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At least 433 records · Page 24

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NASA NTRS1987

Roles of initial condition and vortex pairing in jet noise

Sound generation by vortex pairing in circular and elliptic cold-air jets at Mach 0.15-0.35 is investigated experimentally, with a focus on the effects of initial conditions. The results are presented in graphs and interpreted using the theory of vortex sound proposed by Moehring (1978) and vortex-filament models of jet coherent structure. Tripping the nozzle boundary layer is shown to (1) preempt formation of shear-layer vortices, (2) remove the sound they produce in later pairing, and (3) increase the diffusion of coherent vorticity in the vortex rings. Hence pairing noise should not be significant in practical jets, which are initially turbulent.

Bridges, J. E.↗

NASA NTRS1991

Surface effects on hydrogen permeation through Ti-14Al-21Nb alloy

Hydrogen transport through Ti-14Al-21Nb (wt percent) alloy is measured using ultrahigh vacuum permeation techniques over the temperature range of 500 to 900 C and hydrogen pressure range of 0.25 to 10 torr. Hydrogen permeability through the alloy can be described through two different mechanisms depending on th temperature of exposure. In the 675 to 900 C range, the process is diffusion-limited: the permeability has a weak temperature dependence, but the diffusivity has a strong temperature dependence. Below 675 C, the permeation rate of hydrogen is very sensitive to surface controlled processes such as the formation of a barrier layer from contaminants. A physical model explaining the role of surface films on the transport of hydrogen through Ti-14Al-21Nb alloy was described.

Sankaran, Sandara N.↗

NASA NTRS2010

L Band Brightness Temperature from Forest: Comparison of Approximate Techniques

In this paper, three approximate physical microwave radiometry models have been used to calculate brightness temperatures from a forest canopy at L-band. These models are (1) tau-omega model (zero order scattering approximation to radiative transfer equations), (2) successive order of scattering model up to first order (first order scattering approximation to the radiative transfer equations), and (3) Peak technique utilizing the active solution obtained from the Distorted Born Approximation (DBA). These models are physically-based and treat vegetation as a layer of discrete scatterers over a rough surface. Vegetation components within the canopy are represented by canonical shapes such as dielectric discs and cylinders. The tau-omega model is based on a zero-order solution to the radiative transfer (RT) equations. The model ignores scattering except for the effect of the scatterers in the attenuation of the emission through the vegetation. Application of the tau-omega model to data acquired during airborne and ground-based campaigns over the years has solidified scientific understanding of microwave interactions with different landscapes. In particular, shrubland, grasslands, agricultural crops, and light to moderate vegetation have been investigated. Its applicability to areas with a significant tree fraction is unknown. The first order scattering model is based on an iterative solution of the RT equation up to the first order. The first order solution is obtained by substituting the zeroth-order solution into the scattering source term and then solving the resulting radiative transfer equations. This formulation adds a new scattering term to the tau-omega model. It represents emission by particles in the layer and emission by the ground that is scattered once by particles in the layer. The resulting model represents an improvement over the standard zero-order solution (the tau-omega model) since it accounts for the scattered vegetation and ground radiation that can have a pronounced effect on the observed brightness temperature. The third model is based on the Peake formulation in conjunction with the DBA. The procedure for calculation of forest emission is accomplished by first calculating the bistatic scattering cross section for each type of scatterer, then by using the DBA to calculate specular albedo of the ground and the diffused albedo of the layer. Once the albedos are determined, Peake s principle relating active and passive problems can be used to determine the effective emissivity of the forest layer.

