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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Role of clay-associated humic substances in catalyzing bioreduction of structural Fe(III) in nontronite by Shewanella putrefaciens CN32

Previous studies have shown that humic substances can serve as electron shuttle to catalyze bioreduction of structural Fe(III) in clay minerals, but it is unclear if clay-sorbed humic substances can serve the same function. It is unknown if the electron shuttling function is dependent on electron donor type and if humic substances undergo change as a result. Here, humic acid (HA) and fulvic acid (FA) were sorbed onto nontronite (NAu-2) surface. Structural Fe(III) in HA- and FA-coated NAu-2 samples was bioreduced by Shewanella putrefaciens CN32 using H 2 and lactate as electron donors. The results showed a contrasting effect of humic substances on bioreduction of structural Fe(III), depending on the electron donor type. With H 2 as electron donor, humic substances had little effect on bioreduction of Fe(III) (the reduction extent: 26.2%, 27.4%, 29.3% for HA-coated, FA-coated, and uncoated NAu-2, respectively). In contrast, these substances significantly enhanced bioreduction of Fe(III) with lactate as electron donor (the reduction extent: 20.2%, 20.7%, 11.5% for HA-coated, FA-coated, and uncoated NAu-2, respectively). This contrasting behavior is likely caused by the difference in reaction free energy and electron transport process between H 2 and lactate. When H 2 served as electron donor, more energy was released than when lactate served as electron donor. In addition, because of different cellular locations of lactate dehydrogenase (inner membrane) and H 2 hydrogenase (the periplasm), electrons generated by H 2 hydrogenase may pass through the electron transport chain more rapidly than those generated from lactate dehydrogenase. Through their functions as electron shuttle and/or carbon source, clay-sorbed HA/FA underwent partial transformation to amino acids and other compounds. The availability of external carbon source played an important role in the amount and type of secondary product generation. These results have important implications for coupled iron and carbon biogeochemical cycles in clay- and humic substance-rich environments.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Collaborative Research: Vlasov-Maxwell Simulations to Resolve Electron Heating and Dissipation, in Quasi-Perpendicular Shocks

The major goals of the project are to study three fundamental questions related to collisionless, non-relativistic, quasi-perpendicular shocks by combining continuum Vlasov-Maxwell simulations (the Gkeyll framework) and high resolution, in situ heliospheric observations from the MMS spacecraft. The specific questions are: 1. How and where are electrons energized and heated in a quasi-perpendicular shock, including the ultimate source of entropy production? 2. What role do waves, turbulence, and secondary instabilities play in the conversion of directed flow energy to electron energy? 3. How do the parameters of the shock determine the energization of electrons?

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1978

Isotopic anomalies from neutron reactions during explosive carbon burning

The possibility that the newly discovered correlated isotopic anomalies for heavy elements in the Allende meteorite were synthesized in the secondary neutron capture episode during the explosive carbon burning, the possible source of the O-16 and Al-26 anomalies, is examined. Explosive carbon burning calculations under typical conditions were first performed to generate time profiles of temperature, density, and free particle concentrations. These quantities were inputted into a general neutron capture code which calculates the resulting isotopic pattern from exposing the preexisting heavy seed nuclei to these free particles during the explosive carbon burning conditions. The interpretation avoids the problem of the Sr isotopic data and may resolve the conflict between the time scales inferred from 1-129, Pu-244, and Al-26.

Lee, T.↗
NASA NTRS1981

Nonthermal hard X-ray emission from the nucleus of NGC 1275

Observations confirming the HEAO 1 discovery of a hard X-ray component in the X-ray spectrum of the Perseus cluster are reported. A comparison of the results with 1978 HEAO 1 observations and 1974 balloon limits shows that this component is variable on a time scale of one year. Synchrotron self-Compton models of the compact radio source centered on the nucleus of NGC 1275 predict a substantial secondary X-ray flux based on the observed radio data. While the observed X-ray flux is one-fourth the predicted value, uncertainties in the radio data are sufficient to account for the discrepancy. It is concluded that the hard X-ray flux originates in the active nucleus of the Seyfert galaxy NGC 1275 through the synchrotron self-Compton process.

