Broadband perfect absorber based on one ultrathin layer of refractory metal
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Established combined characterization techniques to study oxygen activities. Confirmed oxygen anion redox reversibly contributing to the overall capacity of Li-rich layered oxides. Identified the structure irreversible transformation and large amount of strain formation induced by oxygen vacancies formation. Applied GSIR modification method to precisely control oxygen activity in Li-rich layered oxides. Identified several possible contributing factors to irreversible capacity loss routinely seen on the first cycle of classical layered oxides: phase transformation in bulk classical diffusion limitations irreversible surface side reactions generation of dislocations or other extended defects loss of electrical connectivity among cathode particles
Electrically conductive adhesive layers were deposited on top of aerospace grade carbon fiber reinforced plastic (CFRP) panels using a small-scale 3D printer. Polylactic acid (PLA) filaments with copper filler (CU-PLA) and graphene filler (GO-PLA) were used to print around 0.7 mm thick electrically conductive layer on top of CFRP panels. 3D printed polymeric layers were tested for their effectiveness as a lightning strike protection (LSP) material by subjected to a simulated lightning strike. A painted, electrically non-conductive unprotected panel was also tested for comparison. In the case of the CU-PLA protected sample, a high electrical conductivity proved to be useful in fast dissipation of the lightning current. Fast current dissipation helped to reduce the resistive heating after a lightning strike. Thermography and high-speed camera analysis were employed to study the heat generation and current dissipation during the lightning strike. These results established that a useful Faraday Cage was applied via additive manufacturing successfully. This work shows the successful application of 3D printing for producing LSP technologies, with future work aimed at investigating optimal printable electrically conductive thermoset material candidates.
We report single crystals of four new layered uranyl phosphates, including three oxyfluoride-phosphates, were synthesized by molten flux methods using alkali chloride melts, and their structures were determined by single-crystal X-ray diffraction. Cs 11 [(UO 2 ) 12 (PO 4 ) 3 O 13 ] ( 1 ) and Rb 11 [UO 2 ) 12 (PO 4 ) 3 O 12 F 2 ] ( 2 ) contain uranyl phosphate layers exhibiting a new sheet topology that can be related to that of β-U 3 O 8 , while Cs 4.4 K 0.6 [(UO 2 ) 6 O 4 F(PO 4 ) 4 (UO 2 )] ( 3 ) and Rb 4.4 K 0.6 [(UO 2 ) 6 O 4 F(PO 4 ) 4 (UO 2 )] ( 4 ) contain layers of a known isomer of the prominent phosphuranylite topology. The location of the fluorine in structures 2 - 4 is discussed using bond valence sums. First principles calculations were used to explore why a pure oxide structure is obtained for the Cs containing phase ( 1 ) and in contrast an oxyfluoride phase for the Rb containing phase ( 2 ). Ion exchange experiments were performed on 1 and 2 and demonstrate the ability of these structures to exchange approximately half of the parent alkali cation with a target alkali cation in an aqueous concentrated salt solution. Optical measurements were performed on 1 and 2 and the UV-vis and fluorescence spectra show features characteristic of the UO 2 2 + uranyl group.
High-throughput roll-to-roll (R2R) manufacturing of perovskite solar cells (PSCs) is currently limited by thermal processes that take tens of minutes each, translating to impractically long annealing tools at high web speeds. In addition, PSCs are usually made with metal oxide transport layer materials that require high temperatures for thermal annealing. Here, we demonstrate the fabrication of PSCs using photonic curing, instead of thermal annealing, to convert NiO x directly from sol-gel precursors for hole transport layers and to crystallize methylammonium lead iodide (MAPbI 3 ) active layers on flexible Willow ® Glass substrates. Photonic curing uses short, intense pulses of light to process materials at a high speed, hence it is compatible with R2R manufacturing. We achieved power conversion efficiencies (PCEs) of 11.7% in forward-scan and 10.9% in reverse-scan for PSCs made with photonic cured NiO x and MAPbI 3 films. Furthermore, both NiO x and MAPbI 3 films could be processed with a single photonic curing pulse, with a web speed of 5.7 m/min, and still produce PCEs comparable to thermally annealed control samples. Based on the single-pulse photonic curing condition for each film, we project a web speed of 26 m/min, laying a pathway to high-throughput production of perovskite solar modules.