Kurum, Mehmet↗

NASA NTRS2018

Reynolds-Stress Budgets in an Impinging Shock Wave/Boundary-Layer Interaction

Implicit large-eddy simulation (ILES) of a shock wave/boundary-layer interaction (SBLI) was performed. Comparisons with experimental data showed a sensitivity of the current prediction to the modeling of the sidewalls. This was found to be common among various computational studies in the literature where periodic boundary conditions were used in the spanwise direction, as was the case in the present work. Thus, although the experiment was quasi-two-dimensional, the present simulation was determined to be two-dimensional. Quantities present in the exact equation of the Reynolds-stress transport, i.e., production, molecular diffusion, turbulent transport, pressure diffusion, pressure strain, dissipation, and turbulent mass flux were calculated. Reynolds-stress budgets were compared with past large-eddy simulation and direct numerical simulation datasets in the undisturbed portion of the turbulent boundary layer to validate the current approach. The budgets in SBLI showed the growth in the production term for the primary normal stress and energy transfer mechanism was led by the pressure strain term in the secondary normal stresses. The pressure diffusion term, commonly assumed as negligible by turbulence model developers, was shown to be small but non-zero in the normal stress budgets, however it played a key role in the primary shear stress budget.

shock wave/boundary-layer interactio↗

DOE OSTI2021

Variable Laser Ignition Pathways in Al/Pt Reactive Multilayers across 10 Decades of Pulse Duration

Pulsed laser irradiation is used to investigate the local initiation of rapid, self-propagating formation reactions in Al/Pt multilayers. The single pulse direct laser ignition of these 1.6 μm thick freestanding foils was characterized over 10 decades of pulse duration (10 ms to 150 fs). Finite element, reactive heat transport modeling of the near-threshold conditions has identified three distinct ignition pathways. For milli- to microsecond pulses, ignition occurs following sufficient absorption of laser energy to enable diffusion of Al and Pt between layers such that the heat released from the corresponding exothermic reaction overcomes conductive losses outside the laser-irradiated zone. When pulse duration is decreased into the nanosecond regime, heat is concentrated near the surface such that the Al locally melts, and a portion of the top-most bilayers react initially. The favorable kinetics and additional heat enable ignition. Further reducing pulse duration to hundreds of femtoseconds leads to a third ignition pathway. In this work, while much of the energy from these pulses is lost to ablation, the remaining heat beneath the crater can be sufficiently concentrated to drive a transverse self-propagating reaction, wherein the heat released from mixing at each interface occurs under kinetic conditions capable of igniting the subsequent layer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1986

Comparison of analytical and experimental performance of a wind-tunnel diffuser section

Wind tunnel diffuser performance is evaluated by comparing experimental data with analytical results predicted by an one-dimensional integration procedure with skin friction coefficient, a two-dimensional interactive boundary layer procedure for analyzing conical diffusers, and a two-dimensional, integral, compressible laminar and turbulent boundary layer code. Pressure, temperature, and velocity data for a 3.25 deg equivalent cone half-angle diffuser (37.3 in., 94.742 cm outlet diameter) was obtained from the one-tenth scale Altitude Wind Tunnel modeling program at the NASA Lewis Research Center. The comparison is performed at Mach numbers of 0.162 (Re = 3.097x19(6)), 0.326 (Re = 6.2737x19(6)), and 0.363 (Re = 7.0129x10(6)). The Reynolds numbers are all based on an inlet diffuser diameter of 32.4 in., 82.296 cm, and reasonable quantitative agreement was obtained between the experimental data and computational codes.

Shyne, R. J.↗

NASA NTRS1991

Hydrogen reduction mechanisms of ilmenite between 823 and 1353 K

In situ gravimetric measurements and microscopic examinations were used to determine the mechanisms of oxygen removal from synthetic ilmenite disks between 823 and 1353 K. Under a hydrogen atmosphere, iron was observed to form a layer of low porosity on the surface of samples early in the reduction. This created diffusion limitations for hydrogen to the reaction front and for the escape of water vapor. A shrinking core reduction model, modified to include the growth of this iron film, was capable of predicting the conversion-time relationships of ilmenite samples. An activation energy of 43.2 +/- 2.6 kcal/gmole was determined to be representative of reaction control over the temperature range 823-1023 K.

