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At least 433 records · Page 24

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NASA NTRS1980

Ground-state rotational constants of /C-13/H3D

Rotational constants for the vibrational ground state of (C-13)H3D, which has been detected in the atmospheres of Jupiter and Saturn, are reported. High-resolution spectra of monodeuteromethane were obtained in the region 1800 to 2500 kaysers by a vacuum Fourier interferometer, and the values of the rotational constants B0, D0J, D0JK, H0JJJ, H0JJK and H0JKK were calculated by an analysis of ground-state combination differences in the nu 2(A1) band. The calculated frequency and intensity of this transition are found to be in agreement with the observed values.

Chackerian, C., Jr.↗

NASA NTRS1981

High-resolution laser absorption spectroscopy of ozone near 1129.4 cm (-1)

A Beer's Law experiment was performed with a tunable diode laser to determine self broadened line shape parameters of one infrared absorption ozone line in the nu1 band for ten pressures from 0.26 to 6.29 torr at 285 K. The SO2 line positions were used for wavelength calibration. Line shapes were iteratively fitted to the Voigt function at a Doppler width of 29.54 MHz (HWHM) resulting in values for the integrated line strength, (S), of (0.144 +/- 0.007) x 10 to the minus 20th/cm molecule/cu cm, line center frequency, nu sub o, of 1129.426/cm and the Lorentzian contributions to halfwidth. A linear least squares fit of (alpha sub L)5 as a function of pressure yielded a zero intercept of 15.27 +/- 0.29 MHz (rho = 0.99) and a broadening parameter, (alpha sub L)5, of 5.71 +/- 0.29 MHz/Torr. This results in a line width (FWHM) of 0.144 +/- .007/cm at 760 torr and 285 K.

Majorana, L. N.↗

NASA NTRS1981

Acceleration wave breakup of liquid jets with airstreams

Characteristic mean drop diameters were determined for downstream and upstream injection into nonswirling and swirling airflows. The effects of the aerodynamic and liquid surface forces on the mean drop size were obtained with a scanning radiometer. Water jet breakup was studied primarily in the acceleration wave regime with values of WeRe 10 to the 6th power and the following empirical expression was obtained: D(o)/D(m) =C (WeRe) to the 0.4, power where D(o) and D(m) are the orifice and mean drop diameters, respectively. We and Re are the Weber and Reynolds numbers defined as repectively, We = rho(a)D(o)V(r)/sigma and Re = D(o)V(r)/nu, where V(r) and rho(a) are airstream relative velocity and density, respectively, and sigma and nu are surface tension and kinematic viscosity of the liquid, respectively. The proportionally constant C was evaluated as follows: for downstream injection, C = 0.023 with nonswirling airflow, and C = 0.027 with swirling airflow. For upstream injection, the empirical expression D(o)/D(m) = 0.0045 (WeRe) to the 0.5 power was obtained with nonswirling airflow. Experimental conditions included a water flow rate of 68 liter per hour and an airflow rate per unit area range of 4.6 to 25.2 gm/sq cm sec at 293 K and atmospheric pressure.

Ingebo, R. D.↗

NASA NTRS1981

Photoexcitation of lasers and chemical reactions for NASA missions: A theoretical study

The possibility of obtaining CW laser oscillation by optical pumping in the infrared at an elevated gas pressure is reviewed. A specific example utilizing a mixture of CO and NO gases is included. The gas pressures considered are in excess of several atmospheres. Laser frequency tuning over a broad region becomes possible at such elevated gas pressures due to collisional broadening of the amplifying transitions. The prior-rate and surprisal analysis are applied to obtain detailed VV and VT rates for CO and NO molecules and the transfer rates in a CO-NO gas mixture. The analysis is capable of giving temperature dependence of the rate constants. Computer estimates of the rates are presented for vibrational levels up to v = 50. The results show that in the high-lying vibrational states the VV transfer rates with Delta nu = 2 become appreciable.

Javan, A.↗

NASA NTRS1981

Influence of thermal boundary conditions on heat transfer from a cylinder in cross flow

Local heat transfer data over the leading surface of a cylinder in crossflow were obtained for a Reynolds number range of 50,000. The cylinder was operated at both uniform-wall-temperature and uniform-heat-flux thermal ance of 80 deg from the front stagnation point, the uniform-wall-temperature heat transfer coefficients were as much as 66 percent lower than the uniform-heat-flux data. Between the stagnation point and 60 deg around the cylinder, there were no significant differences in the data. This region of the cylinder is within the cylindrical curvature region of the front end of a real turbine so it was concluded that either thermal boundary condition could be used to model turbine flow over that region of the blade. Results of evaluating the exponent x in the fundamental relationship Nu=f(Re) sup x, which is used in data correlation show the exponent varies as a function of local position on the cylinder even in the laminar flow region. The value of x increases linearly from 0.50 at the stagnation point to 0.59 at 60 deg around the cylinder. This linear trend continued into the separation region at 80 deg for the uniform-wall-temperature data, but x increased markedly in the separation region for the uniform-heat-flux data.

