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At least 433 records · Page 24

Ultrafast heat transfer in single palladium nanocrystals seen with an X-ray free-electron laser

We report transient highly strained structural states in individual palladium (Pd) nanocrystals, electronically heated using an optical laser, which precede their uniform thermal expansion. Using an X-ray free-electron laser probe, the evolution of individual 111 Bragg peaks is measured as a function of delay time at various laser fluences. Above a laser fluence threshold at a sufficient pump-probe delay, the Bragg peak splits into multiple peaks, indicating heterogeneous strain, before returning to a single peak, corresponding to even heat distribution throughout the lattice expanded crystal. Our findings are supported by a lattice displacement and strain model of a single nanocrystal at different delay times, which agrees with the experimental data. Our observations have implications for understanding femtosecond laser interactions with metals and the potential photo-catalytic performance of Pd.

36 MATERIALS SCIENCE↗

Observation of laser ablation of silicon as a function of pulse length at constant fluence via time-resolved x-ray spectroscopy

We investigate the ablation of silicon as a function of laser pulse length at a constant fluence using time-resolved x-ray spectroscopy data obtained from OMEGA EP experiments at the University of Rochester's Laboratory for Laser Energetics. Our targets consisted of three-layer planar structures composed of Si (50 μm), Cu (25 μm), and SiO 2 (500 μm) layers. The Si layer was irradiated by a 351-nm laser with varying pulse widths of 250 ps, 500 ps, 1 ns, and 10 ns while maintaining a constant fluence of ~27.9 kJ/cm 2 . Electron temperatures and densities of the ablated plasma were determined by analyzing the time-resolved x-ray spectroscopy data through a comparison of experimental measurements with synthetic results obtained from Si atomic calculations in a steady state and non-local thermodynamic equilibrium. These calculations were computed using PrismSPECT. Additionally, radiation-hydrodynamics simulations with FLASH are used to generate simulated plasma-density and plasma-temperature profiles, which are then compared with the experimental measurements. Our analyses reveal that increasing the laser pulse length at a constant fluence results in a decrease in electron temperatures and densities. Furthermore, the longer pulses with lower intensities lead to deeper ablation regions before reaching the peak ablation but lower ionization balances in the silicon layer. Furthermore, these findings emphasize the critical role of laser pulse length in plasma ablation and shock generation for laser-impulse studies.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Pathways of China's PM 2.5 air quality 2015–2060 in the context of carbon neutrality

Clean air policies in China have substantially reduced particulate matter (PM 2.5 ) air pollution in recent years, primarily by curbing end-of-pipe emissions. However, reaching the level of the World Health Organization (WHO) guidelines may instead depend upon the air quality co-benefits of ambitious climate action. Here, we assess pathways of Chinese PM 2.5 air quality from 2015 to 2060 under a combination of scenarios that link global and Chinese climate mitigation pathways (i.e. global 2°C- and 1.5°C-pathways, National Determined Contributions (NDC) pledges and carbon neutrality goals) to local clean air policies. We find that China can achieve both its near-term climate goals (peak emissions) and PM 2.5 air quality annual standard (35 μg/m3) by 2030 by fulfilling its NDC pledges and continuing air pollution control policies. However, the benefits of end-of-pipe control reductions are mostly exhausted by 2030, and reducing PM 2.5 exposure of the majority of the Chinese population to below 10 μg/m 3 by 2060 will likely require more ambitious climate mitigation efforts such as China's carbon neutrality goals and global 1.5°C-pathways. Our results thus highlight that China's carbon neutrality goals will play a critical role in reducing air pollution exposure to the level of the WHO guidelines and protecting public health.

54 ENVIRONMENTAL SCIENCES↗

Charge disproportionation in the spin-liquid candidate κ – ( ET ) 2 Cu 2 ( CN ) 3 at 6 K revealed by Cu 63 NQR measurements

The spin-liquid candidate κ – ( ET ) 2 Cu 2 ( CN ) 3 [ET: bis(ethylenedithio)tetrathiafulvalene] does not exhibit magnetic ordering down to a very low temperature, but shows a mysterious anomaly at 6 K. The origin of the so-called 6-K anomaly is still under debate. We carried out nuclear quadrupole resonance (NQR) measurements on the copper sites of the insulating layers, which are sensitive to the charge dynamics unlike conventional spin- 1 / 2 nuclear magnetic resonance (NMR). The main finding of this Rapid Communication is that the observation of a sharp peak behavior in the nuclear spin-lattice relaxation rate T 1 – 1 of Cu 63 NQR at 6 K while T 1 – 1 of both C 13 and H 1 NMR show no clear anomaly. This behavior can be understood as a second-order phase transition related to charge disproportionation in the ET layers.