Briggs, R. A.↗

NASA NTRS2001

Long-Term Reliability of SiGe/Si HBTs From Accelerated Lifetime Testing

Accelerated lifetime tests were performed on double-mesa structure Si(0.7)Ge(0.3)/Si npn heterojunction bipolar transistors, grown by molecular beam epitaxy, in the temperature range of 175 C-275 C. The transistors (with 5x20 sq micron emitter area) have DC current gains approx. 40-50 and f(sub T) and f(sub max) of up to 22 GHz and 25 GHz, respectively. It is found that a gradual degradation in these devices is caused by the recombination enhanced impurity diffusion (REID) of boron atoms from the p-type base region and the associated formation of parasitic energy barriers to electron transport from the emitter to collector layers. This REED has been quantitatively modeled and explained, to the first order of approximation, and the agreement with the measured data is good. The mean time to failure (MTTF) of these devices at room temperature under 1.35 x 10(exp 4) A/sq cm current density operation is estimated from the extrapolation of the Arrhenius plots of device lifetime versus reciprocal temperature. The results of the reliability tests offer valuable feedback for SiGe heterostructure design in order to improve the long-term reliability of the devices and circuits made with them. Hot electron induced degradation of the base-emitter junction was also observed during the accelerated lifetime testing. In order to improve the HBT reliability endangered by the hot electrons, deuterium sintered techniques have been proposed. The preliminary results from this study show that a deuterium-sintered HBT is, indeed, more resistant to hot-electron induced base-emitter junction degradation.

Bhattacharya, Pallab↗

NASA NTRS2003

Long-Term Reliability of High Speed SiGe/Si Heterojunction Bipolar Transistors

Accelerated lifetime tests were performed on double-mesa structure Si/Si0.7Ge0.3/Si npn heterojunction bipolar transistors, grown by molecular beam epitaxy, in the temperature range of 175C-275C. Both single- and multiple finger transistors were tested. The single-finger transistors (with 5x20 micron sq m emitter area) have DC current gains approximately 40-50 and f(sub T) and f(sub MAX) of up to 22 GHz and 25 GHz, respectively. The multiple finger transistors (1.4 micron finger width, 9 emitter fingers with total emitter area of 403 micron sq m) have similar DC current gain but f(sub T) of 50 GHz. It is found that a gradual degradation in these devices is caused by the recombination enhanced impurity diffusion (REID) of boron atoms from the p-type base region and the associated formation of parasitic energy barriers to electron transport from the emitter to collector layers. This REID has been quantitatively modeled and explained, to the first order of approximation, and the agreement with the measured data is good. The mean time to failure (MTTF) of the devices at room temperature is estimated from the extrapolation of the Arrhenius plots of device lifetime versus reciprocal temperature. The results of the reliability tests offer valuable feedback for SiGe heterostructure design in order to improve the long-term reliability of the devices and circuits made with them. Hot electron induced degradation of the base-emitter junction was also observed during the accelerated lifetime testing. In order to improve the HBT reliability endangered by the hot electrons, deuterium sintered techniques have been proposed. The preliminary results from this study show that a deuterium-sintered HBT is, indeed, more resistant to hot-electron induced base-emitter junction degradation. SiGe/Si based amplifier circuits were also subjected to lifetime testing and we extrapolate MTTF is approximately 1.1_10(exp 6) hours at 125iC junction temperature from the circuit lifetime data.

Ponchak, George E.↗

DOE OSTI2021

Toward predictive permeabilities: Experimental measurements and multiscale simulation of methanol transport in Nafion

A polymer membrane's permeability to solutes determines its suitability for various applications: a permeability value is essential for predicting performance in diverse contexts. Using aqueous methanol permeation through Nafion as an example, we describe a methodology for determining membrane permeability that accounts for boundary layer effects and the possibility of swelling. For the materials and apparatus used herein, analysis of a permeance measurement and computational fluid dynamics simulations show that the mass transfer boundary layer is on the order of ones to tens of microns. Additionally, the data are used to develop and validate a multiscale model describing solute permeation through a hydrated membrane as a series of physical mechanistic steps: reversible adsorption from solution at the membrane interface, diffusion driven by a concentration gradient within the membrane, and reversible desorption into solution at the opposite membrane interface. The validated model is used to predict methanol transport across a solar-driven CO 2 reduction device and to assess the impact of polymer changes on the measured value. The approach of combining experimental data, computational fluid dynamics, and the mechanistic multiscale model is expected to provide more accurate analysis of membrane permeation data in cases with polymer swelling or unusual device geometries, among others.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1986