Papell, S. S.↗

NASA NTRS1980

Infrared observations of circumstellar ammonia in OH/IR supergiants

Ammonia has been detected in the circumstellar envelopes of VY Canis Majoris, VX Sagittarii, and IRC +10420 by means of several absorption lines in the nu-2 vibration-rotation band near 950 kaysers. The line profiles are well resolved (0.2 km/sec resolution) and show the gas being accelerated to terminal expansion velocities near 30 km/sec. The observations reveal a method for determining the position of the central star on VLBI maps of OH maser emission to an accuracy of approximately 0.2 arcsec. A firm lower limit of 2 x 10 to the 15th/sq cm is obtained for the NH3 column density in VY Canis Majoris.

Mclaren, R. A.↗

NASA NTRS1980

Infrared heterodyne spectroscopy of circumstellar molecules

Ammonia has been detected in the circumstellar envelopes of IRC+10216, VY CMa, VX Sgr, and IRC+10420. A number of absorption lines of (N-14)H3 in the nu sub 2 vibration-rotation band around 28 THz (950 per cm) have been observed at a velocity resolution of 0.2 km/s. Typical linewidths are 1 to 4 km/s, and the details of the line profiles provide additional insights on the process of mass loss in these stars.

Betz, A. L.↗

NASA NTRS1981

Ethylene in IRC +10216

Ethylene has been detected in the circumstellar gas surrounding the supergiant star IRC +10216. Two lines of the nu sub 7 vibration-rotation band near 28 THz (949/cm) have been seen in absorption at an expansion velocity of 14 km/sec relative to the central star. The line intensities indicate a rotational temperature of T greater than 400 K and a radial C2H4 column density of 10 to the 16th to 10 to the 17th per sq cm.

Betz, A. L.↗

NASA NTRS1982

N2 pressure - broadened O3 line widths and strengths near 1129.4 cm-1

A Beer's Law experiment was performed with a tunable diode laser to find the N2 pressure broadening characteristics of a single 03 absorption line at 1129.426 cm for N2 pressures from 10 to 100 torr (O3 pressure = 3.16 torr). SO2 line positions were used for wavelength calibration. Line shapes were interatively fitted to a Lorentz function. Results were delta (HWHM in MHz) = 47.44 (+ or - 5.34) MHz + 1.730 (+ or - 0.088) MHz/torr *p(torr) with sigma = 0.9897. This intercept compares well with the Doppler O3 - O3 broadened (at 3.16 torr) width of 44.52 Hz. This result in a HWHM line width of 0.44 cm atm at 760 torr and 285 K. The line strengths integrated over delta nu = 0.55 cm were found to be N2 pressure dependent.

Copeland, G. E.↗

NASA NTRS1982

The peculiar UV extinction of Herschel 36

The differential extinction curve of Herschel 36 was determined from International Ultraviolet Explorer data. It is quite unusual, characterized by a distinct 2200 A peak with a very low far blue end at 5 to 7 mu to the -1 power. The star appears to be an extreme member of the group Savage drew attention to, previously consisting only of theta Ori, NU Ori, sigma Sco, and rho Oph. It appears that multiple scattering effects are needed to explain the observations.

Hecht, J.↗

NASA NTRS1981

The resonance line of B II in IUE spectra of chemically peculiar stars

A description is presented of high-dispersion spectroscopic observations of eight chemically peculiar stars including Kappa Cnc and Mu Lep, and of one normal comparison star, Nu Cap, in the vicinity of 1362 A. The reported data were obtained with the International Ultraviolet Explorer during the first 15 months of its operation. The initial reduction of the data, which were originally described in a qualitative summary by Leckrone (1980), was affected by a serious error in the calibration of the instrument's intensity transfer function. This error has been corrected in the currently presented data. The results of spectrum syntheses of the 1362 A feature are also described for several of the stars.

Leckrone, D. S.↗

NASA NTRS1981

The detection of HCN on Jupiter

The detection of HCN on Jupiter is reported. Three R-branch lines of the nu-2 fundamental of HCN near 13.5 microns were observed in absorption, from which the HCN column density is inferred to be 0.005 cm-am with an uncertainty of a factor of two. If emission from the stratosphere exists, then the derived column density is only a lower limit. It is suggested that the Jovian HCN most likely originates from the photolysis of CH4 and NH3 in the lower stratosphere and upper troposphere. In addition, an upper limit of 0.025 cm-am was established for the column density of HCN on Saturn.