36 MATERIALS SCIENCE↗

Kilonovae Across the Nuclear Physics Landscape: The Impact of Nuclear Physics Uncertainties on r-process-powered Emission

Merging neutron stars produce “kilonovae”—electromagnetic transients powered by the decay of unstable nuclei synthesized via rapid neutron capture (the r-process) in material that is gravitationally unbound during inspiral and coalescence. Kilonova emission, if accurately interpreted, can be used to characterize the masses and compositions of merger-driven outflows, helping to resolve a long-standing debate about the origins of r-process material in the Universe. We explore how the uncertain properties of nuclei involved in the r-process complicate the inference of outflow properties from kilonova observations. Using r-process simulations, we show how nuclear physics uncertainties impact predictions of radioactive heating and element synthesis. For a set of models that span a large range in both predicted heating and final abundances, we carry out detailed numerical calculations of decay product thermalization and radiation transport in a kilonova ejecta with a fixed mass and density profile. The light curves associated with our models exhibit great diversity in their luminosities, with peak brightness varying by more than an order of magnitude. We also find variability in the shape of the kilonova light curves and their color, which in some cases runs counter to the expectation that increasing levels of lanthanide and/or actinide enrichment will be correlated with longer, dimmer, redder emission.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

A comparison of the 0.1-17 keV/e ion composition in the near equatorial magnetosphere between quiet and disturbed conditions

Data from the near-equatorial magnetosphere are analyzed by comparing the plasma composition during storm conditions with the composition during extended periods of low magnetic activity. It is found that at L less than or equal to 5, the O(+) is typically comparable to the H(+) in density and is often the dominant species, particularly during quiet times and at the inner edge of the region of significant fluxes. The He(+) in most cases contributes a significant fraction of the density and is sometimes the second most abundant species, following the O(+). Another finding is that both the He(+)/H(+) and the O(+)/H(+) ratios peak at the lowest L values and are, on the average, higher during quiet times than they are during the early main phase of major magnetic storms; this is seen as suggesting that charge exchange may be a significant loss process at low L. It is pointed out that the mean energies of the H(+), He(+), and O(+) ions often decrease gradually with decreasing L toward the inner edge of the energetic particle population.

Lennartsson, W.↗

Near-infrared imaging of Markarian 231: Evidence for a double nucleus

Near-infrared (1.2-2.4 micrometers) images are presented for the central 10 arcsec of the Seyfert 1 galaxy Markarian 231. We find a faint, but intrinsically luminous (M(sub k) approximately -20.7) secondary peak in the near-infrared light distribution approximately 3.5 arcsec (2.7 kpc) south of the primary Seyfert 1 nucleus. Since there is no optical or infrared evidence for ongoing star formation at the location of this secondary peak, and its near-infrared luminosity and color are comparable to slightly reddened spiral bulges or elliptical nuclei, we identify this peak with the stripped nucleus of the companion galaxy involved in the Mrk 231 merger event. Depending upon the exact ratio of the masses of the primary and secondary nucleus in the Mrk 231 system we estimate a merger time scale of less than or equal to 10(exp 9) yr. The morphology of the southern nucleus suggests that it may have recently survived a close passage (r less than 200 pc) with the Seyfert 1 nucleus on a highly elliptical orbit, in which case the merger time scale may be significantly shorter (approximately 10(exp 7) yr. We re-calculate the average merger time scale for the seven ultraluminous infrared galaxies with double nuclei in the Bright Galaxy Sample (the BGS) of Soifer et al. (AJ, 98, 766 (1989)) and derive a value of approximately 10(exp 8) yr. Since seven of ten of the ultraluminous infrared galaxies in the BGS are now known to be double, we estimate the ultraluminous 'phase' may be close to this value. Along with Arp 220 and Mrk 273, Mrk 231 is the third member of the class to possess a high brightness temperature non-thermal radio core and a double nucleus, suggesting the time scale for the generation or fueling of the active nucleus can be much less than the dynamical time scale for the merger of the progenitor nuclei.