Rothschild, R. E.↗
NASA NTRS1989

High pressure gas scintillation drift chambers with wave shifter fiber readout. I

The authors present results from a prototype xenon-gas scintillation drift chamber. It was operated at pressures up to 20 atm, and the scintillation light yield was measured at various pressures and reduced fields. Scintillation-reduced fields ranged from 1.3 to 3 kV/cm/atm in a 5.4-mm scintillation gap. Drift fields ranged from 45 to 100 V/cm/atm in an 8-cm drift region. The chamber was exposed to an 241Am source in a port either 2.7 or 5.4 cm from the secondary scintillation region. The authors also describe the high-voltage problems encountered during operation at high pressures. Further tests with the wave shifter fiber readout showed that the problem of gas contamination by the fibers is manageable but that the interaction between the optical fibers and the high-pressure xenon gas can lead to fiber damage. A solution to this problem is described.

Parsons, A.↗
NASA NTRS1989

Investigation of the Saturn dust environment from the analysis of energetic charged particle measurements

In order to assist the Cassini project in evaluating risks of collisions with particulate matter in the rotational equatorial plane, available Pioneer 11 and Voyager energetic charged particle data were reinvestigated to constrain the column mass density of absorbing material within several radial ranges. Within the orbit of Mimas, CRAND proton phase space densities maximize near 2.67 R sub s and exhibit secondary maximum at 2.43 R sub s. From the condition that sources must exceed losses near these maxima and using available theoretical models for CRAND proton production rates, upper bounds on the column mass density at these two radial locations are calculated. Detailed fits of radial diffusion models to the observed flux maxima yield somewhat more restrictive upper limits. The upper limits compare to a lower limit on the column mass density, estimated from previous model calculations by Van Allen. Aside from continuous rings, longitudinally limited, low optical depth clouds of particulates may exist in orbit with several of the inner satellites including Mimas and Enceladus. A brief review of Voyager energetic particle microsignatures that suggest the presence of material co-orbiting with these two satellites is presented. Finally, Pioneer 11 and Voyager measurements of low energy electron fluxes exhibit minima near the location of the tenuous E Ring centered on approx. 4 R sub s. Pioneer 11 pitch angle distributions appear to support the possibility that direct absorption by Ring E particulates produced the observed flux decreases.

Hood, L. L.↗
NASA NTRS1990

New aspects of heavy cosmic rays from calcium to nickel (Z = 20 to 28)

Over the two year course of this grant a study was conducted to explore the implications of composition measurements of heavy cosmic rays made by the Third High Energy Astronomy Observatory (HEAO-3). To interpret these and other measurements this study combined for the first time new laboratory measurements of the fragmentation cross sections of heavy nuclei, a new semi-empirical cross section formula, and the latest in cosmic ray propagation and solar modulation models. These models were used to interpret abundance measurements from six recent satellite experiments, including, in particular, two from HEAO-3. The principal results of the study were: (1) an improved interpretation of the Mn-54 clock in cosmic rays, including predictions of the isotopic abundances of Mn for comparison with future isotope measurements; (2) the first realization of the effect of Mn-54 decay on studies of the source abundances of Fe isotopes; (3) improved source abundances of the elements Ar, Ca, Cr, Mn, Fe, and Ni in the cosmic ray source material; (4) an improved fit to the abundances of Fe secondaries in cosmic rays; and (5) additional evidence that supports the validity of the leaky-box model of cosmic ray propagation in the galaxy. This final report summarizes these new results, the new tools that were developed to obtain them, and presents a bibliography of talks and publications that resulted from this work.