Tokunaga, A. T.↗

NASA NTRS1982

A reinvestigation of the rate of the C/+/ + H2 radiative association reaction

It is noted that new experimental results and statistical theories have prompted a reinvestigation of the rate coefficient of the interstellar reaction in which C(+) + H2 yields CH2(+) + h(nu) in the 10-100 K temperature range. The results presented here indicate a rate coefficient between 10 to the -16 and 10 to the -15 cu cm/s at all temperatures studied. In applying the modified thermal and phase space theories, it is expected that they will be as accurate as for radiative association as for three-body association, provided the ab initio value for the radiative decay rate is correct. It is expected that the calculated values of the rate coefficient will be accurate to within an order of magnitude and will have the correct temperature dependence.

Herbst, E.↗

NASA NTRS1982

Photon bunching and the photon-noise-limited performance of infrared detectors

The photon-noise-limited performance of a radiation detector exposed to a thermal background of temperature T is analyzed by calculating the resulting specific detectivity. Both ideal photon detectors of arbitrary quantum efficiency eta and ideal thermal detectors of arbitrary emissivity eta are considered; and the effects of both shot noise and excess noise are taken into account. The relative contributions of these two sources depend on the quantum efficiency or emissivity of the system. For frequencies nu such that hnu/kT is much less than eta, excess noise can make an appreciable contribution to the total system noise. For the case of the detection of the narrow-band radiation, the specific detectivity is independent of eta in the limit hnu/kT is much less than eta.

Boyd, R. W.↗

NASA NTRS1981

A theory of the n-i-p silicon solar cell

A computer model has been developed, based on an analytical theory of the high base resistivity BSF n(+)(pi)p(+) or p(+)(nu)n(+) silicon solar cell. The model makes very few assumptions and accounts for nonuniform optical generation, generation and recombination in the junction space charge region, and bandgap narrowing in the heavily doped regions. The paper presents calculated results based on this model and compares them to available experimental data. Also discussed is radiation damage in high base resistivity n(+)(pi)p(+) space solar cells.

Goradia, C.↗

NASA NTRS1982

Solution of axisymmetric fluid structure interaction problems with NASTRAN

The solution of axisymmetric acoustic fluid structure interaction problems, employing the NASTRAN computer program is presented. A previously developed 3-D Cartesian Coordinates pressure element formulation is adapted especially for axisymmetric elements. Analogous to the 3-D Cartesian Coordinate predecessor, the fluid portion of the problem is modeled with finite elements wherein one of the displacement components serves as a dummy variable for the pressure unknowns. Two alternatives for implementation of the analogy are presented: (1) an approximate method by which dummy values of G, and nu are used to approximately invoke the analogy wherein the accuracy of the approximation is made as close as desired to the proper analogy within an arbitrary small parameter epsiton; (2) an exact method whereby the NASTRAN FORTRAN coding is slightly changed to invoke the analogy exactly. Comparison of the finite element solution to the exact solution to the same problem is given.

Kalinowski, A. J.↗

NASA NTRS1982

Effects of moisture, residual thermal curing stresses, and mechanical load on the damage development in quasi-isotropic laminates

This investigation demonstrates how moisture absorbed in (0/+ or - 45/90)s and (0/90/+ or - 45)s graphite epoxy laminates significantly alters the stress state and chronology of damage development along the laminate edge during static tension and tension-tension cyclic loading. Emphasis is placed on using reasonable approximations for wet and dry elastic properties, including out-of-plane properties (nu sub 23 and G sub 23), since these properties are required by finite element and shear lag models to predict the stress state at the laminate edge. Moisture was observed to alter the dry edge stress state in the 90-deg plies of the (0/+ or - 45/90)s laminate such that delaminations occurred at a lower load and transverse cracks occurred at a higher load. A model was developed which predicted the differences in loads required to initiate damage in the 90-deg plies of the two laminates in the wet and dry conditions. Although moisture can alter the chronology of damage development, the damage state in each laminate observed prior to fracture appeared to be independent of moisture content.

Kriz, R. D.↗

NASA NTRS1982

Ground-based infrared spectroscopic measurements of atmospheric hydrogen cyanide

A number of lines of the nu-3 band of hydrogen cyanide have been detected in solar absorption spectra recorded near sunrise and sunset at Kitt Peak National Observatory (elevation 2095 m) with a 0.01/cm resolution Fourier transform spectrometer. Analysis of two of the strongest and best isolated lines has led to a value of 2.73 x 10 to the 15th molecules/sq cm for the vertical column abundance of HCN above Kitt Peak. The accuracy of this value is estimated as + or - 25%. This result, combined with the stratospheric concentration of HCN derived by Coffey, Mankin, and Cicerone (1981), yields 166 parts per trillion by volume for the average mixing ratio of HCN between 2 and 12 km. This is the first determination of the HCN concentration in the nonurban troposphere.

Rinsland, C. P.↗