Modifications of the turbulent boundary layer (TBL) computer program refer to a more accurate representation of boundary layer edge conditions, internal calculation of the Prandtl number, a changed friction coefficient relationship, and computation of the performance degradation. Important input parameters of the modified TBL program such as wall temperature distribution, Prandtl number, Stanton number, and velocity profile exponent were changed and the individual effects on significant boundary layer parameters, heat transfer, and performance degradation are described.
An implicit finite-difference procedure is presented for solving the compressible three-dimensional boundary-layer equations. The method is second-order accurate, unconditionally stable (conditional stability for reverse cross flow), and efficient from the viewpoint of computer storage and processing time. The Reynolds stress terms are modeled by (1) a single-layer mixing length model and (2) a two-layer eddy viscosity model. These models, although simple in concept, accurately predicted the equilibrium turbulent flow for the conditions considered. Numerical results are compared with experimental wall and profile data for a cone at an angle of attack larger than the cone semiapex angle. These comparisons clearly indicate that the numerical procedure and turbulence models accurately predict the experimental data with as few as 21 nodal points in the plane normal to the wall boundary.
Predictions of mixing length by Pletcher's (1976) method (using a two-layer eddy viscosity model for a turbulent boundary layer at low Reynolds numbers) are compared to some values derived from turbulent boundary-layer profiles by other authors. The model is incorporated into a finite-difference scheme, to accurately predict low Reynolds number skin friction in supersonic flow.
The fundamentals of stability theory, its chief results, and the physical mechanisms at work are presented. The stability theory of the laminar boundary determines whether a small disturbance introduced into the boundary layer will amplify or damp. If the disturbance damps, the boundary layer remains laminar. If the disturbance amplifies, and by a sufficient amount, then transition to turbulence eventually takes place. The stability theory establishes those states of the boundary layer which are most likely to lead to transition, identifys those frequencies which are the most dangerous, and indicates how the external parameters can best be changed to avoid transition.
The boundary layer drag on a 0.28 m x 0.91 m flat-plate was measured to evaluate the performance of smooth-wall drag reducing outer-layer devices in rough-wall boundary layers up to a chord Reynolds number, Re(c) of 17,000. The devices were a pair of thin flat ribbons placed in tandem. The wall conditions examined were smooth, transverse-groove roughnesses having cavity width/depth ratios of 0.7 (d-type) and 3 (k-type), and sandpaper roughness (k-type) of grit sizes 180, 50 and 36. The area-averaged wall-drag was reduced compared to the respective normal levels for all wall conditions. All k-type rough walls exhibited a comparable level of drag reduction (about 7 percent) which was lower than that in the smooth-wall. The d-type rough-wall exhibited a transitional behavior in that the drag reduction dropped from the smooth-wall level to that of the k-type roughnesses with increase in the flow speed. In further experiments on a 6 meter long sandpaper roughened wall and with a pair of symmetric airfoil devices in tandem at an Re(c) of 77,500, it was possible to recover the device drag penalty fully, but no net drag reduction was achieved. The apparent loss of performance of the devices in a rough-wall is explained in terms of their inability to alter the pressure component of the drag in a significant way.
The passive control of compressible boundary layer growth by boundary layer trips has been studied experimentally. Axisymmetric trips and three dimensional trips were used in this study. The nomial freestream Mach numbers are 1.5 and 4. The results show that trips are effective in promoting boundary layer growth. Trips are more effective for Mach 1.5 flows than for Mach 4 flows.
