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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24

Structural tests on a tile/strain isolation pad thermal protection system

The aluminum skin of the space shuttle is covered by a thermal protection system (TPS) consisting of a low density ceramic tile bonded to a matted-felt material called strain insulation pad (SIP). The structural characteristics of the TPS were studied experimentally under selected extreme load conditions. Three basic types of loads were imposed: tension, eccentrically applied tension, and combined in-plane force and transverse pressure. For some tests, transverse pressure was applied rapidly to simulate a transient shock wave passing over the tile. The failure mode for all specimens involved separation of the tile from the SIP at the silicone rubber bond interface. An eccentrically applied tension load caused the tile to separate from the SIP at loads lower than experienced at failure for pure tension loading. Moderate in-plane as well as shock loading did not cause a measurable reduction in the TPS ultimate failure strength. A strong coupling, however, was exhibited between in-plane and transverse loads and displacements.

Williams, J. G.↗

A modified T-value method for selection of strain gages for measuring loads on a low aspect ratio wing

A technique which may be useful for selecting strain gages for use in load equations is described. The technique is an adaptation of the previously used T-value method and is applied to a multispar structure. The technique, called the modified T-value method, is used to reduce the number of strain gages used in a load equation from twelve to two. A parallel reduction is made by calculating relative equation accuracies from three applied load distributions. The equations developed from the modified T-value method proved to be accurate more consistently than the T-value method.

Tang, M. H.↗

Atomic Layer Deposition of Cu Electrocatalysts on Gas Diffusion Electrodes for CO 2 Reduction

Electrochemical reduction of CO 2 using Cu catalysts enables the synthesis of C 2+ products including C 2 H 4 and C 2 H 5 OH. Here, in this study, Cu catalysts were fabricated using plasma-enhanced atomic layer deposition (PEALD), achieving conformal deposition of catalysts throughout 3-D gas diffusion electrode (GDE) substrates while maintaining tunable control of Cu nanoparticle size and areal loading. The electrochemical CO 2 reduction at the Cu surface yielded a total Faradaic efficiency (FE) > 75% for C 2+ products. Parasitic hydrogen evolution was minimized to a FE of ~10%, and a selectivity of 42.2% FE for C 2 H 4 was demonstrated. Compared to a line-of-sight physical vapor deposition method, PEALD Cu catalysts show significant suppression of C 1 products compared to C 2+ , which is associated with improved control of catalyst morphology and conformality within the porous GDE substrate. Finally, PEALD Cu catalysts demonstrated a stable performance for 15 h with minimal reduction in the C 2 H 4 production rate.

42 ENGINEERING↗

Heat Pumps with Phase Change Thermal Storage: Flexible, Efficient, and Electrification Friendly

As we continue to electrify space- and water-heating, the electricity demand profile of many buildings will change significantly, and periods of high electricity demand will likely not align with renewable energy generation. We expect electricity demands will increase substantially in the winter, annual maximum electricity demands will increase, and more regions will experience annual peak electrical demands – and higher wholesale electricity prices – in the winter. This is especially important for cold climates where 60% of site energy use in buildings is for heating, and where heat pumps perform least efficiently. This paper focuses on one promising solution among the many paths to electrification: the use of phase change materials (PCM) for compact low-cost thermal energy storage (TES). We present the design and simulation of a combi heat pump and phase change thermal storage system used for space- and water-heating in a multifamily residence in a cold climate. To assess the benefits of this technology, we compare its annual performance to that of a current state-of-the-art air-to-air heat pump and separate heat pump water heater. Simulation results for IECC Climate Zone 6A reveal that the combi heat pump with phase change thermal storage can reduce the design size for heat pumps by 40-60%, reduce maximum electric demand by 30-50%, reduce electricity use during 4-12-hour load shed periods by 50%, and avoid the need for auxiliary electric resistance for both space- and water-heating. Tariff structures are highly varied between different utilities and currently reflect higher wholesale market prices for electricity during summer days. Consequently, although this system design provides large electric demand reductions during hypothetical 4-12-hour load shed periods, it does not provide energy cost reductions with current winter residential time-of-use tariffs.