Mewaldt, Richard A.↗
NASA NTRS2001

Geoscience Laser Altimeter System (GLAS) Instrument: Flight Loop Heat Pipe (LHP) Acceptance Thermal Vacuum Test

Two loop heat pipes (LHPs) are to be used for tight thermal control of the Geoscience Laser Altimeter System (GLAS) instrument, planned for flight in late 2001. The LHPs are charged with Propylene as a working fluid. One LHP will be used to transport 110 W from a laser to a radiator, the other will transport 160 W from electronic boxes to a separate radiator. The application includes a large amount of thermal mass in each LHP system and low initial startup powers. The initial design had some non-ideal flight design compromises, resulted in a less than ideal charge level for this design concept with a symmetrical secondary wick. This less than ideal charge was identified as the source of inadequate performance of the flight LHPs during the flight thermal vacuum test in October of 2000. We modified the compensation chamber design, re-built and charged the LHPs for a final LHP acceptance thermal vacuum test. This test performed March of 2001 was 100% successful. This is the last testing to be performed on the LHPs prior to instrument thermal vacuum test. This sensitivity to charge level was shown through varying the charge on a Development Model Loop Heat Pipe (DM LHP) and evaluating performance at various fill levels. At lower fills similar to the original charge in the flight units, the same poor performance was observed. When the flight units were re-designed and filled to the levels similar to the initial successful DM LHP test, the flight units also successfully fulfilled all requirements. This final flight Acceptance test assessed performance with respect to startup, low power operation, conductance, and control heater power, and steady state control. The results of the testing showed that both LHPs operated within specification. Startup on one of the LHPs was better than the other LHP because of the starter heater placement and a difference in evaporator design. These differences resulted in a variation in the achieved superheat prior to startup. The LHP with the lower superheat was sensitive to the thermal environment around the compensation chamber, while the LHP with the higher superheat (similar in design to DM LHP) was not. In response to the test results the placement of the starter heater will be optimized for the flight instrument testing for higher achieved superheat. This presentation discusses startup behavior, overall conductance of a radiator system, low power operation, high power operation, temperature control stability, and control heater power requirements as measured during this acceptance thermal vacuum test. A brief summary of 'lessons learned' will be included.

Baker, Charles↗
NASA NTRS2007

Fast Airborne Aerosol Size and Chemistry Measurements with the High Resolution Aerosol Mass Spectrometer during the MILAGRO Campaign

The concentration, size, and composition of non-refractory submicron aerosol (NR-PM(sub l)) was measured over Mexico City and central Mexico with a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) onboard the NSF/NCAR C-130 aircraft as part of the MILAGRO field campaign. This was the first aircraft deployment of the HR-ToF-AMS. During the campaign the instrument performed very well, and provided 12 s data. The aerosol mass from the AMS correlates strongly with other aerosol measurements on board the aircraft. Organic aerosol (OA) species dominate the NR-PM(sub l) mass. OA correlates strongly with CO and HCN indicating that pollution (mostly secondary OA, SOA) and biomass burning (BB) are the main OA sources. The OA to CO ratio indicates a typical value for aged air of around 80 microg/cubic m (STP) ppm(exp -1). This is within the range observed in outflow from the Northeastern US, which could be due to a compensating effect between higher BB but lower biogenic VOC emissions during this study. The O/C atomic ratio for OA is calculated from the HR mass spectra and shows a clear increase with photochemical age, as SOA forms rapidly and quickly overwhelms primary urban OA, consistent with Volkamer et al. (2006) and Kleinman et al. (2008). The stability of the OA/CO while O/C increases with photochemical age implies a net loss of carbon from the OA. BB OA is marked by signals at m/z 60 and 73, and also by a signal enhancement at large m/z indicative of larger molecules or more resistance to fragmentation. The main inorganic components show different spatial patterns and size distributions. Sulfate is regional in nature with clear volcanic and petrochemical/power plant sources, while the urban area is not a major regional source for this species. Nitrate is enhanced significantly in the urban area and immediate outflow, and is strongly correlated with CO indicating a strong urban source. The importance of nitrate decreases with distance from the city likely due to evaporation. BB does not appear to be a strong source of nitrate despite its high emissions of nitrogen oxides, presumably due to low ammonia emissions. NR-chloride often correlates with HCN indicating a fire source, although other sources likely contribute as well. This is the first aircraft study of the regional evolution of aerosol chemistry from a tropical megacity.

