods were designed and tested for Fe-Pt, Fe3C and Fe3O4 nanoparticles. Off-stoichiometric Laves phases in the Fe-Si-Zr, Fe-Nb and Fe-Ta systems, as well as Fe5(Si,Ge)B2 compounds were assessed as new rare-earth-free permanent magnet materials; all except the Fe-Si-Zr Laves phases were found to be promising enough to merit a further exploration. A new method for manufacturing rare-earth-free magnets based on the MnBi compound was developed; by purposely avoiding oxidation-sensitive fine single-crystalline powders, the new method yields magnets with a 50% larger energy storage capacity. Studies of rare-earth-lean permanent-magnet materials (lean compared to the currently predominant Nd-Fe-B materials) were focused on the tetragonal compound of the ThMn12 structure type and included both discovery and characterization of new formulations and exploration of new fabrication/processing techniques. Among the most significant achievements were successful preparation of a vanadium-lean SmFe11V compound, the first observation of thermomechanically induced texture in nanocrystalline Sm(Fe,V)12 alloys, and a breakthrough reduction-diffusion synthesis of Sm1-xZrx(Fe0.8Co0.2)11.2Ti0.8 single-crystal particles with a coercivity as high as 12.6 kOe. Several experiments aimed at improvement of the Nd-Fe-B magnet have also been undertaken including a five-fold increase of the coercivity through a grain-boundary diffusion treatment of a Nd10Fe84B6 nanocrystalline alloy.
The promotional presentation discusses the graduate degree program at the University of California, San Diego, Jacobs School of Engineering, related to structural engineering. Structural Health Monitoring (SHM) encompasses the integration of a broad range of technologies from sensing/actuating, data interrogation, and statistical modeling to enable system-level or component-level health assessment and predictive modeling. The course is available via distance learning to Los Alamos National Laboratory engineers.
There have been breakthroughs of latest cryo electron microscopy (cryo-EM) data analysis algorithms to classify cryo-EM image data. However, most of these cryo-EM reconstruction methods have focused on classifying distinctly different biomolecule structures. Here, we present our approaches of deep learning to differentiate homologous structures that are distinguishable only with inner morphological differences. We succeeded supervised classification of these subtly different homologues. However, we could not differentiate them with unsupervised methods. Here we discuss what further approaches are likely needed for successful unsupervised classification.
Structure-performance relationships in lignin-based transesterification vitrimers: The role of lignin structural features
Structural design synthesis of recoverable launch vehicle structures
Structural analysis of Injun 5 spacecraft structure
Determination of magnitude of structural over-test received by spacecraft structures when qualified in reverberant rooms
Development of expandable structures concepts for application to structures used in space missions - Part 2
Specimens representative of metal aircraft structural components reinforced with boron filamentary composites were manufactured and tested under cyclic loading, cyclic temperature, or continuously applied loading to evaluate some of the factors that affect structural integrity under cyclic conditions. Bonded, stepped joints were used throughout to provide composite-to-metal transition regions at load introduction points. Honeycomb panels with titanium or aluminum faces reinforced with unidirectional boron composite were fatigue tested at constant amplitude under completely reversed loading. Results indicated that the matrix material was the most fatigue-sensitive part of the design, with debonding initiating in the stepped joints. However, comparisons with equal weight all-metal specimens show a 10 to 50 times improved fatigue life. Fatigue crack propagation and residual strength were studied for several different stiffened panel concepts, and were found to vary considerably depending on the configuration. Composite-reinforced metal specimens were also subjected to creep and thermal cycling tests. Thermal cycling of stepped joint tensile specimens resulted in a ten percent decrease in residual strength after 4000 cycles.
A method of predicting broadband random vibration criteria for components on space vehicles is presented. Large amounts of vibration and acoustic data obtained from flights and static firing tests of space vehicle were formulated into vibroacoustic data banks for structural categories of ring frame, skin stringer, and honeycomb. The vibration spectra with their associated acoustic spectra are normalized to a reference acoustic spectrum. The individual normalized spectra are grouped according to definite structural characteristics and statistically analyzed to form the vibroacoustic data banks described in this report. These data banks represent the reference vibration criteria available for determining the new vehicle vibration criteria.
New design and programming techniques for shuttle software. Based on previous Apollo experience, recommendations are made to apply top-down structured programming techniques to shuttle software. New software verification techniques for large software systems are recommended. HAL, the higher order language selected for the shuttle flight code, is discussed and found to be adequate for implementing these techniques. Recommendations are made to apply the workable combination of top-down, bottom-up methods in the management of shuttle software. Program structuring is discussed relevant to both programming and management techniques.
The use of a structural synthesis computer program to design components for a heavy lift launch vehicle is defined. A loads program was used to determine the vehicle shears, bending moments, and axial loads at two design loading conditions. A comparison was made between results from the structures program and the results of a weight estimating program which used historical data in determining component weights.
The dynamics and stability of large orbiting flexible beams, and platforms and dish type structures oriented along the local horizontal are treated both analytically and numerically. It is assumed that such structures could be gravitationally stabilized by attaching a rigid light-weight dumbbell at the center of mass by a spring loaded hinge which also could provide viscous damping. For the beam, the small amplitude inplane pitch motion, dumbbell librational motion, and the anti-symmetric elastic modes are all coupled. The three dimensional equations of motion for a circular flat plate and shallow spherical shell in orbit with a two-degree-of freedom gimballed dumbbell are also developed and show that only those elastic modes described by a single nodal diameter line are influenced by the dumbbell motion. Stability criteria are developed for all the examples and a sensitivity study of the system response characteristics to the key system parameters is carried out.
A number of missions for the space shuttle were proposed which involve placing large truss platforms on-orbit. These platforms range in size from tens of meters in span for reflector application to several thousand meters for solar power collector application. These proposed sizes and the operational requirements considered are unconventional in comparison to Earthbound structures and little information exists concerning efficient proportions of the structural elements forming the framework of the platforms. Such proportions are of major concern because they have a strong influence on the packaging efficiency and, thus, the transportation effectiveness of the shuttle. The present study is undertaken to: (1) identify efficient ranges of application of deployable and erectable platforms configured for shuttle transport to orbit, and (2) determine sensitivity to key parameters of minimum mass deployable and erectable platform designs.
The feasibility of fabricating beams in space and using them as components of a large, crew assembled structure, was investigated. Two projects were undertaken: (1) design and development of a ground version of an automated beam builder capable of producing triangular cross section aluminum beams; and (2) design and fabrication of lap joints to connect the beams orthogonally and centroidal end caps to connect beams end to end at any desired angle. The first project produced a beam building machine which fabricates aluminum beams suitable for neutral buoyancy evaluation. The second project produced concepts for the lap joint and end cap. However, neither of these joint concepts was suitable for use by a pressure suited crew member in a zero gravity environment. It is concluded that before the beams can be evaluated the joint designs need to be completed and sufficient joints produced to allow assembly of a complex structure.