Helmns, Dre↗

Detailed Laboratory Evaluation of Electric Demand Load Shifting Potential of Controlled Heat Pump Water Heaters

The demand profile management of electric end uses is vital research for utilities and policymakers planning greenhouse gas emission reductions. In this study, detailed laboratory research was conducted on the load shifting potential of 4 grid-connected HPWHs and one electric resistance water heaters (ERWH). The testing applied different CTA-2045 shed and critical peak command designs under three water draw profiles. Highly-controlled laboratory experiments were conducted in Florida. One of the four HPWHs was a prototype incorporating the new CTA-2045-B protocol feature allowing ‘advanced’ load-up above tank setpoint. A three-hour morning (6 – 9 AM) and four-hour evening curtailment (4 – 8 PM) were defined as the shed or critical peak periods reflecting high-value control periods for utility coincident load for system-wide electric demand reductions. Tests were performed under baseline conditions (no load shift) and under varied load-shifting schemes, including load up and advanced load up, ahead of shed and critical peak commands. Data were collected from December 2020 – February 2022 in the laboratory and compared with field experiments in Florida and the Pacific Northwest. Grid-connected HPWHs were found to reduce peak demand by up to 0.47 kW compared to uncontrolled HPWH units, depending on time of day, control scheme, draw profile, and temperature cluster. The load up strategy demonstrated the ability of all units to utilize heat pump mode for extended periods ahead of peak events. Demand reductions for the HPWHs were much larger when compared with the ERWH— up to 1.64 kW with large hot water draws in winter.

Fenaughty, Karen↗

Composite Reflective Absorptive IR-Blocking Filters Embedded in Metamaterial Antireflection Coated Silicon

Infrared (IR)-blocking filters are crucial for controlling the radiative loading on cryogenic systems and for optimizing the sensitivity of bolometric detectors in the far-IR. We present a new IR filter approach based on a combination of patterned frequency-selective structures on silicon and a thin (2575 micron thick) absorptive composite based on powdered reststrahlen absorbing materials. For a 300 K blackbody, this combination reflects approximately 50% of the incoming light and blocks greater than.99.8% of the total power with negligible thermal gradients and excellent low-frequency transmission. This allows a reduction in the IR thermal loading to negligible levels in a single cold filter. These composite filters are fabricated on silicon substrates, which provide excellent thermal transport laterally through the filter and ensure that the entire area of the absorptive filter stays near the bath temperature. A metamaterial antireflection coating cut into these substrates reduces in-band reflections to below 1%, and the in-band absorption of the powder mix is below 1% for signal bands below 750 GHz. This type of filter can be directly incorporated into silicon refractive optical elements.

Munson, C. D.↗

Load alleviation maneuvers for a launch vehicle

This paper addresses the design of a forward-looking autopilot that is capable of employing a priori knowledge of wind gusts ahead of the flight path to reduce the bending loads experienced by a launch vehicle. The analysis presented in the present paper is only preliminary, employing a very simple vehicle dynamical model and restricting itself to wind gusts of the form of isolated spikes. The main result of the present study is that LQR based feedback laws are inappropriate to handle spike-type wind perturbations with large amplitude and narrow base. The best performance is achieved with an interior-point penalty optimal control formulation which can be well approximated by a simple feedback control law. Reduction of the maximum bending loads by nearly 50 percent is demonstrated.

Seywald, Hans↗

Dependence of the spectral surface irradiance on aerosol properties and surface reflectivity

A reduction in global surface irradiance occurs with increasing aerosol loadings when the aerosols are absorbing. For scattering aerosols, a reduction is pronounced for isotropic scattering (characteristic of small particles) but reduction is not as significant for scattering with a high anisotropy of a large forward peak (characteristic of large particles). This distinction between isotropic and anisotropic scattering becomes small or null over highly reflecting terrain; and for reflectivities higher than 0.5 and solar elevation angles close to the zenith, the global irradiance can be slightly higher for isotropic scattering than in the case of an anisotropy of a forward peak. Under such conditions, which can be encountered in reflective infrared bands over dense vegetation or over sandy deserts (close to noon, in low latitudes) the surface irradiance becomes nearly independent of the aerosol optical thickness.

Otterman, J.↗

Load alleviation maneuvers for a launch vehicle

This paper addresses the design of a forward-looking autopilot that is capable of employing a priori knowledge of wind gusts ahead of the flight path to reduce the bending loads experienced by a launch vehicle. The analysis presented in the present paper is only preliminary, employing a very simple vehicle dynamical model and restricting itself to wind gusts of the form of isolated spikes. The main result of the present study is that linear quadratic regulator (LQR) based feedback laws are inappropriate to handle spike-type wind perturbations with large amplitude and narrow base. The best performance is achieved with an interior-point penalty optimal control formulation which can be well approximated by a simple feedback control law. Reduction of the maximum bending loads by nearly 50% is demonstrated.