DeCarlo, P. F.↗
NASA NTRS2012

Multi-Mission Power Analysis Tool (MMPAT) Version 3

The Multi-Mission Power Analysis Tool (MMPAT) simulates a spacecraft power subsystem including the power source (solar array and/or radioisotope thermoelectric generator), bus-voltage control, secondary battery (lithium-ion or nickel-hydrogen), thermostatic heaters, and power-consuming equipment. It handles multiple mission types including heliocentric orbiters, planetary orbiters, and surface operations. Being parametrically driven along with its user-programmable features can reduce or even eliminate any need for software modifications when configuring it for a particular spacecraft. It provides multiple levels of fidelity, thereby fulfilling the vast majority of a project s power simulation needs throughout the lifecycle. It can operate in a stand-alone mode with a graphical user interface, in batch mode, or as a library linked with other tools. This software can simulate all major aspects of a spacecraft power subsystem. It is parametrically driven to reduce or eliminate the need for a programmer. Added flexibility is provided through user-designed state models and table-driven parameters. MMPAT is designed to be used by a variety of users, such as power subsystem engineers for sizing power subsystem components; mission planners for adjusting mission scenarios using power profiles generated by the model; system engineers for performing system- level trade studies using the results of the model during the early design phases of a spacecraft; and operations personnel for high-fidelity modeling of the essential power aspect of the planning picture.

Wood, Eric G.↗
NASA NTRSDate not supplied

Impact Experiments into Granular Targets Containing Solitary Blocks of Varying Strength and Size

Crater scaling relationships provide a means to correlate dimensions of laboratory-scale impact experiments to naturally formed craters at planetary scales. For relatively larger impact events, where gravity is the dominant arresting force against crater growth, these scaling relations are comparatively simple. For smaller craters, however, the target properties have increasing influence over the cratering process. Further complexities are easily envisaged when considering realistic surfaces that contain small-scale heterogeneities in cohesive strength, density, porosity, friction, as these properties will each have unequal effects on the resultant crater morphometry. Even when produced under controlled laboratory conditions, understanding (and controlling) the entire relevant parameter space is daunting, and deconvolution of the relevant contributors can be complicated even in the best-case scenario. To this end, we have begun an extensive series of impact experiments that will provide a nascent framework that will aid in the interpretation of craters observed on complex natural surfaces throughout the solar system. To start with the simplest configuration, experiments were performed with cylindrical PVC buckets that were filled with quartz sand and contained a single cubic block of synthetic sandstone. The blocks varied in size (14-33 mm) and unconfined compressive strength (0.5-7.4 MPa) and were placed in/on the sand along the trajectory of the incoming impactor and buried to different depths. All experiments were conducted using the vertical gun located in the Experimental Impact Lab at NASA Johnson Space Center with alumina projectiles that were accelerated to ~1.53 km s^-1 under a vacuum of 1 torr. After the impact, target containers were removed from the chamber are morphometric data were extracted by using a Peel 2 3D-scanner in combination with the open-source software, CloudCompare. Initial results show that block strength is a secondary effect on crater diameter and depth, but when at least one edge of the block is exposed and the surface (partial burial) the strength will dictate the number of surviving block fragments around the crater, as well as how much disrupted block material is retained within the crater walls.

Christopher J. Cline II↗
NASA NTRS2023

Sources of Formaldehyde in U.S. Oil and Gas Production Regions

We analyzed observational and model data to study the sources of formaldehyde over oil and gas production regions and to investigate how these observations may be used to constrain oil and gas VOC emissions. The analysis of aircraft and satellite data consistently found that formaldehyde over oil and gas production regions during spring and summer is mostly formed by the photooxidation of precursor VOCs. Formaldehyde columns over the Permian basin, one of the largest oil and gas producing regions in the United States, are correlated with production locations. Formaldehyde simulations by the atmospheric chemistry and transport model WRF-Chem, which included oil and gas NOx and VOC emissions from the fuel-based oil and gas inventory, were in very good agreement with TROPOMI satellite measurements. Sensitivity studies illustrated that VOCs released from oil and gas activities are important precursors to formaldehyde, but other sources of VOCs contribute as well, and that the formation of secondary formaldehyde is highly sensitive to NOx. We also investigated the ability of the chemical mechanism used in WRF-Chem to represent formaldehyde formation from oil and gas hydrocarbons by comparing against the Master Chemical Mechanism. Further, our work provides estimates of primary formaldehyde emissions from oil and gas production activities, with per basin averages ranging from 0.07 kg h -1 to 2.2 kg h -1 in 2018. A separate estimate for natural gas flaring found that flaring emissions could contribute 5% to 12% to the total primary formaldehyde emissions for the Permian basin in 2018.