Armus, L.↗

Multiple Equilibria Associated with Response of the ITCZ to Seasonal SST Forcing

Supported by numerical experiment results, the abrupt change of the location of the intertropical convergence zone (ITCZ), from the equatorial trough flow regime to the monsoon trough flow regime is interpreted as a subcritical instability. The existence of these multiple quasi-equilibria is due to the balance of two "forces" on the ITCZ: one toward the equator, due to the earth's rotation, has a nonlinear latitudinal dependence; and the other toward the latitude of the sea surface (or ground) temperature peak has a relatively linear latitudinal dependence. This work pivots on the finding that the ITCZ and Hadley circulation can still exist without the pole-to-equator gradient of radiative-convective equilibrium temperature.

Chao, Winston C.↗

Planetary Regolith Microstructure: An Unexpected Opposition Effect Result

The Opposition Effect (OE) is the non-linear increase in the intensity of light scattered from a surface as phase angle approaches 0 deg. It is seen in laboratory experiments and in remote sensing observations of planetary surfaces. Understanding the OE is a requirement to fitting photometric models which will produce meaningful results about regolith texture. Our previous laboratory studies are consistent with the hypothesis that the OE in particulate materials is due to two processes, Shadow Hiding (SHOE) and Coherent Backscattering (CBOE). SHOE arises because, as phase angle approaches zero, shadows cast by regolith grains on other grains become invisible to the observer. CBOE results from constructive interference between rays traveling the same path but in opposite directions. In this study we measured the angular scattering properties of 9 mixtures of Aluminum Oxide and Boron Carbide powders of the same particle diameter (25 microns). The reflectance of the materials ranged from 7% (pure B4C) to 91% (pure Al2O3). Along with the reflectance phase curve we measured the circular polarization ratio (CPR) - the ratio of the intensity of the light returned with the same helicity as the incident light to that with the opposite helicity. An increase in CPR with decreasing phase angle indicates increased multiple scattering and is consistent with CBOE (Hapke, 1993). Popular conceptions of CBOE (Belskaya et al, 2003) hold that materials of higher albedo would exhibit increased multiple scattering and that the contribution of CBOE to the OE would increase as albedo increases. Remarkably, we find the highest albedo samples did not have the strongest CBOE opposition peaks. Instead, the maximum CBOE contribution is observed in samples with reflectance between 15 and 40%.

Nelson, R. M.↗

A strongly changing accretion morphology during the outburst decay of the neutron star x-ray binary 4U 1608-52

It is commonly assumed that the properties and geometry of the accretion flow in transient low-mass X-ray binaries (LMXBs) significantly change when the X-ray luminosity decays below ∼10−2 of the Eddington limit (LEdd). However, there are few observational cases where the evolution of the accretion flow is tracked in a single X-ray binary over a wide dynamic range. In this work, we use NuSTAR and NICER observations obtained during the 2018 accretion outburst of the neutron star LMXB 4U 1608−52, to study changes in the reflection spectrum. We find that the broad Fe–Kα line and Compton hump, clearly seen during the peak of the outburst when the X-ray luminosity is ∼1037 erg s−1 (∼0.05 LEdd), disappear during the decay of the outburst when the source luminosity drops to ∼4.5 × 1035 erg s−1 (∼0.002 LEdd). We show that this non-detection of the reflection features cannot be explained by the lower signal-to-noise ratio at lower flux, but is instead caused by physical changes in the accretion flow. Simulating synthetic NuSTAR observations on a grid of inner disc radius, disc ionization, and reflection fraction, we find that the disappearance of the reflection features can be explained by either increased disc ionization (log ξ  4.1) or a much decreased reflection fraction. A changing disc truncation alone, however, cannot account for the lack of reprocessed Fe–Kα emission. The required increase in ionization parameter could occur if the inner accretion flow evaporates from a thin disc into a geometrically thicker flow, such as the commonly assumed formation of a radiatively inefficient accretion flow at lower mass accretion rates.