Seywald, Hans↗

Microbial Survival in Brewed Tea

Loose-leaf bagged tea is a commonly requested crew food item that comprises up to 7% of samples in the spaceflight food system. Tea preferences are typically specific and vary between different crew members, and there is significant interest to provide preferred food selections for the physical and mental wellbeing of the crew. Loose leaf bagged teas are made from herbs and spices that frequently have high microbial loads which do not meet the microbiological standards outlined in NASA-STD-3001. The food industry on earth does not require standards for microbial load of loose-leaf teas, because tea is brewed in boiling (100C) water, which is assumed to reduce the number of microorganisms. However, hot water from the ISS PWD is typically dispensed at a temperature between 155F (68C) and 175F (79C), which is below the suggested temperature range for safe brewing (180F/80C – 212F/100C). In this study, a commonly requested chamomile tea bags were infected with Bacillus cereus, a pathogenic, spore forming bacterium known to cause foodborne illness. Brewing B. cereus infected tea bags with boiling (212F/100C) or ISS PWD (155F/68C) temperature water showed no significant reduction in the overall microbial load of the tea (p=0.535). The addition of boiling and ISS PWD temperature water also was not sufficient to kill 100% of the infected B. cereus, and in one case of ISS PWD temperature water, B. cereus was detected at levels above a previously reported infectious dose. This study showed that the microbiological risk associated with drinking brewed tea on ISS is not reduced by the brewing process.

S G Thornhill↗

Controlling selectivity for dechlorination of poly(vinyl chloride) with (xantphos)RhCl

Reaction of poly(vinyl chloride) (PVC) with 5 equiv. of triethyl silane in THF, in the presence of in situ generated (xantphos)RhCl catalyst, results in partial reduction of PVC via hydrodechlorination to yield poly(vinyl chloride-co-ethylene). Increasing catalyst loading or using N,N-dimethylacetamide (DMA) as a solvent both diminished selectivity for hydrodechlorination, promoting competitive dehydrochlorination reactions. Reaction of PVC with 2 equiv. of sodium formate in THF in the presence of (xantphos)RhCl affords excellent selectivity for hydrodechlorination along with complete PVC dechlorination, yielding polyethylene-like polymers. Higher catalyst loadings were necessary to activate PVC towards reduction in this case. In contrast, reaction of PVC with 1 equiv. of NaH in DMA, in the presence of (xantphos)RhCl, exhibited good selectivity for dehydrochlorination, as well as much higher reaction rates. These results combined shed light on the interplay between critical reaction parameters that control PVC's mode of reactivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Alternate Methods of Model Reduction to Avoid Dynamic Modal Truncation Error

Loads analysis is traditionally performed using dynamically reduced models, which provides the benefit to reduce run time. If the reduced model frequency cutoff is not chosen appropriately, the model will lack the dynamic content required to fully represent the response of the non-reduced model. Standard guidance for reduced model frequency content, provided in NASA-STD-5002, is to solve fixed base modes up to a minimum of 1.5x the model frequency content of interest and to employ static modal truncation methods such as residual vectors, the mode acceleration method, and the residual flexibility method to account for the truncated flexibility of the missing modes. Fixed base modes require the selection of a set of degrees of freedom to be constrained which, if not properly selected, may affect the accuracy of the reduced model by excluding some of the dynamic characteristic of the full model. In this case, the standard NASA guidance would be insufficient, but it may not be readily apparent that a portion of the reduced model response is missing. This error was encountered during an independent verification and validation (IV&V) effort, where it was observed that the resulting dynamic response was lower than the inline analysis. In this specific case, despite following the standard NASA model reduction guidelines in the selection of the frequency cutoff, the inline model still did not fully capture the necessary dynamic content. As part of the IV&V, an alternate reduction methodology was employed using an unconstrained mode acceleration method. The original model initially performed a constrained reduction to twice the frequency content of interest before doing a free-free run, employing the mode acceleration method to account for the truncated modes. In contrast in the IV&V, the unconstrained model reduced directly to the needed frequency content of the free-free run, avoiding any interactions between constraints and dynamic content. To verify the model, the original reduction methodology was used to generate a series of Hurty-Craig-Bampton reductions, each with a higher frequency cutoff than the previous. The results were shown to converge once the frequency cutoff increased past eight times the frequency content of interest. At the same frequency cutoff, the results of the Hurty-Craig-Bampton model converged with the results of the unconstrained mode acceleration model. This comparative study provided confidence that the results of the unconstrained modal acceleration reduced model were correct and that the Hurty-Craig-Bampton needed to increase its frequency cutoff to fully capture the dynamic response.