SAF↗
NASA NTRSDate not supplied

Data Quality Challenges for Analysis Ready Data (ARD)

Data quality plays a critical role in research and applications. The Earth Science Information Partners (ESIP) Information Quality Cluster (IQC) defines four aspects of information quality: Science, Product, Stewardship, and Services. The ESIP IQC has become internationally recognized as an authoritative and responsive resource of information and guidance to data producers and distributors on how to implement data quality standards and best practices for their science data systems, datasets, and data/metadata dissemination services. In recent years, cloud computing environments have provided scale-up capabilities such as data archives and services, enabling interdisciplinary science and applications. More value-added products are expected from data service providers, including Analysis Ready Data (ARD). ARD refers to data that has been preprocessed into a form that allows immediate analysis by the end user, processed to a minimum set of requirements and provides interoperability over time and across multiple datasets. Once a dataset has been developed from its original form to produce ARD, what quality characteristics should the derived dataset or ARD possess? Also, is it safe to assume that the quality of the ARD is consistent with the quality of the source data, or are there special attributes to an ARD that would warrant a secondary, independent quality assessment? What provenance (also called “data lineage”) information needs to be included in ARD? It is important to answer these questions, especially given the ease of use of ARD, and the consequent temptation by users to trust ARD without understanding the limitations or possible variations in quality compared to the source data. In this presentation, we will discuss data quality challenges for ARD products and services and introduce IQC for participation.

data quality↗
DOE OSTI2023

A full year of aerosol size distribution data from the central Arctic under an extreme positive Arctic Oscillation: insights from the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition

Abstract. The Arctic environment is rapidly changing due to accelerated warming in the region. The warming trend is driving a decline in sea ice extent, which thereby enhances feedback loops in the surface energy budget in the Arctic. Arctic aerosols play an important role in the radiative balance and hence the climate response in the region, yet direct observations of aerosols over the Arctic Ocean are limited. In this study, we investigate the annual cycle in the aerosol particle number size distribution (PNSD), particle number concentration (PNC), and black carbon (BC) mass concentration in the central Arctic during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition. This is the first continuous, year-long data set of aerosol PNSD ever collected over the sea ice in the central Arctic Ocean. We use a k-means cluster analysis, FLEXPART simulations, and inverse modeling to evaluate seasonal patterns and the influence of different source regions on the Arctic aerosol population. Furthermore, we compare the aerosol observations to land-based sites across the Arctic, using both long-term measurements and observations during the year of the MOSAiC expedition (2019–2020), to investigate interannual variability and to give context to the aerosol characteristics from within the central Arctic. Our analysis identifies that, overall, the central Arctic exhibits typical seasonal patterns of aerosols, including anthropogenic influence from Arctic haze in winter and secondary aerosol processes in summer. The seasonal pattern corresponds to the global radiation, surface air temperature, and timing of sea ice melting/freezing, which drive changes in transport patterns and secondary aerosol processes. In winter, the Norilsk region in Russia/Siberia was the dominant source of Arctic haze signals in the PNSD and BC observations, which contributed to higher accumulation-mode PNC and BC mass concentrations in the central Arctic than at land-based observatories. We also show that the wintertime Arctic Oscillation (AO) phenomenon, which was reported to achieve a record-breaking positive phase during January–March 2020, explains the unusual timing and magnitude of Arctic haze across the Arctic region compared to longer-term observations. In summer, the aerosol PNCs of the nucleation and Aitken modes are enhanced; however, concentrations were notably lower in the central Arctic over the ice pack than at land-based sites further south. The analysis presented herein provides a current snapshot of Arctic aerosol processes in an environment that is characterized by rapid changes, which will be crucial for improving climate model predictions, understanding linkages between different environmental processes, and investigating the impacts of climate change in future Arctic aerosol studies.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1984

Algorithm for astronomical, point source, signal to noise ratio calculations

An algorithm was developed to simulate the expected signal to noise ratios as a function of observation time in the charge coupled device detector plane of an optical telescope located outside the Earth's atmosphere for a signal star, and an optional secondary star, embedded in a uniform cosmic background. By choosing the appropriate input values, the expected point source signal to noise ratio can be computed for the Hubble Space Telescope using the Wide Field/Planetary Camera science instrument.