J. van den Eijnden↗

Predicting river turbidity in Pine Island Bayou using machine learning techniques coupled with variational mode decomposition

Elevated turbidity levels pose significant public health risks by facilitating the transport of harmful pollutants, including metals, organic compounds, and pathogenic microorganisms into the surface water. These conditions create serious challenges for public recreational water use and drinking water treatment, leading to economic losses and health risks. This study utilizes water monitoring data in Pine Island Bayou, Texas, and develops a Sequence-to-Sequence (S2S) model to predict turbidity using Attention-based Gated Recurrent Units with Encoder-Decoder (AT-GRU-ED) and Long Short-Term Memory (LSTM), coupled with Variational Mode Decomposition (VMD). Compared to the model without VMD, the model demonstrates satisfactory 72-hour turbidity prediction performance, achieving MAEs of 2.60 and 3.29 NTU (reductions of 53% and 58%), RMSEs of 21.08 and 31.49 NTU (reductions of 82% and 80%), and R² values of 0.96 and 0.84 on the validation and test sets, respectively. Feature importance analysis reveals that water temperature is the dominant factor influencing seasonal turbidity patterns, while real-time hourly rainfall significantly contributes to short-term variability. Turbidity typically peaks within 48 hours after rainfall events due to lagged effects from surface runoff and upstream flow. Findings suggest suspending recreational water use and water supply pumping for three days after heavy rainfall can benefit public health and improve water treatment processes. Discharges above 100 m3/s are found to accelerate sediment dilution and transport, reducing turbidity levels more quickly after the peak. In conclusion, the proposed model demonstrates reliable 72-hour turbidity prediction, supporting decision-making for water treatment plant operations and providing early warning for public recreational water use.

Deep learning↗

Comparing Delay-, Distance-, and Cordon-Based Congestion Pricing Strategies Via Large-Scale Simulation

This study compares the impacts of delay-, distance-, and cordon-based congestion pricing strategies for Austin, Texas, using the POLARIS agent-based activity-based travel demand simulation model. This approach enables agent-level heterogeneity and realistic choice options (including destination, mode, and activity scheduling) for dynamic traffic assignment and congestion feedbacks across a major metro region, which are features lacking in past work. To ensure comparability, distance-based tolls were set to generate the same revenue as delay-based tolling of $3.5 M/day, averaging $1.17/resident/day or $0.42/vehicle-trip. Delay-based pricing delivers 44% lower network delay and 13% lower VHT compared to the no-toll baseline, levels unmatched by other pricing strategies. At the height of the AM peak, drivers pay up to $0.13/mile on average, though most links in the network remain untolled. Distance-based pricing is the most effective at reducing VMT (by 4%), but VHT reductions (of 6%) primarily stem from drivers selecting closer destinations, achieving only one-fourth the delay reduction of delay-based pricing. Across various implementations of delay- and distance-based pricing, the results suggest that spatial variations of tolls are far more important than temporal variations. Cordon tolls produce minimal impacts at the network-wide level, but offer substantial delay reductions inside the cordon. Other major findings include: 1) delay-based pricing increases trip-making during the PM peak period due to backward shifts in discretionary-activity start times by higher-income residents; and 2) tolls’ spatial impacts, including changes in network flows and tolls paid by residents, vary substantially between delay- and distance-based pricing strategies.

Agent-based modeling↗

Formation and Past Evolution of the Showers of 96P/Machholz Complex

In this work we model the dynamical evolution of meteoroid streams of comet 96P/Machholz, and the largest member of the Marsden sunskirters, comet P/1999 J6. We simultaneously fit the characteristics of eight meteor showers which have been proposed to be linked to the complex, using observations from a range of techniques - visual, video, TV and radar. The aim is to obtain a self-consistent scenario of past capture of a large comet into a short-period orbit, and its subsequent fragmentation history. Moreover, we also aim to constrain the dominant parent of these showers. The fit of our simulated shower characteristics to observations is consistent with the scenario of a capture of a proto-comet 96P/Machholz by Jupiter circa 20000 BCE (Before Christian Era), and a subsequent major breakup around 100-950 CE (Christian Era) which resulted in the formation of the Marsden group of comets. We find that the Marsden group of comets are not the immediate parents of the daytime Arietids and Northern and Southern delta-Aquariids, as previously suggested. In fact, the hypothesis that the Northern delta-Aquariids are related to the Marsden group of comets is not supported by this study. The bulk of the observational characteristics of all eight showers can be explained by meteoroid ejection primarily from comet 96P/Machholz between 10000 BCE and 20000 BCE. Assuming the Marsden group of comets originated between 100 CE-950 CE, we conclude that sunskirting comets contribute mainly to the meteoroid stream near the time of the peak of the daytime Arietids, Southern delta-Aquariids, kappa-Velids. Finally, we find that the meteor showers identified by Babadzhanov and Obrubov (1992) as the alpha-Cetids, the Ursids and Carinids correspond to the daytime lambda-Taurids, the November iota-Draconids or December alpha-Draconids and the theta-Carinids.