Erin Simmons↗

Alternate Methods of Model Reduction to Avoid Dynamic Modal Truncation Error

Loads analysis is traditionally performed using dynamically reduced models, which provides the benefit to reduce run time. If the reduced model frequency cutoff is not chosen appropriately, the model will lack the dynamic content required to fully represent the response of the non-reduced model. Standard guidance for reduced model frequency content, provided in NASA-STD-5002, is to solve fixed base modes up to a minimum of 1.5x the model frequency content of interest and to employ static modal truncation methods such as residual vectors, the mode acceleration method, and the residual flexibility method to account for the truncated flexibility of the missing modes. Fixed base modes require the selection of a set of degrees of freedom to be constrained which, if not properly selected, may affect the accuracy of the reduced model by excluding some of the dynamic characteristic of the full model. In this case, the standard NASA guidance would be insufficient, but it may not be readily apparent that a portion of the reduced model response is missing. This error was encountered during an independent verification and validation (IV&V) effort, where it was observed that the resulting dynamic response was lower than the inline analysis. In this specific case, despite following the standard NASA model reduction guidelines in the selection of the frequency cutoff, the inline model still did not fully capture the necessary dynamic content. As part of the IV&V, an alternate reduction methodology was employed using an unconstrained mode acceleration method. The original model initially performed a constrained reduction to twice the frequency content of interest before doing a free-free run, employing the mode acceleration method to account for the truncated modes. In contrast in the IV&V, the unconstrained model reduced directly to the needed frequency content of the free-free run, avoiding any interactions between constraints and dynamic content. To verify the model, the original reduction methodology was used to generate a series of Hurty-Craig-Bampton reductions, each with a higher frequency cutoff than the previous. The results were shown to converge once the frequency cutoff increased past eight times the frequency content of interest. At the same frequency cutoff, the results of the Hurty-Craig-Bampton model converged with the results of the unconstrained mode acceleration model. This comparative study provided confidence that the results of the unconstrained modal acceleration reduced model were correct and that the Hurty-Craig-Bampton needed to increase its frequency cutoff to fully capture the dynamic response.

Erin Simmons↗

Medium-Voltage Isolated Auxiliary Power Supply Design for High Insulation Capability, Ultra-Low Coupling Capacitance, and Small Size

To fully utilize the benefits of medium-voltage (MV) silicon carbide (SiC)-based converter and achieve high power density, the isolated auxiliary power supply (IAPS) needs to be as small as possible. However, the high insulation and low coupling capacitance requirements, considering the high voltage and high dv / dt , are constraints of size reduction. This article proposes an MV IAPS design for high insulation capability, ultra-low coupling capacitance, and small size. The topology selection, efficiency, load regulation, coupling capacitance, and size reduction considerations are discussed. A 2.5 W MV IAPS is designed and built for a 10 kV SiC mosfet -based 13.8 kV/100 kW three-phase converter, achieving a partial discharge (PD) inception voltage of higher than 15 kV rms, ultra-low coupling capacitance of 1.03 pF, and smaller size than that of the commercial products as well as the state-of-art research prototypes. Experimental results of PD test, 10 kV SiC mosfet -based half-bridge test, and 13.8 kV/100 kVA three-phase converter full rating test are conducted for design validation.

42 ENGINEERING↗

The effect of Tricresyl-Phosphate (TCP) as an additive on wear of Iron (Fe)

The effect of tricresyl phosphate (TCP) as an antiwear additive in lubricant trimethyol propane triheptanoate (TMPTH) was investigated. The objective was to examine step loading wear by use of surface analysis, wetting, and chemical bonding changes in the lubricant. The investigation consisted of steploading wear studies by a pin or disk tribometer, the effects on wear related to wetting by contact angle and surface tension measurements of various liquid systems, the chemical bonding changes between lubricant and TCP chromatographic analysis, and by determining the reaction between the TCP and metal surfaces through wear scar analysis by Auger emission spectroscopy (AES). The steploading curve for the base fluid alone shows rapid increase of wear rate with load. The steploading curve for the base fluid in presence of 4.25 percent by volume TCP under dry air purge has shown a great reduction of wear rate with all loads studied. It has also been found that the addition of 4.25 percent by volume TCP plus 0.33 percent by volume water to the base lubricant under N2 purge also greatly reduces the wear rate with all loads studied. AES surface analysis reveals a phosphate type wear resistant film, which greatly increases load-bearing capacity, formed on the iron disk. Preliminary chromatographic studies suggest that this film forms either because of ester oxidation or TCP degradation. Wetting studies show direct correlation between the spreading coefficient and the wear rate.