Jayroe, R. R.↗
DOE OSTI2021

High-fidelity modeling of breakdown in helium: initiation processes and secondary electron emission

Understanding the role of physical processes contributing to breakdown is critical for many applications in which breakdown is undesirable, such as capacitors, and applications in which controlled breakdown is intended, such as plasma medicine, lightning protection, and materials processing. The electron emission from the cathode is a critical source of electrons which then undergo impact ionization to produce electrical breakdown. In this study, the role of secondary electron yields due to photons (γ ph ) and ions (γ i ) in direct current breakdown is investigated using a particle-in-cell direct simulation Monte Carlo model. The plasma studied is a one-dimensional discharge in 50 Torr of pure helium with a platinum cathode, gap size of 1.15 cm, and voltages of 1.2–1.8 kV. The current traces are compared with experimental measurements. Larger values of γ ph generally result in a faster breakdown, while larger values of γ i result in a larger maximum current. The 58.4 nm photons emitted from He(2 1 P) are the primary source of electrons at the cathode before the cathode fall is developed. Of the values of γ ph and γ i investigated, those which provide the best agreement with the experimental current measurements are γ ph = 0.005 and γ i = 0.01. In this work, these values are significantly lower than those in the literature for pristine platinum or for a graphitic carbon film which we speculate may cover the platinum. This difference is in part due to the limitations of a one-dimensional model but may also indicate surface conditions and exposure to a plasma can have a significant effect on the secondary electron yields. The effects of applied voltage and the current produced by a UV diode which was used to initiate the discharge, are also discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1978

Propagation of cosmic rays in extragalactic radio sources

A model of extragalactic radio sources is considered which assumes that relativistic electrons carry energy from the central galaxy to the radio lobes and also emit the radio waves. It is suggested that the radio emission is confined to an axis because electrons propagate parallel to the magnetic field more readily than perpendicular to it and that symmetric radio lobes appear on this axis because electrons are deposited at supercoherent transitions far from the central galaxy, where they propagate diffusively. The slow drift velocities that characterize this propagation are shown to explain the secondary structure between the main lobes and to establish a relationship between double sources and galactic radio trails.

Earl, J. A.↗
DOE OSTI2025

Rapid High-Resolution Analysis of Polysaccharide-Lignin Interactions in Secondary Plant Cell Walls Using Proton-Detected Solid-State NMR

The plant secondary cell wall, a complex matrix composed of cellulose, hemicellulose, and lignin, is crucial for the mechanical strength and water-proofing properties of plant tissues, and serves as a primary source of biomass for biorenewable energy and biomaterials. Structural analysis of these polymers and their interactions within the secondary cell wall has been heavily relying on 13 C-based solid-state NMR techniques. In this study, we explore the application of 1 H-detected solid-state NMR techniques for rapid, high-resolution structural characterization of polysaccharides and lignin, demonstrated on the stems of hardwood eucalyptus. We explored the use of synthesized 2D spectra to resolve central 1 H resonances and the combined application of 3D hCCH and hCHH experiments for complete resonance assignment and unambiguous identification of lignin-carbohydrate interactions. Our findings emphasize the central role of acetylated three-fold xylan conformers, rather than two-fold, in stabilizing the carbohydrate-lignin interface, with glucuronic acid sidechains in eucalyptus glucuronoxylan colocalizing with lignin, revised cellulose-lignin interactions involving uncoated microfibril surfaces, and pectin-lignin interactions indicative of early-stage lignification. These results present a novel approach for rapid structural analysis of lignocellulosic biomaterials without the need for solubilization or extraction.

09 BIOMASS FUELS↗