Abedin, Abedin↗

Exploring the transition from continuous turbulence fluctuations to bursting ELMs in high SOL density regimes

BOUT++ turbulence simulations of the DIII-D reveal that the density profile between the separatrix and pedestal plays a crucial role in the dynamics of edge localized modes (ELMs) and edge plasma turbulent transport. Nonlinear simulations demonstrate that small ELMs in the DIII-D hybrid scenario under high SOL density conditions are predominantly driven by local ballooning modes near the separatrix, stabilizing global instabilities while enhancing localized pressure fluctuations. A key control parameters for ELM dynamics is the separatrix-to-pedestal density ratio, n e,sep /n e,ped . A high ratio indicates a shallow gradient, favoring small ELMs, while a lower ratio signals a steep gradient, which increases the likelihood of large ELMs. Comprehensive parameter scans, including n e,sep /n e,ped , density gradient profiles near the separatrix, and resistivity, reveal the critical role of these parameters in shaping transitions between turbulence-driven transport and ELM bursting. The scans demonstrate that in high SOL density regimes, small ELMs can result from either global resistive MHD instabilities or local ballooning modes near the separatrix, depending on the steepness of the separatrix density gradient. These findings also highlight the transition from continuous turbulence to small ELMs. The post-crash peak in pressure fluctuations, δP rms serves as a critical metric for identifying transition from continuous turbulence fluctuations to ELM bursting. Larger δP rms values correlate with ELM bursts driven by local or global instabilities, whereas smaller values indicate turbulence-dominated transport. Drift-Alfvén and resistive ballooning turbulence enhance the entrainment of fluctuations from the pedestal to the SOL, contributing to the complex interplay of dynamics in this regime. These findings emphasize the importance of separatrix density shaping and pedestal gradient control for optimizing ELM behavior in ITER and future fusion devices.

Li, Nami [Lawrence Livermore National Laboratory (↗

Agricultural Breadbaskets Shift Poleward Given Adaptive Farmer Behavior Under Climate Change

Modern food production is spatially concentrated in global “breadbaskets”. A major unresolved question is whether these peak production regions will shift poleward as the climate warms, allowing some recovery of potential climaterelated losses. While agricultural impacts studies to date have focused on currently cultivated land, the Global Gridded Crop Model Intercomparison Project (GGCMI) Phase 2 experiment allows us to assess changes in both yields and the location of peak productivity regions under warming. We examine crop responses under projected end-of-century warming using 7 process-based models simulating 5 major crops (maize, rice, soybeans, and spring and winter wheat) with a variety of adaptation strategies. We find that in no-adaptation cases, when planting date and cultivar choices are held fixed, regions of peak production remain stationary and yield losses can be severe, since growing seasons contract strongly with warming. When adaptations in management practices are allowed (cultivars that retain growing season length under warming and modified planting dates), peak productivity zones shift poleward and yield losses are largely recovered. While most growing-zone shifts are ultimately limited by geography, breadbaskets studied here move poleward over 600 km on average by end of the century under RCP8.5. These results suggest that agricultural impacts assessments can be strongly biased if restricted in spatial area or in the scope of adaptive behavior considered. Accurate evaluation of food security under climate change requires global modeling and careful treatment of adaptation strategies.