A detailed numerical model of a supersonic reacting mixing layer

A current research effort is underway at the NASA Langley Research Center to achieve a detailed understanding of important phenomena present when a supersonic flow undergoes chemical reaction. A computer program has been developed to study the details of such flows. The program has been constructed to consider the multicomponent diffusion and convection of important species, the finite-rate reaction of these species, and the resulting interaction between the fluid mechanics and chemistry. Code results from the analysis of a spatially developing and reacting mixing layer are presented, and conclusions are drawn regarding the structure of the evolving layer and its associated flame.

Drummond, J. P.↗

NASA NTRS1987

A numerical model for supersonic reacting mixing layers

A current research effort is underway at the NASA Langley Research Center to achieve a detailed understanding of important phenomena present when a supersonic flow undergoes a chemical reaction. A computer program has been developed to study the details of such flows. The program has been constructed to consider the multicomponent diffusion and convection of important species, the finite-rate reaction of these species, and the resulting interaction between the fluid mechanics and chemistry. Code results from the analysis of a spatially developing and reacting mixing layer are presented, and conclusions are drawn regarding the structure of the evolving layer and its associated flame.

Drummond, J. Philip↗

NASA NTRSDate not supplied

Sampling the ENSO response to tropical volcanic eruptions in the GISS-E2-1 model: physical & biogeochemical ocean effects

Despite observational evidence that an El-Niño is likely to follow tropical volcanic eruptions (Predybaylo et al, 2017), modelling studies have so far reached no consensus on either the sign or physical mechanism of El Niño response to volcanism (Khodri et al, 2017) . A previous modelling study found that following the Pinatubo eruption, the tropical Pacific developed El Niño-like conditions that triggered a decrease in the upwelling of DIC and increased carbon uptake (Eddebbar et al., 2019). However, the carbon cycle response to volcanisms as it depends on ENSO phase remains unclear. Here we perform thirty ensemble control simulations using the GISS-E2-1-G model to sample the pre-industrial control ENSO cycle and thirty more to superimpose a Pinatubo-like volcanic eruption. We find that the model tends to favor the development of a weak El-Niño following the volcanic eruption only in the case of a volcano that erupts at the start of a neutral ENSO phase. In response to the weak El-Niño, some anomalies have the same sign as those that develop from a strong El-Niño, such as weaker winds, shallower mixed layer depths, less direct but more diffuse radiation at the surface of the ocean, less nitrate, and lower primary productivity. However, other anomalies show the opposite sign as those from a strong El-Niño, such as more precipitation, less surface DIC, and less surface ocean pCO 2 . In contrast to the neutral phase, the volcanic response during positive ENSO and negative ENSO phases are swamped by the model’s internal variability.

ENSO↗

DOE OSTI2020

The Role of Interfacial Thermal Resistance in Li-Ion Battery Thermal Management: Preprint

Temperature critically affects the performance, life and safety of lithium-ion batteries. Therefore, it is essential to understand heat generation and dissipation within individual battery cells and battery packs to plan a proper thermal management strategy. One of the key challenges is that interfacial heat transfer of a battery unit is difficult to quantify. The steady-state absolute method and the transient laser-flash-diffusivity method were employed to measure heat conductivities of battery layer stacks and individual battery layer separately. Results show flash diffusivity method gives higher thermal conductivity at both cross-plane and in-plane directions. The difference is primarily caused by interfacial thermal resistance so that it can be estimated by steady-state and transient measurements. To investigate the effects of interfacial thermal transport beyond individual cell level, a multiphysics battery model is used. The model is built upon a multi-scale multi-domain modeling framework for battery packs that accounts for the interplay across multiple physical phenomena. Benefits of a battery module using thermal management materials are quantified through numerical experiments. During a thermal runaway event, it is found interfacial thermal resistance can mitigate thermal runaway in a battery module by significantly reducing heat transfer between cells.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2025