A thin film heat transfer gauge is applied to the measurement of heat transfer coefficients in the interaction regions of incident shock waves and fully developed turbulent boundary layers. It was developed to measure heat flux with high spatial resolution and fast response for wind tunnels with long flow duration. To measure the heat transfer coefficients in the interaction region in detail, experiments were performed under the conditions of Mach number = 4, total pressure = 1.2 MPa, 0.59 to approximately 0.65. Reynolds number = 1.3 to approximately 1.5 x 10 to the 7th power and incident shock angles from 17.8 to 22.8 degrees. The results show that the heat transfer coefficient changes complicatedly in the interaction region. At the beginning the interaction region, the heat transfer coefficient decreases at first, reaches its minimum value at the point where the pressure begins to increase, and then increases sharply. When the boundary layer begins to separate, even a small separation bubble causes significant changes in the heat transfer coefficient, while the pressure does not show any changes which suggests that the boundary layer begins to separate.
Calculations of the flows over NACA 4412 and GA(W)-2 airfoils with low-speed flow and over NACA 0012 and RAE 2822 airfoils with transonic flow are reported. They were obtained by solving potential flow and boundary-layer equations, and by solving thin-layer Navier-Stokes equations. The results cover a range of angles of attack up to and including stall and allow the evaluation of the numerical and physical features of the two solution methods. The agreement with measurements is acceptable except between the results of the thin Navier-Stokes equations and measurements in subsonic flow at high angles of attack. The interactive boundary-layer method is considerably more efficient requiring considerably less computer time and storage.
The wall static pressure in the vicinity of drag reducing outer layer devices in flat wall turbulent boundary layers has been measured and compared with an inviscid theory. Symmetric and cambered airfoil devices have been examined at small angles of attack and very low chord Reynolds numbers. Airfoil devices impose a sequence of strong favorable and adverse pressure gradients on the boundary layer whose drag is to be reduced. At very small angles of attack (+ or - 2 deg), this pressure field extends up to about three chord lengths downstream of the trailing edge of an airfoil device. Also examined are the pressures on the upper and lower surfaces of a symmetric airfoil device in the freestream and near the wall. The freestream pressure distribution around an airfoil section is altered by the wall proximity. The relevance of lift enhancement caused by wall proximity to drag reduction has been discussed. The pressure distributions on the flat wall beneath the symmetric airfoil devices are predicted well by the inviscid theory. However, the remaining pressure distributions are predicted only qualitatively, presumably because of strong viscous effects.
A method is presented for evaluating the fluxes of sensible and latent heating at the land surface, using satellite-measured surface temperature changes in a composite surface layer-mixed layer representation of the planetary boundary layer. The basic prognostic model is tested by comparison with synoptic station information at sites where surface evaporation climatology is well known. The remote sensing version of the model, using satellite-measured surface temperature changes, is then used to quantify the sharp spatial gradient in surface heating/evaporation across the central United States. An error analysis indicates that perhaps five levels of evaporation are recognizable by these methods and that the chief cause of error is the interaction of errors in the measurement of surface temperature change with errors in the assigment of surface roughness character. Finally, two new potential methods for remote sensing of the land-surface energy balance are suggested which will relay on space-borne instrumentation planned for the 1990s.
The effects of the state of the initial boundary layers on the development of a two-stream, plane mixing layer, with a velocity ratio of 0.6 are experimentally investigated. Spanwise-average profiles are compared for the first time. The results indicate that both the near and far-field growth rates for the untripped case are significantly higher than the tripped case. The maximum Reynolds stresses and higher-order products for the two cases behave very differently in the near-field, but asymptote to approximately the same constant levels far downstream. The mean velocity and turbulence profiles in this region also collapse adequately for the two cases when plotted in similarity coordinates. The distance required to achieve self-similarity is distinctly shorter for the tripped case, in contrast to previous observations. The higher growth rate for the untripped case is attributed to the presence of streamwise vortices which result in additional entrainment by the mixing layer.
Guided waves in a cross-ply laminated plate are studied. Because of the complexity of the exact dispersion equation that governs the wave propagation in a multi-layered fiber-reinforced plate, a stiffness method that can be applied to any number of layers is presented. It is shown that, for a sufficiently large number of layers, the plate can be modeled as a homogeneous anisotropic plate. Also studied is the reflection of guided waves from the edge of a multilayered plate. These results are quite different than in the case of a single homogeneous plate.