adaptation↗

Robust chain aggregation of low-entropy rigid ladder polymers in solution

Conjugated polymers have been widely investigated where ladder-type conjugated polymers receive more attention due to their rigid backbones and extraordinary properties. However, the understanding of how the rigid conformation of ladder polymers translates to material properties is still limited. Here, we systematically investigated the solution aggregation properties of a carbazole-derived conjugated ladder polymer (LP) and its analogous non-ladder control polymer (CP) via light scattering, neutron scattering, and UV-vis absorption spectroscopy characterization techniques, revealing a highly robust, temperature-insensitive aggregation behavior of the LP. The experimental findings were further validated by computational molecular dynamics simulations. Here we found that the peak positions and intensities of the UV spectra of the LP remained constant between 20 °C and 120 °C in chlorobenzene solution. The polymer also showed a stable hydrodynamic radius measured by dynamic light scattering from 20 °C to 70 °C in the chlorobenzene solution. Using small-angle neutron scattering, no Guinier region was reached in the measured q range down to 0.008 Å –1 , even at elevated temperature. In contrast, the non-ladder control polymer CP was fully soluble in the chlorobenzene solvent without the observation of any notable aggregates. The Brownian dynamics simulation showed that during polymer aggregation, the entropy change of the LP was significantly less negative than that of the non-ladder control polymer. These findings revealed the low entropy nature of rigid conjugated ladder polymers and the low entropy penalty for their aggregation, which is promising for highly robust intermolecular interactions at high temperatures. Such a unique thermodynamic feature of rigid ladder polymers can be leveraged in the design and application of next-generation electronic and optoelectronic devices that function under unconventional high temperature conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Optical and Near-Infrared Observations of SN 2013DX Associated with GRB 130702A

We present optical and near-infrared (NIR) light curves and optical spectra of SN 2013dx, associated with the nearby (redshift 0.145) gamma-ray burst GRB 130702A. The prompt isotropic gamma-ray energy released from GRB 130702A is measured to be E(sub gamma, iso) = 6.4(+1.3/-1.0) x 10(exp 50) erg (1 keV to 10 MeV in the rest frame), placing it intermediate between low-luminosity GRBs like GRB 980425/SN 1998bw and the broader cosmological population. We compare the observed g'r'i'z' light curves of SN 2013dx to a SN 1998bw template, finding that SN 2013dx evolves approx. 20% faster (steeper rise time), with a comparable peak luminosity. Spectroscopically, SN 2013dx resembles other broad-lined SNe Ic, both associated with (SN 2006aj and SN 1998bw) and lacking (SN 1997ef, SN 2007I, and SN 2010ah) gamma-ray emission, with photospheric velocities around peak of approx. 21,000 km/s. We construct a quasi-bolometric (g'r'z'yJ) light curve for SN 2013dx, only the fifth GRB-associated SN with extensive NIR coverage and the third with a bolometric light curve extending beyond (Delta)t > 40 days. Together with the measured photospheric velocity, we derive basic explosion parameters using simple analytic models. We infer a Ni-56 mass of M(sub Ni) = 0.37+/- 0.01 Stellar Mass, an ejecta mass of M(sub ej) = 3.1+/- 0.1 Stellar Mass, and a kinetic energy of E(sub K) = (8.2+/- 0.43) x 10(exp 51) erg (statistical uncertainties only), consistent with previous GRB-associated supernovae. When considering the ensemble population of GRB-associated supernovae, we find no correlation between the mass of synthesized Ni-56 and high-energy properties, despite clear predictions from numerical simulations that M(sub Ni) should correlate with the degree of asymmetry. On the other hand, M(sub Ni) clearly correlates with the kinetic energy of the supernova ejecta across a wide range of core-collapse events.

gamma-ray burst: individual (GRB 130702A) – supe↗

Modeling the Geologic History of Mt. Sharp

Gale is an approximately 155 km diameter crater located on the martian dichotomy boundary (5 deg S 138 deg E). Gale is estimated to have formed 3.8 - 3.5 Gya, in the late Noachian or early Hesperian. Mt. Sharp, at the center of Gale Crater, is a crescent shaped sedimentary mound that rises 5.2 km above the crater floor. Gale is one of the few craters that has a peak reaching higher than the rim of the crater wall. The Curiosity rover is currently fighting to find its way across a dune field at the northwest base of the mound searching for evidence of habitability. This study used orbital images and topographic data to refine models for the geologic history of Mt. Sharp by analyzing its morphological features. In addition, it assessed the possibility of a peak ring in Gale. The presence of a peak ring can offer important information to how Mt. Sharp was formed and eroded early in Gale's history.

Pascuzzo, A.↗