Polyethylene Upcycling to Diacids Using Acid-Only Activation

There is a pressing need to develop plastic recycling technologies. Chemical upcycling converts low-value waste plastics into higher-value products. Here, polyethylene (PE) upcycling is accomplished by using acid-only activation of PE (PEAA), thus eliminating costly and toxic organic solvents. Acid mixtures of chlorosulfuric acid (CSA) and sulfuric acid (SA) were used to effectively sulfonate PE, allowing for subsequent facile depolymerization. Molecular deconstruction of sulfonated PE using H 2 O 2 in the presence of an Fe(III) catalyst achieved molar yields of C 2 –C 4 diacids exceeding 40% (based on estimates of acids generated from sulfonates). The sulfonation step using PEAA is hypothesized to follow a shrinking core mechanism (SCM), in which PE particles quickly reach a saturated state in the outer sulfonated layer as CSA diffuses radially inward. This proposed mechanism is supported by the fact that, regardless of the extent of sulfonation, similar molar yields of products and ratios of liberated carbon to sulfur are observed. Modeling and experimentation show that deviations from the SCM occur by lowering the Damköhler number (Da) or increasing CSA solubility in PE. In both cases, CSA diffusion is enhanced, which favors kinetically limited sulfonation.

36 MATERIALS SCIENCE↗

NASA NTRS1975

Investigation B: Laminar confined coaxial entrance flow with heat generation

The results of a parametric study on the entrance flow region in a gas core nuclear reactor are presented. The physical system is modeled as laminar confined, coaxial flow with heat generation in the inner fluid. The governing equations include the boundary layer approximations and the assumptions of only radial radiative transport of energy represented as an energy diffusion term. The Von Mises transformation and a zeta transformation are used to transform the equations into nonlinear nonhomogeneous convective-diffusion equations. A unique combination of forward and backward difference equations which yields accurate results at moderate computational times, is used in the numerical method. Results show that the rapidly accelerating, heat generating inner stream actually shrinks in radius as it expands axially.

Bobba, G. K. M.↗

NASA NTRS1981

Numerical simulation of reentry flow around the Shuttle Orbiter including real gas effects

The flight environment of a reentry vehicle is predicted from the numerical solution of fluid dynamics equations for the region between the blunt nose and the swept wings. The inviscid portion of the shock layer is modeled by the Euler equations, but the laminar viscous flow adjacent to the wall is modeled by the approximate parabolic Navier-Stokes equations. The approximations made to the axial gradients of pressure and diffusive fluxes enable the coupled inviscid and viscous equations to be solved efficiently along the body axis. The equilibrium air aftbody code contains significant improvements over its predecessor which only considers a perfect gas model and noncircular configurations. The inclusion of numerical damping either explicitly or implicitly has extended its capabilities for predicting flow field around a winged configuration at higher Machs and greater angles of attack. The results are obtained on the cylindrical coordinates and satisfactory for the Shuttle Orbiter at a free-stream Mach number of 22 and an angle of attack of 40 deg. Also discussed are the inviscid formulation and its application for wind-tunnel conditions.

Li, C. P.↗

NASA NTRS1998

Shallow Remineralization in the Sargasso Sea Estimated from Seasonal Variations in Oxygen and Dissolved Inorganic Carbon

A diagnostic model of the mean annual cycles of dissolved inorganic carbon (DIC) and oxygen below the mixed layer at the Bermuda Atlantic Time-series Study (BATS) site is presented and used to estimate organic carbon remineralization in the seasonal thermocline. The model includes lateral and vertical advection as well as vertical, diffusion. Very good agreement is found for the remineralization estimates based on oxygen and DIC. Net remineralization averaged from mid-spring to early fall is found to be a maximum between 120 and 140 in. Remineralization integrated between 100 (the compensation depth) and 250 m during this period is estimated to be about 1 mol C/sq m. This flux is consistent with independent estimates of the loss of particulate and dissolved organic carbon.

Ono, S.↗