Ghose, Hiren M.↗

Single Ru(II) Ions on Ceria as a Highly Active Catalyst for Abatement of NO

Atom trapping leads to catalysts with atomically dispersed Ru 1 O 5 sites on (100) facets of ceria, as identified by spectroscopy and DFT calculations. This is a new class of ceria-based materials with Ru properties drastically different from the known M/ceria materials. They show excellent activity in catalytic NO oxidation, a critical step that requires use of large loadings of expensive noble metals in diesel aftertreatment systems. Ru 1 /CeO 2 is stable during continuous cycling, ramping, and cooling as well as the presence of moisture. Furthermore, Ru 1 /CeO 2 shows very high NO x storage properties due to formation of stable Ru–NO complexes as well as a high spill-over rate of NO x onto CeO 2 . Only ~0.05 wt % of Ru is required for excellent NO x storage. Ru 1 O 5 sites exhibit much higher stability during calcination in air/steam up to 750 °C in contrast to RuO 2 nanoparticles. Here we clarify the location of Ru(II) ions on the ceria surface and experimentally identify the mechanism of NO storage and oxidation using DFT calculations and in situ DRIFTS/mass spectroscopy. Moreover, we show excellent reactivity of Ru 1 /CeO 2 for NO reduction by CO at low temperatures: only 0.1–0.5 wt % of Ru is sufficient to achieve high activity. Modulation-excitation in situ infrared and XPS measurements reveal the individual elementary steps of NO reduction by CO on an atomically dispersed Ru ceria catalyst, highlighting unique properties of Ru 1 /CeO 2 and its propensity to form oxygen vacancies/Ce +3 sites that are critical for NO reduction, even at low Ru loadings. Our study highlights the applicability of novel ceria-based single-atom catalysts to NO and CO abatement.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Multi-Model Framework for Assessing Long- and Short-Term Climate Influences on the Electric Grid

Climate change influences many aspects of the electric grid, but prior work and industry practices often ignore the potential effects of changing climate, or they only consider a single effect or individual effects in isolation. Challenges vary with each grid and include adapting to long-term trends such as changing temperature and precipitation or shorter-term events such as drought or storms that could increase in frequency or intensity. Here we present a multi-model framework designed to analyze the effects of long and short-term climate impacts in combination. This framework couples capacity expansion and production cost models with hydrologic models and future climate scenario data to analyze alternative climate and energy futures at high spatial, temporal, and process resolutions. Furthermore, we constructed and evaluated the results of a suite of simulated scenarios exploring climate impacts on capacity investment and stress-tested the resulting future infrastructures using hourly dispatch modeling under alternative drought and load conditions. We demonstrate the approach through a case study of the U.S. Western Interconnection, where climate impacts depend on interactions between temperature-induced load, water availability for hydropower, technology competitiveness, and demand flexibility. Changes in 2038 generating capacity range from -8.5-16.6 GW, and changes in 2038 transmission capacity range from -1-2 GW. Capacity increases are driven by higher load from higher temperatures, while capacity reductions can be achieved in scenarios with higher future hydropower availability and increased demand flexibility. Scenarios requiring additional capacity cost an additional $\$5$-$\$17$ billion (discounted) from 2018 to 2038; however, scenarios with capacity reductions cost $\$1$-$\$18$ billion less. Stress tests on four 2038 infrastructures demonstrated that the identified systems were able to serve at least 99.999% of load and 99.96% of reserves. However, drought and unexpected high-load conditions can result in reduced capacity to respond to contingency events we did not model. Although these results are system and scenario specific, they highlight the importance of considering multiple climate change impacts simultaneously in long-term planning efforts and demonstrate a multi-model, multiscale approach that can be flexibly applied to any system and set of climate change concerns.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Free-Space Optical Communication for CubeSats in Low Lunar Orbit (LLO)

A fine pointing capability has been developed for laser beam pointing to augment body pointing by CubeSats. An application is made to CubeSats in Low Lunar Orbit (LLO), at 100 km. Body pointing was used by Aerospace Corporation for CubeSats in LEO in NASA’s Optical Communications and Sensors Demonstration (OCSD) program. Computer simulations of this fine pointing capability have been applied to the OCSD program. With fine pointing, the spot size on the Earth could be reduced by a factor of eight with a reduction in laser output power by a factor of sixty-four, thereby mitigating the thermal load challenge on the CubeSats. The same reductions in spot size and laser output power can be achieved for CubeSats in LLO. The new method uses laser arrays for fine laser beam pointing and does not use moving parts. It combines a lens system and a VCSEL/Photodetector Array. For these electro-optical systems, reaction times to pointing changes and vibrations are on a nanosecond time scale, much faster than those for mechanical systems. Results from computer simulations will be presented.

Laser beam pointing↗